DE69501524D1 - Verfahren zur Herstellung von Propylenblockcopolymeren - Google Patents

Verfahren zur Herstellung von Propylenblockcopolymeren

Info

Publication number
DE69501524D1
DE69501524D1 DE69501524T DE69501524T DE69501524D1 DE 69501524 D1 DE69501524 D1 DE 69501524D1 DE 69501524 T DE69501524 T DE 69501524T DE 69501524 T DE69501524 T DE 69501524T DE 69501524 D1 DE69501524 D1 DE 69501524D1
Authority
DE
Germany
Prior art keywords
preparation
block copolymers
propylene block
propylene
copolymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69501524T
Other languages
English (en)
Other versions
DE69501524T2 (de
Inventor
Toshihiko Sugano
Takao Tayano
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corp filed Critical Mitsubishi Chemical Corp
Application granted granted Critical
Publication of DE69501524D1 publication Critical patent/DE69501524D1/de
Publication of DE69501524T2 publication Critical patent/DE69501524T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Graft Or Block Polymers (AREA)
DE69501524T 1994-07-14 1995-07-13 Verfahren zur Herstellung von Propylenblockcopolymeren Expired - Lifetime DE69501524T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP16240594A JP3357186B2 (ja) 1994-07-14 1994-07-14 プロピレンブロック共重合体の製造法

Publications (2)

Publication Number Publication Date
DE69501524D1 true DE69501524D1 (de) 1998-03-05
DE69501524T2 DE69501524T2 (de) 1998-05-14

Family

ID=15753986

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69501524T Expired - Lifetime DE69501524T2 (de) 1994-07-14 1995-07-13 Verfahren zur Herstellung von Propylenblockcopolymeren

Country Status (4)

Country Link
US (1) US5623022A (de)
EP (1) EP0692505B1 (de)
JP (1) JP3357186B2 (de)
DE (1) DE69501524T2 (de)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT403919B (de) * 1996-02-02 1998-06-25 Danubia Petrochem Polymere Verfahren zur herstellung von katalysatorträgern und geträgerter polyolefin-katalysatoren sowie deren verwendung für die herstellung von polyolefinen
US5968864A (en) * 1996-12-20 1999-10-19 Fina Technology, Inc. Catalyst efficiency for supported metallocene catalyst
JP3657071B2 (ja) * 1996-12-24 2005-06-08 出光興産株式会社 プロピレン−エチレンブロック共重合体
US6030918A (en) * 1997-06-25 2000-02-29 The Regents Of The University Of California Gallium based low-interaction anions
WO2000008080A1 (fr) * 1998-08-04 2000-02-17 Chisso Corporation Copolymere sequence propylene//propylene/olefine et son procede de production
CN1406241A (zh) * 2000-02-08 2003-03-26 埃克森美孚化学专利公司 制备14族桥连双环戊二烯基配体的方法
US6492465B1 (en) 2000-02-08 2002-12-10 Exxonmobil Chemical Patents, Inc. Propylene impact copolymers
DE60137341D1 (de) * 2000-08-22 2009-02-26 Exxonmobil Chem Patents Inc Polypropylen filme
JP4655344B2 (ja) * 2000-08-30 2011-03-23 住友化学株式会社 プロピレン系共重合体とその製造方法およびそのプロピレン系共重合体からなるフィルム
JP2002206007A (ja) * 2000-11-08 2002-07-26 National Institute Of Advanced Industrial & Technology オレフィン系ブロック共重合体の製法
JP4723750B2 (ja) 2001-04-23 2011-07-13 アグリテクノ矢崎株式会社 ゲル被覆種子検査装置
EP1298148A1 (de) * 2001-09-27 2003-04-02 Atofina Research S.A. Katalysatorbestandteil, der ein Metallocen mit zwei Tetrahydroindenyl-Liganden enthält, zur Herstellung eines Polyolefins
EP1300423A1 (de) * 2001-09-27 2003-04-09 Atofina Research S.A. Katalysatorsystem aus einer Mischung von Katalysatorbestandteilen zur Herstellung einer Polyolefinmischung
JPWO2004044013A1 (ja) * 2002-11-14 2006-03-09 出光興産株式会社 プロピレン−エチレンブロック共重合体の製造方法及びプロピレン−エチレンブロック共重合体
US7390575B2 (en) * 2003-10-31 2008-06-24 Japan Polypropylene Corporation Propylene-ethylene random block copolymer and biaxially oriented multi-layer film using the same as a surface layer
JP3670002B2 (ja) * 2005-02-02 2005-07-13 出光興産株式会社 プロピレン−エチレンブロック共重合体
WO2007013585A1 (ja) 2005-07-29 2007-02-01 Japan Polypropylene Corporation プロピレン系ブロック共重合体及びその製造方法
US7533585B2 (en) 2006-12-27 2009-05-19 Caterpillar Inc. Dilution device
JP2007131863A (ja) * 2007-01-18 2007-05-31 Mitsubishi Chemicals Corp プロピレンブロック共重合体の製造法
US8637616B2 (en) * 2010-10-07 2014-01-28 Chevron Philips Chemical Company Lp Bridged metallocene catalyst systems with switchable hydrogen and comonomer effects
US8609793B2 (en) 2010-10-07 2013-12-17 Chevron Phillips Chemical Company Lp Catalyst systems containing a bridged metallocene
US8629292B2 (en) 2010-10-07 2014-01-14 Chevron Phillips Chemical Company Lp Stereoselective synthesis of bridged metallocene complexes

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4924593B1 (de) 1970-04-25 1974-06-24
JPS4930264B1 (de) 1970-06-15 1974-08-12
JPS4945308B2 (de) 1971-08-06 1974-12-03
JPS5810415B2 (ja) 1974-02-27 1983-02-25 三菱油化株式会社 ヘンセイポリプロピレン ノ セイゾウホウ
JPS51136735A (en) 1975-05-22 1976-11-26 Mitsui Toatsu Chem Inc Thermoplastic resin com position
JPS5335789A (en) 1976-09-16 1978-04-03 Mitsui Toatsu Chem Inc Preparation of propylene-ethylene copolymer
JPS54110072A (en) 1978-02-16 1979-08-29 Mitsui Toatsu Chemicals Multilayer container
JPS58222132A (ja) 1982-06-18 1983-12-23 Mitsubishi Petrochem Co Ltd タルク含有ポリプロピレン組成物
JPS6112742A (ja) 1984-06-27 1986-01-21 Mitsubishi Petrochem Co Ltd 外装部材用樹脂組成物
JPS63150343A (ja) 1986-12-12 1988-06-23 Mitsubishi Petrochem Co Ltd 自動車外装部材
US5391629A (en) * 1987-01-30 1995-02-21 Exxon Chemical Patents Inc. Block copolymers from ionic catalysts
DE3904468A1 (de) * 1989-02-15 1990-08-16 Hoechst Ag Polypropylenwachs und verfahren zu seiner herstellung
US5280074A (en) * 1989-12-21 1994-01-18 Hoechst Ag Process for the preparation of a polypropylene molding composition
DE3942363A1 (de) 1989-12-21 1991-06-27 Hoechst Ag Verfahren zur herstellung einer polypropylen-formmasse
DE3942364A1 (de) * 1989-12-21 1991-06-27 Hoechst Ag Verfahren zur herstellung einer polypropylen-formmasse
DE3942365A1 (de) 1989-12-21 1991-06-27 Hoechst Ag Verfahren zur herstellung einer polypropylen-formmasse
EP0513216B1 (de) * 1990-02-09 1997-10-22 Exxon Chemical Patents Inc. Blockcopolymere von ionischen katalysatoren
US5239022A (en) * 1990-11-12 1993-08-24 Hoechst Aktiengesellschaft Process for the preparation of a syndiotactic polyolefin
TW309523B (de) 1991-11-30 1997-07-01 Hoechst Ag
ES2114978T3 (es) * 1992-08-03 1998-06-16 Targor Gmbh Procedimiento para la obtencion de un polimero de olefina bajo empleo de metalocenos con ligandos indenilo de substitucion especial.

Also Published As

Publication number Publication date
JPH0827237A (ja) 1996-01-30
DE69501524T2 (de) 1998-05-14
EP0692505A2 (de) 1996-01-17
EP0692505A3 (de) 1996-10-30
JP3357186B2 (ja) 2002-12-16
EP0692505B1 (de) 1998-01-28
US5623022A (en) 1997-04-22

Similar Documents

Publication Publication Date Title
DE69501524T2 (de) Verfahren zur Herstellung von Propylenblockcopolymeren
DE59509204D1 (de) Verfahren zur Herstellung von Hydrogenalkoxysilanen
DE69519831D1 (de) Verfahren zur Herstellung von Methacryloxypropyl-Dimethylchlorosilan
DE59509333D1 (de) Verfahren zur Herstellung von 3-Acryloxypropylalkoxysilanen
DE69702550T2 (de) Verfahren zur Herstellung von peroxiperfluoropolyxyalkylene
DE69501412D1 (de) Verfahren zur Herstellung von Isocanaten
DE69734526D1 (de) Verfahren zur herstellung von thiazolederivaten
DE19680784T1 (de) Verfahren zur Herstellung von Isobuten-Cyclodien Copolymeren
DE59702177D1 (de) Verfahren zur Herstellung von Hydroxymethylcyclopropan
DE59505473D1 (de) Verfahren zur Herstellung von Glykoloylaniliden
DE59610221D1 (de) Verfahren zur Herstellung von 2-Acetyl-gamma-butyrolacton
DE59501150D1 (de) Verfahren zur Herstellung von Polyisoolefinen
DE69703764T2 (de) Verfahren zur Herstellung von N-Acetonylbenzamide
DE59501307D1 (de) Verfahren zur Herstellung von Fluoranilinen
DE69408279T2 (de) Verfahren zur Herstellung von Copolymeren
DE59500563D1 (de) Verfahren zur Herstellung von N-Alkenylcarbonsäureamiden
DE69703599T2 (de) Verfahren zur Herstellung von 2-H-Heptafluorpropan
DE69737685D1 (de) Verfahren zur herstellung von hexanitrohexaazawurtzitaneen
DE59500564D1 (de) Verfahren zur Herstellung von Benzthiazolylazoanilinen
DE59505555D1 (de) Verfahren zur Herstellung von 1-Chlor-3-methyl-but-2-en
DE69711276T2 (de) Verfahren zur Herstellung von Acetonylbenzamiden
DE59705748D1 (de) Verfahren zur Herstellung von Cyclopentanolen
DE59704518D1 (de) Verfahren zur Herstellung von Isocamphyl-cyclohexanolen
DE69705810T2 (de) Verfahren zur Herstellung von 2-Hydroxy-4-Alkyloxy-Benzophenon
DE69700508D1 (de) Verfahren zur Herstellung von Organodisilanen

Legal Events

Date Code Title Description
8364 No opposition during term of opposition