IT1265051B1 - Processo per l'alchilazione di idrocarburi alifatici con olefine - Google Patents

Processo per l'alchilazione di idrocarburi alifatici con olefine

Info

Publication number
IT1265051B1
IT1265051B1 IT93MI001796A ITMI931796A IT1265051B1 IT 1265051 B1 IT1265051 B1 IT 1265051B1 IT 93MI001796 A IT93MI001796 A IT 93MI001796A IT MI931796 A ITMI931796 A IT MI931796A IT 1265051 B1 IT1265051 B1 IT 1265051B1
Authority
IT
Italy
Prior art keywords
aliphatic hydrocarbons
olefins
alkyling
silica
hammet
Prior art date
Application number
IT93MI001796A
Other languages
English (en)
Inventor
Mario Gabriele Clerici
Carlo Perego
Angelis Alberto De
Luciano Montanari
Original Assignee
Eniricerche Spa
Agip Petroli
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eniricerche Spa, Agip Petroli filed Critical Eniricerche Spa
Publication of ITMI931796A0 publication Critical patent/ITMI931796A0/it
Priority to IT93MI001796A priority Critical patent/IT1265051B1/it
Priority to EP94202241A priority patent/EP0638363B1/en
Priority to DE69423398T priority patent/DE69423398T2/de
Priority to AT94202241T priority patent/ATE190521T1/de
Priority to ES94202241T priority patent/ES2142907T3/es
Priority to PT94202241T priority patent/PT638363E/pt
Priority to DK94202241T priority patent/DK0638363T3/da
Priority to US08/283,509 priority patent/US5571762A/en
Priority to AU68853/94A priority patent/AU683661B2/en
Priority to CA002129389A priority patent/CA2129389A1/en
Priority to HU9402296A priority patent/HU214083B/hu
Priority to KR1019940019230A priority patent/KR100194230B1/ko
Priority to RU94028658A priority patent/RU2126295C1/ru
Priority to JP6202916A priority patent/JPH07165414A/ja
Priority to BR9403189A priority patent/BR9403189A/pt
Priority to PL94304574A priority patent/PL179479B1/pl
Priority to PL94335288A priority patent/PL179947B1/pl
Priority to CN94115032A priority patent/CN1054152C/zh
Publication of ITMI931796A1 publication Critical patent/ITMI931796A1/it
Priority to US08/448,252 priority patent/US5659105A/en
Application granted granted Critical
Publication of IT1265051B1 publication Critical patent/IT1265051B1/it
Priority to MXPA99005011A priority patent/MXPA99005011A/es
Priority to GR20000400668T priority patent/GR3032968T3/el

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B01J31/0227—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C07C2/62—Catalytic processes with acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/025—Sulfonic acids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Silicon Polymers (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Silicon Compounds (AREA)

Abstract

Procedimento per l'alchilazione di idrocarburi alifatici con olefine catalizzato da un materiale a base di silice caratterizzato dal fatto che i gruppi Si-OH superficiali di detta silice sono esterificati con un acido fluoroalchilsolfonico di formula dove n è un numero intero compreso tra 0 e 11, detto materiale presentando una acidità di Hammet Ho ?-12.
IT93MI001796A 1993-08-06 1993-08-06 Processo per l'alchilazione di idrocarburi alifatici con olefine IT1265051B1 (it)

Priority Applications (21)

Application Number Priority Date Filing Date Title
IT93MI001796A IT1265051B1 (it) 1993-08-06 1993-08-06 Processo per l'alchilazione di idrocarburi alifatici con olefine
EP94202241A EP0638363B1 (en) 1993-08-06 1994-08-01 Catalyst based on grafted-silica and process for the alkylation of aliphatic hydrocarbons with olefins
DE69423398T DE69423398T2 (de) 1993-08-06 1994-08-01 Katalysator auf der Basis von funktionalisierte Kieselsaüre und Verfahren zur Alkylierung von aliphatischen Kohlenwasserstoffen mit Olefinen
AT94202241T ATE190521T1 (de) 1993-08-06 1994-08-01 Katalysator auf der basis von funktionalisierte kieselsaüre und verfahren zur alkylierung von aliphatischen kohlenwasserstoffen mit olefinen
ES94202241T ES2142907T3 (es) 1993-08-06 1994-08-01 Catalizador a base de silice injertada y procedimiento para la alquilacion de hidrocarburos alifaticos con olefinas.
PT94202241T PT638363E (pt) 1993-08-06 1994-08-01 Catalisador a base de silica enxertada e processo de alquilacao da hidrocarbonetos alifaticos com olefinas
DK94202241T DK0638363T3 (da) 1993-08-06 1994-08-01 Katalysator på basis af podet silica og fremgangsmåde til alkylering af alifatiske carbonlydrider med olefiner
US08/283,509 US5571762A (en) 1993-08-06 1994-08-01 Catalyst and process for the alkylation of aliphatic hydrocarbons with olefins
AU68853/94A AU683661B2 (en) 1993-08-06 1994-08-02 Process for the alkylation of aliphatic hydrocarbons with olefins
CA002129389A CA2129389A1 (en) 1993-08-06 1994-08-03 Process for the alkylation of aliphatic hydrocarbons with olefins
HU9402296A HU214083B (en) 1993-08-06 1994-08-04 Catalyst, based on silica processes for making thereof and process for the alkylation by use of said catalyst
KR1019940019230A KR100194230B1 (ko) 1993-08-06 1994-08-04 올레핀을 사용하여 지방족 탄화수소를 알킬화 하는 방법
CN94115032A CN1054152C (zh) 1993-08-06 1994-08-05 基于二氧化硅的材料及其制备方法和用途
JP6202916A JPH07165414A (ja) 1993-08-06 1994-08-05 シリカ基材物質
BR9403189A BR9403189A (pt) 1993-08-06 1994-08-05 Material à base de sílica e processo para sua preparação, processo para a alquilação de um hidrocarboneto alifático e processo para regenerar um catalisador
PL94304574A PL179479B1 (pl) 1993-08-06 1994-08-05 Material oparty na krzemionce i sposób jego wytwarzania PL PL
PL94335288A PL179947B1 (pl) 1993-08-06 1994-08-05 Sposób alkilowania weglowodorów alifatycznych PL PL PL PL PL PL
RU94028658A RU2126295C1 (ru) 1993-08-06 1994-08-05 Материал на основе двуокиси кремния, способ получения материала, способ получения катализатора, способ алкилирования алифатического углеводорода, способ регенерации катализатора
US08/448,252 US5659105A (en) 1993-08-06 1995-05-23 Process for the alkylation of aliphatic hydrocarbons with olefins
MXPA99005011A MXPA99005011A (es) 1993-08-06 1999-05-31 Procedimiento para la alquilacion de hidrocarburos alifaticos con olefinas.
GR20000400668T GR3032968T3 (en) 1993-08-06 2000-03-16 Process for the alkylation of aliphatic hydrocarbons with olefins.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT93MI001796A IT1265051B1 (it) 1993-08-06 1993-08-06 Processo per l'alchilazione di idrocarburi alifatici con olefine

Publications (3)

Publication Number Publication Date
ITMI931796A0 ITMI931796A0 (it) 1993-08-06
ITMI931796A1 ITMI931796A1 (it) 1995-02-06
IT1265051B1 true IT1265051B1 (it) 1996-10-28

Family

ID=11366796

Family Applications (1)

Application Number Title Priority Date Filing Date
IT93MI001796A IT1265051B1 (it) 1993-08-06 1993-08-06 Processo per l'alchilazione di idrocarburi alifatici con olefine

Country Status (19)

Country Link
US (2) US5571762A (it)
EP (1) EP0638363B1 (it)
JP (1) JPH07165414A (it)
KR (1) KR100194230B1 (it)
CN (1) CN1054152C (it)
AT (1) ATE190521T1 (it)
AU (1) AU683661B2 (it)
BR (1) BR9403189A (it)
CA (1) CA2129389A1 (it)
DE (1) DE69423398T2 (it)
DK (1) DK0638363T3 (it)
ES (1) ES2142907T3 (it)
GR (1) GR3032968T3 (it)
HU (1) HU214083B (it)
IT (1) IT1265051B1 (it)
MX (1) MXPA99005011A (it)
PL (2) PL179947B1 (it)
PT (1) PT638363E (it)
RU (1) RU2126295C1 (it)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2729968B1 (fr) * 1995-01-27 1997-04-11 Inst Francais Du Petrole Procede d'hydrogenation des diolefines et eventuellement des olefines de coupes hydrocarbures riches en composes aromatiques sur des catalyseurs metalliques impregenes de composes organiques soufres
CN1045305C (zh) * 1995-12-20 1999-09-29 中国石油化工总公司石油化工科学研究院 重整生成油烯烃饱和加氢工艺
DK172907B1 (da) * 1996-06-17 1999-09-27 Topsoe Haldor As Fremgangsmåde til rensning af en carbonhydridstrøm
DE19636064A1 (de) * 1996-09-05 1998-03-12 Basf Ag Verfahren zur Hydrierung
EP1140357A4 (en) * 1997-05-07 2002-05-08 George A Olah NANO-SCALE SOLID SUPER ACID CATALYSTS COMPRISING FREE GROUPS OF FLUOROALKYLSULFONIC ACID OR FLUORO ACID, PERFLUOROALKYLSULFONIC ACID
WO1999008960A1 (fr) * 1997-08-20 1999-02-25 Asahi Kasei Kogyo Kabushiki Kaisha Corps spherique poreux
US6184171B1 (en) * 1998-10-05 2001-02-06 W.R. Grace & Co. -Conn Supported bidentate and tridentate catalyst compositions and olefin polymerization using same
US6277342B1 (en) * 1999-08-23 2001-08-21 Air Products And Chemicals, Inc. Storage and safe delivery of hazardous specialty gases by acid/base reactions with ionic polymers
KR100642775B1 (ko) * 2000-06-17 2006-11-13 주식회사 엘지이아이 김치냉장고의 숙성제어방법 및 장치
US6395673B1 (en) 2000-06-29 2002-05-28 E. I. Du Pont De Nemours And Company Catalyst of mixed fluorosulfonic acids
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
US20030018970A1 (en) * 2001-07-19 2003-01-23 Digeo, Inc. Object representation of television programs within an interactive television system
US20050038310A1 (en) 2003-07-15 2005-02-17 Lorkovic Ivan M. Hydrocarbon synthesis
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
US8329603B2 (en) * 2003-09-16 2012-12-11 Uop Llc Isoparaffin-olefin alkylation
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US20070098619A1 (en) * 2005-10-27 2007-05-03 Harmer Mark A Porous microcomposite of fluorinated sulfonic acid and a network of silica
EP1993951B1 (en) 2006-02-03 2014-07-30 GRT, Inc. Separation of light gases from bromine
AP2012006510A0 (en) 2006-02-03 2012-10-31 Grt Inc Continuous process for converting natural gas to liquid hydrocarbons
MX2009012581A (es) 2007-05-24 2010-03-15 Grt Inc Reactor de zonas que incorpora captura y liberacion de haluro de hidrogeno reversible.
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
US8415517B2 (en) 2008-07-18 2013-04-09 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems

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IT1129809B (it) * 1979-03-26 1986-06-11 Ugine Kuhlmann Composizione catalitica per la conversione di idrocarburi e procedimento per la disidratazione di acidi perfluoroalcansolfonici destinati a fare parte bella composizione
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IT1226550B (it) * 1988-07-29 1991-01-24 Enichem Anic Spa Processo di oligomerizzazione selettiva di olefine e nuovo catalizzatore per tale processo.
US5245100A (en) * 1989-12-18 1993-09-14 Haldor Topsoe, S.A. Alkylation process
DK168520B1 (da) * 1989-12-18 1994-04-11 Topsoe Haldor As Fremgangsmåde til væskefase-alkylering af et carbonhydrid med et olefinalkyleringsmiddel
US5179052A (en) * 1991-03-04 1993-01-12 Texaco Chemical Company One step synthesis of metyl t-butyl ether from 5-butanol using fluorosulfonic acid-modified zeolite catalysts
EP0539277B1 (fr) * 1991-10-25 1996-01-10 Institut Francais Du Petrole Utilisation d'un catalyseur en alkylation de paraffines
CA2099359C (en) * 1992-08-27 1999-06-15 Alan D. Eastman Alkylation catalyst regeneration
US5233119A (en) * 1992-11-09 1993-08-03 Phillips Petroleum Company Alkylation process and catalyst therefor

Also Published As

Publication number Publication date
US5571762A (en) 1996-11-05
DE69423398D1 (de) 2000-04-20
GR3032968T3 (en) 2000-07-31
HU214083B (en) 1997-12-29
PL304574A1 (en) 1995-02-20
PT638363E (pt) 2000-06-30
ES2142907T3 (es) 2000-05-01
DK0638363T3 (da) 2000-07-24
RU94028658A (ru) 1996-06-20
CA2129389A1 (en) 1995-02-07
BR9403189A (pt) 1995-04-11
CN1108293A (zh) 1995-09-13
KR100194230B1 (ko) 1999-06-15
EP0638363A1 (en) 1995-02-15
AU6885394A (en) 1995-02-16
HU9402296D0 (en) 1994-09-28
AU683661B2 (en) 1997-11-20
ATE190521T1 (de) 2000-04-15
PL179479B1 (pl) 2000-09-29
EP0638363B1 (en) 2000-03-15
DE69423398T2 (de) 2000-11-02
PL179947B1 (pl) 2000-11-30
JPH07165414A (ja) 1995-06-27
ITMI931796A1 (it) 1995-02-06
US5659105A (en) 1997-08-19
CN1054152C (zh) 2000-07-05
RU2126295C1 (ru) 1999-02-20
HUT71951A (en) 1996-02-28
ITMI931796A0 (it) 1993-08-06
MXPA99005011A (es) 2004-08-31
KR950005781A (ko) 1995-03-20

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