ES2142907T3 - Catalizador a base de silice injertada y procedimiento para la alquilacion de hidrocarburos alifaticos con olefinas. - Google Patents

Catalizador a base de silice injertada y procedimiento para la alquilacion de hidrocarburos alifaticos con olefinas.

Info

Publication number
ES2142907T3
ES2142907T3 ES94202241T ES94202241T ES2142907T3 ES 2142907 T3 ES2142907 T3 ES 2142907T3 ES 94202241 T ES94202241 T ES 94202241T ES 94202241 T ES94202241 T ES 94202241T ES 2142907 T3 ES2142907 T3 ES 2142907T3
Authority
ES
Spain
Prior art keywords
olefins
silice
rental
grafted
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94202241T
Other languages
English (en)
Inventor
Mario Gabriele Clerici
Carlo Perego
Angelis Alberto De
Luciano Montanari
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Agip Petroli SpA
Eni Tecnologie SpA
Original Assignee
Agip Petroli SpA
Eni Tecnologie SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agip Petroli SpA, Eni Tecnologie SpA filed Critical Agip Petroli SpA
Application granted granted Critical
Publication of ES2142907T3 publication Critical patent/ES2142907T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B01J31/0227—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C07C2/62—Catalytic processes with acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/025—Sulfonic acids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Silicon Compounds (AREA)
  • Silicon Polymers (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

UN PROCESO PARA LA ALQUILACION DE HIDROCARBUROS ALIFATICOS CON OLEFINAS CATALIZADAS POR UN MATERIAL BASADO EN SILICIO, CARACTERIZADO EN QUE LOS GRUPOS SI SILICIO ESTAN ESTERIFICADOS CON UN ACIDO FLUOROALQUILSULFONICO DE FORMULA CF3(CF2)NSO3H, DONDE N ES UN NUMERO ENTERO ENTRE 0 Y 11, TENIENDO DICHO MATERIAL UNA ACIDEZ HAMMETT DE HO MENOR O IGUAL QUE - 11.4.
ES94202241T 1993-08-06 1994-08-01 Catalizador a base de silice injertada y procedimiento para la alquilacion de hidrocarburos alifaticos con olefinas. Expired - Lifetime ES2142907T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT93MI001796A IT1265051B1 (it) 1993-08-06 1993-08-06 Processo per l'alchilazione di idrocarburi alifatici con olefine

Publications (1)

Publication Number Publication Date
ES2142907T3 true ES2142907T3 (es) 2000-05-01

Family

ID=11366796

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94202241T Expired - Lifetime ES2142907T3 (es) 1993-08-06 1994-08-01 Catalizador a base de silice injertada y procedimiento para la alquilacion de hidrocarburos alifaticos con olefinas.

Country Status (19)

Country Link
US (2) US5571762A (es)
EP (1) EP0638363B1 (es)
JP (1) JPH07165414A (es)
KR (1) KR100194230B1 (es)
CN (1) CN1054152C (es)
AT (1) ATE190521T1 (es)
AU (1) AU683661B2 (es)
BR (1) BR9403189A (es)
CA (1) CA2129389A1 (es)
DE (1) DE69423398T2 (es)
DK (1) DK0638363T3 (es)
ES (1) ES2142907T3 (es)
GR (1) GR3032968T3 (es)
HU (1) HU214083B (es)
IT (1) IT1265051B1 (es)
MX (1) MXPA99005011A (es)
PL (2) PL179947B1 (es)
PT (1) PT638363E (es)
RU (1) RU2126295C1 (es)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2729968B1 (fr) * 1995-01-27 1997-04-11 Inst Francais Du Petrole Procede d'hydrogenation des diolefines et eventuellement des olefines de coupes hydrocarbures riches en composes aromatiques sur des catalyseurs metalliques impregenes de composes organiques soufres
CN1045305C (zh) * 1995-12-20 1999-09-29 中国石油化工总公司石油化工科学研究院 重整生成油烯烃饱和加氢工艺
DK172907B1 (da) * 1996-06-17 1999-09-27 Topsoe Haldor As Fremgangsmåde til rensning af en carbonhydridstrøm
DE19636064A1 (de) * 1996-09-05 1998-03-12 Basf Ag Verfahren zur Hydrierung
US5922635A (en) * 1997-05-07 1999-07-13 Olah; George A. Nanoscale solid superacid catalysts with pendant fluoroalkylsulfonic acid or fluoro, perfluoroalkylsulfonic acid groups
WO1999008960A1 (fr) * 1997-08-20 1999-02-25 Asahi Kasei Kogyo Kabushiki Kaisha Corps spherique poreux
US6184171B1 (en) * 1998-10-05 2001-02-06 W.R. Grace & Co. -Conn Supported bidentate and tridentate catalyst compositions and olefin polymerization using same
US6277342B1 (en) * 1999-08-23 2001-08-21 Air Products And Chemicals, Inc. Storage and safe delivery of hazardous specialty gases by acid/base reactions with ionic polymers
KR100642775B1 (ko) * 2000-06-17 2006-11-13 주식회사 엘지이아이 김치냉장고의 숙성제어방법 및 장치
US6395673B1 (en) 2000-06-29 2002-05-28 E. I. Du Pont De Nemours And Company Catalyst of mixed fluorosulfonic acids
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
US20030018970A1 (en) * 2001-07-19 2003-01-23 Digeo, Inc. Object representation of television programs within an interactive television system
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
US20050038310A1 (en) 2003-07-15 2005-02-17 Lorkovic Ivan M. Hydrocarbon synthesis
US8329603B2 (en) * 2003-09-16 2012-12-11 Uop Llc Isoparaffin-olefin alkylation
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US20070098619A1 (en) * 2005-10-27 2007-05-03 Harmer Mark A Porous microcomposite of fluorinated sulfonic acid and a network of silica
NZ588129A (en) 2006-02-03 2012-06-29 Grt Inc Continuous process for converting natural gas to liquid hydrocarbons
MY153701A (en) 2006-02-03 2015-03-13 Grt Inc Separation of light gases from halogens
US7998438B2 (en) 2007-05-24 2011-08-16 Grt, Inc. Zone reactor incorporating reversible hydrogen halide capture and release
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
NZ591207A (en) 2008-07-18 2013-03-28 Grt Inc Continuous process for converting natural gas to liquid hydrocarbons
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1129809B (it) * 1979-03-26 1986-06-11 Ugine Kuhlmann Composizione catalitica per la conversione di idrocarburi e procedimento per la disidratazione di acidi perfluoroalcansolfonici destinati a fare parte bella composizione
US4847223A (en) * 1988-04-08 1989-07-11 Concordia University Superacidic catalysts for low temperature conversion of aqueous ethanol to ethylene
IT1226550B (it) * 1988-07-29 1991-01-24 Enichem Anic Spa Processo di oligomerizzazione selettiva di olefine e nuovo catalizzatore per tale processo.
DK168520B1 (da) * 1989-12-18 1994-04-11 Topsoe Haldor As Fremgangsmåde til væskefase-alkylering af et carbonhydrid med et olefinalkyleringsmiddel
US5245100A (en) * 1989-12-18 1993-09-14 Haldor Topsoe, S.A. Alkylation process
US5179052A (en) * 1991-03-04 1993-01-12 Texaco Chemical Company One step synthesis of metyl t-butyl ether from 5-butanol using fluorosulfonic acid-modified zeolite catalysts
EP0539277B1 (fr) * 1991-10-25 1996-01-10 Institut Francais Du Petrole Utilisation d'un catalyseur en alkylation de paraffines
CA2099359C (en) * 1992-08-27 1999-06-15 Alan D. Eastman Alkylation catalyst regeneration
US5233119A (en) * 1992-11-09 1993-08-03 Phillips Petroleum Company Alkylation process and catalyst therefor

Also Published As

Publication number Publication date
ATE190521T1 (de) 2000-04-15
GR3032968T3 (en) 2000-07-31
EP0638363B1 (en) 2000-03-15
JPH07165414A (ja) 1995-06-27
AU6885394A (en) 1995-02-16
PL179947B1 (pl) 2000-11-30
PT638363E (pt) 2000-06-30
HU214083B (en) 1997-12-29
EP0638363A1 (en) 1995-02-15
ITMI931796A0 (it) 1993-08-06
ITMI931796A1 (it) 1995-02-06
PL179479B1 (pl) 2000-09-29
CA2129389A1 (en) 1995-02-07
RU2126295C1 (ru) 1999-02-20
RU94028658A (ru) 1996-06-20
US5571762A (en) 1996-11-05
HU9402296D0 (en) 1994-09-28
KR950005781A (ko) 1995-03-20
CN1108293A (zh) 1995-09-13
BR9403189A (pt) 1995-04-11
PL304574A1 (en) 1995-02-20
AU683661B2 (en) 1997-11-20
DE69423398D1 (de) 2000-04-20
DE69423398T2 (de) 2000-11-02
HUT71951A (en) 1996-02-28
US5659105A (en) 1997-08-19
DK0638363T3 (da) 2000-07-24
KR100194230B1 (ko) 1999-06-15
CN1054152C (zh) 2000-07-05
MXPA99005011A (es) 2004-08-31
IT1265051B1 (it) 1996-10-28

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