JP2007525477A - 炭化水素の合成 - Google Patents
炭化水素の合成 Download PDFInfo
- Publication number
- JP2007525477A JP2007525477A JP2006520386A JP2006520386A JP2007525477A JP 2007525477 A JP2007525477 A JP 2007525477A JP 2006520386 A JP2006520386 A JP 2006520386A JP 2006520386 A JP2006520386 A JP 2006520386A JP 2007525477 A JP2007525477 A JP 2007525477A
- Authority
- JP
- Japan
- Prior art keywords
- hydrocarbon
- reactant
- oxygen
- metal
- carbon number
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 78
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 76
- 230000015572 biosynthetic process Effects 0.000 title claims description 16
- 238000003786 synthesis reaction Methods 0.000 title claims description 7
- 239000000376 reactant Substances 0.000 claims abstract description 49
- 238000000034 method Methods 0.000 claims abstract description 47
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 31
- 239000001301 oxygen Substances 0.000 claims abstract description 30
- 230000003197 catalytic effect Effects 0.000 claims abstract description 25
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 25
- 150000002367 halogens Chemical class 0.000 claims abstract description 25
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910000039 hydrogen halide Inorganic materials 0.000 claims abstract description 10
- 239000012433 hydrogen halide Substances 0.000 claims abstract description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 59
- 239000004215 Carbon black (E152) Substances 0.000 claims description 44
- 239000010457 zeolite Substances 0.000 claims description 27
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 25
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 25
- 229910052799 carbon Inorganic materials 0.000 claims description 25
- 230000008569 process Effects 0.000 claims description 24
- 229910044991 metal oxide Inorganic materials 0.000 claims description 20
- 150000004706 metal oxides Chemical class 0.000 claims description 20
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 13
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 13
- 230000002140 halogenating effect Effects 0.000 claims description 13
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 12
- 229910021536 Zeolite Inorganic materials 0.000 claims description 12
- 229910052794 bromium Inorganic materials 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 150000008282 halocarbons Chemical class 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 150000001350 alkyl halides Chemical class 0.000 claims description 7
- 230000001172 regenerating effect Effects 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 6
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical class Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 claims description 4
- 150000001347 alkyl bromides Chemical class 0.000 claims description 4
- 150000004820 halides Chemical class 0.000 claims description 3
- 229910003455 mixed metal oxide Inorganic materials 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 150000001649 bromium compounds Chemical class 0.000 claims 1
- 230000026030 halogenation Effects 0.000 abstract description 20
- 238000005658 halogenation reaction Methods 0.000 abstract description 20
- 238000006384 oligomerization reaction Methods 0.000 abstract description 14
- 230000008878 coupling Effects 0.000 abstract description 13
- 238000010168 coupling process Methods 0.000 abstract description 13
- 238000005859 coupling reaction Methods 0.000 abstract description 13
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 abstract description 8
- 239000011203 carbon fibre reinforced carbon Substances 0.000 abstract description 8
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 230000002194 synthesizing effect Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 description 36
- 238000006243 chemical reaction Methods 0.000 description 15
- -1 rare earth chloride Chemical class 0.000 description 15
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 150000001336 alkenes Chemical class 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 238000009826 distribution Methods 0.000 description 10
- 239000003054 catalyst Substances 0.000 description 9
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 238000006386 neutralization reaction Methods 0.000 description 8
- 239000003502 gasoline Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 230000008929 regeneration Effects 0.000 description 7
- 238000011069 regeneration method Methods 0.000 description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- 239000005977 Ethylene Substances 0.000 description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 6
- 230000008859 change Effects 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 239000000446 fuel Substances 0.000 description 5
- 239000003345 natural gas Substances 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 150000002170 ethers Chemical class 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 4
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910001509 metal bromide Inorganic materials 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 239000008096 xylene Substances 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000001345 alkine derivatives Chemical class 0.000 description 3
- 150000004996 alkyl benzenes Chemical class 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 230000031709 bromination Effects 0.000 description 3
- 238000005893 bromination reaction Methods 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 229910052734 helium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000001588 bifunctional effect Effects 0.000 description 2
- DIKBFYAXUHHXCS-UHFFFAOYSA-N bromoform Chemical compound BrC(Br)Br DIKBFYAXUHHXCS-UHFFFAOYSA-N 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 239000002019 doping agent Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 150000004795 grignard reagents Chemical class 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 2
- 229910001507 metal halide Inorganic materials 0.000 description 2
- 150000005309 metal halides Chemical class 0.000 description 2
- 229910052680 mordenite Inorganic materials 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000004763 sulfides Chemical class 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 239000007818 Grignard reagent Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000001118 alkylidene group Chemical group 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229950005228 bromoform Drugs 0.000 description 1
- GZUXJHMPEANEGY-UHFFFAOYSA-N bromomethane Chemical compound BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- FJBFPHVGVWTDIP-UHFFFAOYSA-N dibromomethane Chemical compound BrCBr FJBFPHVGVWTDIP-UHFFFAOYSA-N 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000001404 mediated effect Effects 0.000 description 1
- AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 1
- 125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910001960 metal nitrate Inorganic materials 0.000 description 1
- 238000005649 metathesis reaction Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 229940078552 o-xylene Drugs 0.000 description 1
- 230000003606 oligomerizing effect Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011027 product recovery Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000006578 reductive coupling reaction Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 229910021558 transition metal bromide Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/10—Magnesium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/929—Special chemical considerations
- Y10S585/93—Process including synthesis of nonhydrocarbon intermediate
- Y10S585/935—Halogen-containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/929—Special chemical considerations
- Y10S585/943—Synthesis from methane or inorganic carbon source, e.g. coal
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US48736403P | 2003-07-15 | 2003-07-15 | |
| PCT/US2004/023036 WO2005021468A1 (en) | 2003-07-15 | 2004-07-15 | Hydrocarbon synthesis |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011284062A Division JP2012092134A (ja) | 2003-07-15 | 2011-12-26 | 炭化水素の合成 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2007525477A true JP2007525477A (ja) | 2007-09-06 |
| JP2007525477A5 JP2007525477A5 (enExample) | 2012-02-23 |
Family
ID=34272464
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006520386A Pending JP2007525477A (ja) | 2003-07-15 | 2004-07-15 | 炭化水素の合成 |
| JP2011284062A Pending JP2012092134A (ja) | 2003-07-15 | 2011-12-26 | 炭化水素の合成 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011284062A Pending JP2012092134A (ja) | 2003-07-15 | 2011-12-26 | 炭化水素の合成 |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US20050038310A1 (enExample) |
| EP (1) | EP1682465A1 (enExample) |
| JP (2) | JP2007525477A (enExample) |
| AU (1) | AU2004268935B2 (enExample) |
| CA (1) | CA2532367C (enExample) |
| MX (1) | MXPA06000470A (enExample) |
| NO (1) | NO20060166L (enExample) |
| RU (1) | RU2366642C2 (enExample) |
| WO (1) | WO2005021468A1 (enExample) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009512754A (ja) * | 2005-10-19 | 2009-03-26 | マラソン オイル カンパニー | ガス状アルカンをプロセスオレフィン及び液体炭化水素に転換するプロセス |
| JP2009525395A (ja) * | 2006-02-03 | 2009-07-09 | ジーアールティー，インコーポレイティド | 天然ガスを液化炭化水素に転化する連続的な方法 |
| JP2011524873A (ja) * | 2008-06-13 | 2011-09-08 | マラソン ジーティーエフ テクノロジー， リミテッド | 臭素の回収のために電気分解を用いる気状アルカンから液体炭化水素への臭素ベースの変換方法およびシステム |
| JP2011202183A (ja) * | 2004-04-16 | 2011-10-13 | Marathon Gtf Technology Ltd | ガス状アルカンを液状炭化水素に変換する方法 |
| JP2011528664A (ja) * | 2008-07-18 | 2011-11-24 | ジーアールティー，インコーポレイティド | 天然ガスを液化炭化水素に添加する連続的な方法 |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7838708B2 (en) | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
| US20050171393A1 (en) * | 2003-07-15 | 2005-08-04 | Lorkovic Ivan M. | Hydrocarbon synthesis |
| AU2004268935B2 (en) | 2003-07-15 | 2010-12-02 | Grt, Inc. | Hydrocarbon synthesis |
| US8642822B2 (en) | 2004-04-16 | 2014-02-04 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor |
| BRPI0509808B1 (pt) * | 2004-04-16 | 2015-04-07 | Marathon Gtf Technology Ltd | Processo para converter alcanos gasosos em hidrocarbonetos líquidos |
| US20080275284A1 (en) * | 2004-04-16 | 2008-11-06 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
| US8173851B2 (en) * | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
| US7674941B2 (en) | 2004-04-16 | 2010-03-09 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
| US20060229228A1 (en) * | 2005-04-11 | 2006-10-12 | Zachary John Anthony Komon | Method of making alkoxylates |
| WO2007092410A2 (en) | 2006-02-03 | 2007-08-16 | Grt, Inc. | Separation of light gases from halogens |
| EP1837320A1 (en) * | 2006-03-23 | 2007-09-26 | ETH Zürich | Production of saturated C2 to C5 hydrocarbons |
| EA201200888A1 (ru) * | 2007-05-14 | 2013-02-28 | Грт, Инк. | Способ конверсии углеводородного сырья с электролитическим извлечением галогенов |
| EA017699B1 (ru) * | 2007-05-24 | 2013-02-28 | Грт, Инк. | Зонный реактор с обратимым захватыванием и высвобождением галогеноводородов |
| CA2730934C (en) | 2008-07-18 | 2017-07-04 | Grt, Inc. | Continuous process for converting natural gas to liquid hydrocarbons |
| US8536393B2 (en) | 2009-05-13 | 2013-09-17 | Shell Oil Company | Integrated process to produce C4+ hydrocarbons with removal of brominated organic impurities |
| US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
| US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
| US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
| US8436220B2 (en) | 2011-06-10 | 2013-05-07 | Marathon Gtf Technology, Ltd. | Processes and systems for demethanization of brominated hydrocarbons |
| US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
| US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
| US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
| WO2014210016A1 (en) * | 2013-06-24 | 2014-12-31 | Reaction 35, Llc | Coupling of light alkanes to liquid fuels |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60225647A (ja) * | 1984-03-29 | 1985-11-09 | モ−ビル オイル コ−ポレ−ション | アルカン類のオキシハロゲン化及び縮合用触媒 |
| US20020198416A1 (en) * | 2001-06-20 | 2002-12-26 | Zhou Xiao Ping | Integrated process for synthesizing alcohols, ethers, and olefins from alkanes |
| JP2004529189A (ja) * | 2001-05-21 | 2004-09-24 | ダウ グローバル テクノロジーズ インコーポレイティド | ハロゲン化ｃ１炭化水素を生成させるｃ１炭化水素の酸化的ハロゲン化およびこれに関連する統合されたプロセス |
Family Cites Families (642)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3172915A (en) * | 1965-03-09 | Preparation of oxygenated methane derivatives | ||
| GB156122A (en) | 1919-12-08 | 1922-03-30 | Otto Traun S Forschungslaborat | Process for the manufacture of diolefines and derivatives thereof |
| GB294100A (en) | 1927-07-16 | 1929-06-27 | Curt Epner | Improvements in and relating to the production of liquid polymerisation products from gases containing hydrocarbons |
| GB363009A (en) | 1930-09-19 | 1931-12-17 | John Philip Baxter | Production of acetylene and vinyl chloride from ethylene dichloride |
| FR745544A (enExample) | 1931-11-11 | 1933-05-12 | ||
| DE698778C (de) | 1934-11-11 | 1941-07-10 | I G Farbenindustrie Akt Ges | Verfahren zur Herstellung von organischen Monochlor- oder Monobromverbindungen |
| GB474922A (en) | 1936-05-14 | 1937-11-15 | Ig Farbenindustrie Ag | Process for chlorinating and brominating hydrocarbons |
| US2246082A (en) | 1939-08-22 | 1941-06-17 | Shell Dev | Preparation of alkyl halides |
| GB536491A (en) | 1939-09-28 | 1941-05-16 | Bataafsche Petroleum | A process for the production of aromatic hydrocarbons from unsaturated hydrocarbons |
| GB553950A (en) | 1941-09-09 | 1943-06-11 | Du Pont | Improvements in or relating to the manufacture of halogenated hydrocarbons |
| GB586483A (en) | 1944-07-05 | 1947-03-20 | Standard Oil Dev Co | Process for the conversion of normally gaseous olefins to liquid hydrocarbons |
| US2488083A (en) | 1946-06-18 | 1949-11-15 | Socony Vacuum Oil Co Inc | Manufacture of liquid hydrocarbons |
| US2677598A (en) | 1953-01-19 | 1954-05-04 | Dow Chemical Co | Oxidation of ferrous halides to form ferric halides |
| GB775590A (en) | 1953-11-27 | 1957-05-29 | Standard Oil Co | Improvements in or relating to production of ethyl toluenes |
| US2941014A (en) | 1954-08-06 | 1960-06-14 | Hoechst Ag | Manufacture of alkyl chlorination products |
| GB793214A (en) | 1955-02-18 | 1958-04-09 | Bataafsche Petroleum | Process for the conversion of hydrocarbons containing acyclic carbon atoms |
| GB796085A (en) | 1955-12-22 | 1958-06-04 | Bataafsche Petroleum | Hydrocarbon conversion process |
| GB796048A (en) | 1956-02-06 | 1958-06-04 | Bataafsche Petroleum | Conversion of hydrocarbons |
| DE1037137B (de) * | 1957-01-25 | 1958-08-21 | Bayer Ag | Verfahren zur Herstellung halogenhaltiger, aromatisch-aliphatischer Polyaether |
| GB883256A (en) | 1958-05-02 | 1961-11-29 | Columbia Southern Chem Corp | Halogenation process |
| US3562321A (en) * | 1961-10-10 | 1971-02-09 | Sun Oil Co | Preparation of oxygenated hydrocarbons |
| BE623466A (enExample) | 1961-10-13 | |||
| GB950976A (en) | 1961-10-13 | 1964-03-04 | British Hydrocarbon Chem Ltd | Improvements in and relating to the production of olefines |
| GB991303A (en) | 1962-07-26 | 1965-05-05 | British Hydrocarbon Chem Ltd | The production of olefines by the dehydrochlorination of alkyl chlorides |
| US3294846A (en) | 1962-10-10 | 1966-12-27 | Dow Chemical Co | Process for preparing metaaryloxy phenols |
| US3246043A (en) | 1962-12-12 | 1966-04-12 | Universal Oil Prod Co | Preparation of olefinic hydrocarbons |
| GB1015033A (en) | 1963-01-31 | 1965-12-31 | Shell Int Research | Preparation of olefin oxides |
| US4011278A (en) | 1963-02-27 | 1977-03-08 | Mobil Oil Corporation | Conversion of polar compounds using a zsm-5 zeolite catalyst |
| NL125428C (enExample) | 1963-02-27 | |||
| US3273964A (en) * | 1963-02-28 | 1966-09-20 | Universal Oil Prod Co | Process for producing bromine from a mixture of hydrogen bromide and olefinic hydrocarbon |
| GB1104294A (en) | 1963-12-10 | 1968-02-21 | Ralph William King | Production of lower alkanols and lower alkyl bromides |
| US3310380A (en) * | 1964-02-13 | 1967-03-21 | Universal Oil Prod Co | Bromine recovery |
| US3923913A (en) | 1964-05-12 | 1975-12-02 | Pechiney Saint Gobain | Process for obtaining chlorinated derivatives of ethylene |
| US3353919A (en) | 1964-07-23 | 1967-11-21 | Air Preheater | Apparatus for the elimination of odors from noxious gases |
| BE672377A (enExample) | 1964-11-24 | 1966-05-16 | ||
| US3353916A (en) * | 1966-04-25 | 1967-11-21 | Universal Oil Prod Co | Quantitative recovery of bromine by two stage catalytic oxidation of hydrogen bromide |
| DE1618686B1 (de) | 1966-04-28 | 1971-08-26 | Marathon Oil Co | Tieftemperatur-Verfahren für die Chlorierung oder Bromierung von Kohlenwasserstoffen |
| US3346340A (en) | 1966-08-11 | 1967-10-10 | Universal Oil Prod Co | Production of bromine by oxidation of hydrogen bromide |
| DE1807780B2 (de) | 1968-11-08 | 1976-11-04 | Henkel & Cie GmbH, 4000 Düsseldorf | Verfahren zur herstellung von aether- und polyaetheralkoholen |
| DE1618254B1 (de) | 1967-06-29 | 1971-07-08 | Kalk Chemische Fabrik Gmbh | Verfahren zur Herstellung von Bromverbindungen aus Alkoholen aus Brom |
| US3496242A (en) * | 1967-08-30 | 1970-02-17 | Fmc Corp | Oxychlorination of mixed hydrocarbons |
| US3598876A (en) | 1967-11-13 | 1971-08-10 | Universal Oil Prod Co | Selective halogenation of hydrocarbons |
| US3879480A (en) | 1967-12-07 | 1975-04-22 | Lummus Co | Vinyl chloride process |
| US3679758A (en) | 1968-02-05 | 1972-07-25 | Sun Oil Co | Dihalogenation of branched alkanes |
| GB1253618A (en) | 1968-03-28 | 1971-11-17 | Perstorp Ab | Process for the production of dry semi-formals |
| CA920775A (en) | 1968-05-13 | 1973-02-13 | Vadekar Mohan | Oxidation of hydrogen chloride using molecular sieve catalysts |
| US3673264A (en) | 1968-05-21 | 1972-06-27 | Dow Chemical Co | Method of preparing optically active propylene chlorohydrins and propylene oxides |
| US3920764A (en) | 1968-10-23 | 1975-11-18 | Lummus Co | Dehydrogenation process |
| US3657367A (en) | 1968-10-31 | 1972-04-18 | Stauffer Chemical Co | Oxychlorination of saturated and unsaturated hydrocarbons in the presence of a fluidized catalyst containing lanthanum and didymium |
| US3670037A (en) | 1969-02-19 | 1972-06-13 | Exxon Research Engineering Co | Catalyst system |
| US3883651A (en) | 1969-08-08 | 1975-05-13 | Boehringer Sohn Ingelheim | Pharmaceutical compositions containing a 2-(aminoalkylamino)-4-amino-thieno{8 3,2-d{9 pyrimidine and method of use |
| US3702886A (en) | 1969-10-10 | 1972-11-14 | Mobil Oil Corp | Crystalline zeolite zsm-5 and method of preparing the same |
| US3705196A (en) | 1969-10-31 | 1972-12-05 | Sun Oil Co | Synthesis of aliphatic and alicyclic ethers |
| US3799997A (en) | 1971-11-08 | 1974-03-26 | Universal Oil Prod Co | Preparation of alkenynes |
| US3968200A (en) | 1972-03-27 | 1976-07-06 | The Lummus Company | Reactor effluent quench system |
| US4172099A (en) | 1972-05-30 | 1979-10-23 | Stauffer Chemical Company | Process for chlorination of ethylene |
| GB1395926A (en) | 1972-07-27 | 1975-05-29 | Bp Chem Int Ltd | Process for the production of isoprene by the chlorination/ dehydrochlorination of 2-methylbutene-2 |
| JPS5231022B2 (enExample) | 1972-10-06 | 1977-08-12 | ||
| US3876715A (en) | 1972-12-01 | 1975-04-08 | Gulf Research Development Co | Process for preparing 2,3-dibromo-2-alkylalkanes |
| IT982662B (it) | 1973-03-30 | 1974-10-21 | Montedison Spa | Procedimento di bromofluorurazio ne del metano |
| US4347391A (en) | 1973-06-11 | 1982-08-31 | Stauffer Chemical Company | Process for preparing ethylene dichloride |
| US3865886A (en) * | 1973-06-20 | 1975-02-11 | Lummus Co | Production of allyl chloride |
| US3894107A (en) * | 1973-08-09 | 1975-07-08 | Mobil Oil Corp | Conversion of alcohols, mercaptans, sulfides, halides and/or amines |
| US3894104A (en) | 1973-08-09 | 1975-07-08 | Mobil Oil Corp | Aromatization of hetero-atom substituted hydrocarbons |
| US3894105A (en) | 1973-08-09 | 1975-07-08 | Mobil Oil Corp | Production of durene |
| US3894103A (en) | 1973-08-09 | 1975-07-08 | Mobil Oil Corp | Aromatization reactions |
| US3879473A (en) | 1973-08-14 | 1975-04-22 | Phillips Petroleum Co | Preparation of ethers from alcohols and olefins catalyzed by iodine |
| US3919336A (en) | 1973-10-23 | 1975-11-11 | Allied Chem | Method of preparing vinyl chloride from liquid ethylene dichloride |
| US3987119A (en) | 1973-10-23 | 1976-10-19 | Allied Chemical Corporation | Production of vinyl chloride from ethane |
| US4092368A (en) | 1974-03-13 | 1978-05-30 | General Electric Company | Vapor phase transesterification |
| US4117251A (en) | 1974-05-15 | 1978-09-26 | Chemische Werke Huls Ag | Method for preparing straight chain primary alcohols from 1-bromoalkanes |
| US4046825A (en) | 1974-05-15 | 1977-09-06 | Mobil Oil Corporation | Conversion of oxygenated compounds to gasoline |
| US4035285A (en) | 1974-05-28 | 1977-07-12 | Mobil Oil Corporation | Hydrocarbon conversion process |
| US3965205A (en) | 1974-06-10 | 1976-06-22 | Mobil Oil Corporation | Conversion of low octane hydrocarbons to high octane gasoline |
| US4169862A (en) | 1974-07-22 | 1979-10-02 | The B. F. Goodrich Company | Low temperature catalytic combustion of chlorohydrocarbons |
| US4058576A (en) | 1974-08-09 | 1977-11-15 | Mobil Oil Corporation | Conversion of methanol to gasoline components |
| US4138440A (en) * | 1974-08-14 | 1979-02-06 | Mobil Oil Corporation | Conversion of liquid alcohols and ethers with a fluid mass of ZSM-5 type catalyst |
| US3928483A (en) | 1974-09-23 | 1975-12-23 | Mobil Oil Corp | Production of gasoline hydrocarbons |
| US4044061A (en) | 1974-09-23 | 1977-08-23 | Mobil Oil Corporation | Preheating methanol effects steady state operation of conversion to gasoline |
| US3974062A (en) | 1974-10-17 | 1976-08-10 | Mobil Oil Corporation | Conversion of full range crude oils with low molecular weight carbon-hydrogen fragment contributors over zeolite catalysts |
| US4071753A (en) * | 1975-03-31 | 1978-01-31 | Gte Laboratories Incorporated | Transducer for converting acoustic energy directly into optical energy |
| US4025575A (en) | 1975-04-08 | 1977-05-24 | Mobil Oil Corporation | Process for manufacturing olefins |
| US4049734A (en) | 1975-04-08 | 1977-09-20 | Mobil Oil Corporation | Conversion of coal to high octane gasoline |
| US4025576A (en) | 1975-04-08 | 1977-05-24 | Mobil Oil Corporation | Process for manufacturing olefins |
| US4133838A (en) * | 1975-05-15 | 1979-01-09 | Pearson Research Corp. | Process for preparing hydrocarbons from methanol and phosphorus pentoxide |
| CA1099656A (en) | 1975-07-02 | 1981-04-21 | Clarence D. Chang | Manufacture of gasoline |
| US4039600A (en) | 1975-07-02 | 1977-08-02 | Mobil Oil Corporation | Conversion of synthesis gas to aromatic hydrocarbons |
| US4087475A (en) | 1975-07-03 | 1978-05-02 | Robert Kenneth Jordan | Carbonyl fluorination process |
| US4052471A (en) | 1975-08-06 | 1977-10-04 | Pearsall Chemical Corporation | Process for chlorinating C8 to C30 linear hydrocarbons |
| US3992466A (en) | 1975-08-13 | 1976-11-16 | Mobil Oil Corporation | Hydrocarbon conversion |
| US4052472A (en) | 1976-01-16 | 1977-10-04 | Mobil Oil Corporation | Mordenite conversion of alkanols to penta- and hexamethyl benzenes |
| US4049573A (en) | 1976-02-05 | 1977-09-20 | Mobil Oil Corporation | Zeolite catalyst containing oxide of boron or magnesium |
| US4006169A (en) * | 1976-02-26 | 1977-02-01 | Smithkline Corporation | Epoxidation of α,β-ethylenic ketones |
| US4060568A (en) | 1976-03-31 | 1977-11-29 | Mobil Oil Corporation | Silica-modified zeolite catalyst and conversion therewith |
| US4072733A (en) * | 1976-04-02 | 1978-02-07 | Ethyl Corporation | Conversion of methanol and dimethyl ether |
| US4110180A (en) | 1976-04-28 | 1978-08-29 | Diamond Shamrock Technologies S.A. | Process for electrolysis of bromide containing electrolytes |
| IT1075503B (it) | 1976-05-08 | 1985-04-22 | Basf Ag | Processo per la preparazione di glicolesteri |
| US4025571A (en) | 1976-05-12 | 1977-05-24 | Mobil Oil Corporation | Manufacture of hydrocarbons |
| US4025572A (en) | 1976-05-12 | 1977-05-24 | Mobil Oil Corporation | Manufacture of hydrocarbons |
| GB1542112A (en) | 1976-06-11 | 1979-03-14 | Shell Int Research | Process for the preparation of 2-phenylethanol or derivatives thereof |
| US4035430A (en) | 1976-07-26 | 1977-07-12 | Mobil Oil Corporation | Conversion of methanol to gasoline product |
| US4194990A (en) | 1977-02-11 | 1980-03-25 | Allied Chemical Corporation | Catalyst and process for the production of chlorofluorinated hydrocarbons |
| US4380682A (en) | 1977-03-30 | 1983-04-19 | Diamond Shamrock Corporation | Balanced chlorination process |
| US4156698A (en) | 1977-05-05 | 1979-05-29 | Mobil Oil Corporation | Conversion of alcohols or ethers using rare earth crystalline aluminosilicate in an alumina matrix |
| IT1077342B (it) | 1977-07-18 | 1985-05-04 | Snam Progetti | Processo per la produzione di oligomeri da alfaolefine lineari,successiva idrogenazione degli stessi e prodotti saturi cosi' ottenuti |
| NL7710901A (nl) | 1977-10-05 | 1979-04-09 | Esmil B V Stationsstraat 48 | Werkwijze voor het gelijktijdig verwerken van gebruikt metaal en/of metaalafval van gehaloge- neerde koolwaterstoffen. |
| US4300005A (en) | 1977-12-02 | 1981-11-10 | Monsanto Co. | Preparation of vinyl chloride |
| US4133966A (en) * | 1977-12-23 | 1979-01-09 | Gulf Research & Development Company | Selective formation of ethanol from methanol, hydrogen and carbon monoxide |
| US4282159A (en) | 1978-06-19 | 1981-08-04 | Wisconsin Alumni Research Foundation | Preparation of alkylene oxides |
| DE2832532A1 (de) | 1978-07-25 | 1980-02-07 | Hoechst Ag | Verfahren zur gewinnung von reinen 2-(perfluoralkyl)-aethanolen aus ihren gemischen mit 2-(perfluoralkyl)-aethylenen und gegebenenfalls 2-(perfluoralkyl)- aethylestern |
| US4187255A (en) * | 1978-08-21 | 1980-02-05 | Conoco, Inc. | Process for methylating naphthalene |
| FR2434861A1 (fr) | 1978-08-31 | 1980-03-28 | Inst Francais Du Petrole | Procede de production d'essence a haut indice d'octane et en particulier d'essence utilisable sans plomb |
| US4849573A (en) | 1978-09-05 | 1989-07-18 | Mobil Oil Corporation | Process for manufacturing light olefins |
| JPS5573619A (en) * | 1978-11-30 | 1980-06-03 | Mitsubishi Heavy Ind Ltd | Condensation of methyl chloride through dehydrochlorination |
| US4300009A (en) | 1978-12-28 | 1981-11-10 | Mobil Oil Corporation | Conversion of biological material to liquid fuels |
| US4311865A (en) * | 1979-04-04 | 1982-01-19 | Mobil Oil Corporation | Manufacture of hydrocarbons from oxygenates |
| NL7902886A (nl) * | 1979-04-12 | 1980-10-14 | Shell Int Research | Werkwijze voor de bereiding van een koolwaterstof- mengsel. |
| US4496752A (en) * | 1979-05-03 | 1985-01-29 | The Lummus Company | Production of epoxy compounds from olefinic compounds |
| US4443620A (en) | 1979-05-03 | 1984-04-17 | The Lummus Company | Production of epoxy compounds from olefinic compounds |
| US4410714A (en) | 1979-05-03 | 1983-10-18 | The Lummus Company | Production of epoxy compounds from olefinic compounds |
| US4272338A (en) | 1979-06-06 | 1981-06-09 | Olin Corporation | Process for the treatment of anolyte brine |
| EP0021497A1 (en) | 1979-06-21 | 1981-01-07 | THE PROCTER & GAMBLE COMPANY | Synthesis of polyoxyalkylene glycol monoalkyl ethers |
| US4371716A (en) * | 1979-09-04 | 1983-02-01 | Shell Oil Company | β-(Sec-alkoxy) ethanol process |
| US4462814A (en) | 1979-11-14 | 1984-07-31 | Koch Process Systems, Inc. | Distillative separations of gas mixtures containing methane, carbon dioxide and other components |
| US4412086A (en) | 1980-02-19 | 1983-10-25 | Vulcan Materials Company | Process for separating ferric iron from chlorinated hydrocarbons |
| US4307261A (en) | 1980-02-19 | 1981-12-22 | Vulcan Materials Company | Process for separating ferric iron from chlorinated hydrocarbons |
| US4350511A (en) | 1980-03-18 | 1982-09-21 | Koch Process Systems, Inc. | Distillative separation of carbon dioxide from light hydrocarbons |
| EP0039547B1 (en) | 1980-05-01 | 1984-07-18 | Imperial Chemical Industries Plc | Halogenation process using a halide carrier and process for regeneration of the halide carrier |
| US4302619A (en) | 1980-06-04 | 1981-11-24 | Mobil Oil Corporation | Control of CO emissions in a process for producing gasoline from methanol |
| US4317934A (en) | 1980-08-15 | 1982-03-02 | Ethyl Corporation | Preparation of carbonyl compounds |
| US4320241A (en) | 1980-08-28 | 1982-03-16 | Occidental Research Corporation | Process for converting oxygenated hydrocarbons into hydrocarbons |
| US4308403A (en) | 1980-09-12 | 1981-12-29 | Texaco Inc. | Process for preparing glycol ethers |
| US4317943A (en) | 1980-09-12 | 1982-03-02 | Texaco Inc. | Process for preparing glycol ethers |
| US4301253A (en) * | 1980-09-25 | 1981-11-17 | Union Carbide Corporation | Process for the selective production of ethanol and methanol directly from synthesis gas |
| US4333852A (en) * | 1980-09-25 | 1982-06-08 | Union Carbide Corporation | Catalyst for the selective production of ethanol and methanol directly from synthesis gas |
| US4431856A (en) * | 1980-09-29 | 1984-02-14 | Mobil Oil Corporation | Fluid zeolite catalyst conversion of alcohols and oxygenated derivatives to hydrocarbons |
| DE3037093C1 (de) | 1980-10-01 | 1981-11-12 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung von Cycloocten-4-ol-1 aus Cyclooctadien-1,5 |
| US4543434A (en) | 1981-01-28 | 1985-09-24 | Mobil Oil Corporation | Process for producing liquid hydrocarbon fuels |
| US4690903A (en) | 1981-02-02 | 1987-09-01 | Mobil Oil Corporation | Process for preparing organic fuels and chemicals from biomass |
| SU1214644A1 (ru) * | 1981-03-02 | 1986-02-28 | Ордена Трудового Красного Знамени Институт Катализа Со Ан Ссср | Способ получени олефинов @ - @ |
| GB2095245A (en) | 1981-03-19 | 1982-09-29 | Ici Plc | Chlorination of alkanes |
| GB2095243A (en) | 1981-03-19 | 1982-09-29 | Ici Plc | Production of methylene chloride |
| IN157669B (enExample) | 1981-03-23 | 1986-05-17 | Pfizer | |
| DE3117135A1 (de) | 1981-04-30 | 1982-11-18 | Bayer Ag, 5090 Leverkusen | Kristallines alumosilicat, verfahren zu dessen herstellung sowie dessen verwendung zur katalytischen umwandlung von methanol und/oder dimethylether in kohlenwasserstoffe |
| US4389391A (en) | 1981-06-28 | 1983-06-21 | Dunn Jr Wendell E | Process for beneficiating titaniferous ores |
| US4373109A (en) * | 1981-08-05 | 1983-02-08 | Olah George A | Bifunctional acid-base catalyzed conversion of hetero-substituted methanes into olefins |
| DE3132692A1 (de) | 1981-08-19 | 1983-03-17 | Bayer Ag, 5090 Leverkusen | Verfahren zur halogenierung von organischen verbindungen |
| US4465893A (en) * | 1982-08-25 | 1984-08-14 | Olah George A | Oxidative condensation of natural gas or methane into gasoline range hydrocarbons |
| US4523040A (en) * | 1981-09-01 | 1985-06-11 | Olah George A | Methyl halides and methyl alcohol from methane |
| US4467130A (en) | 1981-09-01 | 1984-08-21 | Olah George A | Condensation of natural gas or methane into gasoline-range hydrocarbons |
| US4513164A (en) | 1981-09-01 | 1985-04-23 | Olah George A | Condensation of natural gas or methane into gasoline range hydrocarbons |
| DE3275539D1 (en) | 1981-09-01 | 1987-04-09 | Olah George A | Process for the production of methyl halides and methyl alcohol from methane |
| US4433192A (en) * | 1981-09-01 | 1984-02-21 | Olah George A | Condensation of natural gas or methane into gasoline range hydrocarbons |
| DE3137751A1 (de) | 1981-09-23 | 1983-03-31 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zum erzeugen von benzinkohlenwasserstoffen aus methanol |
| US4605803A (en) | 1981-11-21 | 1986-08-12 | Mobil Oil Corporation | Acid-catalyzed organic compound conversion |
| CA1186345A (en) | 1981-12-14 | 1985-04-30 | Martin M.Y. Chang | Hydrocarbon production |
| US4568660A (en) * | 1982-01-25 | 1986-02-04 | Hercules Incorporated | Cycloolefin polymerization catalyst composition |
| US4489211A (en) | 1982-02-04 | 1984-12-18 | Onoda Cement Co., Ltd. | Process for producing 2,2,2-trifluoroethanol |
| US4538015A (en) | 1982-03-08 | 1985-08-27 | Mobil Oil Corporation | Catalysis over activated zeolites |
| US4538014A (en) | 1982-03-08 | 1985-08-27 | Mobil Oil Corporation | Catalysis over activated zeolites |
| US4384159A (en) | 1982-03-12 | 1983-05-17 | The Dow Chemical Company | Catalytic dehydrohalogenation process |
| IT1150678B (it) | 1982-03-12 | 1986-12-17 | Anic Spa | Procedimento per la produzione di eteri alchil terbutilici in presenza di butadiene |
| US4433189A (en) * | 1982-03-18 | 1984-02-21 | Mobil Oil Corporation | Catalytic conversion of methanol to light olefins |
| US4588835A (en) | 1982-03-29 | 1986-05-13 | Otsuka Kagaku Yakuhin Kabushiki Kaisha | Process for preparing alkoxyphenols |
| US4499314A (en) * | 1982-03-31 | 1985-02-12 | Imperial Chemical Industries Plc | Methanol conversion to hydrocarbons with zeolites and cocatalysts |
| DE3216722A1 (de) * | 1982-05-05 | 1983-11-10 | Hoechst Ag, 6230 Frankfurt | 4-halomethylbenzoesaeure-alkylester-imine und verfahren zu deren herstellung |
| GB2120249B (en) | 1982-05-15 | 1985-11-27 | British Petroleum Co Plc | Process for the production of methyl or ethyl mono-halide |
| US4467133A (en) | 1982-06-21 | 1984-08-21 | Mobil Oil Corporation | Conversion of alcohols and ethers to distillate range hydrocarbons |
| FR2529883A1 (fr) | 1982-07-06 | 1984-01-13 | Ugine Kuhlmann | Procede de fabrication de chlorure de vinyle |
| US4440871A (en) * | 1982-07-26 | 1984-04-03 | Union Carbide Corporation | Crystalline silicoaluminophosphates |
| US4509955A (en) | 1982-08-09 | 1985-04-09 | The Lubrizol Corporation | Combinations of carboxylic acylating agents substituted with olefin polymers of high and low molecular weight mono-olefins, derivatives thereof, and fuels and lubricants containing same |
| US4465884A (en) | 1982-08-17 | 1984-08-14 | Mobil Oil Corporation | Olefin processing |
| US4814527A (en) | 1982-10-18 | 1989-03-21 | The Dow Chemical Company | Catalytic process for ethylene dichloride |
| US4654449A (en) * | 1982-12-09 | 1987-03-31 | Mobil Oil Corporation | Formation of halogenated hydrocarbons from hydrocarbons |
| US4655893A (en) | 1983-02-07 | 1987-04-07 | Battelle Development Corporation | Cubic boron nitride preparation utilizing a boron and nitrogen bearing gas |
| US4788377A (en) | 1983-04-22 | 1988-11-29 | Mobil Oil Corporation | Process for manufacturing olefins |
| US4720600A (en) * | 1983-06-29 | 1988-01-19 | Mobil Oil Corporation | Production of middle distillate range hydrocarbons by light olefin upgrading |
| US4547612A (en) | 1984-09-25 | 1985-10-15 | Mobil Oil Corporation | Production of lubricant and/or heavy distillate range hydrocarbons by light olefin upgrading |
| US4675410A (en) | 1983-07-11 | 1987-06-23 | Nepera Inc. | Process for the production of pyridine or alkyl substituted pyridines |
| US4540826A (en) | 1983-08-12 | 1985-09-10 | Phillips Petroleum Company | Process for preparing olefinic aldehydes |
| CA1202610A (en) | 1983-08-15 | 1986-04-01 | Ralph M. Dessau | Activity enhancement of high silica zeolites |
| DE3470527D1 (en) | 1983-08-25 | 1988-05-26 | Huels Chemische Werke Ag | Process for the preparation of 3,3- or 2,3-dimethyl butene and 2,3- dimethyl butadiene or for the simultaneous preparation of these olefins and glycol or polyglycol-n-alkyl-3,3- or 2,3-dimethyl butyl ether from mono- and dichloro-dimethyl butane |
| US5175382A (en) | 1983-09-22 | 1992-12-29 | Werner Hebgen | Preparation of 1,2-Dichloroethane |
| US4524228A (en) | 1983-09-29 | 1985-06-18 | Mobil Oil Corporation | Production of durene and gasoline from synthesis gas |
| US4524227A (en) | 1983-09-29 | 1985-06-18 | Mobil Oil Corporation | Coproduction of durene and gasoline from synthesis gas and alcohols and separation of durene-gasoline mixtures |
| US4524231A (en) | 1983-09-29 | 1985-06-18 | Mobil Oil Corporation | Production of durene from alcohols and ethers |
| US4709108A (en) | 1983-10-31 | 1987-11-24 | Chevron Research Company | Conversions of low molecular weight hydrocarbons to higher molecular weight hydrocarbons using a metal compound-containing catalyst |
| US4599474A (en) | 1983-10-31 | 1986-07-08 | Chevron Research Company | Conversions of low molecular weight hydrocarbons to higher molecular weight hydrocarbons using a metal-containing catalyst |
| US4704488A (en) | 1983-10-31 | 1987-11-03 | Chevron Research Company | Conversions of low molecular weight hydrocarbons to higher molecular weight hydrocarbons using a metal compound-containing catalyst (111-A) |
| US4704493A (en) | 1983-10-31 | 1987-11-03 | Chevron Corporation | Conversions of low molecular weight hydrocarbons to higher molecular weight hydrocarbons using a metal compound-containing catalyst (II-A) |
| GB8331982D0 (en) | 1983-11-30 | 1984-01-04 | British Petroleum Co Plc | Hydrocarbons from c1 to c4 alkyl monohalides |
| GB8333613D0 (en) * | 1983-12-16 | 1984-01-25 | British Petroleum Co Plc | Production of hydrocarbons from c1 to c4 alkyl monohalides |
| EP0150594B1 (en) | 1983-12-16 | 1988-03-23 | The British Petroleum Company p.l.c. | Process for the production of hydrocarbons from hetero-substituted alkanes |
| JPS60136525A (ja) | 1983-12-26 | 1985-07-20 | Agency Of Ind Science & Technol | エタノ−ルの製造法 |
| US4642404A (en) * | 1984-01-23 | 1987-02-10 | Mobil Oil Corporation | Conversion of olefins and paraffins to higher hydrocarbons |
| US4621161A (en) | 1984-01-23 | 1986-11-04 | Mobil Oil Corporation | Oxygenate conversion over activated zeolite catalyst |
| US4550218A (en) | 1984-03-05 | 1985-10-29 | Mobil Oil Corporation | Hydrocarbon synthesis with zeolite catalyst of improved hydrothermal stability |
| LU85285A1 (fr) | 1984-04-03 | 1985-11-27 | Labofina Sa | Procede d'isomerisation d'olefines |
| US4634800A (en) * | 1984-04-16 | 1987-01-06 | Atlantic Richfield Company | Methane conversion process |
| GB8410479D0 (en) | 1984-04-24 | 1984-05-31 | British Petroleum Co Plc | Conversion process |
| US4497967A (en) * | 1984-06-15 | 1985-02-05 | The Halcon Sd Group, Inc. | Process for the preparation of ethanol from methanol, carbon monoxide _and hydrogen |
| US4590310A (en) | 1984-08-02 | 1986-05-20 | The Boc Group, Inc. | Process for the preparation of 2,2,2-trifluoroethanol |
| US4550217A (en) | 1984-08-29 | 1985-10-29 | Mobil Oil Corporation | Conversion of methanol to olefins using large size catalyst particles |
| US4696985A (en) | 1984-11-16 | 1987-09-29 | Hercules Incorporated | Catalyst composition for polymerization of cycloolefins |
| GB8429007D0 (en) * | 1984-11-16 | 1984-12-27 | British Petroleum Co Plc | Aromatics from ethane/ethylene |
| US4579977A (en) | 1984-12-20 | 1986-04-01 | Phillips Petroleum Company | Process for the oxidation of organic halides to organic aldehydes |
| US4764356A (en) * | 1984-12-21 | 1988-08-16 | Exxon Research & Engineering Co. | Process for synthesizing a zeolite catalyst on a pH controlled basis to improve catalyst life |
| US4544781A (en) | 1985-01-09 | 1985-10-01 | Mobil Oil Corporation | Control of temperature exotherms in the conversion of methanol to gasoline hydrocarbons |
| DE194931T1 (de) | 1985-03-14 | 1987-02-26 | Societe Nationale Elf Aquitaine (Production), Courbevoie | Verfahren und vorrichtung zur photochemischen sulfochlorinierung von gasfoermigen alkanen. |
| US4658077A (en) | 1985-06-07 | 1987-04-14 | Phillips Petroleum Company | Composition of matter and method of oxidative conversion of organic compounds therewith |
| US5210357A (en) | 1985-06-07 | 1993-05-11 | Phillips Petroleum Company | Composition of matter and method of oxidative conversion of organic compounds therewith |
| JPS61242901A (ja) | 1985-04-17 | 1986-10-29 | Toyo Soda Mfg Co Ltd | 臭素回収用吸着剤及び臭素回収方法 |
| US5146027A (en) | 1985-05-24 | 1992-09-08 | Atlantic Richfield Co. | Methane conversion process |
| US5959170A (en) * | 1985-05-24 | 1999-09-28 | Atlantic Richfield Company | Methane conversion process |
| US5093542A (en) | 1985-05-24 | 1992-03-03 | Atlantic Richfield Company | Methane conversion process |
| US4774216A (en) | 1985-06-07 | 1988-09-27 | Phillips Petroleum Company | Composition of matter for oxidative conversion of organic compounds |
| US5105045A (en) | 1985-06-07 | 1992-04-14 | Phillips Petroleum Company | Method of oxidative conversion |
| US4724275A (en) * | 1985-07-01 | 1988-02-09 | National Distillers And Chemical Corporation | Crystalline aluminosilicates and their use in the conversion of methanol to low molecular weight hydrocarbons |
| GB8518820D0 (en) | 1985-07-25 | 1985-08-29 | British Petroleum Co Plc | Chemical process |
| GB8520977D0 (en) | 1985-08-21 | 1985-09-25 | British Petroleum Co Plc | Production of aromatics |
| US4795843A (en) * | 1985-08-26 | 1989-01-03 | Uop Inc. | Conversion of methane into larger organic hydrocarbons |
| US4665259A (en) | 1985-08-28 | 1987-05-12 | The Standard Oil Company | Methane conversion process using phosphate-containing catalysts |
| US4658073A (en) | 1985-09-23 | 1987-04-14 | Mobil Oil Corporation | Control system for multistage chemical upgrading |
| US4633027A (en) | 1985-09-23 | 1986-12-30 | Mobil Oil Corporation | Process for converting olefins to gasoline, distillate and alkylate liquid hydrocarbons |
| CA1322768C (en) | 1988-12-29 | 1993-10-05 | John E. Stauffer | Process for the chlorination of ethane |
| US4788369A (en) | 1985-12-31 | 1988-11-29 | Mobil Oil Corporation | Conversion of methanol to gasoline |
| LU86280A1 (fr) | 1986-01-29 | 1987-09-03 | Labofina Sa | Procede de production d'essence |
| GB8613673D0 (en) | 1986-06-05 | 1986-07-09 | Bp Benzin Und Petroleum Ag | Chemical process |
| ZA874948B (en) * | 1986-07-07 | 1989-02-22 | Mobil Oil Corp | Aromatisation of aliphatics over gallium-containing zeolites |
| US4781733A (en) | 1986-07-23 | 1988-11-01 | Bend Research, Inc. | Semipermeable thin-film membranes comprising siloxane, alkoxysilyl and aryloxysilyl oligomers and copolymers |
| US4814532A (en) | 1986-08-04 | 1989-03-21 | Chemical Company, Ltd. Asahi | Process for producing alkylcyclopentadiene derivatives |
| US4795848A (en) * | 1986-08-28 | 1989-01-03 | The Standard Oil Company | Method for upgrading a low molecular weight alkane with a lead-zirconate catalyst |
| US5082816A (en) * | 1986-08-28 | 1992-01-21 | The Standard Oil Company | Lead-zirconate catalysts |
| US4720602A (en) * | 1986-09-08 | 1988-01-19 | Mobil Oil Corporation | Process for converting C2 to C12 aliphatics to aromatics over a zinc-activated zeolite |
| US5120332A (en) | 1986-11-06 | 1992-06-09 | The Haser Company Limited | Gas resonance device |
| US5118899A (en) | 1986-12-22 | 1992-06-02 | Phillips Petroleum Company | Composition of matter and method of oxidative conversion of organic compounds therewith |
| US5160502A (en) | 1986-12-22 | 1992-11-03 | Phillips Petroleum Company | Composition of matter and method of oxidative conversion of organic compounds therewith |
| US5087787A (en) * | 1986-12-29 | 1992-02-11 | Phillips Petroleum Company | Method of oxidative conversion |
| DE3700132A1 (de) | 1987-01-03 | 1988-07-14 | Dow Chemical Gmbh | Verfahren zum herstellen von ethylendichlorid |
| US4769504A (en) * | 1987-03-04 | 1988-09-06 | The United States Of America As Represented By The United States Department Of Energy | Process for converting light alkanes to higher hydrocarbons |
| US4792642A (en) | 1987-03-25 | 1988-12-20 | Eastman Kodak Company | Process for preparing iodinated aromatic compounds |
| US4795737A (en) * | 1987-03-25 | 1989-01-03 | Eastman Kodak Company | Process for the iodination of aromatic compounds over solid catalysts |
| US4886932A (en) | 1987-03-30 | 1989-12-12 | Atlantic Richfield Company | Thin bed cofeed reaction system for methane conversion |
| CA1322769C (en) | 1988-12-30 | 1993-10-05 | John E. Stauffer | Process for the chlorination of ethane |
| US4777321A (en) | 1987-04-29 | 1988-10-11 | Mobil Oil Corporation | Feedstock preparation and conversion of oxygenates to olefins |
| US4775462A (en) | 1987-06-22 | 1988-10-04 | Uop Inc. | Non-oxidative method of sweetening a sour hydrocarbon fraction |
| US4808763A (en) * | 1987-08-05 | 1989-02-28 | Amoco Corporation | Process for upgrading light paraffins |
| US4804797A (en) * | 1987-08-24 | 1989-02-14 | Gas Research Institute | Production of commodity chemicals from natural gas by methane chlorination |
| US4783566A (en) | 1987-08-28 | 1988-11-08 | Uop Inc. | Hydrocarbon conversion process |
| GB8724373D0 (en) | 1987-10-17 | 1987-11-18 | British Petroleum Co Plc | Chemical process |
| US5157189A (en) | 1987-10-19 | 1992-10-20 | Karra Sankaram B | Conversion of light hydrocarbons to higher hydrocarbons |
| US4973786A (en) | 1987-10-19 | 1990-11-27 | Karra Sankaram B | Process for the pyrolytic oxidation of methane to higher molecular weight hydrocarbons and synthesis gas |
| US4814536A (en) | 1987-12-15 | 1989-03-21 | Mobil Oil Corporation | Conversion of oxygenates to gasoline at variable space velocity |
| US4814535A (en) | 1987-12-15 | 1989-03-21 | Mobil Oil Corporation | Conversion of oxygenates to gasoline at variable inlet temperature |
| GB8802731D0 (en) | 1988-02-06 | 1988-03-09 | British Petroleum Co Plc | Chemical process |
| US5059744A (en) | 1988-03-03 | 1991-10-22 | Mobil Oil Corporation | Reactor and recovery system for upgrading lower olefins |
| GB8806675D0 (en) | 1988-03-21 | 1988-04-20 | Shell Int Research | Process for preparing liquid hydrocarbons |
| US4851602A (en) | 1988-04-11 | 1989-07-25 | Mobil Oil Corporation | Alkanes and alkenes conversion to high octane gasoline |
| US4851606A (en) | 1988-04-25 | 1989-07-25 | Mobil Oil Corporation | Control of waste water chemical oxygen demand in an oxygenate to hydrocarbon conversion process |
| US4886925A (en) | 1988-05-02 | 1989-12-12 | Mobil Oil Corp | Olefins interconversion and etherification process |
| JPH07106998B2 (ja) | 1988-05-17 | 1995-11-15 | ダイキン工業株式会社 | １，１，１−トリフルオロ−２，２−ジクロロエタンの製造方法 |
| US5013793A (en) | 1990-07-26 | 1991-05-07 | Exxon Chemical Patents Inc. | Dynamically cured thermoplastic olefin polymers and process for producing the same |
| US4990711A (en) * | 1988-06-23 | 1991-02-05 | Mobil Oil Corporation | Synthetic polyolefin lubricant blends having high viscosity indices |
| US4950822A (en) | 1988-06-27 | 1990-08-21 | Ethyl Corporation | Olefin oligomer synlube process |
| US4899002A (en) * | 1988-07-25 | 1990-02-06 | Mobil Oil Corp. | Integrated staged conversion of methanol to gasoline and distillate |
| FR2635101B1 (fr) | 1988-08-05 | 1990-09-28 | Rhone Poulenc Chimie | Procede de preparation du trifluoroethanol par hydrolyse, en phase gazeuse, du chlorotrifluoroethane |
| US4939311A (en) | 1988-08-17 | 1990-07-03 | Amoco Corporation | Catalysts for the oxidative conversion of methane to higher hydrocarbons |
| US5055633A (en) | 1988-10-06 | 1991-10-08 | Uop | Adsorption and isomerization of normal and mono-methyl paraffins |
| US5055634A (en) | 1988-10-06 | 1991-10-08 | Uop | Adsorption and isomerization of normal and mono-methyl paraffins |
| US4956521A (en) | 1988-10-06 | 1990-09-11 | Uop | Adsorption and isomerization of normal and mono-methyl paraffins |
| US5215648A (en) | 1988-10-20 | 1993-06-01 | Chevron Research And Technology Company | Hydrocarbon conversion processes using SSZ-31 |
| US4899001A (en) * | 1988-11-21 | 1990-02-06 | Uop | Process for the simultaneous hydroconversion of a first feedstock comprising unsaturated, halogenated organic compounds and a second feedstock comprising saturated, halogenated organic compounds |
| US5194244A (en) | 1988-11-23 | 1993-03-16 | Shell Oil Company | Basic alkali metal-zeolite compositions |
| US4929781A (en) | 1988-11-30 | 1990-05-29 | Uop | Process for the simultaneous hydroconversion of a first feedstock comprising unsaturated, halogenated organic compounds and a second feedstock comprising saturated, halogenated organic compounds |
| US4895995A (en) * | 1988-12-02 | 1990-01-23 | Uop | Process for the simultaneous hydroconversion of a first feedstock comprising unsaturated, halogenated organic compounds and a second feedstock comprising saturated, halogenated organic compounds |
| US5034566A (en) | 1988-12-07 | 1991-07-23 | Sumitomo Chemical Company, Limited | Process for the production of 2,3-dimethylbutenes |
| GB8829923D0 (en) | 1988-12-22 | 1989-02-15 | Ici Plc | Zeolites |
| US5178748A (en) * | 1988-12-22 | 1993-01-12 | Imperial Chemical Industries | Catalytic reactions using zeolites |
| CA1304419C (en) | 1988-12-22 | 1992-06-30 | Raj N. Pandey | Conversion of methane to gasoline-range hydrocarbons via isobutene |
| US4990696A (en) * | 1988-12-29 | 1991-02-05 | Stauffer John E | Methyl alcohol process |
| US4899000A (en) * | 1989-01-27 | 1990-02-06 | Stauffer John E | Production of allyl chloride |
| US5436378A (en) | 1989-02-16 | 1995-07-25 | Atochem | Drying of hydrocarbon/hydrochloric acid/water admixtures |
| US5107051A (en) | 1989-03-14 | 1992-04-21 | Exxon Chemical Patents Inc. | Halogen resistant hydrotreating process and catalyst |
| US4945175A (en) | 1989-05-26 | 1990-07-31 | Uop | Dehydrocyclodimerization process start-up procedure |
| US5202511A (en) | 1989-08-16 | 1993-04-13 | The Dow Chemical Company | Catalyst diluent for oxychlorination process |
| US5071815A (en) | 1989-09-01 | 1991-12-10 | British Columbia Research Corporation | Method for producing catalysts |
| ZA907446B (en) | 1989-09-19 | 1991-07-31 | Union Carbide Chem Plastic | Silver-containing catalysts for oxidative coupling |
| US5073656A (en) | 1989-09-19 | 1991-12-17 | Union Carbide Chemicals And Plastics Company, Inc. | High ethylene to ethane processes for oxidative coupling |
| US5073657A (en) | 1989-09-19 | 1991-12-17 | Union Carbide Chemicals And Plastics Company Inc. | Vapor phase modifiers for oxidative coupling |
| DD295828A5 (de) | 1989-09-19 | 1991-11-14 | Union Carbide Chemicals And Plastics Co. Inc.,Us | Tieftemperaturkatalysatoren fuer oxydative kopplungsverfahren |
| DE3933656A1 (de) | 1989-10-09 | 1991-04-11 | Basf Ag | Verdunstungsarme polyesterharze |
| US5026944A (en) | 1989-12-20 | 1991-06-25 | Energy Mines And Resources Canada | Synthesis of isobutene from methane and acetylene |
| US4982024A (en) * | 1989-12-26 | 1991-01-01 | Ethyl Corporation | Process for the selective dehydrohalogenation of an admixture of alkylhalides |
| US5004847A (en) | 1989-12-27 | 1991-04-02 | Ethyl Corporation | Recovery of hexabromocyclododecane particles |
| US5026937A (en) | 1989-12-29 | 1991-06-25 | Uop | Aromatization of methane using zeolite incorporated in a phosphorus-containing alumina |
| US4982041A (en) * | 1990-01-10 | 1991-01-01 | Union Carbide Chemicals And Plastics Company Inc. | Double perovskite catalysts for oxidative coupling |
| US5026934A (en) | 1990-02-12 | 1991-06-25 | Lyondell Petrochemical Company | Method for converting light hydrocarbons to olefins, gasoline and methanol |
| US5043502A (en) | 1990-03-16 | 1991-08-27 | Uop | Production of xylenes from light aliphatic hydrocarbons via dehydrocyclodimerization and methylation |
| US5228888A (en) | 1990-03-23 | 1993-07-20 | The Boc Group, Inc. | Economical air separator |
| US5107061A (en) | 1990-04-06 | 1992-04-21 | Exxon Chemical Patents Inc. | Removal of organochlorides from hydrocarbon feed streams |
| US5087786A (en) * | 1990-04-25 | 1992-02-11 | Amoco Corporation | Halogen-assisted conversion of lower alkanes |
| US5001293A (en) | 1990-04-25 | 1991-03-19 | Amoco Corporation | Halocarbon conversion |
| US5087779A (en) * | 1990-04-25 | 1992-02-11 | Amoco Corporation | Hydrocarbon halogenation |
| US5019652A (en) | 1990-04-30 | 1991-05-28 | The United States As Represented By The United States Department Of Energy | Catalysts and method |
| US5139991A (en) | 1990-04-30 | 1992-08-18 | The United States Of American As Represented By The United States Department Of Energy | Oxyhydrochlorination catalyst |
| US5068478A (en) | 1990-05-25 | 1991-11-26 | Energia Andina, Ltd. | Producing alkenes and alkynes from alkanes and alkenes |
| GB9013859D0 (en) | 1990-06-21 | 1990-08-15 | Ici Plc | Zeolites |
| GB9013916D0 (en) | 1990-06-22 | 1990-08-15 | Ici Plc | Zeolites |
| US4988660A (en) * | 1990-06-25 | 1991-01-29 | Union Carbide Chemicals And Plastics Company Inc. | Double perovskite catalysts for oxidative coupling |
| US5096469A (en) | 1990-07-23 | 1992-03-17 | Keefer Bowie | Adsorptive gas separator with inertial energy exchange |
| US5082473A (en) * | 1990-07-23 | 1992-01-21 | Keefer Bowie | Extraction and concentration of a gas component |
| US5401890A (en) | 1990-07-30 | 1995-03-28 | Albemarle Corporation | Process and apparatus for heat treating halogenated compounds |
| US5013424A (en) | 1990-07-30 | 1991-05-07 | Uop | Process for the simultaneous hydrogenation of a first feedstock comprising hydrocarbonaceous compounds and having a non-distillable component and a second feedstock comprising halogenated organic compounds |
| US5138112A (en) | 1990-08-31 | 1992-08-11 | Uop | Process for converting a C2 -C6 aliphatic hydrocarbon to high octane transportable fuel |
| DE4029875A1 (de) | 1990-09-21 | 1992-03-26 | Hoechst Ag | Verfahren zur inhibierung und zerstoerung von peroxiden in dialkylethern |
| JP2970683B2 (ja) | 1990-10-12 | 1999-11-02 | 日石三菱株式会社 | 水素化脱アルキル触媒を用いた水素化脱アルキル法 |
| US5085674A (en) * | 1990-10-25 | 1992-02-04 | Union Carbide Industrial Gases Technology Corporation | Duplex adsorption process |
| US5071449A (en) | 1990-11-19 | 1991-12-10 | Air Products And Chemicals, Inc. | Gas separation by rapid pressure swing adsorption |
| US5107032A (en) | 1990-11-20 | 1992-04-21 | Noramco, Inc. | Process for the preparation of o-phthalaldehydes |
| KR100220114B1 (ko) * | 1990-12-06 | 1999-09-01 | 퓨어를 리챠드 디. | 에틸렌 또는 에틸렌과 비닐클로라이드와의 혼합물의 제조방법 |
| US5055235A (en) | 1990-12-12 | 1991-10-08 | Ethyl Corporation | Bromination process |
| US5223471A (en) | 1990-12-12 | 1993-06-29 | Amoco Corporation | Fluorine-containing materials |
| US5105046A (en) | 1990-12-12 | 1992-04-14 | Amoco Corporation | Oxidative conversion of lower alkanes to higher hydrocarbons via fluorine-containing materials |
| US5306855A (en) | 1991-02-15 | 1994-04-26 | Catalytica, Inc. | Catalytic process for converting lower alkanes to esters, alcohols, and to hydrocarbons |
| US5233113A (en) | 1991-02-15 | 1993-08-03 | Catalytica, Inc. | Process for converting lower alkanes to esters |
| GB9105167D0 (en) | 1991-03-12 | 1991-04-24 | Ici Plc | Chemical process |
| US5188725A (en) * | 1991-03-15 | 1993-02-23 | Mobil Oil Corporation | Fluidized catalyst process for production and etherification of olefins |
| US5237115A (en) | 1991-03-15 | 1993-08-17 | Phillips Petroleum Company | Integrated olefin processing |
| FR2674769B1 (fr) | 1991-04-04 | 1994-04-29 | Inst Francais Du Petrole | Catalyseur du type galloaluminosilicate contenant du gallium, un metal noble de la famille du platine et au moins un metal additionnel, et son utilisation en aromatisation des hydrocarbures. |
| EP0510238A1 (en) | 1991-04-26 | 1992-10-28 | NOVAMONT S.p.A. | Process for producing lower poliols and mixtures thereof |
| US5288677A (en) | 1991-06-28 | 1994-02-22 | Exxon Chemical Patents Inc. | Immobilized Lewis acid catalysts |
| GB9116172D0 (en) | 1991-07-26 | 1991-09-11 | Thames Water Utilities | A method of and apparatus for treating a fluid |
| US5399258A (en) | 1991-08-15 | 1995-03-21 | Mobil Oil Corporation | Hydrocarbon upgrading process |
| MY108348A (en) | 1991-08-16 | 1996-09-30 | Exxon Chemical Patents Inc | Ester free ethers. |
| US5264635A (en) | 1991-10-03 | 1993-11-23 | Mobil Oil Corporation | Selective cracking and etherification of olefins |
| US5245109A (en) | 1991-10-11 | 1993-09-14 | Amoco Corporation | Hydrocarbon conversion |
| US5276240A (en) * | 1991-10-18 | 1994-01-04 | Board Of Regents, The University Of Texas System | Catalytic hydrodehalogenation of polyhalogenated hydrocarbons |
| JP3120292B2 (ja) | 1991-10-18 | 2000-12-25 | イハラケミカル工業株式会社 | 脂肪族カルボン酸ハロメチルエステル類の製造法 |
| US5268518A (en) | 1991-11-15 | 1993-12-07 | The Dow Chemical Company | Reactor feed pipe design |
| US5191142A (en) | 1991-12-23 | 1993-03-02 | Amoco Corporation | Process for converting methanol to olefins or gasoline |
| EP0626885A4 (en) | 1992-02-04 | 1995-11-22 | Catalytica Inc | Cebr 3? catalyst and process for producing bromine. |
| US6169218B1 (en) * | 1992-02-10 | 2001-01-02 | Catalytic Distillation Technologies | Selective hydrogenation of highly unsaturated compounds in hydrocarbon streams |
| CA2088939A1 (en) | 1992-03-10 | 1993-09-11 | Istvan T. Horvath | Low temperature conversion of alkanes |
| US5354916A (en) | 1992-03-10 | 1994-10-11 | Exxon Research And Engineering Company | Low temperature conversion of alkanes |
| US5202506A (en) | 1992-04-02 | 1993-04-13 | E. I. Du Pont De Nemours And Company | Oxidative drown process for 2-perfluoroalkylethyl alcohols |
| US5185479A (en) * | 1992-04-21 | 1993-02-09 | Stauffer John E | Process for methyl alcohol |
| CA2097090A1 (en) | 1992-06-02 | 1993-12-03 | Quang N. Le | Process for the production of tertiary alkyl ether rich fcc gasoline |
| US5395981A (en) | 1992-06-22 | 1995-03-07 | Uop | Hydrocarbon conversion by catalytic distillation |
| US5254790A (en) | 1992-07-01 | 1993-10-19 | Phillips Petroleum Company | Integrated process for producing motor fuels |
| US5284990A (en) * | 1992-07-16 | 1994-02-08 | Stratco, Inc. | Method for converting a hydrogen fluoride alkylation unit to a sulfuric acid alkylation unit |
| US5276242A (en) * | 1992-08-26 | 1994-01-04 | Phillips Petroleum Company | Alkylation process |
| US5243114A (en) | 1992-09-08 | 1993-09-07 | Mobil Oil Corporation | Oligomerization of alpha-olefins over layered silicate compositions containing pillars of silica and group VIB metal oxide |
| IT1255710B (it) | 1992-10-01 | 1995-11-10 | Snam Progetti | Procedimento integrato per produrre olefine da miscele gassose contenenti metano |
| US5453557A (en) | 1992-10-01 | 1995-09-26 | The Dow Chemical Company | Processes for converting chlorinated byproducts and waste products to useful materials |
| US5430214A (en) | 1992-10-01 | 1995-07-04 | The Dow Chemical Company | Hydrodehalogenation process and catalyst for use therein |
| US5276226A (en) * | 1992-10-05 | 1994-01-04 | Exxon Research & Engineering Company | Low temperature halogenation of alkanes |
| US5300126A (en) | 1992-10-19 | 1994-04-05 | Mobil Oil Corporation | Process for improving olefin etherification catalyst life |
| US5243098A (en) * | 1992-11-04 | 1993-09-07 | Energia Andina Ltd. | Conversion of methane to methanol |
| US5744669A (en) | 1992-11-25 | 1998-04-28 | Uop | Process for the conversion of a halogenated organic stream containing trace quantities of organic nitrates |
| US5817904A (en) | 1992-12-11 | 1998-10-06 | Repsol Petroleo S.A. | Method for the conversion of methane into longer chain hydrocarbons |
| TW291486B (enExample) * | 1992-12-17 | 1996-11-21 | Exxon Chemical Patents Inc | |
| US5470377A (en) | 1993-03-08 | 1995-11-28 | Whitlock; David R. | Separation of solutes in gaseous solvents |
| US5354931A (en) | 1993-03-10 | 1994-10-11 | Uop | Process for hydrotreating an organic feedstock containing oxygen compounds and a halogen component |
| US5382743A (en) * | 1993-04-26 | 1995-01-17 | Mobil Oil Corporation | Skeletal isomerization of n-pentenes using ZSM-35 in the presence of hydrogen |
| US5465699A (en) | 1993-06-01 | 1995-11-14 | Volkswagen Ag | Intake pipe arrangement for an internal combustion engine having individual arc-shaped cylinder intake pipes |
| US5382704A (en) * | 1993-06-30 | 1995-01-17 | E. I. Du Pont De Nemours And Company | Fluorinated methyl ethers |
| US5382744A (en) * | 1993-07-12 | 1995-01-17 | Phillips Petroleum Company | Control of synthetic isopentane production during alkylation of amylenes |
| US5510525A (en) | 1993-07-22 | 1996-04-23 | Gas Research Institute | Direct catalytic oxidative carbonylation of lower alkanes to acids |
| IT1265051B1 (it) | 1993-08-06 | 1996-10-28 | Eniricerche Spa | Processo per l'alchilazione di idrocarburi alifatici con olefine |
| US5500297A (en) | 1993-08-09 | 1996-03-19 | The Trustees Of Princeton University | Electron acceptor compositions technical field |
| US5695890A (en) | 1993-08-09 | 1997-12-09 | The Trustees Of Princeton University | Heterolamellar photoelectrochemical films and devices |
| US5906892A (en) * | 1993-08-09 | 1999-05-25 | The Trustees Of Princeton University | Electron acceptor compositions on polymer templates |
| US5430210A (en) | 1993-08-27 | 1995-07-04 | Mobil Oil Corporation | Selective hydrogen combustion processes |
| GB9318505D0 (en) | 1993-09-07 | 1993-10-20 | Evc Tech Ag | By-product recycling in oxychlorination process |
| GB9318507D0 (en) | 1993-09-07 | 1993-10-20 | Evc Tech Ag | Vinyl chloride production process |
| US5371313A (en) | 1993-11-24 | 1994-12-06 | Polysar Rubber Corporation | Purification of hydrocarbon streams |
| US5600045A (en) * | 1993-12-02 | 1997-02-04 | The Dow Chemical Company | Process for conversion of crude hydrocarbon mixtures |
| US5414173A (en) | 1993-12-22 | 1995-05-09 | The Dow Chemical Company | Process of preparing cyclopentadiene and substituted derivatives thereof |
| GB9400569D0 (en) | 1994-01-13 | 1994-03-09 | Rhone Poulenc Chemicals | Process for the production of substituted aromatic hydrocarbons from corresponding anilines by dediazoniation |
| DE69514333T2 (de) | 1994-02-18 | 2000-10-12 | Chevron Chemical Co. Llc, San Francisco | Zeolith ssz-42 |
| US5565092A (en) | 1994-03-16 | 1996-10-15 | Exxon Chemical Patents Inc. | Halogen resistant hydrogenation process and catalyst |
| US5780703A (en) | 1994-05-02 | 1998-07-14 | Mobil Oil Corporation | Process for producing low aromatic diesel fuel with high cetane index |
| US5565616A (en) | 1994-05-09 | 1996-10-15 | Board Of Regents, The University Of Texas System | Controlled hydrothermal processing |
| US5444168A (en) | 1994-05-16 | 1995-08-22 | Mobil Oil Corporation | Process for the production of symmetrical ethers from secondary alcohols |
| US5401894A (en) | 1994-06-07 | 1995-03-28 | Uop | Process for the treatment of halogenated organic feedstocks |
| US5591421A (en) | 1994-07-11 | 1997-01-07 | Chevron U.S.A. Inc. | Zeolite SSZ-41 |
| US5523503A (en) | 1994-07-13 | 1996-06-04 | Uop | Cocurrent simulated moving bed hydrocarbon alkylation process |
| GB9414972D0 (en) | 1994-07-26 | 1994-09-14 | Bnfl Fluorchem Ltd | Halogenation reactions |
| US5661097A (en) | 1994-08-12 | 1997-08-26 | The Dow Chemical Company | Supported olefin polymerization catalyst |
| US6015867A (en) * | 1994-09-28 | 2000-01-18 | Showa Denko K.K. | 3-alkoxypropionic ester derivative, olefin polymerization catalyst, and process for preparation of polyolefin |
| EP0784648B2 (en) | 1994-10-05 | 2010-10-27 | Great Lakes Chemical Corporation | Continuous bromination process and products thereof |
| GB2294262B (en) * | 1994-10-20 | 1998-07-08 | Evc Tech Ag | Single stage fixed bed oxychlorination of ethylene |
| CA2203115C (en) | 1994-10-20 | 2006-09-19 | Pierluigi Fatutto | Single stage fixed bed oxychlorination of ethylene |
| US5489727A (en) * | 1994-10-28 | 1996-02-06 | Phillips Petroleum Company | Isopentane disproportionation |
| US5693191A (en) | 1994-11-23 | 1997-12-02 | The Dow Chemical Company | Process for recovery of anhydrous hydrogen chloride from mixtures with non-condensable gases |
| JPH10509711A (ja) | 1994-11-24 | 1998-09-22 | ソルベイ（ソシエテ アノニム） | 塩素化アルカンを塩素化度のより低いアルケンに転化させる方法 |
| US5486627A (en) * | 1994-12-02 | 1996-01-23 | The Dow Chemical Company | Method for producing epoxides |
| US5639930A (en) | 1995-01-04 | 1997-06-17 | Penick; Joe E. | Process of producing alkylates |
| US5600043A (en) * | 1995-03-27 | 1997-02-04 | The Geon Company | Oxychlorination process |
| AU721384B2 (en) | 1995-04-21 | 2000-06-29 | Procter & Gamble Company, The | Shampoos with insoluble silicone conditioning agent and cationic polymer |
| FR2734172B1 (fr) | 1995-05-19 | 1997-06-20 | Air Liquide | Dispositif et procede de separation de gaz par adsorption |
| DE19520612A1 (de) | 1995-06-06 | 1996-12-12 | Bayer Ag | Verfahren zur Herstellung von Benzylalkohol |
| US5675052A (en) | 1995-09-15 | 1997-10-07 | The Boc Group, Inc. | Hydrocarbon alkylation process |
| US5705712A (en) * | 1995-10-05 | 1998-01-06 | Uop | Integrated process for producing diisopropyl ether, an isopropyl tertiary alkyl ether and isopropyl alcohol |
| US5705729A (en) * | 1995-11-22 | 1998-01-06 | Mobil Oil Corporation | Isoparaffin-olefin alkylation process |
| DE19548876A1 (de) | 1995-12-27 | 1997-07-03 | Bayer Ag | Verfahren zur kontinuierlichen Herstellung von Benzylalkohol |
| AU692723B2 (en) * | 1996-02-01 | 1998-06-11 | Phillips Petroleum Company | Catalyst composition and process for selecting hydrogenation of diolefins |
| SE517561C2 (sv) | 1996-03-04 | 2002-06-18 | Aga Ab | Förfarande och anordning för framställning av en gas genom separation från en gasblandning |
| US5663474A (en) | 1996-03-07 | 1997-09-02 | Alliedsignal Inc. | Alkylation process using hydrogen fluoride-containing alkylation catalysts |
| US5684213A (en) | 1996-03-25 | 1997-11-04 | Chemical Research & Licensing Company | Method for the preparation of dialkyl ethers |
| US5675046A (en) | 1996-04-10 | 1997-10-07 | Showa Denko K.K. | Process for producing perfluorocarbon |
| USRE38493E1 (en) | 1996-04-24 | 2004-04-13 | Questair Technologies Inc. | Flow regulated pressure swing adsorption system |
| US5720858A (en) * | 1996-07-17 | 1998-02-24 | The United States Of America As Represented By The United States Department Of Energy | Method for the photocatalytic conversion of methane |
| US5708246A (en) * | 1996-08-28 | 1998-01-13 | Battelle Memorial Institute | Method of photocatalytic conversion of C-H organics |
| HU220573B1 (hu) | 1996-11-18 | 2002-03-28 | AGRO-CHEMIE Növényvédőszer Gyártó, Értékesítő és Forgalmazó Kft. | Eljárás benzil-éterek előállítására |
| US7182871B2 (en) | 1996-12-17 | 2007-02-27 | Global Biosciences, Inc. | Wastewater treatment with alkanes |
| SG74047A1 (en) | 1997-04-30 | 2000-07-18 | Mitsubishi Chem Corp | Process for producing alkylene glycol |
| US6018088A (en) * | 1997-05-07 | 2000-01-25 | Olah; George A. | Superacid catalyzed formylation-rearrangement of saturated hydrocarbons |
| DE19721301C1 (de) | 1997-05-21 | 1998-10-01 | Basf Ag | Verfahren zur Hydrolyse von Alkylmonohalogeniden |
| US6056804A (en) | 1997-06-30 | 2000-05-02 | Questor Industries Inc. | High frequency rotary pressure swing adsorption apparatus |
| US5856584A (en) | 1997-08-06 | 1999-01-05 | The Nutrasweet Company | Preparation of 3,3-dimethylbutyraldehyde by oxidation of 3, 3-dimethylbutanol |
| DE19755636A1 (de) | 1997-12-15 | 1999-06-17 | Bayer Ag | Verfahren zur elektrochemischen Aufarbeitung von HCl-Gas zu hochreinem Chlor |
| US5968236A (en) | 1998-02-20 | 1999-10-19 | Bassine; Stuart | Valve free oxygen concentrator |
| US6187983B1 (en) * | 1998-04-29 | 2001-02-13 | Exxon Chemical Patents Inc | Converting oxygenates to olefins in the presence of electromagnetic energy |
| US5998679A (en) * | 1998-05-20 | 1999-12-07 | Jlm Technology, Ltd. | Methods for converting lower alkanes and alkanes to alcohols and diols |
| EP0976705A1 (en) | 1998-07-30 | 2000-02-02 | Ube Industries, Ltd. | Method of producing a phenolalkylether compound |
| IT1302003B1 (it) | 1998-08-05 | 2000-07-20 | Enitecnologie Spa | Procedimento per la trasformazione selettiva di idrocarburi. |
| US6087294A (en) | 1998-08-12 | 2000-07-11 | Kansas State University Research Foundation | Dispersion and stabilization of reactive atoms on the surface of metal oxides |
| US6921597B2 (en) | 1998-09-14 | 2005-07-26 | Questair Technologies Inc. | Electrical current generation system |
| DE69908886T2 (de) * | 1998-11-02 | 2003-12-04 | Institut Francais Du Petrole, Rueil-Malmaison | Verfahren zur Herstellung eines Zeoliths des EUO-Typs mittels Vorläufern des Strukturbildners und dessen Verwendung als Isomerisierungskatalysator von Aromaten mit acht Kohlenstoffatomen |
| EP0999182B1 (fr) * | 1998-11-02 | 2003-05-14 | Institut Francais Du Petrole | Procédé de préparation d'une zéolithe de type structural EUO à l'aide de germes de matériaux zéolitiques et son utilisation comme catalyseur d'isomérisation des aromatiques à huit atomes de carbone |
| US6936565B2 (en) * | 1999-01-12 | 2005-08-30 | Hyperion Catalysis International, Inc. | Modified carbide and oxycarbide containing catalysts and methods of making and using thereof |
| EP1153005A1 (en) | 1999-02-22 | 2001-11-14 | Symyx Technologies | Compositions comprising nickel and their use as catalyst in oxidative dehydrogenation of alkanes |
| US7220391B1 (en) | 1999-03-25 | 2007-05-22 | University Of Central Florida Research Foundation, Inc. | UV photochemical option for closed cycle decomposition of hydrogen sulfide |
| US7273957B2 (en) | 1999-05-04 | 2007-09-25 | Catalytic Distillation Technologies | Process for the production of gasoline stocks |
| US6545192B2 (en) | 1999-05-11 | 2003-04-08 | Shell Oil Company | Process for separating olefins from saturated hydrocarbons |
| FR2793706B1 (fr) * | 1999-05-18 | 2001-08-03 | Total Raffinage Distribution | Support catalytique a base d'oxyde d'un metal du groupe ivb de la classification periodique des elements, sa preparation et ses utilisations |
| US6444223B1 (en) * | 1999-05-28 | 2002-09-03 | Alkermes Controlled Therapeutics, Inc. | Method of producing submicron particles of a labile agent and use thereof |
| US6406523B1 (en) | 1999-06-09 | 2002-06-18 | Questair Technologies, Inc. | Rotary pressure swing adsorption apparatus |
| SE520971C2 (sv) | 1999-08-20 | 2003-09-16 | Perstorp Ab | Förfarande för tillverkning av en eteralkohol |
| US20020102672A1 (en) | 1999-10-04 | 2002-08-01 | Joseph Mizrahi | Process for producing a purified lactic acid solution |
| DE19949211A1 (de) | 1999-10-13 | 2001-05-31 | Veba Oel Ag | Verfahren zur Herstellung von n-Alkanen aus Mineralölfraktionen und Katalysator zur Durchführung des Verfahrens |
| HUP0204181A2 (en) | 1999-11-22 | 2003-05-28 | Dow Chemical Co | A process for the conversion of ethylene to vinyl chloride, and novel catalyst compositions useful for such process |
| US6680415B1 (en) * | 1999-11-22 | 2004-01-20 | Dow Global Technologies Inc. | Oxyhalogenation process using catalyst having porous rare earth halide support |
| US6909024B1 (en) | 1999-11-22 | 2005-06-21 | The Dow Chemical Company | Process for the conversion of ethylene to vinyl chloride and novel catalyst compositions useful for such process |
| US6514319B2 (en) | 1999-12-09 | 2003-02-04 | Questair Technologies Inc. | Life support oxygen concentrator |
| AU2578201A (en) | 1999-12-14 | 2001-06-25 | Halocarbon Products Corporation | Hydrothermal hydrolysis of halogenated compounds |
| JP4724997B2 (ja) | 2000-02-02 | 2011-07-13 | ダイキン工業株式会社 | 含水素フッ素化炭化水素の製造方法 |
| IT1317757B1 (it) | 2000-02-03 | 2003-07-15 | Enitecnologie Spa | Metodo per la preparazione di idrocarburi idrogenati. |
| US6710213B2 (en) | 2000-03-31 | 2004-03-23 | Showa Denko K.K. | Production process and use for propargyl alcohol and its intermediate |
| CA2306311C (en) | 2000-04-20 | 2007-04-10 | Quest Air Gases Inc. | Absorbent laminate structures |
| KR100702191B1 (ko) * | 2000-05-31 | 2007-04-03 | 셰브런 유.에스.에이.인크. | 제올라이트 에스에스제트-53 |
| FR2812301B1 (fr) | 2000-07-26 | 2003-04-04 | Inst Francais Du Petrole | Procede flexible de production de bases huiles et de distillats moyens a partir de charge contenant des heteroatomes |
| IT1318680B1 (it) | 2000-08-11 | 2003-08-27 | Enichem Spa | Processo per la produzione in continuo di ossidi olefinici. |
| FR2813809B1 (fr) * | 2000-09-11 | 2003-07-25 | Air Liquide | Colonne a garnissage d'echange de chaleur et/ou de matiere |
| EP1228023B1 (de) * | 2000-11-29 | 2004-04-28 | Vinnolit GmbH & Co. KG | Verfahren zur herstelling von 1,2-dichlorethan |
| AU2002215752A1 (en) | 2000-12-08 | 2002-06-18 | Denis Connor | Methods and apparatuses for gas separation by pressure swing adsorption with partial gas product feed to fuel cell power source |
| CA2329475A1 (en) | 2000-12-11 | 2002-06-11 | Andrea Gibbs | Fast cycle psa with adsorbents sensitive to atmospheric humidity |
| FR2818284B1 (fr) | 2000-12-15 | 2006-08-04 | Inst Francais Du Petrole | Procede flexible ameliore de production de bases huiles et distillats moyens avec une conversion-hydroisomerisation suivie d'un deparaffinage catalytique |
| US6511526B2 (en) * | 2001-01-12 | 2003-01-28 | Vbox, Incorporated | Pressure swing adsorption gas separation method and apparatus |
| US6509485B2 (en) * | 2001-02-22 | 2003-01-21 | Sri International | Preparation of epoxides from alkanes using lanthanide-promoted silver catalysts |
| CN1301947C (zh) | 2001-02-23 | 2007-02-28 | 昭和电工株式会社 | 全氟化碳的生产方法及其用途 |
| US20030196680A1 (en) | 2002-04-19 | 2003-10-23 | Dielectric Systems, Inc | Process modules for transport polymerization of low epsilon thin films |
| US6525230B2 (en) | 2001-04-18 | 2003-02-25 | Grt, Inc. | Zone reactor |
| US6472572B1 (en) | 2001-06-20 | 2002-10-29 | Grt, Inc. | Integrated process for synthesizing alcohols and ethers from alkanes |
| US7019182B2 (en) | 2001-04-18 | 2006-03-28 | Grt, Inc. | Method of hydrocarbon preservation and environmental protection |
| US7230150B2 (en) | 2001-04-18 | 2007-06-12 | Grt, Inc. | Zone reactor |
| CN1511128A (zh) | 2001-05-23 | 2004-07-07 | 陶氏环球技术公司 | 采用空气进料从乙烷和乙烯的氯乙烯制造方法和可选的HCl处理方法 |
| WO2002094749A1 (en) | 2001-05-23 | 2002-11-28 | Dow Global Technologies Inc. | Production of vinyl halide from single carbon feedstocks |
| JP4275952B2 (ja) | 2001-05-23 | 2009-06-10 | ダウ グローバル テクノロジーズ インコーポレイティド | Ｃ３＋炭化水素の酸化的ハロゲン化および任意的な脱水素 |
| EP1527035B1 (en) | 2001-06-08 | 2015-03-04 | Albemarle Netherlands B.V. | Continuous process for the alkylation of hydrocarbons |
| US7001872B2 (en) | 2001-06-11 | 2006-02-21 | Halliburton Energy Services, Inc. | Subterranean formation treating fluid and methods of fracturing subterranean formations |
| US7161050B2 (en) * | 2001-06-20 | 2007-01-09 | Grt, Inc. | Method and apparatus for synthesizing olefins, alcohols, ethers, and aldehydes |
| US7838708B2 (en) | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
| US20050192468A1 (en) | 2001-06-20 | 2005-09-01 | Sherman Jeffrey H. | Hydrocarbon conversion process improvements |
| US20030069452A1 (en) * | 2001-06-20 | 2003-04-10 | Sherman Jeffrey H. | Method and apparatus for synthesizing from alcohols and ethers from alkanes, alkenes, and aromatics |
| US20030078456A1 (en) * | 2001-06-20 | 2003-04-24 | Aysen Yilmaz | Integrated process for synthesizing alcohols, ethers, aldehydes, and olefins from alkanes |
| US6465699B1 (en) | 2001-06-20 | 2002-10-15 | Gri, Inc. | Integrated process for synthesizing alcohols, ethers, and olefins from alkanes |
| US6440894B1 (en) | 2001-06-25 | 2002-08-27 | Exxonmobil Chemical Patents, Inc. | Methods of removing halogen from non-zeolitic molecular sieve catalysts |
| WO2003002251A2 (en) | 2001-06-28 | 2003-01-09 | Honeywell International, Inc. | Process for preparing fluorination catalyst |
| US20030065239A1 (en) | 2001-06-29 | 2003-04-03 | Peter Zhu | Non-hazardous basic neutralization of aldehydes |
| US6646102B2 (en) | 2001-07-05 | 2003-11-11 | Dow Global Technologies Inc. | Process for manufacturing an alpha-dihydroxy derivative and epoxy resins prepared therefrom |
| US6867302B2 (en) | 2001-07-13 | 2005-03-15 | Board Of Trustees Of Michigan State University | Process for the catalytic synthesis of biaryls and polymers from aryl compounds |
| US7094936B1 (en) | 2001-07-20 | 2006-08-22 | Great Lakes Chemical Corporation | Process for preparing halogenated alkanes |
| FR2828193B1 (fr) | 2001-08-03 | 2004-04-02 | Atofina | Nouveau procede de preparation du 1,1,1,-trifluoro-2,2-dichloroethane |
| EP1414777A1 (en) | 2001-08-03 | 2004-05-06 | Eastman Chemical Company | Vapor phase carbonylation process using iridium-gold co-catalysts |
| US6858770B2 (en) | 2001-08-21 | 2005-02-22 | Catalytic Distillation Technologies | Paraffin alkylation |
| US6797851B2 (en) | 2001-08-30 | 2004-09-28 | Exxonmobil Chemical Patents Inc. | Two catalyst process for making olefin |
| US6552238B1 (en) | 2001-08-31 | 2003-04-22 | Vulcan Chemicals | Separation of heavy ends from streams of halogenated alkanes |
| WO2003022827A1 (en) | 2001-09-11 | 2003-03-20 | Grt, Inc. | Process for synthesizing olefin oxides |
| EP1426351B1 (en) | 2001-09-14 | 2013-06-19 | Tosoh F-Tech, Inc. | Process for preparation of 2,2,2-trifluoroethanol |
| WO2003043575A2 (en) | 2001-11-19 | 2003-05-30 | Merck & Co., Inc. | Process for the synthesis of (r)-1-(3,5-bis(trifluoromethyl)-phenyl)ethan-1-ol and esters thereof by dynamic kinetic resolution |
| ZA200209011B (en) | 2001-11-20 | 2003-05-26 | Rohm & Haas | Electroactive catalysis. |
| AU2002357355A1 (en) | 2001-12-18 | 2003-06-30 | Metabolix, Inc. | Methods of making intermediates from polyhydroxyalkanoates |
| US7199255B2 (en) | 2001-12-18 | 2007-04-03 | Univation Technologies, Llc | Imino-amide catalysts for olefin polymerization |
| CN1271020C (zh) | 2002-01-24 | 2006-08-23 | Grt公司 | 由烷烃合成醇、醚和烯烃的综合工艺 |
| ATE419217T1 (de) | 2002-01-25 | 2009-01-15 | Council Scient Ind Res | Herstellung von ungefährlichen bromierungsreagenzien |
| US7091270B2 (en) | 2002-01-31 | 2006-08-15 | Bromine Compounds Ltd. | Pentabromobenzyl alkyl ethers and their use as fire retardants |
| AU2003214158A1 (en) | 2002-03-13 | 2003-09-29 | University Of Florida | Process for trifluoromethylation of sulfates |
| AU2003209894A1 (en) | 2002-03-14 | 2003-09-22 | Questair Technologies Inc. | Gas separation by combined pressure swing and displacement purge |
| US20040152929A1 (en) | 2002-05-08 | 2004-08-05 | Clarke William D | Process for vinyl chloride manufacture from ethane and ethylene with air feed and alternative hcl processing methods |
| EP1386664B1 (en) | 2002-07-31 | 2016-05-11 | Ineos Technologies (Vinyls) Limited | A hollow parallelepiped pellet suitable as carrier of catalysts for selective exothermic reactions |
| US7238846B2 (en) | 2002-08-14 | 2007-07-03 | Exxonmobil Chemical Patents Inc. | Conversion process |
| CN100464840C (zh) | 2002-08-22 | 2009-03-04 | 纳幕尔杜邦公司 | 钴取代的氧化铬组合物,它们的制备以及它们作为催化剂和催化剂前体的用途 |
| DE10242223A1 (de) | 2002-09-12 | 2004-03-25 | Clariant Gmbh | Verfahren zur Hydrodechlorierung von kernchlorierten ortho-Xylolen |
| US6740146B2 (en) | 2002-09-12 | 2004-05-25 | Edward L. Simonds | Oxygen concentrator |
| FR2845077A1 (fr) | 2002-09-26 | 2004-04-02 | Atofina | Procede d'abaissement de la teneur en matieres organiques et produits azotes contenus dans des effluents bromures |
| CN1203032C (zh) | 2002-11-12 | 2005-05-25 | 石油大学(北京) | 以复合离子液体为催化剂制备烷基化油剂的方法 |
| US7060865B2 (en) | 2002-11-12 | 2006-06-13 | Exxonmobil Chemical Patents Inc. | Recovery of C4 olefins from a product stream comprising C4 olefins, dimethyl ether and C5+ hydrocarbons |
| US7199083B2 (en) | 2002-12-06 | 2007-04-03 | Self Generating Foam Incoporated | Self-generating foamed drilling fluids |
| DE10257499A1 (de) | 2002-12-10 | 2004-07-01 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 1-Olefinen durch katalytische Spaltung von 1-Alkoxyalkanen |
| WO2004058835A1 (en) | 2002-12-20 | 2004-07-15 | Exxonmobil Chemical Patents Inc. | Polymers substantially free of long chain branching |
| EP1572752B1 (en) | 2002-12-20 | 2014-08-13 | ExxonMobil Chemical Patents Inc. | Polymerization processes |
| EP1440939A1 (en) | 2003-01-07 | 2004-07-28 | Humboldt-Universität zu Berlin | Method for the preparation of amorphous metal fluorides |
| DE10303304A1 (de) | 2003-01-28 | 2004-07-29 | Ruhrgas Ag | Verfahren zum Herstellen nichtaromatischer Kohlenwassersstoffe |
| US7265193B2 (en) | 2003-01-31 | 2007-09-04 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| US20040158108A1 (en) | 2003-02-06 | 2004-08-12 | Snoble Karel A.J. | Purification of alcohol |
| KR100501922B1 (ko) | 2003-02-19 | 2005-07-18 | 에스케이 주식회사 | 메탄올로부터 디메틸에테르의 제조방법 |
| US7091391B2 (en) | 2003-03-19 | 2006-08-15 | Stauffer John E | Methane to olefins |
| FR2852866B1 (fr) | 2003-03-25 | 2006-07-14 | Bp Lavera Snc | Compose metallique fixe sur un support, procede de preparation et utilisation du compose dans des reactions de metathese d'hydrocarbure |
| US20040187684A1 (en) | 2003-03-26 | 2004-09-30 | Saleh Elomari | Using molecular sieve SSZ-65 for reduction of oxides of nitrogen in a gas stream |
| US7011811B2 (en) | 2003-03-26 | 2006-03-14 | Chevron U.S.A. Inc. | Molecular sieve SSZ-65 composition of matter and synthesis thereof |
| US7083714B2 (en) | 2003-03-26 | 2006-08-01 | Chevron U.S.A. Inc. | Hydrocarbon conversion using molecular sieve SSZ-65 |
| US7301060B2 (en) | 2003-03-28 | 2007-11-27 | Ab-Cwt, Llc | Process for conversion of organic, waste, or low-value materials into useful products |
| JP4111035B2 (ja) | 2003-03-31 | 2008-07-02 | 日本ゼオン株式会社 | 重合トナーの製造方法 |
| EP1622857B1 (en) | 2003-04-09 | 2011-10-05 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of alkanediol |
| US7057081B2 (en) | 2003-05-09 | 2006-06-06 | Conocophillips Company | Method for treating alkanes |
| OA13183A (en) | 2003-06-21 | 2006-12-13 | Alan K Richards | Anhydrous processing of methane into methane-sulfonic acid, methanol, and other compounds. |
| US7193093B2 (en) | 2003-06-30 | 2007-03-20 | Shell Oil Company | Process for producing alkylene oxide |
| US20050171393A1 (en) | 2003-07-15 | 2005-08-04 | Lorkovic Ivan M. | Hydrocarbon synthesis |
| AU2004268935B2 (en) | 2003-07-15 | 2010-12-02 | Grt, Inc. | Hydrocarbon synthesis |
| UA84436C2 (ru) | 2003-08-08 | 2008-10-27 | Солвей (Сосьетэ Аноним) | Способ регенерации катализатора гидрирования и способ получения мономера винилхлорида |
| DE10338581A1 (de) | 2003-08-22 | 2005-03-17 | Oxeno Olefinchemie Gmbh | Verfahren zur Erzeugung von tert.-Butanol |
| US6958306B2 (en) | 2003-08-28 | 2005-10-25 | Univation Technologies, Llc | Activated catalyst systems from substituted dialuminoxane complexes |
| US7045670B2 (en) | 2003-09-03 | 2006-05-16 | Synfuels International, Inc. | Process for liquid phase hydrogenation |
| GB0320684D0 (en) * | 2003-09-03 | 2003-10-01 | Bp Chem Int Ltd | Process |
| US7105710B2 (en) | 2003-09-26 | 2006-09-12 | Shell Oil Company | Process of preparing an alkylene glycol |
| PL1675813T3 (pl) | 2003-10-13 | 2008-05-30 | Merck Serono Sa | Sposób wytwarzania para-fenyloalkinylobenzaldehydów |
| US7335802B2 (en) | 2003-10-15 | 2008-02-26 | Shell Oil Company | Methods of preparing branched aliphatic alcohols |
| WO2005035121A2 (en) | 2003-10-16 | 2005-04-21 | Universiteit Gent | Schiff base metal complexes for use as catalysts in organic synthesis |
| US6838576B1 (en) | 2003-10-23 | 2005-01-04 | 3M Innovative Properties Company | Process for preparing functional group-containing olefinic compounds |
| US7196239B2 (en) | 2003-11-19 | 2007-03-27 | Exxonmobil Chemical Patents Inc. | Methanol and ethanol production for an oxygenate to olefin reaction system |
| ES2284071T3 (es) | 2003-11-28 | 2007-11-01 | Firmenich Sa | Compuestos perfumantes del almizcle. |
| WO2005054120A2 (en) | 2003-12-05 | 2005-06-16 | Idaho Research Foundation, Inc. | Polymer-supported metal nanoparticles and method for their manufacture and use |
| US7244795B2 (en) | 2003-12-08 | 2007-07-17 | Univation Technologies, Llc | Polymerization process using metallocene catalyst systems |
| WO2005056525A2 (en) | 2003-12-09 | 2005-06-23 | Bio-Technical Resources | Deacetylation of n-acetylglucosamine |
| US7586017B2 (en) | 2003-12-18 | 2009-09-08 | Exxonmobil Chemical Patents Inc. | Hydrogenation |
| US7064238B2 (en) * | 2004-01-02 | 2006-06-20 | Marathon Oil Company | Conversion of alkanes to oxygenates |
| FR2865731B1 (fr) | 2004-01-30 | 2007-09-07 | Solvay | Procede de fabrication d'un hydrofluoroalcane |
| FR2866023B1 (fr) | 2004-02-05 | 2007-10-12 | Rhodia Chimie Sa | Procede de preparation d'un compose fluoaromatique a partir d'un compose aminoaromatique |
| US7429621B2 (en) | 2004-03-12 | 2008-09-30 | University Of Utah Research Foundation | Cyclone reactor and associated methods |
| WO2005095310A2 (en) | 2004-03-23 | 2005-10-13 | Shell Internationale Research Maatschappij B.V. | The utilization of zirconium and zirconium based alloys for the containment of halogen containing environments used in the production of olefins, alcohols, ethers, ethoxylates glycols, and olefin oxides from alkanes |
| US20060100469A1 (en) | 2004-04-16 | 2006-05-11 | Waycuilis John J | Process for converting gaseous alkanes to olefins and liquid hydrocarbons |
| US7244867B2 (en) | 2004-04-16 | 2007-07-17 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
| JP5027655B2 (ja) | 2004-04-20 | 2012-09-19 | ユーオーピー エルエルシー | 結晶性アルミノシリケートゼオライト質組成物：ｕｚｍ−１５ |
| US7091387B2 (en) | 2004-04-21 | 2006-08-15 | Shell Oil Company | Process to convert alkanes into primary alcohols |
| US7462752B2 (en) | 2004-04-21 | 2008-12-09 | Shell Oil Company | Process to convert linear alkanes into alpha olefins |
| CN1972867B (zh) | 2004-04-23 | 2010-11-03 | 环球油品公司 | 高氧化硅沸石uzm-5hs |
| WO2005110953A1 (en) | 2004-04-30 | 2005-11-24 | Shell Internationale Research Maatschappij B.V. | Derivatives of alcohols and olefins |
| US7435760B2 (en) | 2004-05-14 | 2008-10-14 | Battelle Memorial Institute | Method of generating hydrocarbon reagents from diesel, natural gas and other logistical fuels |
| CN100537018C (zh) | 2004-06-16 | 2009-09-09 | 陶氏环球技术公司 | 用于齐格勒-纳塔研究的装置和方法 |
| CN1972886B (zh) | 2004-06-23 | 2010-05-05 | 株式会社德山 | 多卤代金刚十四烷类及其衍生物的制造方法 |
| DE102004030943B4 (de) | 2004-06-26 | 2013-10-02 | Evonik Oxeno Gmbh | Verfahren zur Herstellung von tert.-Butanol aus Isobuten-haltigen Kohlenwasserstoffgemischen |
| ATE454370T1 (de) | 2004-07-21 | 2010-01-15 | Dow Global Technologies Inc | Umwandlung eines mehrfach hydroxylierten aliphatischen kohlenwasserstoffes oder esters daraus in ein chlorhydrin |
| US7429683B2 (en) | 2004-07-27 | 2008-09-30 | Eastman Kodak Company | Process of maing naphthacene from propargyl alcohol |
| WO2006015824A1 (en) | 2004-08-13 | 2006-02-16 | Exxonmobil Chemical Patents Inc. | Process for producing sec-butyl benzene |
| US7371916B1 (en) | 2004-09-16 | 2008-05-13 | Uop Llc | Conversion of an alcoholic oxygenate to propylene using moving bed technology and an etherification step |
| US7271303B1 (en) | 2004-09-22 | 2007-09-18 | Uop Llc | Multi-zone process for the production of diesel and aromatic compounds |
| CA2582295A1 (en) | 2004-09-30 | 2006-04-13 | Chevron U.S.A. Inc. | Molecular sieve ssz-65 |
| DE602005019081D1 (de) | 2004-10-15 | 2010-03-11 | Toagosei Co Ltd | Verfahren zur herstellung eines metalloxidkatalysators |
| GB0423586D0 (en) | 2004-10-22 | 2004-11-24 | United States Borax Inc | Selective oxidation of organic compounds |
| EP1817102A1 (en) | 2004-11-12 | 2007-08-15 | Velocys, Inc. | Process using microchannel technology for conducting alkylation or acylation reaction |
| TWI332418B (en) | 2004-11-18 | 2010-11-01 | Rohm & Haas | Hybrid catalyst systems and hybrid process for converting alkanes to alkenes and to their corresponding oxygenated products |
| EP1824599B1 (en) | 2004-12-21 | 2020-06-17 | Albemarle Netherlands B.V. | Attrition-resistant catalyst, a process for its preparation and its use |
| EP2377610A3 (en) | 2004-12-22 | 2012-02-08 | E. I. Du Pont De Nemours And Company | Process for increasing the fluorine content by photochemical reactions |
| US20080108856A1 (en) | 2004-12-23 | 2008-05-08 | Michel Strebelle | Process For The Manufacture Of 1,2-Dichloroethane |
| BRPI0519628A2 (pt) | 2004-12-23 | 2009-02-25 | Solvay | processos para a fabricaÇço de 1,2-dicloroetano, de cloreto de vinila e de cloreto de polivinila |
| AR053423A1 (es) | 2004-12-23 | 2007-05-09 | Solvay | Proceso de elaboracion de 1,2-dicloretano |
| BRPI0518657A2 (pt) | 2004-12-23 | 2008-12-02 | Solvay | processos para a fabricaÇço de 1,2-dicloroetano e para a fabricaÇço de cloreto de vinila |
| US7537685B2 (en) | 2004-12-23 | 2009-05-26 | Chevron U.S.A. Inc. | Hydrocarbon conversion using molecular sieve SSZ-71 |
| CN101115679B (zh) | 2004-12-23 | 2012-10-03 | 切夫里昂美国公司 | 分子筛ssz-70组合物及其合成 |
| EP1843975B1 (en) | 2004-12-23 | 2014-06-11 | Chevron U.S.A. Inc. | Molecular sieve ssz-70 composition of matter and synthesis thereof |
| DE102005003109B4 (de) | 2005-01-22 | 2015-02-12 | Air Liquide Global E&C Solutions Germany Gmbh | Verfahren zur Herstellung von synthetischen Kraftstoffen aus Oxigenaten |
| US7253328B2 (en) | 2005-01-24 | 2007-08-07 | John Stauffer | Method for producing vinyl chloride monomer |
| WO2006104909A2 (en) | 2005-03-28 | 2006-10-05 | Shell Internationale Research Maatschappij B.V. | Catalytic distillation process for primary haloalkanes |
| US20060229475A1 (en) | 2005-04-11 | 2006-10-12 | Weiss Michael J | Synthesis of hydroxylated hydrocarbons |
| US20060229228A1 (en) | 2005-04-11 | 2006-10-12 | Zachary John Anthony Komon | Method of making alkoxylates |
| EP1869720A4 (en) | 2005-04-15 | 2011-09-21 | Du Pont | SUBSTITUTED ARYL-ETHYLENE AROMATIC COMPOUNDS AND USE AS ORGANIC SEMICONDUCTORS |
| ITMI20050723A1 (it) | 2005-04-21 | 2006-10-22 | Consiglio Nazionale Ricerche | Metodo di produzione del biodiesel |
| MX2007013735A (es) | 2005-05-04 | 2008-01-28 | Dow Global Technologies Inc | Halogenacion oxidante de hidrocarburos de c1 a hidrocarburos de c1 halogenados. |
| EA200702553A1 (ru) | 2005-05-20 | 2008-06-30 | Солвей (Сосьете Аноним) | Способ получения хлоргидрина |
| WO2007017900A2 (en) | 2005-05-26 | 2007-02-15 | Sisir Kumar Mandal | Preparation of para dichlorobenzene from benzene or mono chlorobenzene |
| US20060270863A1 (en) | 2005-05-27 | 2006-11-30 | Amyris Biotechnologies | Conversion of amorpha-4,11-diene to artemisinin and artemisinin precursors |
| CA2510093C (en) | 2005-06-16 | 2009-09-29 | Apotex Pharmachem Inc. | Novel process for the preparation of.alpha.-chlorovinyl, .alpha.,.alpha.-dichloro, and acetylenes from ketones |
| CN101242887B (zh) | 2005-06-23 | 2011-12-14 | 切夫里昂美国公司 | 分子筛ssz-56组合物及其合成 |
| US7442354B2 (en) | 2005-06-23 | 2008-10-28 | Chevron U.S.A. Inc. | Treatment of engine exhaust using molecular sieve SSZ-56 |
| US7226569B2 (en) | 2005-06-23 | 2007-06-05 | Chevron U.S.A. Inc. | Reduction of oxides of nitrogen in a gas stream using molecular sieve SSZ-56 |
| KR101310994B1 (ko) | 2005-06-23 | 2013-09-24 | 셰브런 유.에스.에이.인크. | 분자체 ｓｓｚ-56 조성물 및 이의 합성 |
| US7390395B2 (en) | 2005-06-23 | 2008-06-24 | Saleh Elomari | Hydrocarbon conversion using molecular sieve SSZ-56 |
| US7084308B1 (en) | 2005-07-29 | 2006-08-01 | Stauffer John E | Manufacture of formaldehyde from methyl bromide |
| US8957259B2 (en) | 2005-09-30 | 2015-02-17 | Battelle Memorial Institute | Dimethyl ether production from methanol and/or syngas |
| CN101287693B (zh) | 2005-10-07 | 2012-04-04 | 巴杰许可有限责任公司 | 双酚-a装置收率增强 |
| US7683230B2 (en) | 2005-10-27 | 2010-03-23 | Stauffer John E | Methyl bromide to olefins |
| CA2627378A1 (en) | 2005-10-28 | 2007-05-03 | Shell Internationale Research Maatschappij B.V. | Internal olefins process |
| US7888520B2 (en) | 2005-12-21 | 2011-02-15 | University Of Saskatchewan | Process for the preparation of biodiesel |
| US20070213545A1 (en) | 2005-12-22 | 2007-09-13 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| US20070197801A1 (en) | 2005-12-22 | 2007-08-23 | Bolk Jeroen W | Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitables for such a process |
| US7432402B2 (en) | 2005-12-28 | 2008-10-07 | Chevron U.S.A. | Partial oxidation using molecular sieve SSZ-74 |
| US7357904B2 (en) | 2005-12-28 | 2008-04-15 | Chevron Corporation | Reduction of oxides of nitrogen in a gas stream using molecular sieve SSZ-74 |
| US7422732B2 (en) | 2005-12-28 | 2008-09-09 | Chevron U.S.A. Inc | Synthesis of amines using molecular sieve SSZ-74 |
| US20070149778A1 (en) | 2005-12-28 | 2007-06-28 | Chevron U.S.A. Inc. | Beckmann rearrangement using molecular sieve ssz-74 |
| US7510697B2 (en) | 2005-12-28 | 2009-03-31 | Chevron U.S.A. Inc. | Molecular sieve SSZ-74 composition of matter and synthesis thereof |
| US7762059B2 (en) | 2005-12-28 | 2010-07-27 | Chevron U.S.A. Inc. | Treatment of engine exhaust using molecular sieve SSZ-74 |
| US7473807B2 (en) | 2005-12-28 | 2009-01-06 | Chevron Usa, Inc. | Acylation using molecular sieve SSZ-74 |
| US20080115666A1 (en) | 2005-12-28 | 2008-05-22 | Chevron U.S.A. Inc. | Gas separation using molecular sieve ssz-74 |
| US7485766B2 (en) | 2005-12-28 | 2009-02-03 | Chevron U.S.A., Inc. | Oxygenate conversion using molecular sieve SSZ-74 |
| WO2007092410A2 (en) | 2006-02-03 | 2007-08-16 | Grt, Inc. | Separation of light gases from halogens |
| EA015515B1 (ru) | 2006-02-03 | 2011-08-30 | ДжиАрТи, ИНК. | Непрерывный способ превращения природного газа в жидкие углеводороды |
| GB0602424D0 (en) | 2006-02-07 | 2006-03-22 | Sinclair Pharmaceuticals Ltd | Compounds |
| EP2004579A2 (en) | 2006-03-23 | 2008-12-24 | Velocys Inc. | Process for making styrene using microchannel process technology |
| EP1837320A1 (en) | 2006-03-23 | 2007-09-26 | ETH Zürich | Production of saturated C2 to C5 hydrocarbons |
| JP2007269708A (ja) | 2006-03-31 | 2007-10-18 | Sumitomo Chemical Co Ltd | 第３級オレフィンおよび脂肪族アルコールの製造方法 |
| US20070238905A1 (en) | 2006-04-05 | 2007-10-11 | Victor Manuel Arredondo | Processes for converting glycerol to glycerol ethers |
| BRPI0601460B1 (pt) | 2006-04-26 | 2015-11-10 | Petroleo Brasileiro Sa | processo para hidroconversão de mistura de óleos orgânicos de diferentes origens |
| EP2035140A1 (en) | 2006-05-08 | 2009-03-18 | ExxonMobil Chemical Patents, Inc., A Corporation of the State of Delaware | Improved catalyst composition |
| CN101437783B (zh) | 2006-05-08 | 2012-12-12 | 埃克森美孚化学专利公司 | 有机化合物转化方法 |
| US7304193B1 (en) | 2006-05-18 | 2007-12-04 | Uop Llc | Integrated process for aromatics production |
| US7268263B1 (en) | 2006-05-18 | 2007-09-11 | Uop Llc | Integrated process for aromatics production |
| KR101385396B1 (ko) | 2006-06-08 | 2014-04-14 | 셰브런 유.에스.에이.인크. | 분자체 ｓｓｚ-75 조성물 및 이의 합성 |
| WO2007141295A1 (en) | 2006-06-08 | 2007-12-13 | High Point Pharmaceuticals, Llc | Process for preparing phenoxy acetic acid derivatives |
| WO2007142745A1 (en) | 2006-06-09 | 2007-12-13 | Exxonmobil Chemical Patents Inc. | Intergrown molecular sieve, its synthesis and its use in the conversion of oxygenates to olefins |
| CA2664102A1 (en) | 2006-09-21 | 2008-03-27 | Albemarle Corporation | Methods for conversion of methane to useful hydrocarbons, catalysts for use therein, and regeneration of the catalysts |
| RU2009114835A (ru) | 2006-09-21 | 2010-10-27 | Альбемарл Корпорейшн (Us) | Способы превращения метана в полезные углеводороды и катализаторы для применения в них |
| US20100030005A1 (en) | 2007-02-28 | 2010-02-04 | Sauer Joe D | Processes for producing higher hydrocarbons from methane and bromine |
| EA201200888A1 (ru) | 2007-05-14 | 2013-02-28 | Грт, Инк. | Способ конверсии углеводородного сырья с электролитическим извлечением галогенов |
| EA017699B1 (ru) | 2007-05-24 | 2013-02-28 | Грт, Инк. | Зонный реактор с обратимым захватыванием и высвобождением галогеноводородов |
| WO2008157044A1 (en) | 2007-06-14 | 2008-12-24 | Albemarle Corporation | Processes for producing higher hydrocarbons from methane |
| WO2008157047A1 (en) | 2007-06-14 | 2008-12-24 | Albemarle Corporation | Processes for producing hydrogen from hydrocarbon feed sources |
| WO2008157046A1 (en) | 2007-06-14 | 2008-12-24 | Albemarle Corporation | Processes for producing higher hydrocarbons from methane |
| WO2008157045A1 (en) | 2007-06-14 | 2008-12-24 | Albemarle Corporation | Processes for producing higher hydrocarbons from hydrocarbon feed sources |
| WO2008157043A1 (en) | 2007-06-14 | 2008-12-24 | Albemarle Corporation | Processes for producing higher hydrocarbons from methane |
| CA2730934C (en) | 2008-07-18 | 2017-07-04 | Grt, Inc. | Continuous process for converting natural gas to liquid hydrocarbons |
-
2004
- 2004-07-15 AU AU2004268935A patent/AU2004268935B2/en not_active Ceased
- 2004-07-15 US US10/893,418 patent/US20050038310A1/en not_active Abandoned
- 2004-07-15 WO PCT/US2004/023036 patent/WO2005021468A1/en not_active Ceased
- 2004-07-15 JP JP2006520386A patent/JP2007525477A/ja active Pending
- 2004-07-15 RU RU2006104623/04A patent/RU2366642C2/ru not_active IP Right Cessation
- 2004-07-15 EP EP04778505A patent/EP1682465A1/en not_active Withdrawn
- 2004-07-15 MX MXPA06000470A patent/MXPA06000470A/es active IP Right Grant
- 2004-07-15 CA CA2532367A patent/CA2532367C/en not_active Expired - Fee Related
-
2006
- 2006-01-11 NO NO20060166A patent/NO20060166L/no not_active Application Discontinuation
-
2008
- 2008-07-02 US US12/217,311 patent/US7847139B2/en not_active Expired - Fee Related
-
2011
- 2011-12-26 JP JP2011284062A patent/JP2012092134A/ja active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60225647A (ja) * | 1984-03-29 | 1985-11-09 | モ−ビル オイル コ−ポレ−ション | アルカン類のオキシハロゲン化及び縮合用触媒 |
| JP2004529189A (ja) * | 2001-05-21 | 2004-09-24 | ダウ グローバル テクノロジーズ インコーポレイティド | ハロゲン化ｃ１炭化水素を生成させるｃ１炭化水素の酸化的ハロゲン化およびこれに関連する統合されたプロセス |
| US20020198416A1 (en) * | 2001-06-20 | 2002-12-26 | Zhou Xiao Ping | Integrated process for synthesizing alcohols, ethers, and olefins from alkanes |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011202183A (ja) * | 2004-04-16 | 2011-10-13 | Marathon Gtf Technology Ltd | ガス状アルカンを液状炭化水素に変換する方法 |
| JP2009512754A (ja) * | 2005-10-19 | 2009-03-26 | マラソン オイル カンパニー | ガス状アルカンをプロセスオレフィン及び液体炭化水素に転換するプロセス |
| JP2009525395A (ja) * | 2006-02-03 | 2009-07-09 | ジーアールティー，インコーポレイティド | 天然ガスを液化炭化水素に転化する連続的な方法 |
| JP2011524873A (ja) * | 2008-06-13 | 2011-09-08 | マラソン ジーティーエフ テクノロジー， リミテッド | 臭素の回収のために電気分解を用いる気状アルカンから液体炭化水素への臭素ベースの変換方法およびシステム |
| JP2011528664A (ja) * | 2008-07-18 | 2011-11-24 | ジーアールティー，インコーポレイティド | 天然ガスを液化炭化水素に添加する連続的な方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2005021468A1 (en) | 2005-03-10 |
| AU2004268935A1 (en) | 2005-03-10 |
| US20080269534A1 (en) | 2008-10-30 |
| AU2004268935B2 (en) | 2010-12-02 |
| CA2532367A1 (en) | 2005-03-10 |
| US7847139B2 (en) | 2010-12-07 |
| JP2012092134A (ja) | 2012-05-17 |
| EP1682465A1 (en) | 2006-07-26 |
| NO20060166L (no) | 2006-04-05 |
| CA2532367C (en) | 2013-04-23 |
| RU2006104623A (ru) | 2007-08-20 |
| US20050038310A1 (en) | 2005-02-17 |
| RU2366642C2 (ru) | 2009-09-10 |
| MXPA06000470A (es) | 2006-08-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2012092134A (ja) | 炭化水素の合成 | |
| US7964764B2 (en) | Hydrocarbon synthesis | |
| RU2356876C2 (ru) | Способ синтеза олефинов | |
| KR101740419B1 (ko) | 천연 가스를 액체 탄화수소로 변환시키는 연속 공정 | |
| JP5940836B2 (ja) | 天然ガスを液化炭化水素に転化する連続的な方法 | |
| EP1999090B1 (en) | Production of saturated c2 to c5 hydrocarbons | |
| MXPA06001927A (en) | Method and apparatus for synthesizing olefins, alcohols, ethers, and aldehydes |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20091001 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20091020 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20091224 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20100106 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20100219 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20100226 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100420 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20101214 |
|
| A524 | Written submission of copy of amendment under article 19 pct |
Free format text: JAPANESE INTERMEDIATE CODE: A524 Effective date: 20110310 |
|
| RD13 | Notification of appointment of power of sub attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7433 Effective date: 20110310 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20110310 Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110310 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20110823 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20111226 |
|
| A524 | Written submission of copy of amendment under article 19 pct |
Free format text: JAPANESE INTERMEDIATE CODE: A524 Effective date: 20111226 |
|
| A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20120111 |
|
| A912 | Re-examination (zenchi) completed and case transferred to appeal board |
Free format text: JAPANESE INTERMEDIATE CODE: A912 Effective date: 20120406 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20121225 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20130107 |