ITMI941517A0 - Processo multistadio per la (co)polimerizzazione di olefine - Google Patents

Processo multistadio per la (co)polimerizzazione di olefine

Info

Publication number
ITMI941517A0
ITMI941517A0 ITMI941517A ITMI941517A ITMI941517A0 IT MI941517 A0 ITMI941517 A0 IT MI941517A0 IT MI941517 A ITMI941517 A IT MI941517A IT MI941517 A ITMI941517 A IT MI941517A IT MI941517 A0 ITMI941517 A0 IT MI941517A0
Authority
IT
Italy
Prior art keywords
olefins
polymerization
multistage process
multistage
Prior art date
Application number
ITMI941517A
Other languages
English (en)
Inventor
Gabriele Govoni
Mario Sacchetti
Stefano Pasquali
Original Assignee
Spherilene Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Spherilene Srl filed Critical Spherilene Srl
Publication of ITMI941517A0 publication Critical patent/ITMI941517A0/it
Priority to ITMI941517A priority Critical patent/IT1273662B/it
Priority to EP95111234A priority patent/EP0693506B1/en
Priority to ES95111234T priority patent/ES2161810T3/es
Priority to DE69522393T priority patent/DE69522393T2/de
Priority to RU95113175/04A priority patent/RU95113175A/ru
Priority to US08/504,319 priority patent/US6391991B1/en
Priority to JP7184124A priority patent/JPH0859722A/ja
Priority to CN95115261A priority patent/CN1052736C/zh
Priority to CA002154300A priority patent/CA2154300A1/en
Priority to KR1019950021367A priority patent/KR960004380A/ko
Publication of ITMI941517A1 publication Critical patent/ITMI941517A1/it
Application granted granted Critical
Publication of IT1273662B publication Critical patent/IT1273662B/it
Priority to CN99118617A priority patent/CN1267656A/zh

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465Indenes; Completely or partially hydrogenated indenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00Systems containing two condensed rings
    • C07C2602/02Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61925Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
ITMI941517A 1994-07-20 1994-07-20 Procedimento per la preparazione di polimeri amorfi del propiline' IT1273662B (it)

Priority Applications (11)

Application Number Priority Date Filing Date Title
ITMI941517A IT1273662B (it) 1994-07-20 1994-07-20 Procedimento per la preparazione di polimeri amorfi del propiline'
EP95111234A EP0693506B1 (en) 1994-07-20 1995-07-18 Process for the preparation of amorphous polymers of propylene
ES95111234T ES2161810T3 (es) 1994-07-20 1995-07-18 Procedimiento para la preparacion de polimeros amorfos de propileno.
DE69522393T DE69522393T2 (de) 1994-07-20 1995-07-18 Verfahren zur Herstellung von amorphen Propylenpolymeren
RU95113175/04A RU95113175A (ru) 1994-07-20 1995-07-19 Способ получения аморфных полимеров пропилена, способ получения инденового соединения
US08/504,319 US6391991B1 (en) 1994-07-20 1995-07-19 Process for the preparation of amorphous polymers of propylene
JP7184124A JPH0859722A (ja) 1994-07-20 1995-07-20 非晶質のプロピレンのポリマーの製造方法
CN95115261A CN1052736C (zh) 1994-07-20 1995-07-20 无定形丙烯聚合物的制备方法
CA002154300A CA2154300A1 (en) 1994-07-20 1995-07-20 Process for the preparation of amorphous polymers of propylene
KR1019950021367A KR960004380A (ko) 1994-07-20 1995-07-20 무정형 프로필렌 중합체의 제조방법
CN99118617A CN1267656A (zh) 1994-07-20 1999-08-31 制备适用作金属茂配位体的茚化合物的方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI941517A IT1273662B (it) 1994-07-20 1994-07-20 Procedimento per la preparazione di polimeri amorfi del propiline'

Publications (3)

Publication Number Publication Date
ITMI941517A0 true ITMI941517A0 (it) 1994-07-20
ITMI941517A1 ITMI941517A1 (it) 1996-01-20
IT1273662B IT1273662B (it) 1997-07-09

Family

ID=11369318

Family Applications (1)

Application Number Title Priority Date Filing Date
ITMI941517A IT1273662B (it) 1994-07-20 1994-07-20 Procedimento per la preparazione di polimeri amorfi del propiline'

Country Status (10)

Country Link
US (1) US6391991B1 (it)
EP (1) EP0693506B1 (it)
JP (1) JPH0859722A (it)
KR (1) KR960004380A (it)
CN (2) CN1052736C (it)
CA (1) CA2154300A1 (it)
DE (1) DE69522393T2 (it)
ES (1) ES2161810T3 (it)
IT (1) IT1273662B (it)
RU (1) RU95113175A (it)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1277696B1 (it) * 1995-12-22 1997-11-11 Enichem Spa Catalizzatori per la polimerizzazione di alfa-olefine
US5705579A (en) * 1996-07-17 1998-01-06 Phillips Petroleum Company Olefin polymerization
DE19644040A1 (de) * 1996-10-31 1998-05-07 Hoechst Ag Verfahren zur Hydrierung von Metallocenen
SG85238A1 (en) 1998-07-02 2001-12-19 Montell Technology Company Bv Compositions containing substantially amorphous alpha-olefin polymers
JP4358470B2 (ja) 1999-12-28 2009-11-04 バセル テクノロジー カンパニー ビー.ブイ. メタロセン化合物、リガンド、触媒、ポリマーの製造方法及びプロピレンホモポリマー
JP4771938B2 (ja) 2003-05-12 2011-09-14 バーゼル・ポリオレフィン・ゲーエムベーハー 1−ブテンの重合方法
US8247495B2 (en) 2010-02-19 2012-08-21 Exxonmobil Chemical Patents Inc. Elastomeric polymer blends and processes for their production
WO2011087729A2 (en) 2010-01-14 2011-07-21 Exxonmobil Chemical Patents Inc. Processes and apparatus for polymer finishing and packaging
CN105348417B (zh) 2010-01-14 2019-03-01 埃克森美孚化学专利公司 连续溶液聚合的方法和设备
US8425847B2 (en) 2010-01-14 2013-04-23 Exxonmobil Chemical Patents Inc. Processes and apparatus for continuous solution polymerization
WO2011107560A1 (en) * 2010-03-04 2011-09-09 Total Petrochemicals Research Feluy Modified catalyst supports
US20120178333A1 (en) * 2011-01-07 2012-07-12 Rextac Llc Bi-modal Poly-alpha-olefin Blend
US8916659B1 (en) 2013-10-31 2014-12-23 Exxonmobil Chemical Patents Inc. Process and apparatus for continuous solution polymerization
EP3218426B1 (en) 2014-11-12 2022-03-30 ExxonMobil Chemical Patents Inc. Purification of plasticizer and use thereof in a polymer production process and plant
CN107614541B (zh) 2015-06-15 2019-08-09 埃克森美孚化学专利公司 连续溶液聚合方法
WO2018022263A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
CN112334499B (zh) 2018-06-04 2023-03-24 埃克森美孚化学专利公司 具有si-si桥的茂金属
US11198747B2 (en) 2018-06-04 2021-12-14 Exxonmobil Chemical Patents Inc. Catalyst systems including two hafnocene catalyst compounds
WO2020060745A1 (en) 2018-09-19 2020-03-26 Exxonmobil Chemical Patents Inc. Devolatilization processes
KR20210068482A (ko) 2018-09-28 2021-06-09 다우 글로벌 테크놀로지스 엘엘씨 시클로펜테논의 합성
CA3113628A1 (en) * 2018-09-28 2020-04-02 Dow Global Technologies Llc Synthesis of substituted cyclopentadiene compounds and metallocenes
WO2020167399A1 (en) 2019-02-11 2020-08-20 Exxonmobil Chemical Patents Inc. Biphasic polymerization processes and ethylene-based polyolefins therefrom
KR20210023122A (ko) * 2019-08-22 2021-03-04 한화솔루션 주식회사 전이금속 화합물, 이를 포함하는 촉매 및 이들의 제조방법
EP4077424A2 (en) 2019-12-17 2022-10-26 ExxonMobil Chemical Patents Inc. Solution polymerization process for making high-density polyethylene long-chain branching
WO2023097161A1 (en) 2021-11-23 2023-06-01 Exxonmobil Chemical Patents Inc. Plants and processes for forming polymers

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3127133A1 (de) 1981-07-09 1983-01-27 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von polyolefinen und deren copolymerisaten
US4874880A (en) 1987-03-10 1989-10-17 Chisso Corporation Bis(di-, tri- or tetra-substituted-cyclopentadienyl)-zirconium dihalides
US4931417A (en) 1987-11-09 1990-06-05 Chisso Corporation Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure
DE3916553A1 (de) 1989-05-20 1990-11-22 Hoechst Ag Syndio- isoblockpolymer und verfahren zu seiner herstellung
EP0672688B2 (en) 1990-06-22 2002-04-17 ExxonMobil Chemical Patents Inc. Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
ES2071888T3 (es) * 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
TW300901B (it) * 1991-08-26 1997-03-21 Hoechst Ag
TW309523B (it) * 1991-11-30 1997-07-01 Hoechst Ag
EP0575875B1 (en) 1992-06-18 2000-08-09 Montell Technology Company bv Catalysts for the polymerization of olefins
JPH072936A (ja) * 1992-07-10 1995-01-06 Fina Technol Inc アイソタクチツクポリオレフイン製造のための方法及び触媒
EP0582194B1 (de) * 1992-08-03 1998-05-06 TARGOR GmbH Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
NL9201970A (nl) * 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
IT1256260B (it) * 1992-12-30 1995-11-29 Montecatini Tecnologie Srl Polipropilene atattico
IT1256259B (it) * 1992-12-30 1995-11-29 Montecatini Tecnologie Srl Composti mettallocenici aventi leganti di tipo fluorenilico
IT1264680B1 (it) 1993-07-07 1996-10-04 Spherilene Srl Catalizzatori supportati per la polimerizzazione delle olefine
US5491207A (en) * 1993-12-14 1996-02-13 Exxon Chemical Patents Inc. Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system
US5594080A (en) * 1994-03-24 1997-01-14 Leland Stanford, Jr. University Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor

Also Published As

Publication number Publication date
US6391991B1 (en) 2002-05-21
DE69522393T2 (de) 2002-10-17
CN1052736C (zh) 2000-05-24
CN1267656A (zh) 2000-09-27
RU95113175A (ru) 1997-06-27
ITMI941517A1 (it) 1996-01-20
IT1273662B (it) 1997-07-09
KR960004380A (ko) 1996-02-23
EP0693506B1 (en) 2001-08-29
DE69522393D1 (de) 2001-10-04
EP0693506A2 (en) 1996-01-24
CA2154300A1 (en) 1996-01-21
JPH0859722A (ja) 1996-03-05
EP0693506A3 (en) 1998-04-08
ES2161810T3 (es) 2001-12-16
CN1123796A (zh) 1996-06-05

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Legal Events

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TA Fee payment date (situation as of event date), data collected since 19931001

Effective date: 19970725