DE69522393D1 - Verfahren zur Herstellung von amorphen Propylenpolymeren - Google Patents

Verfahren zur Herstellung von amorphen Propylenpolymeren

Info

Publication number
DE69522393D1
DE69522393D1 DE69522393T DE69522393T DE69522393D1 DE 69522393 D1 DE69522393 D1 DE 69522393D1 DE 69522393 T DE69522393 T DE 69522393T DE 69522393 T DE69522393 T DE 69522393T DE 69522393 D1 DE69522393 D1 DE 69522393D1
Authority
DE
Germany
Prior art keywords
preparation
propylene polymers
amorphous propylene
amorphous
polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69522393T
Other languages
English (en)
Other versions
DE69522393T2 (de
Inventor
Luigi Resconi
Fabrizio Piemontesi
Davide Balboni
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Technology Co BV
Original Assignee
Basell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Technology Co BV filed Critical Basell Technology Co BV
Application granted granted Critical
Publication of DE69522393D1 publication Critical patent/DE69522393D1/de
Publication of DE69522393T2 publication Critical patent/DE69522393T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465Indenes; Completely or partially hydrogenated indenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00Systems containing two condensed rings
    • C07C2602/02Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61925Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
DE69522393T 1994-07-20 1995-07-18 Verfahren zur Herstellung von amorphen Propylenpolymeren Expired - Fee Related DE69522393T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI941517A IT1273662B (it) 1994-07-20 1994-07-20 Procedimento per la preparazione di polimeri amorfi del propiline'

Publications (2)

Publication Number Publication Date
DE69522393D1 true DE69522393D1 (de) 2001-10-04
DE69522393T2 DE69522393T2 (de) 2002-10-17

Family

ID=11369318

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69522393T Expired - Fee Related DE69522393T2 (de) 1994-07-20 1995-07-18 Verfahren zur Herstellung von amorphen Propylenpolymeren

Country Status (10)

Country Link
US (1) US6391991B1 (de)
EP (1) EP0693506B1 (de)
JP (1) JPH0859722A (de)
KR (1) KR960004380A (de)
CN (2) CN1052736C (de)
CA (1) CA2154300A1 (de)
DE (1) DE69522393T2 (de)
ES (1) ES2161810T3 (de)
IT (1) IT1273662B (de)
RU (1) RU95113175A (de)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1277696B1 (it) * 1995-12-22 1997-11-11 Enichem Spa Catalizzatori per la polimerizzazione di alfa-olefine
US5705579A (en) * 1996-07-17 1998-01-06 Phillips Petroleum Company Olefin polymerization
DE19644040A1 (de) * 1996-10-31 1998-05-07 Hoechst Ag Verfahren zur Hydrierung von Metallocenen
ATE304556T1 (de) 1998-07-02 2005-09-15 Basell Polyolefine Gmbh Verfahren zur herstellung von amorphen alpha- olefinpolymeren, diese enthaltende zusammensetzungen und verfahren zur herstellung von verbrückten liganden
DE60045930D1 (de) 1999-12-28 2011-06-16 Basell Polyolefine Gmbh Heterocyclische Metallocene und ihre Verwendung in Katalysatorsystemen zur Herstellung von Olefin Polymeren
KR101060985B1 (ko) 2003-05-12 2011-08-31 바젤 폴리올레핀 게엠베하 1-부텐의 중합 방법
US8425847B2 (en) 2010-01-14 2013-04-23 Exxonmobil Chemical Patents Inc. Processes and apparatus for continuous solution polymerization
JP5602249B2 (ja) 2010-01-14 2014-10-08 エクソンモービル・ケミカル・パテンツ・インク 連続的溶液重合のための方法および装置
WO2011087729A2 (en) 2010-01-14 2011-07-21 Exxonmobil Chemical Patents Inc. Processes and apparatus for polymer finishing and packaging
WO2011102946A1 (en) 2010-02-19 2011-08-25 Exxonmobil Chemical Parents Inc. Elastomeric polymer blends and processes for their production
EP2542594B1 (de) * 2010-03-04 2018-02-21 Total Research & Technology Feluy Modifizierte Katalysatorträger
US20120178333A1 (en) * 2011-01-07 2012-07-12 Rextac Llc Bi-modal Poly-alpha-olefin Blend
US8916659B1 (en) 2013-10-31 2014-12-23 Exxonmobil Chemical Patents Inc. Process and apparatus for continuous solution polymerization
EP3218426B1 (de) 2014-11-12 2022-03-30 ExxonMobil Chemical Patents Inc. Reinigung eines weichmachers und verwendung davon in polymerherstellungsverfahren und -anlage
EP3307794B1 (de) 2015-06-15 2019-02-27 ExxonMobil Chemical Patents Inc. Verfahren zur kontinuierlichen lösungspolymerisierung
WO2018022263A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
CN112334499B (zh) 2018-06-04 2023-03-24 埃克森美孚化学专利公司 具有si-si桥的茂金属
US11198747B2 (en) 2018-06-04 2021-12-14 Exxonmobil Chemical Patents Inc. Catalyst systems including two hafnocene catalyst compounds
WO2020060745A1 (en) 2018-09-19 2020-03-26 Exxonmobil Chemical Patents Inc. Devolatilization processes
KR102813863B1 (ko) 2018-09-28 2025-05-29 다우 글로벌 테크놀로지스 엘엘씨 시클로펜테논의 합성
JP7405839B2 (ja) * 2018-09-28 2023-12-26 ダウ グローバル テクノロジーズ エルエルシー 置換シクロペンタジエン化合物およびメタロセンの合成
WO2020167399A1 (en) 2019-02-11 2020-08-20 Exxonmobil Chemical Patents Inc. Biphasic polymerization processes and ethylene-based polyolefins therefrom
KR102687447B1 (ko) * 2019-08-22 2024-07-23 한화솔루션 주식회사 전이금속 화합물, 이를 포함하는 촉매 및 이들의 제조방법
EP4077424A2 (de) 2019-12-17 2022-10-26 ExxonMobil Chemical Patents Inc. Lösungspolymerisationsverfahren zur herstellung von langkettigen polyethylenverzweigungen hoher dichte
KR20240093897A (ko) 2021-11-23 2024-06-24 엑손모빌 케미칼 패턴츠 인코포레이티드 중합체 형성을 위한 플랜트 및 방법

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3127133A1 (de) 1981-07-09 1983-01-27 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von polyolefinen und deren copolymerisaten
US4874880A (en) 1987-03-10 1989-10-17 Chisso Corporation Bis(di-, tri- or tetra-substituted-cyclopentadienyl)-zirconium dihalides
US4931417A (en) 1987-11-09 1990-06-05 Chisso Corporation Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure
DE3916553A1 (de) 1989-05-20 1990-11-22 Hoechst Ag Syndio- isoblockpolymer und verfahren zu seiner herstellung
WO1992000333A2 (en) 1990-06-22 1992-01-09 Exxon Chemical Patents Inc. Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
ES2071888T3 (es) * 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
TW300901B (de) * 1991-08-26 1997-03-21 Hoechst Ag
TW309523B (de) * 1991-11-30 1997-07-01 Hoechst Ag
IL106042A (en) 1992-06-18 1999-05-09 Montell Technology Company Bv Catalysts for the polymerization of olefins obtained from organometallic cyclopentadienyl compounds alumino-organic compounds and water and process for the preparation of an ethylene homo- and copolymer
EP0581754A1 (de) * 1992-07-10 1994-02-02 Fina Technology, Inc. Verfahren und Katalysator für Herstellung isotaktischen Polyolefinen
ES2114978T3 (es) * 1992-08-03 1998-06-16 Targor Gmbh Procedimiento para la obtencion de un polimero de olefina bajo empleo de metalocenos con ligandos indenilo de substitucion especial.
NL9201970A (nl) * 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
IT1256259B (it) * 1992-12-30 1995-11-29 Montecatini Tecnologie Srl Composti mettallocenici aventi leganti di tipo fluorenilico
IT1256260B (it) * 1992-12-30 1995-11-29 Montecatini Tecnologie Srl Polipropilene atattico
IT1264680B1 (it) 1993-07-07 1996-10-04 Spherilene Srl Catalizzatori supportati per la polimerizzazione delle olefine
US5491207A (en) * 1993-12-14 1996-02-13 Exxon Chemical Patents Inc. Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system
US5594080A (en) * 1994-03-24 1997-01-14 Leland Stanford, Jr. University Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor

Also Published As

Publication number Publication date
KR960004380A (ko) 1996-02-23
ITMI941517A0 (it) 1994-07-20
EP0693506A3 (de) 1998-04-08
CN1267656A (zh) 2000-09-27
RU95113175A (ru) 1997-06-27
EP0693506A2 (de) 1996-01-24
CN1052736C (zh) 2000-05-24
US6391991B1 (en) 2002-05-21
EP0693506B1 (de) 2001-08-29
CN1123796A (zh) 1996-06-05
DE69522393T2 (de) 2002-10-17
ITMI941517A1 (it) 1996-01-20
JPH0859722A (ja) 1996-03-05
ES2161810T3 (es) 2001-12-16
CA2154300A1 (en) 1996-01-21
IT1273662B (it) 1997-07-09

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Legal Events

Date Code Title Description
8332 No legal effect for de
8370 Indication related to discontinuation of the patent is to be deleted
8339 Ceased/non-payment of the annual fee