MXPA99005011A - Procedimiento para la alquilacion de hidrocarburos alifaticos con olefinas. - Google Patents

Procedimiento para la alquilacion de hidrocarburos alifaticos con olefinas.

Info

Publication number
MXPA99005011A
MXPA99005011A MXPA99005011A MX9905011A MXPA99005011A MX PA99005011 A MXPA99005011 A MX PA99005011A MX PA99005011 A MXPA99005011 A MX PA99005011A MX 9905011 A MX9905011 A MX 9905011A MX PA99005011 A MXPA99005011 A MX PA99005011A
Authority
MX
Mexico
Prior art keywords
alkylation
aliphatic hydrocarbons
olefins
silica
nso3h
Prior art date
Application number
MXPA99005011A
Other languages
English (en)
Inventor
Montanari Luciano
Original Assignee
Eniricerche Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eniricerche Spa filed Critical Eniricerche Spa
Publication of MXPA99005011A publication Critical patent/MXPA99005011A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B01J31/0227—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C07C2/62—Catalytic processes with acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/025—Sulfonic acids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Silicon Compounds (AREA)
  • Silicon Polymers (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Un procedimiento para alquilacion de hidrocarburos alifaticos con olefinas catalizas con un material a base de silica, caracterizado porque los grupos superficiales Si-OH de esa silica se esterifican con acido fluoroalquilsulfonico de la formula CF3(F2)nSO3H, en donde n es un numero entero entre 0 y 11, el material tiene un acidez Hammett Ho-11.4.
MXPA99005011A 1993-08-06 1999-05-31 Procedimiento para la alquilacion de hidrocarburos alifaticos con olefinas. MXPA99005011A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT93MI001796A IT1265051B1 (it) 1993-08-06 1993-08-06 Processo per l'alchilazione di idrocarburi alifatici con olefine

Publications (1)

Publication Number Publication Date
MXPA99005011A true MXPA99005011A (es) 2004-08-31

Family

ID=11366796

Family Applications (1)

Application Number Title Priority Date Filing Date
MXPA99005011A MXPA99005011A (es) 1993-08-06 1999-05-31 Procedimiento para la alquilacion de hidrocarburos alifaticos con olefinas.

Country Status (19)

Country Link
US (2) US5571762A (es)
EP (1) EP0638363B1 (es)
JP (1) JPH07165414A (es)
KR (1) KR100194230B1 (es)
CN (1) CN1054152C (es)
AT (1) ATE190521T1 (es)
AU (1) AU683661B2 (es)
BR (1) BR9403189A (es)
CA (1) CA2129389A1 (es)
DE (1) DE69423398T2 (es)
DK (1) DK0638363T3 (es)
ES (1) ES2142907T3 (es)
GR (1) GR3032968T3 (es)
HU (1) HU214083B (es)
IT (1) IT1265051B1 (es)
MX (1) MXPA99005011A (es)
PL (2) PL179947B1 (es)
PT (1) PT638363E (es)
RU (1) RU2126295C1 (es)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2729968B1 (fr) * 1995-01-27 1997-04-11 Inst Francais Du Petrole Procede d'hydrogenation des diolefines et eventuellement des olefines de coupes hydrocarbures riches en composes aromatiques sur des catalyseurs metalliques impregenes de composes organiques soufres
CN1045305C (zh) * 1995-12-20 1999-09-29 中国石油化工总公司石油化工科学研究院 重整生成油烯烃饱和加氢工艺
DK172907B1 (da) * 1996-06-17 1999-09-27 Topsoe Haldor As Fremgangsmåde til rensning af en carbonhydridstrøm
DE19636064A1 (de) * 1996-09-05 1998-03-12 Basf Ag Verfahren zur Hydrierung
EP1140357A4 (en) * 1997-05-07 2002-05-08 George A Olah NANO-SCALE SOLID SUPER ACID CATALYSTS COMPRISING FREE GROUPS OF FLUOROALKYLSULFONIC ACID OR FLUORO ACID, PERFLUOROALKYLSULFONIC ACID
WO1999008960A1 (fr) * 1997-08-20 1999-02-25 Asahi Kasei Kogyo Kabushiki Kaisha Corps spherique poreux
US6184171B1 (en) * 1998-10-05 2001-02-06 W.R. Grace & Co. -Conn Supported bidentate and tridentate catalyst compositions and olefin polymerization using same
US6277342B1 (en) * 1999-08-23 2001-08-21 Air Products And Chemicals, Inc. Storage and safe delivery of hazardous specialty gases by acid/base reactions with ionic polymers
KR100642775B1 (ko) * 2000-06-17 2006-11-13 주식회사 엘지이아이 김치냉장고의 숙성제어방법 및 장치
US6395673B1 (en) 2000-06-29 2002-05-28 E. I. Du Pont De Nemours And Company Catalyst of mixed fluorosulfonic acids
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
US20030018970A1 (en) * 2001-07-19 2003-01-23 Digeo, Inc. Object representation of television programs within an interactive television system
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
US20050038310A1 (en) 2003-07-15 2005-02-17 Lorkovic Ivan M. Hydrocarbon synthesis
US8329603B2 (en) * 2003-09-16 2012-12-11 Uop Llc Isoparaffin-olefin alkylation
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US20070098619A1 (en) * 2005-10-27 2007-05-03 Harmer Mark A Porous microcomposite of fluorinated sulfonic acid and a network of silica
KR101335397B1 (ko) 2006-02-03 2013-12-02 지알티, 인코포레이티드 할로겐으로부터 가벼운 기체를 분리하는 방법
NZ588129A (en) 2006-02-03 2012-06-29 Grt Inc Continuous process for converting natural gas to liquid hydrocarbons
CA2687589A1 (en) 2007-05-24 2008-12-04 Grt, Inc. Zone reactor incorporating reversible hydrogen halide capture and release
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
KR101740419B1 (ko) 2008-07-18 2017-05-26 지알티, 인코포레이티드 천연 가스를 액체 탄화수소로 변환시키는 연속 공정
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1129809B (it) * 1979-03-26 1986-06-11 Ugine Kuhlmann Composizione catalitica per la conversione di idrocarburi e procedimento per la disidratazione di acidi perfluoroalcansolfonici destinati a fare parte bella composizione
US4847223A (en) * 1988-04-08 1989-07-11 Concordia University Superacidic catalysts for low temperature conversion of aqueous ethanol to ethylene
IT1226550B (it) * 1988-07-29 1991-01-24 Enichem Anic Spa Processo di oligomerizzazione selettiva di olefine e nuovo catalizzatore per tale processo.
DK168520B1 (da) * 1989-12-18 1994-04-11 Topsoe Haldor As Fremgangsmåde til væskefase-alkylering af et carbonhydrid med et olefinalkyleringsmiddel
US5245100A (en) * 1989-12-18 1993-09-14 Haldor Topsoe, S.A. Alkylation process
US5179052A (en) * 1991-03-04 1993-01-12 Texaco Chemical Company One step synthesis of metyl t-butyl ether from 5-butanol using fluorosulfonic acid-modified zeolite catalysts
DE69207548T2 (de) * 1991-10-25 1996-05-15 Inst Francais Du Petrole Verwendung von einem Katalysator zur Alkylierung von Paraffinen
CA2099359C (en) * 1992-08-27 1999-06-15 Alan D. Eastman Alkylation catalyst regeneration
US5233119A (en) * 1992-11-09 1993-08-03 Phillips Petroleum Company Alkylation process and catalyst therefor

Also Published As

Publication number Publication date
PL304574A1 (en) 1995-02-20
BR9403189A (pt) 1995-04-11
IT1265051B1 (it) 1996-10-28
KR100194230B1 (ko) 1999-06-15
US5659105A (en) 1997-08-19
AU6885394A (en) 1995-02-16
ITMI931796A1 (it) 1995-02-06
CN1054152C (zh) 2000-07-05
RU2126295C1 (ru) 1999-02-20
AU683661B2 (en) 1997-11-20
PL179947B1 (pl) 2000-11-30
HU9402296D0 (en) 1994-09-28
HU214083B (en) 1997-12-29
EP0638363A1 (en) 1995-02-15
CA2129389A1 (en) 1995-02-07
DE69423398D1 (de) 2000-04-20
CN1108293A (zh) 1995-09-13
DK0638363T3 (da) 2000-07-24
RU94028658A (ru) 1996-06-20
ES2142907T3 (es) 2000-05-01
GR3032968T3 (en) 2000-07-31
ATE190521T1 (de) 2000-04-15
ITMI931796A0 (it) 1993-08-06
JPH07165414A (ja) 1995-06-27
PL179479B1 (pl) 2000-09-29
PT638363E (pt) 2000-06-30
US5571762A (en) 1996-11-05
HUT71951A (en) 1996-02-28
EP0638363B1 (en) 2000-03-15
KR950005781A (ko) 1995-03-20
DE69423398T2 (de) 2000-11-02

Similar Documents

Publication Publication Date Title
MXPA99005011A (es) Procedimiento para la alquilacion de hidrocarburos alifaticos con olefinas.
AU643673B2 (en) Catalysts for the polymerization of olefins
LTIP1624A (en) Process for preparing light olefins by dehydrogenation of the corresponding paraffins
NO920723D0 (no) Fremgangsmaate for omdannelse av et raastoff omfattende lineaere olefiner
PT90360A (pt) Processo para a preparacao de n-t-alquil-1,2-diacil-hidrazinas e de composicoes insecticidas que as contem
EP0776972A4 (en) GENE ENCODING THE IgG-Fc-BINDING PROTEIN
DE3465463D1 (en) Process for the valence-isomerisation of olefins
EP0516037A3 (en) A regulating method for regulating the temperature in a reactor utilized in the polymerization of olefines
FR2555163B1 (fr) Procede pour la fabrication d'olefines, de produits aromatiques et de carburants legers
SG45382A1 (en) Process for the conversion of a feedstock comprising linear olefins
FI93462B (fi) Säätömenetelmä olefiinien polymeroinnissa käytetyn reaktorin konsentraatioiden säätämiseksi
DE3474460D1 (en) Method for preparing a synthetic fuel and/or synthetic components for fuels, and the product obtained thereby
RO100669A2 (ro) Ceruri sintetice emulsionabile de tip esteric
FI922625A0 (fi) Säätömenetelmä olefiinien polymeroinnissa käytetyn reaktorin lämpötilan säätämiseksi

Legal Events

Date Code Title Description
FA Abandonment or withdrawal