ITMI931796A0 - Processo per l'alchilazione di idrocarburi alifatici con olefine - Google Patents
Processo per l'alchilazione di idrocarburi alifatici con olefineInfo
- Publication number
- ITMI931796A0 ITMI931796A0 IT93MI1796A ITMI931796A ITMI931796A0 IT MI931796 A0 ITMI931796 A0 IT MI931796A0 IT 93MI1796 A IT93MI1796 A IT 93MI1796A IT MI931796 A ITMI931796 A IT MI931796A IT MI931796 A0 ITMI931796 A0 IT MI931796A0
- Authority
- IT
- Italy
- Prior art keywords
- alkylation
- olefins
- aliphatic hydrocarbons
- hydrocarbons
- aliphatic
- Prior art date
Links
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 title 1
- 150000001336 alkenes Chemical class 0.000 title 1
- 230000029936 alkylation Effects 0.000 title 1
- 238000005804 alkylation reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0215—Sulfur-containing compounds
- B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
- B01J31/0227—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
- B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/56—Addition to acyclic hydrocarbons
- C07C2/58—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/56—Addition to acyclic hydrocarbons
- C07C2/58—Catalytic processes
- C07C2/62—Catalytic processes with acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/025—Sulfonic acids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Silicon Polymers (AREA)
- Silicon Compounds (AREA)
Priority Applications (21)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT93MI001796A IT1265051B1 (it) | 1993-08-06 | 1993-08-06 | Processo per l'alchilazione di idrocarburi alifatici con olefine |
ES94202241T ES2142907T3 (es) | 1993-08-06 | 1994-08-01 | Catalizador a base de silice injertada y procedimiento para la alquilacion de hidrocarburos alifaticos con olefinas. |
PT94202241T PT638363E (pt) | 1993-08-06 | 1994-08-01 | Catalisador a base de silica enxertada e processo de alquilacao da hidrocarbonetos alifaticos com olefinas |
AT94202241T ATE190521T1 (de) | 1993-08-06 | 1994-08-01 | Katalysator auf der basis von funktionalisierte kieselsaüre und verfahren zur alkylierung von aliphatischen kohlenwasserstoffen mit olefinen |
DE69423398T DE69423398T2 (de) | 1993-08-06 | 1994-08-01 | Katalysator auf der Basis von funktionalisierte Kieselsaüre und Verfahren zur Alkylierung von aliphatischen Kohlenwasserstoffen mit Olefinen |
EP94202241A EP0638363B1 (en) | 1993-08-06 | 1994-08-01 | Catalyst based on grafted-silica and process for the alkylation of aliphatic hydrocarbons with olefins |
US08/283,509 US5571762A (en) | 1993-08-06 | 1994-08-01 | Catalyst and process for the alkylation of aliphatic hydrocarbons with olefins |
DK94202241T DK0638363T3 (da) | 1993-08-06 | 1994-08-01 | Katalysator på basis af podet silica og fremgangsmåde til alkylering af alifatiske carbonlydrider med olefiner |
AU68853/94A AU683661B2 (en) | 1993-08-06 | 1994-08-02 | Process for the alkylation of aliphatic hydrocarbons with olefins |
CA002129389A CA2129389A1 (en) | 1993-08-06 | 1994-08-03 | Process for the alkylation of aliphatic hydrocarbons with olefins |
HU9402296A HU214083B (en) | 1993-08-06 | 1994-08-04 | Catalyst, based on silica processes for making thereof and process for the alkylation by use of said catalyst |
KR1019940019230A KR100194230B1 (ko) | 1993-08-06 | 1994-08-04 | 올레핀을 사용하여 지방족 탄화수소를 알킬화 하는 방법 |
PL94335288A PL179947B1 (pl) | 1993-08-06 | 1994-08-05 | Sposób alkilowania weglowodorów alifatycznych PL PL PL PL PL PL |
CN94115032A CN1054152C (zh) | 1993-08-06 | 1994-08-05 | 基于二氧化硅的材料及其制备方法和用途 |
PL94304574A PL179479B1 (pl) | 1993-08-06 | 1994-08-05 | Material oparty na krzemionce i sposób jego wytwarzania PL PL |
RU94028658A RU2126295C1 (ru) | 1993-08-06 | 1994-08-05 | Материал на основе двуокиси кремния, способ получения материала, способ получения катализатора, способ алкилирования алифатического углеводорода, способ регенерации катализатора |
JP6202916A JPH07165414A (ja) | 1993-08-06 | 1994-08-05 | シリカ基材物質 |
BR9403189A BR9403189A (pt) | 1993-08-06 | 1994-08-05 | Material à base de sílica e processo para sua preparação, processo para a alquilação de um hidrocarboneto alifático e processo para regenerar um catalisador |
US08/448,252 US5659105A (en) | 1993-08-06 | 1995-05-23 | Process for the alkylation of aliphatic hydrocarbons with olefins |
MXPA99005011A MXPA99005011A (es) | 1993-08-06 | 1999-05-31 | Procedimiento para la alquilacion de hidrocarburos alifaticos con olefinas. |
GR20000400668T GR3032968T3 (en) | 1993-08-06 | 2000-03-16 | Process for the alkylation of aliphatic hydrocarbons with olefins. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT93MI001796A IT1265051B1 (it) | 1993-08-06 | 1993-08-06 | Processo per l'alchilazione di idrocarburi alifatici con olefine |
Publications (3)
Publication Number | Publication Date |
---|---|
ITMI931796A0 true ITMI931796A0 (it) | 1993-08-06 |
ITMI931796A1 ITMI931796A1 (it) | 1995-02-06 |
IT1265051B1 IT1265051B1 (it) | 1996-10-28 |
Family
ID=11366796
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IT93MI001796A IT1265051B1 (it) | 1993-08-06 | 1993-08-06 | Processo per l'alchilazione di idrocarburi alifatici con olefine |
Country Status (19)
Country | Link |
---|---|
US (2) | US5571762A (it) |
EP (1) | EP0638363B1 (it) |
JP (1) | JPH07165414A (it) |
KR (1) | KR100194230B1 (it) |
CN (1) | CN1054152C (it) |
AT (1) | ATE190521T1 (it) |
AU (1) | AU683661B2 (it) |
BR (1) | BR9403189A (it) |
CA (1) | CA2129389A1 (it) |
DE (1) | DE69423398T2 (it) |
DK (1) | DK0638363T3 (it) |
ES (1) | ES2142907T3 (it) |
GR (1) | GR3032968T3 (it) |
HU (1) | HU214083B (it) |
IT (1) | IT1265051B1 (it) |
MX (1) | MXPA99005011A (it) |
PL (2) | PL179947B1 (it) |
PT (1) | PT638363E (it) |
RU (1) | RU2126295C1 (it) |
Families Citing this family (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2729968B1 (fr) * | 1995-01-27 | 1997-04-11 | Inst Francais Du Petrole | Procede d'hydrogenation des diolefines et eventuellement des olefines de coupes hydrocarbures riches en composes aromatiques sur des catalyseurs metalliques impregenes de composes organiques soufres |
CN1045305C (zh) * | 1995-12-20 | 1999-09-29 | 中国石油化工总公司石油化工科学研究院 | 重整生成油烯烃饱和加氢工艺 |
DK172907B1 (da) * | 1996-06-17 | 1999-09-27 | Topsoe Haldor As | Fremgangsmåde til rensning af en carbonhydridstrøm |
DE19636064A1 (de) * | 1996-09-05 | 1998-03-12 | Basf Ag | Verfahren zur Hydrierung |
JP2001524027A (ja) * | 1997-05-07 | 2001-11-27 | ジョージ エイ オラー | ペンダントフルオロアルキルスルホン酸又はフルオロ、パーフルオロアルキルスルホン酸基を持つナノスケールの固体超酸触媒 |
WO1999008960A1 (fr) * | 1997-08-20 | 1999-02-25 | Asahi Kasei Kogyo Kabushiki Kaisha | Corps spherique poreux |
US6184171B1 (en) * | 1998-10-05 | 2001-02-06 | W.R. Grace & Co. -Conn | Supported bidentate and tridentate catalyst compositions and olefin polymerization using same |
US6277342B1 (en) * | 1999-08-23 | 2001-08-21 | Air Products And Chemicals, Inc. | Storage and safe delivery of hazardous specialty gases by acid/base reactions with ionic polymers |
KR100642775B1 (ko) * | 2000-06-17 | 2006-11-13 | 주식회사 엘지이아이 | 김치냉장고의 숙성제어방법 및 장치 |
US6395673B1 (en) | 2000-06-29 | 2002-05-28 | E. I. Du Pont De Nemours And Company | Catalyst of mixed fluorosulfonic acids |
US7838708B2 (en) | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
US20030018970A1 (en) * | 2001-07-19 | 2003-01-23 | Digeo, Inc. | Object representation of television programs within an interactive television system |
US20050171393A1 (en) | 2003-07-15 | 2005-08-04 | Lorkovic Ivan M. | Hydrocarbon synthesis |
CA2532367C (en) | 2003-07-15 | 2013-04-23 | Grt, Inc. | Hydrocarbon synthesis |
US8329603B2 (en) * | 2003-09-16 | 2012-12-11 | Uop Llc | Isoparaffin-olefin alkylation |
US8173851B2 (en) | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US7674941B2 (en) | 2004-04-16 | 2010-03-09 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US20080275284A1 (en) | 2004-04-16 | 2008-11-06 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
US8642822B2 (en) | 2004-04-16 | 2014-02-04 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor |
US20060100469A1 (en) | 2004-04-16 | 2006-05-11 | Waycuilis John J | Process for converting gaseous alkanes to olefins and liquid hydrocarbons |
US7244867B2 (en) | 2004-04-16 | 2007-07-17 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
US20070098619A1 (en) * | 2005-10-27 | 2007-05-03 | Harmer Mark A | Porous microcomposite of fluorinated sulfonic acid and a network of silica |
US7883568B2 (en) | 2006-02-03 | 2011-02-08 | Grt, Inc. | Separation of light gases from halogens |
KR101433781B1 (ko) | 2006-02-03 | 2014-08-25 | 리액션 35, 엘엘씨 | 탄화수소를 형성하기 위한 시스템 및 방법 |
AU2008256606A1 (en) | 2007-05-24 | 2008-12-04 | Grt, Inc. | Zone reactor incorporating reversible hydrogen halide capture and release |
US8282810B2 (en) | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
US8415517B2 (en) | 2008-07-18 | 2013-04-09 | Grt, Inc. | Continuous process for converting natural gas to liquid hydrocarbons |
US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
US8436220B2 (en) | 2011-06-10 | 2013-05-07 | Marathon Gtf Technology, Ltd. | Processes and systems for demethanization of brominated hydrocarbons |
US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1129809B (it) * | 1979-03-26 | 1986-06-11 | Ugine Kuhlmann | Composizione catalitica per la conversione di idrocarburi e procedimento per la disidratazione di acidi perfluoroalcansolfonici destinati a fare parte bella composizione |
US4847223A (en) * | 1988-04-08 | 1989-07-11 | Concordia University | Superacidic catalysts for low temperature conversion of aqueous ethanol to ethylene |
IT1226550B (it) * | 1988-07-29 | 1991-01-24 | Enichem Anic Spa | Processo di oligomerizzazione selettiva di olefine e nuovo catalizzatore per tale processo. |
US5245100A (en) * | 1989-12-18 | 1993-09-14 | Haldor Topsoe, S.A. | Alkylation process |
DK168520B1 (da) * | 1989-12-18 | 1994-04-11 | Topsoe Haldor As | Fremgangsmåde til væskefase-alkylering af et carbonhydrid med et olefinalkyleringsmiddel |
US5179052A (en) * | 1991-03-04 | 1993-01-12 | Texaco Chemical Company | One step synthesis of metyl t-butyl ether from 5-butanol using fluorosulfonic acid-modified zeolite catalysts |
DE69207548T2 (de) * | 1991-10-25 | 1996-05-15 | Inst Francais Du Petrol | Verwendung von einem Katalysator zur Alkylierung von Paraffinen |
CA2099359C (en) * | 1992-08-27 | 1999-06-15 | Alan D. Eastman | Alkylation catalyst regeneration |
US5233119A (en) * | 1992-11-09 | 1993-08-03 | Phillips Petroleum Company | Alkylation process and catalyst therefor |
-
1993
- 1993-08-06 IT IT93MI001796A patent/IT1265051B1/it active IP Right Grant
-
1994
- 1994-08-01 DK DK94202241T patent/DK0638363T3/da active
- 1994-08-01 PT PT94202241T patent/PT638363E/pt unknown
- 1994-08-01 EP EP94202241A patent/EP0638363B1/en not_active Expired - Lifetime
- 1994-08-01 AT AT94202241T patent/ATE190521T1/de not_active IP Right Cessation
- 1994-08-01 US US08/283,509 patent/US5571762A/en not_active Expired - Fee Related
- 1994-08-01 DE DE69423398T patent/DE69423398T2/de not_active Expired - Fee Related
- 1994-08-01 ES ES94202241T patent/ES2142907T3/es not_active Expired - Lifetime
- 1994-08-02 AU AU68853/94A patent/AU683661B2/en not_active Ceased
- 1994-08-03 CA CA002129389A patent/CA2129389A1/en not_active Abandoned
- 1994-08-04 HU HU9402296A patent/HU214083B/hu not_active IP Right Cessation
- 1994-08-04 KR KR1019940019230A patent/KR100194230B1/ko not_active IP Right Cessation
- 1994-08-05 CN CN94115032A patent/CN1054152C/zh not_active Expired - Fee Related
- 1994-08-05 JP JP6202916A patent/JPH07165414A/ja not_active Withdrawn
- 1994-08-05 PL PL94335288A patent/PL179947B1/pl unknown
- 1994-08-05 BR BR9403189A patent/BR9403189A/pt not_active IP Right Cessation
- 1994-08-05 RU RU94028658A patent/RU2126295C1/ru active
- 1994-08-05 PL PL94304574A patent/PL179479B1/pl unknown
-
1995
- 1995-05-23 US US08/448,252 patent/US5659105A/en not_active Expired - Fee Related
-
1999
- 1999-05-31 MX MXPA99005011A patent/MXPA99005011A/es not_active Application Discontinuation
-
2000
- 2000-03-16 GR GR20000400668T patent/GR3032968T3/el not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP0638363B1 (en) | 2000-03-15 |
US5571762A (en) | 1996-11-05 |
PL179479B1 (pl) | 2000-09-29 |
US5659105A (en) | 1997-08-19 |
PL304574A1 (en) | 1995-02-20 |
ITMI931796A1 (it) | 1995-02-06 |
CN1108293A (zh) | 1995-09-13 |
DE69423398T2 (de) | 2000-11-02 |
ATE190521T1 (de) | 2000-04-15 |
KR950005781A (ko) | 1995-03-20 |
JPH07165414A (ja) | 1995-06-27 |
GR3032968T3 (en) | 2000-07-31 |
AU6885394A (en) | 1995-02-16 |
PL179947B1 (pl) | 2000-11-30 |
CN1054152C (zh) | 2000-07-05 |
CA2129389A1 (en) | 1995-02-07 |
ES2142907T3 (es) | 2000-05-01 |
HU9402296D0 (en) | 1994-09-28 |
KR100194230B1 (ko) | 1999-06-15 |
PT638363E (pt) | 2000-06-30 |
HUT71951A (en) | 1996-02-28 |
EP0638363A1 (en) | 1995-02-15 |
MXPA99005011A (es) | 2004-08-31 |
HU214083B (en) | 1997-12-29 |
IT1265051B1 (it) | 1996-10-28 |
RU94028658A (ru) | 1996-06-20 |
DE69423398D1 (de) | 2000-04-20 |
RU2126295C1 (ru) | 1999-02-20 |
DK0638363T3 (da) | 2000-07-24 |
AU683661B2 (en) | 1997-11-20 |
BR9403189A (pt) | 1995-04-11 |
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