JP2006186114A - Cis系薄膜太陽電池の光吸収層の作製方法 - Google Patents
Cis系薄膜太陽電池の光吸収層の作製方法 Download PDFInfo
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- 238000000034 method Methods 0.000 title claims abstract description 52
- 239000010409 thin film Substances 0.000 title claims description 42
- 238000010521 absorption reaction Methods 0.000 title description 2
- 230000003287 optical effect Effects 0.000 title 1
- 239000011669 selenium Substances 0.000 claims abstract description 43
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 32
- 239000011593 sulfur Substances 0.000 claims abstract description 32
- 229910052711 selenium Inorganic materials 0.000 claims abstract description 31
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000010410 layer Substances 0.000 claims description 98
- 230000031700 light absorption Effects 0.000 claims description 76
- 239000010408 film Substances 0.000 claims description 43
- 239000007789 gas Substances 0.000 claims description 30
- 239000002344 surface layer Substances 0.000 claims description 28
- 239000012495 reaction gas Substances 0.000 claims description 26
- 150000003346 selenoethers Chemical class 0.000 claims description 26
- 238000004519 manufacturing process Methods 0.000 claims description 20
- 239000002184 metal Substances 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000000758 substrate Substances 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 238000005987 sulfurization reaction Methods 0.000 claims description 12
- 229910052798 chalcogen Inorganic materials 0.000 claims description 9
- 150000001787 chalcogens Chemical class 0.000 claims description 9
- 239000011521 glass Substances 0.000 claims description 9
- 239000011261 inert gas Substances 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 229910001873 dinitrogen Inorganic materials 0.000 claims description 8
- 239000002243 precursor Substances 0.000 claims description 8
- 230000005484 gravity Effects 0.000 claims description 7
- 238000005486 sulfidation Methods 0.000 claims description 7
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 6
- -1 CuIn (SSe) 2 Substances 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 229910052733 gallium Inorganic materials 0.000 claims description 2
- 229910052738 indium Inorganic materials 0.000 claims description 2
- JNMWHTHYDQTDQZ-UHFFFAOYSA-N selenium sulfide Chemical compound S=[Se]=S JNMWHTHYDQTDQZ-UHFFFAOYSA-N 0.000 claims description 2
- 150000004678 hydrides Chemical class 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 240000002329 Inga feuillei Species 0.000 description 18
- 238000005259 measurement Methods 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 8
- 238000009826 distribution Methods 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 239000010453 quartz Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000009529 body temperature measurement Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229910000058 selane Inorganic materials 0.000 description 1
- VIDTVPHHDGRGAF-UHFFFAOYSA-N selenium sulfide Chemical compound [Se]=S VIDTVPHHDGRGAF-UHFFFAOYSA-N 0.000 description 1
- 229960005265 selenium sulfide Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
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- H01L31/0248—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
- H01L31/0256—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by the material
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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Abstract
【解決手段】 装置内に雰囲気均一手段であるファン3を設けると共に、反応ガスの対流が円滑となる前記対象物の配置方法、即ち、複数の平板状の対象物2を一定の間隙を設けて、装置の長軸方向に平行に且つその板面を垂直に対象物を配置し、前記対象物群内部の内部流路、上部、下部、両側部のガス流路を有する方法により、各対象物が装置内の反応ガスと接触し易くなり、装置内の温度が均一になり、反応ガス及びセレン、硫黄との接触性が向上する。
【選択図】 図1
Description
なお、前記変換効率の測定は、JIS C 8914Iに準拠し、定常光ソーラーシュミレーターで標準条件で測定(照射強度:100mW/cm2 、AM(アーマス):1.5、温度25℃)した。
1A 石英チャンバー
1B ヒーター
2 製膜対象物
2A Cu−Ga積層膜
2B Cu−In積層膜
2C Cu−Ga−In積層膜
3 ファン
4 ホルダー
4A ホルダー脚部
5 CIS系薄膜太陽電池
5A ガラス基板
5B 金属裏面電極層
5C CIS系光吸収層
5D 高抵抗バッファ層
5E 窓層(透明導電膜)
Claims (9)
- ガラス基板、金属裏面電極層、p形CIS系光吸収層、高抵抗バッファ層、n形窓層の順に積層されたサブストレート構造のpnヘテロ接合デバイスであるCIS系薄膜太陽電池における前記光吸収層の作製方法であって、前記作製方法は、ガラス基板上の金属裏面電極層にCu/Ga、Cu/In、Cu−Ga/Inの何れか1つからなる積層構造の金属プリカーサ膜が形成されたセレン化又は硫化の対象物(以下、対象物という。)をセレン化してセレン化物系CIS系光吸収層を製膜するセレン化工程、前記対象物を硫化して硫化物系CIS系光吸収層を製膜する硫化工程、前記対象物をセレン化・硫化して硫黄・セレン化物系CIS系光吸収層を製膜するセレン化・硫化工程の何れか1つを有し、前記各工程において、装置内に雰囲気均一手段を設けると共に、反応ガスの対流が円滑となる前記対象物の配置方法により、装置内の温度を均一にし、且つ、反応ガス及びカルコゲン元素(セレン、硫黄)との接触性を向上させることを特徴とするCIS系薄膜太陽電池の光吸収層の作製方法。
- 前記雰囲気均一手段は雰囲気ガスを強制的に対流させる電動ファンからなり、前記対象物の配置方法は、複数の平板状の対象物(対象物群)を一定の間隙を設けて、円筒型の装置の長軸方向に平行に且つその板面を垂直に対象物を配置し、前記対象物群内部の上下方向及び前記長軸方向の反応ガス流路並びに対象物群外周囲の上部、下部及び両側部の前記ガス流路を有すると共に、各対象物が装置内の反応ガスと接触し易いものであることを特徴とする請求項1に記載のCIS系薄膜太陽電池の光吸収層の作製方法。
- 前記セレン化工程は、前記セレン源を導入し、封じ込んだ状態で昇温し、装置内を前記請求項1又は2に記載の雰囲気均一手段及び対象物の配置方法により、前記対象物のセレン化反応を均一にし、金属プリカーサ膜を一定温度で、一定時間保持することによりセレン化物系CIS系光吸収層を製膜することを特徴とする請求項1又は2に記載のCIS系薄膜太陽電池の光吸収層の作製方法。
- 前記セレン化工程は、前記対象物を装置内に設置し、装置内部を窒素ガス等の不活性ガスで置換した後、常温で濃度範囲1〜20%、望ましくは2〜10%の希釈したセレン化水素ガス等のセレン源を導入し、封じ込んだ状態で、前記請求項1又は2に記載の雰囲気均一手段及び対象物の配置方法により、装置内でガス比重差により上下に分離する傾向のあるガス雰囲気を均一にし、毎分10〜100℃で、400〜550℃迄、望ましくは、450〜500℃迄、昇温し、前記温度到達後、その到達温度に一定時間、即ち、10〜200分間、望ましくは、30〜120分間、保持することによりセレン化物系CIS系光吸収層を製膜することを特徴とする請求項1、2又は3に記載のCIS系薄膜太陽電池の光吸収層の作製方法。
- 前記硫化工程は、前記対象物を装置内に設置し、装置内部を窒素ガス等の不活性ガスで置換した後、常温で濃度範囲1〜30%、望ましくは2〜20%の希釈した硫化ガス等の硫黄源を導入し、封じ込んだ状態で、前記請求項1又は2に記載の雰囲気均一手段及び対象物の配置方法により、装置内でガス比重差により上下に分離する傾向のあるガス雰囲気を均一にし、毎分10〜100℃で、400〜550℃迄、望ましくは、450〜550℃迄、昇温し、前記温度到達後、その到達温度に一定時間、即ち、10〜200分間、望ましくは、30〜120分間、保持することにより硫化物系CIS系光吸収層を製膜することを特徴とする請求項1又は2に記載のCIS系薄膜太陽電池の光吸収層の作製方法。
- 前記セレン化・硫化工程は、請求項1、2、3又は4に記載のセレン化物系CIS系光吸収層を製膜後、封じ込んだセレン雰囲気の装置内を硫黄雰囲気に入替えた状態で、装置内温度を昇温しながら、前記請求項1又は2に記載の雰囲気均一手段及び対象物の配置方法により、硫化反応を均一にし、前記請求項1、2又は3に記載のセレン化物系CIS系光吸収層を一定温度で一定時間保持することで、硫黄と反応させることにより硫黄・セレン化物系CIS系光吸収層を製膜することを特徴とする請求項1又は2に記載のCIS系薄膜太陽電池の光吸収層の作製方法。
- 前記セレン化物系CIS系光吸収層は、CuInSe2 、Cu(InGa)Se2 又はCuGaSe2 からなることを特徴とする請求項1、2、3又は4に記載のCIS系薄膜太陽電池の光吸収層の作製方法。
- 前記硫黄化物系CIS系光吸収層は、CuInS2 、Cu(InGa)S2 、CuGaS2 からなることを特徴とする請求項1、2又は5に記載のCIS系薄膜太陽電池の光吸収層の作製方法。
- 前記硫黄・セレン化物系CIS系光吸収層は、CuIn(SSe)2 、Cu(InGa)(SSe)2 、CuGa(SSe)2 、CuIn(SSe)2 を表面層として持つCuInSe2 、CuIn(SSe)2 を表面層として持つCu(InGa)Se2 、CuIn(SSe)2 を表面層として持つCu(InGa)(SSe)2 、CuIn(SSe)2 を表面層として持つCuGaSe2 、CuIn(SSe)2 を表面層として持つCuGaSe2 、Cu(InGa)(SSe)2 を表面層として持つCu(InGa)Se2 、Cu(InGa)(SSe)2 を表面層として持つCuGaSe2 、CuGa(SSe)2 を表面層として持つCu(InGa)Se2 又はCuGa(SSe)2 を表面層として持つCuGaSe2 からなることを特徴とする請求項1、2又は6に記載のCIS系薄膜太陽電池の光吸収層の作製方法。
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Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004378398A JP4131965B2 (ja) | 2004-12-28 | 2004-12-28 | Cis系薄膜太陽電池の光吸収層の作製方法 |
EP05819563.7A EP1833097A4 (en) | 2004-12-28 | 2005-12-26 | Method for forming light absorbing layer in cis-based thin film solar battery |
CNB2005800453373A CN100490184C (zh) | 2004-12-28 | 2005-12-26 | 用于形成cis型薄膜太阳能电池的光吸收层的方法 |
US11/722,604 US20080110495A1 (en) | 2004-12-28 | 2005-12-26 | Method for Forming Light Absorption Layer of Cis Type Thin-Film Solar Cell |
KR1020077014672A KR101193034B1 (ko) | 2004-12-28 | 2005-12-26 | Cis계 박막 태양 전지의 광 흡수층의 제작방법 |
PCT/JP2005/023791 WO2006070745A1 (ja) | 2004-12-28 | 2005-12-26 | Cis系薄膜太陽電池の光吸収層の作製方法 |
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JP4131965B2 JP4131965B2 (ja) | 2008-08-13 |
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US (1) | US20080110495A1 (ja) |
EP (1) | EP1833097A4 (ja) |
JP (1) | JP4131965B2 (ja) |
KR (1) | KR101193034B1 (ja) |
CN (1) | CN100490184C (ja) |
WO (1) | WO2006070745A1 (ja) |
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Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4581108A (en) * | 1984-01-06 | 1986-04-08 | Atlantic Richfield Company | Process of forming a compound semiconductive material |
JPS61237476A (ja) * | 1985-04-12 | 1986-10-22 | シーメンス・ソラー・インダストリエス・リミテッド・パートナーシップ | 化合物半導体の製造方法 |
US4638111A (en) * | 1985-06-04 | 1987-01-20 | Atlantic Richfield Company | Thin film solar cell module |
US4915745A (en) * | 1988-09-22 | 1990-04-10 | Atlantic Richfield Company | Thin film solar cell and method of making |
US5015503A (en) * | 1990-02-07 | 1991-05-14 | The University Of Delaware | Apparatus for producing compound semiconductor thin films |
US5186764A (en) * | 1990-02-13 | 1993-02-16 | Viscodrive Gmbh | Method and apparatus for treating plates with gas |
JP3249408B2 (ja) * | 1996-10-25 | 2002-01-21 | 昭和シェル石油株式会社 | 薄膜太陽電池の薄膜光吸収層の製造方法及び製造装置 |
JP4089113B2 (ja) * | 1999-12-28 | 2008-05-28 | 株式会社Ihi | 薄膜作成装置 |
JP4402846B2 (ja) * | 2001-02-20 | 2010-01-20 | 中外炉工業株式会社 | 平面ガラス基板用連続式焼成炉 |
JP2003165735A (ja) * | 2001-11-29 | 2003-06-10 | Showa Mfg Co Ltd | ガラス基板用熱処理装置 |
JP2004327653A (ja) * | 2003-04-24 | 2004-11-18 | Ishikawajima Harima Heavy Ind Co Ltd | 真空処理装置 |
-
2004
- 2004-12-28 JP JP2004378398A patent/JP4131965B2/ja not_active Expired - Fee Related
-
2005
- 2005-12-26 CN CNB2005800453373A patent/CN100490184C/zh not_active Expired - Fee Related
- 2005-12-26 US US11/722,604 patent/US20080110495A1/en not_active Abandoned
- 2005-12-26 KR KR1020077014672A patent/KR101193034B1/ko not_active IP Right Cessation
- 2005-12-26 WO PCT/JP2005/023791 patent/WO2006070745A1/ja active Application Filing
- 2005-12-26 EP EP05819563.7A patent/EP1833097A4/en not_active Withdrawn
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Also Published As
Publication number | Publication date |
---|---|
JP4131965B2 (ja) | 2008-08-13 |
KR101193034B1 (ko) | 2012-10-22 |
EP1833097A4 (en) | 2017-03-29 |
US20080110495A1 (en) | 2008-05-15 |
KR20070097472A (ko) | 2007-10-04 |
CN100490184C (zh) | 2009-05-20 |
WO2006070745A1 (ja) | 2006-07-06 |
EP1833097A1 (en) | 2007-09-12 |
CN101095240A (zh) | 2007-12-26 |
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