ES2142907T3 - Catalizador a base de silice injertada y procedimiento para la alquilacion de hidrocarburos alifaticos con olefinas. - Google Patents
Catalizador a base de silice injertada y procedimiento para la alquilacion de hidrocarburos alifaticos con olefinas.Info
- Publication number
- ES2142907T3 ES2142907T3 ES94202241T ES94202241T ES2142907T3 ES 2142907 T3 ES2142907 T3 ES 2142907T3 ES 94202241 T ES94202241 T ES 94202241T ES 94202241 T ES94202241 T ES 94202241T ES 2142907 T3 ES2142907 T3 ES 2142907T3
- Authority
- ES
- Spain
- Prior art keywords
- olefins
- silice
- rental
- grafted
- procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title 1
- 229910052710 silicon Inorganic materials 0.000 abstract 2
- 239000010703 silicon Substances 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract 1
- 230000029936 alkylation Effects 0.000 abstract 1
- 238000005804 alkylation reaction Methods 0.000 abstract 1
- YXZBWJWYWHRIMU-UBPCSPHJSA-I calcium trisodium 2-[bis[2-[bis(carboxylatomethyl)amino]ethyl]amino]acetate ytterbium-169 Chemical compound [Na+].[Na+].[Na+].[Ca+2].[169Yb].[O-]C(=O)CN(CC([O-])=O)CCN(CC(=O)[O-])CCN(CC([O-])=O)CC([O-])=O YXZBWJWYWHRIMU-UBPCSPHJSA-I 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
- B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0215—Sulfur-containing compounds
- B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
- B01J31/0227—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/56—Addition to acyclic hydrocarbons
- C07C2/58—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/56—Addition to acyclic hydrocarbons
- C07C2/58—Catalytic processes
- C07C2/62—Catalytic processes with acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/025—Sulfonic acids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Silicon Polymers (AREA)
- Silicon Compounds (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
UN PROCESO PARA LA ALQUILACION DE HIDROCARBUROS ALIFATICOS CON OLEFINAS CATALIZADAS POR UN MATERIAL BASADO EN SILICIO, CARACTERIZADO EN QUE LOS GRUPOS SI SILICIO ESTAN ESTERIFICADOS CON UN ACIDO FLUOROALQUILSULFONICO DE FORMULA CF3(CF2)NSO3H, DONDE N ES UN NUMERO ENTERO ENTRE 0 Y 11, TENIENDO DICHO MATERIAL UNA ACIDEZ HAMMETT DE HO MENOR O IGUAL QUE - 11.4.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT93MI001796A IT1265051B1 (it) | 1993-08-06 | 1993-08-06 | Processo per l'alchilazione di idrocarburi alifatici con olefine |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2142907T3 true ES2142907T3 (es) | 2000-05-01 |
Family
ID=11366796
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94202241T Expired - Lifetime ES2142907T3 (es) | 1993-08-06 | 1994-08-01 | Catalizador a base de silice injertada y procedimiento para la alquilacion de hidrocarburos alifaticos con olefinas. |
Country Status (19)
Country | Link |
---|---|
US (2) | US5571762A (es) |
EP (1) | EP0638363B1 (es) |
JP (1) | JPH07165414A (es) |
KR (1) | KR100194230B1 (es) |
CN (1) | CN1054152C (es) |
AT (1) | ATE190521T1 (es) |
AU (1) | AU683661B2 (es) |
BR (1) | BR9403189A (es) |
CA (1) | CA2129389A1 (es) |
DE (1) | DE69423398T2 (es) |
DK (1) | DK0638363T3 (es) |
ES (1) | ES2142907T3 (es) |
GR (1) | GR3032968T3 (es) |
HU (1) | HU214083B (es) |
IT (1) | IT1265051B1 (es) |
MX (1) | MXPA99005011A (es) |
PL (2) | PL179479B1 (es) |
PT (1) | PT638363E (es) |
RU (1) | RU2126295C1 (es) |
Families Citing this family (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2729968B1 (fr) * | 1995-01-27 | 1997-04-11 | Inst Francais Du Petrole | Procede d'hydrogenation des diolefines et eventuellement des olefines de coupes hydrocarbures riches en composes aromatiques sur des catalyseurs metalliques impregenes de composes organiques soufres |
CN1045305C (zh) * | 1995-12-20 | 1999-09-29 | 中国石油化工总公司石油化工科学研究院 | 重整生成油烯烃饱和加氢工艺 |
DK172907B1 (da) * | 1996-06-17 | 1999-09-27 | Topsoe Haldor As | Fremgangsmåde til rensning af en carbonhydridstrøm |
DE19636064A1 (de) * | 1996-09-05 | 1998-03-12 | Basf Ag | Verfahren zur Hydrierung |
AU7291598A (en) * | 1997-05-07 | 1998-11-27 | George A. Olah | Nanoscale solid superacid catalysts with pendant fluoroalkylsulfonic acid or fluoro, perfluoroalkylsulfonic acid groups |
WO1999008960A1 (fr) * | 1997-08-20 | 1999-02-25 | Asahi Kasei Kogyo Kabushiki Kaisha | Corps spherique poreux |
US6184171B1 (en) * | 1998-10-05 | 2001-02-06 | W.R. Grace & Co. -Conn | Supported bidentate and tridentate catalyst compositions and olefin polymerization using same |
US6277342B1 (en) * | 1999-08-23 | 2001-08-21 | Air Products And Chemicals, Inc. | Storage and safe delivery of hazardous specialty gases by acid/base reactions with ionic polymers |
KR100642775B1 (ko) * | 2000-06-17 | 2006-11-13 | 주식회사 엘지이아이 | 김치냉장고의 숙성제어방법 및 장치 |
US6395673B1 (en) | 2000-06-29 | 2002-05-28 | E. I. Du Pont De Nemours And Company | Catalyst of mixed fluorosulfonic acids |
US7838708B2 (en) | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
US20030018970A1 (en) * | 2001-07-19 | 2003-01-23 | Digeo, Inc. | Object representation of television programs within an interactive television system |
US20050171393A1 (en) | 2003-07-15 | 2005-08-04 | Lorkovic Ivan M. | Hydrocarbon synthesis |
JP2007525477A (ja) | 2003-07-15 | 2007-09-06 | ジーアールティー インコーポレイテッド | 炭化水素の合成 |
US8329603B2 (en) * | 2003-09-16 | 2012-12-11 | Uop Llc | Isoparaffin-olefin alkylation |
US20080275284A1 (en) | 2004-04-16 | 2008-11-06 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
US20060100469A1 (en) | 2004-04-16 | 2006-05-11 | Waycuilis John J | Process for converting gaseous alkanes to olefins and liquid hydrocarbons |
US8642822B2 (en) | 2004-04-16 | 2014-02-04 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor |
US7674941B2 (en) | 2004-04-16 | 2010-03-09 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US7244867B2 (en) | 2004-04-16 | 2007-07-17 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
US8173851B2 (en) | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US20070098619A1 (en) * | 2005-10-27 | 2007-05-03 | Harmer Mark A | Porous microcomposite of fluorinated sulfonic acid and a network of silica |
SG187456A1 (en) | 2006-02-03 | 2013-02-28 | Grt Inc | Separation of light gases from halogens |
EA020442B1 (ru) | 2006-02-03 | 2014-11-28 | ДжиАрТи, ИНК. | Способ превращения углеводородного сырья (варианты) и система для его осуществления |
EP2148846A1 (en) | 2007-05-24 | 2010-02-03 | GRT, Inc. | Zone reactor incorporating reversible hydrogen halide capture and release |
US8282810B2 (en) | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
CA2730934C (en) | 2008-07-18 | 2017-07-04 | Grt, Inc. | Continuous process for converting natural gas to liquid hydrocarbons |
US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
US8436220B2 (en) | 2011-06-10 | 2013-05-07 | Marathon Gtf Technology, Ltd. | Processes and systems for demethanization of brominated hydrocarbons |
US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1129809B (it) * | 1979-03-26 | 1986-06-11 | Ugine Kuhlmann | Composizione catalitica per la conversione di idrocarburi e procedimento per la disidratazione di acidi perfluoroalcansolfonici destinati a fare parte bella composizione |
US4847223A (en) * | 1988-04-08 | 1989-07-11 | Concordia University | Superacidic catalysts for low temperature conversion of aqueous ethanol to ethylene |
IT1226550B (it) * | 1988-07-29 | 1991-01-24 | Enichem Anic Spa | Processo di oligomerizzazione selettiva di olefine e nuovo catalizzatore per tale processo. |
US5245100A (en) * | 1989-12-18 | 1993-09-14 | Haldor Topsoe, S.A. | Alkylation process |
DK168520B1 (da) * | 1989-12-18 | 1994-04-11 | Topsoe Haldor As | Fremgangsmåde til væskefase-alkylering af et carbonhydrid med et olefinalkyleringsmiddel |
US5179052A (en) * | 1991-03-04 | 1993-01-12 | Texaco Chemical Company | One step synthesis of metyl t-butyl ether from 5-butanol using fluorosulfonic acid-modified zeolite catalysts |
EP0539277B1 (fr) * | 1991-10-25 | 1996-01-10 | Institut Francais Du Petrole | Utilisation d'un catalyseur en alkylation de paraffines |
CA2099359C (en) * | 1992-08-27 | 1999-06-15 | Alan D. Eastman | Alkylation catalyst regeneration |
US5233119A (en) * | 1992-11-09 | 1993-08-03 | Phillips Petroleum Company | Alkylation process and catalyst therefor |
-
1993
- 1993-08-06 IT IT93MI001796A patent/IT1265051B1/it active IP Right Grant
-
1994
- 1994-08-01 EP EP94202241A patent/EP0638363B1/en not_active Expired - Lifetime
- 1994-08-01 PT PT94202241T patent/PT638363E/pt unknown
- 1994-08-01 DE DE69423398T patent/DE69423398T2/de not_active Expired - Fee Related
- 1994-08-01 DK DK94202241T patent/DK0638363T3/da active
- 1994-08-01 ES ES94202241T patent/ES2142907T3/es not_active Expired - Lifetime
- 1994-08-01 AT AT94202241T patent/ATE190521T1/de not_active IP Right Cessation
- 1994-08-01 US US08/283,509 patent/US5571762A/en not_active Expired - Fee Related
- 1994-08-02 AU AU68853/94A patent/AU683661B2/en not_active Ceased
- 1994-08-03 CA CA002129389A patent/CA2129389A1/en not_active Abandoned
- 1994-08-04 KR KR1019940019230A patent/KR100194230B1/ko not_active IP Right Cessation
- 1994-08-04 HU HU9402296A patent/HU214083B/hu not_active IP Right Cessation
- 1994-08-05 PL PL94304574A patent/PL179479B1/pl unknown
- 1994-08-05 RU RU94028658A patent/RU2126295C1/ru active
- 1994-08-05 CN CN94115032A patent/CN1054152C/zh not_active Expired - Fee Related
- 1994-08-05 JP JP6202916A patent/JPH07165414A/ja not_active Withdrawn
- 1994-08-05 BR BR9403189A patent/BR9403189A/pt not_active IP Right Cessation
- 1994-08-05 PL PL94335288A patent/PL179947B1/pl unknown
-
1995
- 1995-05-23 US US08/448,252 patent/US5659105A/en not_active Expired - Fee Related
-
1999
- 1999-05-31 MX MXPA99005011A patent/MXPA99005011A/es not_active Application Discontinuation
-
2000
- 2000-03-16 GR GR20000400668T patent/GR3032968T3/el not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
PT638363E (pt) | 2000-06-30 |
KR100194230B1 (ko) | 1999-06-15 |
EP0638363A1 (en) | 1995-02-15 |
BR9403189A (pt) | 1995-04-11 |
ITMI931796A0 (it) | 1993-08-06 |
AU6885394A (en) | 1995-02-16 |
MXPA99005011A (es) | 2004-08-31 |
IT1265051B1 (it) | 1996-10-28 |
RU94028658A (ru) | 1996-06-20 |
ATE190521T1 (de) | 2000-04-15 |
DK0638363T3 (da) | 2000-07-24 |
US5659105A (en) | 1997-08-19 |
KR950005781A (ko) | 1995-03-20 |
US5571762A (en) | 1996-11-05 |
AU683661B2 (en) | 1997-11-20 |
EP0638363B1 (en) | 2000-03-15 |
PL179947B1 (pl) | 2000-11-30 |
PL179479B1 (pl) | 2000-09-29 |
CA2129389A1 (en) | 1995-02-07 |
RU2126295C1 (ru) | 1999-02-20 |
HU214083B (en) | 1997-12-29 |
CN1108293A (zh) | 1995-09-13 |
JPH07165414A (ja) | 1995-06-27 |
PL304574A1 (en) | 1995-02-20 |
DE69423398T2 (de) | 2000-11-02 |
HUT71951A (en) | 1996-02-28 |
GR3032968T3 (en) | 2000-07-31 |
HU9402296D0 (en) | 1994-09-28 |
CN1054152C (zh) | 2000-07-05 |
DE69423398D1 (de) | 2000-04-20 |
ITMI931796A1 (it) | 1995-02-06 |
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