JP2003512407A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2003512407A5 JP2003512407A5 JP2001532727A JP2001532727A JP2003512407A5 JP 2003512407 A5 JP2003512407 A5 JP 2003512407A5 JP 2001532727 A JP2001532727 A JP 2001532727A JP 2001532727 A JP2001532727 A JP 2001532727A JP 2003512407 A5 JP2003512407 A5 JP 2003512407A5
- Authority
- JP
- Japan
- Prior art keywords
- filler
- agglomerated
- composition
- silica particles
- curable resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000945 filler Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 230000001427 coherent Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 229910003439 heavy metal oxide Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Description
【特許請求の範囲】
【請求項1】 シラン処理された表面を有する非凝集シリカ粒子を含む乾燥粒子形態の充填剤であって、その非凝集シリカ粒子の平均粒子径が約200nm未満である、充填剤。
【請求項2】 請求項1に記載の乾燥粒子形態の充填剤の製造方法であって、シラン処理された表面を有する非凝集シリカ粒子の揮発性液体分剤体を乾燥する工程を含み、その非凝集シリカ粒子の平均粒子径が約200nm未満である、充填剤の製造方法。
【請求項3】 硬化性樹脂中に、請求項1に記載の充填剤を、それに重金属酸化物を加えるか、または加えないで、分散させる工程を含む、充填剤の製造方法。
【請求項4】 歯科用物品の製造方法であって、請求項1に記載の充填剤を硬化性樹脂中に分散して、硬化性樹脂中に平均直径約200nm未満を有する非集塊化、非凝集性のシリカ粒子が分散された分散体を含む組成物を形成する工程であって、前記組成物が少なくとも非集塊化、非凝集性のシリカ粒子を、少なくとも約40重量%含む、工程、
前記組成物を硬化して、歯科用ミルブランク、歯科用補綴材料、矯正装置、人口歯冠、前方充填材、後方充填材、およびキャビティライナーからなる群から選択される歯科用物品を製造する工程、および
さらに前記組成物を硬化する前に、その組成物の形状を変化させる工程を有するか、またはこの工程を有さない、
歯科用物品の製造方法。
【請求項5】 組成物の製造方法であって、請求項1に記載の充填剤を硬化性樹脂中に分散して、硬化性樹脂中に平均直径約200nm未満を有する非集塊化、非凝集性のシリカ粒子が分散された分散体を形成する工程、および
ヒュームドシリカを前記硬化性樹脂中に分散する工程であって、硬化後の前記組成物が約0.4未満の視覚不透明度を有する、工程、
を含む組成物の製造方法。
【請求項1】 シラン処理された表面を有する非凝集シリカ粒子を含む乾燥粒子形態の充填剤であって、その非凝集シリカ粒子の平均粒子径が約200nm未満である、充填剤。
【請求項2】 請求項1に記載の乾燥粒子形態の充填剤の製造方法であって、シラン処理された表面を有する非凝集シリカ粒子の揮発性液体分剤体を乾燥する工程を含み、その非凝集シリカ粒子の平均粒子径が約200nm未満である、充填剤の製造方法。
【請求項3】 硬化性樹脂中に、請求項1に記載の充填剤を、それに重金属酸化物を加えるか、または加えないで、分散させる工程を含む、充填剤の製造方法。
【請求項4】 歯科用物品の製造方法であって、請求項1に記載の充填剤を硬化性樹脂中に分散して、硬化性樹脂中に平均直径約200nm未満を有する非集塊化、非凝集性のシリカ粒子が分散された分散体を含む組成物を形成する工程であって、前記組成物が少なくとも非集塊化、非凝集性のシリカ粒子を、少なくとも約40重量%含む、工程、
前記組成物を硬化して、歯科用ミルブランク、歯科用補綴材料、矯正装置、人口歯冠、前方充填材、後方充填材、およびキャビティライナーからなる群から選択される歯科用物品を製造する工程、および
さらに前記組成物を硬化する前に、その組成物の形状を変化させる工程を有するか、またはこの工程を有さない、
歯科用物品の製造方法。
【請求項5】 組成物の製造方法であって、請求項1に記載の充填剤を硬化性樹脂中に分散して、硬化性樹脂中に平均直径約200nm未満を有する非集塊化、非凝集性のシリカ粒子が分散された分散体を形成する工程、および
ヒュームドシリカを前記硬化性樹脂中に分散する工程であって、硬化後の前記組成物が約0.4未満の視覚不透明度を有する、工程、
を含む組成物の製造方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US42893799A | 1999-10-28 | 1999-10-28 | |
US09/428,937 | 1999-10-28 | ||
PCT/US2000/005089 WO2001030307A1 (en) | 1999-10-28 | 2000-02-25 | Dental materials with nano-sized silica particles |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2011107644A Division JP5255092B2 (ja) | 1999-10-28 | 2011-05-12 | ナノサイズシリカ粒子を含有する歯科材料 |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2003512407A JP2003512407A (ja) | 2003-04-02 |
JP2003512407A5 true JP2003512407A5 (ja) | 2007-03-29 |
JP4800535B2 JP4800535B2 (ja) | 2011-10-26 |
Family
ID=23701047
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2001532727A Expired - Lifetime JP4800535B2 (ja) | 1999-10-28 | 2000-02-25 | ナノサイズシリカ粒子を含有する歯科材料 |
JP2011107644A Expired - Lifetime JP5255092B2 (ja) | 1999-10-28 | 2011-05-12 | ナノサイズシリカ粒子を含有する歯科材料 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2011107644A Expired - Lifetime JP5255092B2 (ja) | 1999-10-28 | 2011-05-12 | ナノサイズシリカ粒子を含有する歯科材料 |
Country Status (7)
Country | Link |
---|---|
US (1) | US6899948B2 (ja) |
EP (2) | EP1586294B2 (ja) |
JP (2) | JP4800535B2 (ja) |
AU (1) | AU3505400A (ja) |
CA (1) | CA2387215C (ja) |
DE (2) | DE60042038D1 (ja) |
WO (1) | WO2001030307A1 (ja) |
Families Citing this family (229)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030134035A1 (en) * | 1997-03-20 | 2003-07-17 | Unisearch Limited, A.C.N. 000 263 025 | Hydrophobic films |
US6730156B1 (en) * | 1999-10-28 | 2004-05-04 | 3M Innovative Properties Company | Clustered particle dental fillers |
US6537563B2 (en) * | 2000-05-11 | 2003-03-25 | Jeneric/Pentron, Inc. | Dental acid etchant composition and method of use |
US7709029B2 (en) * | 2001-01-24 | 2010-05-04 | Ada Foundation | Calcium-containing restoration materials |
US6593395B2 (en) | 2001-05-16 | 2003-07-15 | Kerr Corporation | Dental composition containing discrete nanoparticles |
US6890968B2 (en) | 2001-05-16 | 2005-05-10 | Kerr Corporation | Prepolymerized filler in dental restorative composite |
CN100415198C (zh) * | 2001-08-15 | 2008-09-03 | 3M创新有限公司 | 可硬化的自支撑结构和方法 |
JP4149924B2 (ja) | 2001-09-11 | 2008-09-17 | スリーエム イノベイティブ プロパティズ カンパニー | 耐汚染性ナノ複合材ハードコートおよびその製造方法 |
FR2833484B1 (fr) * | 2001-12-18 | 2004-12-10 | Rhodia Chimie Sa | Composition dentaire a base de solution de silice colloidale en phase continue silicone |
JP4748938B2 (ja) * | 2002-01-31 | 2011-08-17 | スリーエム イノベイティブ プロパティズ カンパニー | 歯科ペースト、歯科物品、および方法 |
US7008229B2 (en) * | 2002-04-12 | 2006-03-07 | 3M Innovative Properties Company | Stainless steel dental crowns with a polyester/epoxy coating |
US7134875B2 (en) | 2002-06-28 | 2006-11-14 | 3M Innovative Properties Company | Processes for forming dental materials and device |
US6773261B2 (en) | 2002-06-28 | 2004-08-10 | 3M Innovative Properties Company | Processes for forming dental materials |
US7091259B2 (en) | 2002-07-03 | 2006-08-15 | 3M Innovative Properties Company | Dental fillers, pastes, and compositions prepared therefrom |
US20040206932A1 (en) | 2002-12-30 | 2004-10-21 | Abuelyaman Ahmed S. | Compositions including polymerizable bisphosphonic acids and methods |
US7396862B2 (en) * | 2003-02-06 | 2008-07-08 | Weimer Alan W | Dental composite filler particles |
TWI236374B (en) * | 2003-02-13 | 2005-07-21 | Univ Nat Taiwan | Light curable epoxy nano composite for dental restorative material |
US7084182B2 (en) * | 2003-03-13 | 2006-08-01 | Tokuyama Corporation | Photopolymerization initiator |
US7282195B2 (en) * | 2003-04-10 | 2007-10-16 | Macdougald Ian T | Flavored sealants |
KR100708882B1 (ko) | 2003-04-15 | 2007-04-17 | (주) 보람케메탈 | 흄드 실리카를 이용한 나노 실리카 결정 분말의 제조방법 |
US7235118B2 (en) * | 2003-04-16 | 2007-06-26 | National Research Council Of Canada | Process for agglomeration and densification of nanometer sized particles |
US7998375B2 (en) * | 2003-05-08 | 2011-08-16 | Pentron Clinical Technologies, Llc | Method of manufacturing high strength dental restorations |
US20040241609A1 (en) * | 2003-05-08 | 2004-12-02 | Weitao Jia | Method of manufacturing high strength dental restorations |
JP5570091B2 (ja) * | 2003-05-13 | 2014-08-13 | デンツプライ インターナショナル インコーポレーテッド | 歯科用接着剤組成物および方法 |
EP1498098B1 (en) | 2003-07-14 | 2006-05-03 | 3M Espe Ag | Adhesive composition with decreased polarity upon polymerization |
EP1502570A1 (de) * | 2003-08-01 | 2005-02-02 | Nanosolutions GmbH | Röntgenopakes Dentalmaterial mit oberflächenmodifizierten Nanopartikeln |
EP1653913B1 (en) | 2003-08-12 | 2012-05-23 | 3M Innovative Properties Company | Self-etching dental compositions and methods |
US7064152B2 (en) | 2003-09-26 | 2006-06-20 | 3M Innovative Properties Company | Arylsulfinate salts in photoinitiator systems for polymerization reactions |
US7030169B2 (en) | 2003-09-26 | 2006-04-18 | 3M Innovative Properties Company | Arylsulfinate salts in initiator systems for polymeric reactions |
US7250452B2 (en) | 2003-09-26 | 2007-07-31 | 3M Innovative Properties Company | Dental compositions and methods with arylsulfinate salts |
US7026367B2 (en) | 2003-09-26 | 2006-04-11 | 3M Innovative Properties Company | Photoiniators having triarylsulfonium and arylsulfinate ions |
US7189768B2 (en) * | 2003-11-25 | 2007-03-13 | 3M Innovative Properties Company | Solution containing surface-modified nanoparticles |
US20050132928A1 (en) * | 2003-12-22 | 2005-06-23 | Culp Terry L. | Dental composites placement techniques for direct restorations |
DE102005002845A1 (de) * | 2004-02-18 | 2005-09-15 | Heraeus Kulzer Gmbh | Dispersionen nanoskaliger, nicht-agglomerierter Teilchen zum Einsatz in Dentalmaterialien |
US20060004121A1 (en) * | 2004-03-10 | 2006-01-05 | Xingzhe Ding | Polymer-brush modified fillers for composites |
NZ550000A (en) * | 2004-04-15 | 2009-06-26 | Dentofit As | Ultrasonic curing of dental filling materials |
CA2563327C (en) | 2004-04-15 | 2010-09-28 | Dentofit A/S | A composite material, in particular a dental filling material, ultrasonic curing of dental filling materials, and a population of zirconia particles |
KR100858373B1 (ko) * | 2004-04-15 | 2008-09-17 | 덴토피트 에이/에스 | 치과용 충전재의 초음파 경화방법 |
US7090721B2 (en) * | 2004-05-17 | 2006-08-15 | 3M Innovative Properties Company | Use of nanoparticles to adjust refractive index of dental compositions |
US7156911B2 (en) * | 2004-05-17 | 2007-01-02 | 3M Innovative Properties Company | Dental compositions containing nanofillers and related methods |
US7090722B2 (en) | 2004-05-17 | 2006-08-15 | 3M Innovative Properties Company | Acid-reactive dental fillers, compositions, and methods |
US7649029B2 (en) | 2004-05-17 | 2010-01-19 | 3M Innovative Properties Company | Dental compositions containing nanozirconia fillers |
DE102004025030A1 (de) * | 2004-05-18 | 2005-12-15 | S&C Polymer Silicon- und Composite-Spezialitäten GmbH | Nano-Apatit-Füllstoffe enthaltende härtbare Restaurationsmaterialien |
US8465284B2 (en) | 2004-07-08 | 2013-06-18 | 3M Innovative Properties Company | Dental methods, compositions, and kits including acid-sensitive dyes |
AU2005275246B2 (en) | 2004-07-14 | 2011-10-06 | 3M Deutschland Gmbh | Dental compositions containing carbosilane monomers |
EP1765262B1 (en) | 2004-07-14 | 2009-03-04 | 3M Espe AG | Dental composition containing unsaturated halogenated aryl alkyl ether components |
CN101060827A (zh) | 2004-07-14 | 2007-10-24 | 3M埃斯佩股份公司 | 包括环氧基官能的碳硅烷化合物的牙科组合物 |
DE602005015333D1 (de) | 2004-07-14 | 2009-08-20 | 3M Innovative Properties Co | Dentalzusammensetzungen mit carbosilanpolymere |
DE602004029511D1 (de) * | 2004-07-14 | 2010-11-18 | 3M Espe Ag | Dentalzusammensetzung mit epoxy-funktionalen polymerisierbaren verbindungen |
US20060035997A1 (en) | 2004-08-10 | 2006-02-16 | Orlowski Jan A | Curable acrylate polymer compositions featuring improved flexural characteristics |
KR101260525B1 (ko) | 2004-08-11 | 2013-05-06 | 쓰리엠 도이칠란드 게엠베하 | 다수의 산성 화합물을 포함하는 자체-접착성 조성물 |
FR2874498B1 (fr) * | 2004-08-31 | 2006-11-24 | Coste Bruno Clunet | Element d'obturation et d'ancrage dentaire prefabrique en materiau composite radio opaque et translucide |
DE602005014253D1 (de) * | 2004-10-14 | 2009-06-10 | Dentsply Int Inc | Aus nur einer komponente bestehendes selbstätzendes haftmittel |
US8957126B2 (en) | 2004-11-16 | 2015-02-17 | 3M Innovative Properties Company | Dental compositions with calcium phosphorus releasing glass |
KR101277869B1 (ko) | 2004-11-16 | 2013-07-30 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 포스페이트 염을 포함하는 치과용 충전제 및 조성물 |
AU2005306869B2 (en) | 2004-11-16 | 2011-11-10 | 3M Innovative Properties Company | Dental fillers including a phosphoruscontaining surface treatment |
US8278368B2 (en) | 2004-11-16 | 2012-10-02 | 3M Innnovatve Properties Company | Dental fillers, methods, compositions including a caseinate |
BRPI0612426A2 (pt) | 2005-05-09 | 2010-11-09 | 3M Innovative Properties Co | composições dentais endurecìveis, método para preparar uma restauração dental e composto |
US20070123604A1 (en) * | 2005-05-26 | 2007-05-31 | Ada Foundation | Dental releasing materials |
US20060270752A1 (en) * | 2005-05-26 | 2006-11-30 | Ada Foundation | Dental releasing materials |
ATE473723T1 (de) | 2005-08-05 | 2010-07-15 | 3M Espe Ag | Dentalzusammensetzungen mit einem oberflächenmodifizierten füllstoff |
DE102005041014A1 (de) * | 2005-08-29 | 2007-03-01 | Heraeus Kulzer Gmbh | Lichthärtendes, selbstätzendes Nanopartikel enthaltendes Einkomponenten-Dentaladhäsiv |
US7855242B2 (en) * | 2005-09-01 | 2010-12-21 | Pentron Clinical Technologies Llc | Dental resin composition, method of manufacture, and method of use thereof |
EP1940342B1 (en) * | 2005-09-02 | 2017-08-23 | DENTSPLY International Inc. | Dental sealant compositions containing nanometer-sized silica |
US7495054B2 (en) | 2005-09-19 | 2009-02-24 | 3M Innovative Properties Company | Curable compositions containing dithiane monomers |
WO2007034258A1 (de) * | 2005-09-22 | 2007-03-29 | GDF Gesellschaft für Dentale Forschung und Innovationen GmbH | Dentalmaterial |
EP1787627A1 (en) | 2005-11-17 | 2007-05-23 | 3M Innovative Properties Company | Anti-microbial dental impression material |
US7896650B2 (en) | 2005-12-20 | 2011-03-01 | 3M Innovative Properties Company | Dental compositions including radiation-to-heat converters, and the use thereof |
US7658870B2 (en) | 2005-12-20 | 2010-02-09 | University Of Hawaii | Polymer matrix composites with nano-scale reinforcements |
US8026296B2 (en) | 2005-12-20 | 2011-09-27 | 3M Innovative Properties Company | Dental compositions including a thermally labile component, and the use thereof |
US7776940B2 (en) | 2005-12-20 | 2010-08-17 | 3M Innovative Properties Company | Methods for reducing bond strengths, dental compositions, and the use thereof |
DE102005061965A1 (de) * | 2005-12-23 | 2007-07-05 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Oxidische Agglomeratpartikel, Verfahren zur Herstellung von Nanokompositen sowie deren Verwendung |
US8071662B2 (en) | 2005-12-29 | 2011-12-06 | 3M Innovative Properties Company | Dental compositions with surface-treated filler for shelf stability |
US20080306168A1 (en) * | 2005-12-29 | 2008-12-11 | Craig Bradley D | Dental Compositions with a Water Scavenger |
JP5271089B2 (ja) | 2005-12-29 | 2013-08-21 | スリーエム イノベイティブ プロパティズ カンパニー | 歯科用組成物及び多環式芳香族構成要素を有する開始剤系 |
US7556743B2 (en) * | 2006-03-06 | 2009-07-07 | Southwest Research Institute | Nanocomposites and methods for synthesis and use thereof |
EP1849449A1 (en) * | 2006-04-26 | 2007-10-31 | 3M Innovative Properties Company | Filler containing composition and process for production and use thereof |
JP2007314773A (ja) * | 2006-04-28 | 2007-12-06 | Mitsubishi Chemicals Corp | 高屈折率粒子含有樹脂組成物 |
ATE532797T1 (de) | 2006-05-31 | 2011-11-15 | 3M Innovative Properties Co | Polymerisierbare zusammensetzungen enthaltend salze aus barbitursäure-derivaten |
EP2377507B1 (en) | 2006-09-13 | 2013-04-24 | 3M Innovative Properties Company | Dental compositions including organogelators, products, and methods |
US7498197B2 (en) * | 2006-09-13 | 2009-03-03 | Delphi Technologies, Inc. | Silica nanoparticles thermoset resin compositions |
US20080070146A1 (en) * | 2006-09-15 | 2008-03-20 | Cabot Corporation | Hydrophobic-treated metal oxide |
US8455165B2 (en) * | 2006-09-15 | 2013-06-04 | Cabot Corporation | Cyclic-treated metal oxide |
US8435474B2 (en) * | 2006-09-15 | 2013-05-07 | Cabot Corporation | Surface-treated metal oxide particles |
US8202502B2 (en) * | 2006-09-15 | 2012-06-19 | Cabot Corporation | Method of preparing hydrophobic silica |
US20080096150A1 (en) | 2006-10-23 | 2008-04-24 | 3M Innovative Properties Company | Dental articles, methods, and kits including a compressible material |
US9539065B2 (en) | 2006-10-23 | 2017-01-10 | 3M Innovative Properties Company | Assemblies, methods, and kits including a compressible material |
DE102006054879B4 (de) * | 2006-11-20 | 2008-09-11 | Heraeus Kulzer Gmbh | Polymerisierbares Dentalmaterial auf der Basis von Methylmethacrylaten, geeignet zur Herstellung von Prothesenkunststoff |
WO2008076739A2 (en) | 2006-12-13 | 2008-06-26 | 3M Innovative Properties Company | Methods of using a dental composition having an acidic component and a photobleachable dye |
US8263681B2 (en) * | 2006-12-28 | 2012-09-11 | 3M Innovative Properties Company | Dental compositions with natural tooth fluorescence |
CN101610749B (zh) * | 2006-12-28 | 2013-01-02 | 3M创新有限公司 | 牙科填料及方法 |
EP2109436B1 (en) | 2006-12-28 | 2012-01-25 | 3M Innovative Properties Company | Adhesive composition for hard tissue |
FR2911494B1 (fr) * | 2007-01-19 | 2009-04-10 | Rech S Tech Dentaires R T D Sa | Element prothetique dentaire radio-opaque |
ES2734435T3 (es) * | 2007-02-08 | 2019-12-05 | Kuraray Noritake Dental Inc | Composición dental |
US20080214689A1 (en) * | 2007-03-02 | 2008-09-04 | Cheng-Chien Yang | Manufacturing method and foaming manufacturing method of polymethyl methacrylate/silica composite material |
CA2942365C (en) | 2007-05-11 | 2019-04-16 | Dentsply International Inc. | Dental compositions for coating restorations and tooth surfaces |
US20080286724A1 (en) * | 2007-05-18 | 2008-11-20 | Ormco Corporation | Orthodontic adhesives |
US8735463B2 (en) | 2007-05-31 | 2014-05-27 | Creighton University | Self-healing dental composites and related methods |
EP2008636A1 (en) * | 2007-06-29 | 2008-12-31 | 3M Innovative Properties Company | Dental composition containing a polyfunctional (meth)acrylate comprising urethane, urea or amide groups, method of production and use thereof |
EP2025381A1 (de) * | 2007-07-30 | 2009-02-18 | Nanoresins AG | Verfahren zum Entfernen basischer oder saurer Verbindungen aus einer lösungsmittelhaltigen Metalloxiddispersion insbesondere Kieselsäure |
EP2042486A1 (en) * | 2007-09-26 | 2009-04-01 | 3M Innovative Properties Company | Methacrylate Based Monomers containing a Urethane Linkage, Process for Production and Use thereof |
EP2203144A2 (en) | 2007-10-01 | 2010-07-07 | 3M Innovative Properties Company | Orthodontic composition with polymeric fillers |
JP5461415B2 (ja) | 2007-11-01 | 2014-04-02 | スリーエム イノベイティブ プロパティズ カンパニー | 歯科用組成物及び色安定アミン電子供与体を有する開始剤系 |
US9339352B2 (en) | 2007-12-13 | 2016-05-17 | 3M Innovative Properties Company | Orthodontic article having partially hardened composition and related method |
EP2072028A1 (de) | 2007-12-21 | 2009-06-24 | Ernst Mühlbauer GmbH & Co.KG | Stumpfaufbaumaterial |
EP2133064A1 (en) * | 2008-06-10 | 2009-12-16 | 3M Innovative Properties Company | Initiator system containing a diarylalkylamine derivate, hardenable composition and use thereof |
EP2133063A1 (en) | 2008-06-10 | 2009-12-16 | 3M Innovative Properties Company | Initiator system with biphenylene derivates, method of production and use thereof |
WO2009152404A1 (en) * | 2008-06-12 | 2009-12-17 | 3M Innovative Properties Company | Methods of compounding nanoparticles with a resin |
EP2548546A1 (de) * | 2008-08-13 | 2013-01-23 | Ernst Mühlbauer GmbH & Co.KG | Röntgenopaker Infiltrant |
EP2331046A2 (en) * | 2008-09-04 | 2011-06-15 | 3M Innovative Properties Company | Dental composition comprising biphenyl di(meth)acrylate monomer |
US20100068523A1 (en) * | 2008-09-16 | 2010-03-18 | Aveka, Incorporated | Surface modification of and dispersion of particles |
RU2472708C2 (ru) * | 2008-10-15 | 2013-01-20 | Зм Инновейтив Пропертиз Компани | Наполнители и композитные материалы с наночастицами диоксида циркония и кремнезема |
WO2010045096A2 (en) | 2008-10-15 | 2010-04-22 | 3M Innovative Properties Company | Dental compositions with fluorescent pigment |
US8389599B2 (en) * | 2008-10-22 | 2013-03-05 | 3M Innovative Properties Company | Dental composition comprising biphenyl di(meth)acrylate monomer comprising urethane moieties |
US8551457B2 (en) | 2008-11-25 | 2013-10-08 | The Procter & Gamble Company | Oral care compositions comprising spherical fused silica |
US8211406B2 (en) * | 2008-11-25 | 2012-07-03 | The Procter & Gamble Company | Oral care compositions with fused silica |
EP2617762A1 (en) | 2008-12-19 | 2013-07-24 | 3M Innovative Properties Company | Nanocalcite composites |
US20100189663A1 (en) * | 2009-01-24 | 2010-07-29 | Gallis Karl W | Mouth rinse compositions including chemically modified silica or silicate materials for sustained delivery to tooth surfaces |
DE102009006173A1 (de) * | 2009-01-26 | 2010-07-29 | Ernst Mühlbauer Gmbh & Co. Kg | Dentalmaterial |
PL2459867T3 (pl) | 2009-07-30 | 2014-08-29 | 3M Innovative Properties Co | Dysza i sposób jej wytwarzania |
US8816029B2 (en) | 2009-08-28 | 2014-08-26 | 3M Innovative Properties Company | Compositions and articles comprising polymerizable ionic liquid mixture, and methods of curing |
JP5781075B2 (ja) | 2009-08-28 | 2015-09-16 | スリーエム イノベイティブ プロパティズ カンパニー | 多官能性カチオンを含む重合性イオン性液体及び静電気防止コーティング |
WO2011050121A2 (en) | 2009-10-21 | 2011-04-28 | 3M Innovative Properties Company | Solventless functionalization, milling, and compounding process with reactive diluents |
EP2513215B1 (en) | 2009-12-17 | 2019-06-05 | 3M Innovative Properties Company | High magnesium surface concentration nanocalcite composites |
US10023726B2 (en) | 2009-12-17 | 2018-07-17 | 3M Innovative Properties Company | Nanocalcite and vinyl ester composites |
US8853338B2 (en) | 2009-12-22 | 2014-10-07 | 3M Innovative Properties Company | Curable dental compositions and articles comprising polymerizable ionic liquids |
EP2515794B1 (en) | 2009-12-22 | 2020-05-06 | 3M Innovative Properties Company | Dental compositions, mill blocks, and methods |
US20110206749A1 (en) * | 2010-02-19 | 2011-08-25 | J.M. Huber Corporation | Silica materials for reducing oral malador |
US20110236444A1 (en) * | 2010-03-25 | 2011-09-29 | Darsillo Michael S | Antimicrobial Silica Composites |
US9237990B2 (en) | 2010-03-31 | 2016-01-19 | 3M Innovative Properties Company | Polymerizable isocyanurate monomers and dental compositions |
EP2561027B1 (en) | 2010-04-20 | 2014-03-05 | 3M Innovative Properties Company | Pressure sensitive adhesives containing reactive, surface-modified nanoparticles |
EP3696139A1 (en) | 2010-04-23 | 2020-08-19 | Pixelligent Technologies, LLC | Synthesis, capping and dispersion of nanocrystals |
WO2012058271A2 (en) | 2010-10-27 | 2012-05-03 | Pixelligent Technologies, Llc | Synthesis, capping and dispersion of nanocrystals |
RU2565414C2 (ru) | 2010-05-25 | 2015-10-20 | 3М Инновейтив Пропертиз Компани | Метод обработки поверхности частиц неорганического оксида, твердеющие стоматологические композиты, частицы с обработанной поверхностью и соединения для обработки поверхности |
EP2401998A1 (en) | 2010-07-02 | 2012-01-04 | 3M Innovative Properties Company | Dental composition, kit of parts and use thereof |
EP2412361A1 (en) | 2010-07-29 | 2012-02-01 | 3M Innovative Properties Company | Kit of parts, method of producing and use thereof |
WO2012021438A1 (en) | 2010-08-11 | 2012-02-16 | 3M Innovative Properties Company | Aesthetic and abrasion resistant coated dental articles and methods of making the same |
WO2012021442A1 (en) | 2010-08-11 | 2012-02-16 | 3M Innovative Properties Company | Coated dental crows and method of making the same |
WO2012027091A1 (en) | 2010-08-11 | 2012-03-01 | 3M Innovative Properties Company | Dental articles including a ceramic and microparticle coating and method of making the same |
US20130130203A1 (en) | 2010-08-11 | 2013-05-23 | 3M Innovative Properties Company | Polymer coated dental articles and method of making the same |
BR112013005887B1 (pt) | 2010-09-15 | 2018-05-22 | 3M Innovative Properties Company. | Compostos de sacarídeo substituído e composições dentais |
US8669302B2 (en) | 2010-09-30 | 2014-03-11 | Voco Gmbh | Composite material comprising a monomer with a polyalicyclic structure element as a sealing material |
US8697769B2 (en) | 2010-09-30 | 2014-04-15 | Voco Gmbh | Lacquer composition comprising a monomer with a polyalicyclic structure element |
JP5824061B2 (ja) * | 2010-10-27 | 2015-11-25 | スリーエム イノベイティブ プロパティズ カンパニー | 半結晶性樹脂とナノクラスター充填剤とを含む歯科用組成物 |
US9480540B2 (en) | 2010-12-30 | 2016-11-01 | 3M Innovative Properties Company | Bondable dental assemblies and methods including a compressible material |
EP2481390A1 (en) | 2011-01-31 | 2012-08-01 | 3M Innovative Properties Company | Dental composition, method of producing and use thereof |
WO2012106512A2 (en) | 2011-02-02 | 2012-08-09 | 3M Innovative Properties Company | Nozzle and method of making same |
WO2012112321A2 (en) | 2011-02-15 | 2012-08-23 | 3M Innovative Properties Company | Dental compositions comprising mixture of isocyanurate monomer and tricyclodecane monomer |
EP2675422B1 (en) | 2011-02-15 | 2020-09-30 | 3M Innovative Properties Company | Dental compositions comprising ethylenically unsaturated addition-fragmentation agent |
EP2688508A1 (en) | 2011-03-24 | 2014-01-29 | 3M Innovative Properties Company | Dental adhesive comprising a coated polymeric component |
US8431626B2 (en) | 2011-05-18 | 2013-04-30 | 3M Innovative Properties Company | Disulfide monomers comprising ethylenically unsaturated norbornyl groups suitable for dental compositions |
US8455565B2 (en) | 2011-05-18 | 2013-06-04 | 3M Innovative Properties Company | Disulfide monomers comprising ethylenically unsaturated groups suitable for dental compositions |
WO2013003396A2 (en) | 2011-06-29 | 2013-01-03 | 3M Innovative Properties Company | Dental compositions comprising a fatty mono(meth)acrylate |
WO2013023138A1 (en) | 2011-08-11 | 2013-02-14 | 3M Innovative Properties Company | Dental composition, method of producing and use thereof |
BR112014003903B1 (pt) | 2011-08-23 | 2018-05-29 | 3M Innovative Properties Company | Composições dentais que compreendem agentes de adição fragmentação |
EP2578200B1 (de) | 2011-10-04 | 2018-03-28 | VOCO GmbH | Zusammensetzungen zum Infiltrieren und/oder Versiegeln von Zahnhartsubstanz und entsprechende Verfahren |
US9359689B2 (en) | 2011-10-26 | 2016-06-07 | Pixelligent Technologies, Llc | Synthesis, capping and dispersion of nanocrystals |
EP2773587B1 (en) | 2011-11-02 | 2020-09-23 | 3M Innovative Properties Company | Method of making a nozzle |
EP2785307B1 (en) | 2011-12-01 | 2019-06-26 | 3M Innovative Properties Company | One component self-adhesive dental composition, process of production and use thereof |
EP2604247A1 (en) * | 2011-12-15 | 2013-06-19 | Dentsply DeTrey GmbH | Composite filler particles and process for the preparation thereof |
US8999371B2 (en) | 2012-03-19 | 2015-04-07 | Arges Imaging, Inc. | Contrast pattern application for three-dimensional imaging |
DE112013002309B4 (de) | 2012-08-31 | 2024-05-08 | Kettenbach Gmbh & Co. Kg | Radikalisch polymerisierbares Dentalmaterial, gehärtetes Produkt und Verwendung |
US8986003B2 (en) | 2012-09-13 | 2015-03-24 | Orthoaccel Technologies, Inc. | Pearlescent white aligners |
RU2608129C2 (ru) | 2012-11-05 | 2017-01-13 | Дзе Проктер Энд Гэмбл Компани | Термически обработанная осажденная двуокись кремния |
KR102174015B1 (ko) | 2012-11-12 | 2020-11-04 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 부가-단편화제를 포함하는 치과용 조성물 |
EP2931756B1 (en) | 2012-12-17 | 2018-08-08 | 3M Innovative Properties Company | Addition-fragmentation oligomers |
JP6300899B2 (ja) | 2013-03-20 | 2018-03-28 | スリーエム イノベイティブ プロパティズ カンパニー | 高屈折率の付加−開裂剤 |
WO2014172138A1 (en) | 2013-04-15 | 2014-10-23 | 3M Innovative Properties Company | Dental composition containing high refractive index monomers |
DE102013007894A1 (de) | 2013-05-08 | 2014-11-13 | Heraeus Kulzer Gmbh | Langlebiges Dentalmaterial mit verbesserten transparenten Eigenschaften |
US9782329B2 (en) | 2013-07-08 | 2017-10-10 | 3M Innovative Properties Company | Hardenable dental composition containing a mixture of agglomerated and aggregated nano-particles, kit of parts and use thereof |
US9532929B2 (en) | 2013-09-20 | 2017-01-03 | 3M Innovative Properties Company | Trithiocarbonate-containing addition-fragmentation agents |
WO2015051095A1 (en) | 2013-10-04 | 2015-04-09 | 3M Innovative Properties Company | Dental mill blank |
EP3058014B1 (en) | 2013-10-16 | 2018-06-20 | 3M Innovative Properties Company | Allyl disulfide-containing addition-fragmentation oligomers |
CN106029802B (zh) | 2014-02-18 | 2020-08-18 | 3M创新有限公司 | 具有高折射率基团的加成-断裂低聚物 |
JP6599346B2 (ja) | 2014-02-18 | 2019-10-30 | スリーエム イノベイティブ プロパティズ カンパニー | 歯科用組成物及びその使用 |
DE102014107518A1 (de) * | 2014-05-28 | 2015-12-03 | Heraeus Kulzer Gmbh | Reaktiver Mikro-Applikator mit Metall enthaltenden Additiven zur Verwendung mit dental Adhäsiven |
CN106661380B (zh) | 2014-06-27 | 2019-11-05 | 康宁股份有限公司 | 环氧/氧杂环丁烷化合物、环氧官能化倍半硅氧烷和纳米颗粒基玻璃可uv固化涂料组合物 |
JP6857600B2 (ja) | 2014-07-10 | 2021-04-14 | スリーエム イノベイティブ プロパティズ カンパニー | 二成分自己接着性歯科用組成物、その製造方法、及び使用 |
RU2685716C2 (ru) * | 2014-07-31 | 2019-04-23 | 3М Инновейтив Пропертиз Компани | Комплект, содержащий стоматологическую заготовку для фрезерования и раствор для окрашивания |
DE102014013807A1 (de) * | 2014-09-23 | 2016-03-24 | Dph Dental Partner Holding Gmbh | Verfahren zur Präparation von dentalen Werkstücken mit reflektierenden Oberflächen |
EP3206624B1 (en) | 2014-10-14 | 2023-08-30 | 3M Innovative Properties Company | Method of curing a dental article |
US10350297B2 (en) | 2014-10-31 | 2019-07-16 | 3M Innovative Properties Company | Dental materials and methods |
EP3212153A1 (en) | 2014-10-31 | 2017-09-06 | 3M Innovative Properties Company | Dental materials and methods |
CN107406723B (zh) | 2015-02-20 | 2021-05-07 | 3M创新有限公司 | 加成-断裂低聚物 |
EP3265049B1 (en) | 2015-03-05 | 2024-05-01 | Solventum Intellectual Properties Company | Composite material having ceramic fibers |
KR101746793B1 (ko) | 2015-07-22 | 2017-06-14 | 주식회사 쿠보텍 | 금속 산화물을 함유하는 치과용 시멘트 |
DE102015012793A1 (de) * | 2015-10-05 | 2017-04-06 | Birgit Stührenberg Dentale Kompetenz GmbH & Co. KG | Verblendelement zur Abdeckung einer Zahnoberfläche, Verfahren zur Herstellung des Verblendelements und Schichtaufbau mit dem Verblendelement |
US10758456B2 (en) | 2015-11-06 | 2020-09-01 | 3M Innovative Properties Company | Redox polymerizable composition with photolabile transition metal complexes |
US10617607B2 (en) | 2015-11-06 | 2020-04-14 | 3M Innovative Properties Company | Redox polymerizable dental composition with photolabile transition metal complexes |
JP6872548B2 (ja) | 2015-12-03 | 2021-05-19 | スリーエム イノベイティブ プロパティズ カンパニー | 光解離性還元剤を有するレドックス重合性組成物 |
EP3386462A1 (en) | 2015-12-08 | 2018-10-17 | 3M Innovative Properties Company | Two-component self-adhesive dental composition, storage stable initiator system, and use thereof |
CN108601710A (zh) | 2016-02-05 | 2018-09-28 | 3M创新有限公司 | 包含提供在可聚合树脂和填料之间的折射率差的纳米粒子的牙科用组合物 |
BR112018068176B1 (pt) | 2016-03-07 | 2021-11-09 | 3M Innovative Properties Company | Coroa de compósito dental pré-formada, processo de produção e kit de partes de um conjunto da mesma |
US11208562B2 (en) | 2016-03-25 | 2021-12-28 | Nippon Shokubai Co., Ltd. | Zirconium oxide nanoparticles |
EP3479171A1 (en) | 2016-06-30 | 2019-05-08 | 3M Innovative Properties Company | Printable compositions including highly viscous components and methods of creating 3d articles therefrom |
EP3507011A1 (en) | 2016-09-02 | 2019-07-10 | 3M Innovative Properties Company | Shaped gel articles and sintered articles prepared therefrom |
EP3509531A1 (en) | 2016-09-06 | 2019-07-17 | 3M Innovative Properties Company | Methods of improving dental restoration margins and articles |
WO2018075275A1 (en) | 2016-10-20 | 2018-04-26 | 3M Innovative Properties Company | Photoinitiators with protected carbonyl group |
US20190388355A1 (en) | 2016-12-01 | 2019-12-26 | 3M Innovative Properties Company | Basic core material encapsulated in an inorganic shell suitable for use in biological carrier materials |
WO2018154911A1 (ja) * | 2017-02-27 | 2018-08-30 | 株式会社ジーシー | 歯科用硬化性組成物 |
CN110678160B (zh) | 2017-05-15 | 2022-12-30 | 3M创新有限公司 | 牙科用粘合剂组合物,其制备和用途 |
WO2018213074A1 (en) | 2017-05-18 | 2018-11-22 | 3M Innovative Properties Company | Glass ionomer compositions and methods including water-miscible, silane-treated, nano-sized silica particles |
KR102606720B1 (ko) | 2017-06-14 | 2023-11-24 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 치과용 복합재 크라운을 제조하기 위한 경화성 조성물 및 제조 방법 |
US11553996B2 (en) | 2017-09-11 | 2023-01-17 | 3M Innovative Properties Company | Radiation curable compositions and composite articles made using an additive manufacturing process |
US20200237487A1 (en) * | 2017-09-26 | 2020-07-30 | Kuraray Noritake Dental Inc. | Dental mill blank and method for producing same |
JP6942888B2 (ja) | 2017-11-08 | 2021-09-29 | スリーエム イノベイティブ プロパティズ カンパニー | 高弾性率の歯科用組成物 |
EP3706708B1 (en) | 2017-11-08 | 2022-01-12 | 3M Innovative Properties Company | Radiopaque dental composition |
WO2019108808A2 (en) | 2017-11-29 | 2019-06-06 | Corning Incorporated | Highly loaded inorganic filled aqueous resin systems |
WO2019123260A2 (en) | 2017-12-19 | 2019-06-27 | 3M Innovative Properties Company | Multi-part composition having staged viscosity prior to hardening |
JP6865898B2 (ja) | 2017-12-21 | 2021-04-28 | スリーエム イノベイティブ プロパティズ カンパニー | シラン処理された表面を有する歯科用無機充填剤 |
US11912860B2 (en) | 2018-03-29 | 2024-02-27 | Corning Incorporated | Highly loaded inorganic filled organic resin systems |
US20210085570A1 (en) | 2018-05-02 | 2021-03-25 | 3M Innovative Properties Company | One-part dental adhesive composition for fixing dental composite materials |
US20210228315A1 (en) | 2018-06-06 | 2021-07-29 | 3M Innovative Properties Company | Hardenable dental compositions comprising basic core material encapsulated in an inorganic shell and dispensing devices therewith |
CN111295175A (zh) | 2018-08-08 | 2020-06-16 | 株式会社Gc | 牙科用固化性组合物 |
US11642199B2 (en) | 2018-09-24 | 2023-05-09 | 3M Innovative Properties Company | Dental appliance with cosmetic therapeutic aqueous solution |
CN112789263A (zh) | 2018-10-09 | 2021-05-11 | 3M创新有限公司 | 具有悬挂式胺基团的加成-断裂剂 |
EP3880156A1 (en) | 2018-11-14 | 2021-09-22 | 3M Innovative Properties Company | Storage stable two-component dual cure dental composition |
KR102198371B1 (ko) * | 2019-10-18 | 2021-01-05 | 연세대학교 산학협력단 | 치과용 조성물 및 이를 포함하는 치과 교정술 장치 제조 방법 |
WO2021205326A1 (en) | 2020-04-08 | 2021-10-14 | 3M Innovative Properties Company | Curable compositions and methods of using the same |
CN115380053A (zh) | 2020-04-08 | 2022-11-22 | 3M创新有限公司 | 可固化组合物以及使用可固化组合物的方法 |
US11404289B2 (en) * | 2020-08-31 | 2022-08-02 | Micron Technology, Inc. | Semiconductor device assembly with graded modulus underfill and associated methods and systems |
WO2022090831A1 (en) | 2020-10-28 | 2022-05-05 | 3M Innovative Properties Company | Methods and systems for processing photopolymerizable compositions |
WO2022112886A1 (en) | 2020-11-25 | 2022-06-02 | 3M Innovative Properties Company | Curable dental compositions and uses thereof |
US20240065809A1 (en) | 2020-12-30 | 2024-02-29 | 3M Innovative Properties Company | Bondable orthodontic assemblies and methods for bonding |
US20240122815A1 (en) | 2021-03-17 | 2024-04-18 | 3M Innovative Properties Company | Polymerizable 4,4'-spirobi[chromane]-2,2'-diones and curable compositions including the same |
CN117157370A (zh) | 2021-04-19 | 2023-12-01 | 3M创新有限公司 | 用于柔性版印刷板安装带的粘合剂层 |
WO2023105315A1 (en) | 2021-12-06 | 2023-06-15 | 3M Innovative Properties Company | Dental compositions |
WO2023209463A1 (en) | 2022-04-26 | 2023-11-02 | 3M Innovative Properties Company | Dental composition containing a resorcinol or catechol moiety containing component and use thereof |
WO2024018305A1 (en) | 2022-07-21 | 2024-01-25 | 3M Innovative Properties Company | Curable composition for producing transparent orthodontic attachments |
Family Cites Families (141)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2801185A (en) † | 1952-05-16 | 1957-07-30 | Du Pont | Silica hydrosol powder |
US2948628A (en) * | 1955-08-02 | 1960-08-09 | Horizons Inc | Method of making ceramic dielectric |
US2984628A (en) | 1956-11-29 | 1961-05-16 | Du Pont | Concentrated zirconia and hafnia aquasols and their preparation |
US3018262A (en) | 1957-05-01 | 1962-01-23 | Shell Oil Co | Curing polyepoxides with certain metal salts of inorganic acids |
US3179623A (en) | 1959-01-30 | 1965-04-20 | Rafael L Bowen | Method of preparing a monomer having phenoxy and methacrylate groups linked by hydroxy glyceryl groups |
US3066112A (en) | 1959-01-30 | 1962-11-27 | Rafael L Bowen | Dental filling material comprising vinyl silane treated fused silica and a binder consisting of the reaction product of bis phenol and glycidyl acrylate |
GB1051391A (ja) | 1959-12-24 | |||
US3442817A (en) | 1966-04-15 | 1969-05-06 | Du Pont | Preparation of zirconia and hafnia sols |
US3514252A (en) | 1967-07-07 | 1970-05-26 | Grace W R & Co | Process for the preparation of stabilized zirconia powders |
US3860556A (en) | 1968-03-15 | 1975-01-14 | Minnesota Mining & Mfg | Low water absorption dental restorative |
CA878004A (en) | 1968-06-14 | 1971-08-10 | Ii Henry L. Lee | Dental filling package |
US3539533A (en) | 1968-06-14 | 1970-11-10 | Johnson & Johnson | Dental filling material |
US3708296A (en) | 1968-08-20 | 1973-01-02 | American Can Co | Photopolymerization of epoxy monomers |
US3709706A (en) | 1969-05-16 | 1973-01-09 | Minnesota Mining & Mfg | Refractory fibers and other articles of zirconia and silica mixtures |
US3629187A (en) | 1969-06-25 | 1971-12-21 | Dentsply Int Inc | Dental compositions containing adduct of 2 2' - propane bis 3-(4-phenoxy)-1 2-hydroxy propane - 1 - methacrylate and isocyanate |
US3709866A (en) | 1970-06-01 | 1973-01-09 | Dentsply Int Inc | Photopolymerizable dental products |
US3766132A (en) | 1971-02-12 | 1973-10-16 | Lee Pharmaceuticals | Diacrylate esters of low viscosity and the use thereof as binders in dental restorative compositions |
US3751399A (en) | 1971-05-24 | 1973-08-07 | Lee Pharmaceuticals | Polyacrylate resin compositions |
GB1408265A (en) | 1971-10-18 | 1975-10-01 | Ici Ltd | Photopolymerisable composition |
US3808006A (en) | 1971-12-06 | 1974-04-30 | Minnesota Mining & Mfg | Photosensitive material containing a diaryliodium compound, a sensitizer and a color former |
US3729313A (en) | 1971-12-06 | 1973-04-24 | Minnesota Mining & Mfg | Novel photosensitive systems comprising diaryliodonium compounds and their use |
US3741769A (en) | 1972-10-24 | 1973-06-26 | Minnesota Mining & Mfg | Novel photosensitive polymerizable systems and their use |
DE2406557C3 (de) | 1974-02-12 | 1981-02-19 | Kulzer & Co Gmbh, 6380 Bad Homburg | Hydroxyl-Gruppen enthaltende Diester von Acrylsäuren und diese enthaltendes Zahnfüllungsmaterial |
US4115346A (en) | 1974-02-12 | 1978-09-19 | Kulzer & Co. Gmbh | Hydroxy group containing diesters of acrylic acids and their use in dental material |
AU497960B2 (en) | 1974-04-11 | 1979-01-25 | Minnesota Mining And Manufacturing Company | Photopolymerizable compositions |
US4250311A (en) | 1974-05-02 | 1981-02-10 | General Electric Company | P, As, and Sb hexafluoride onium salts as photoinitiators |
GB1512982A (en) | 1974-05-02 | 1978-06-01 | Gen Electric | Salts |
US4027073A (en) * | 1974-06-25 | 1977-05-31 | Dow Corning Corporation | Pigment-free coating compositions |
GB1569021A (en) | 1976-03-17 | 1980-06-11 | Kuraray Co | Adhesive cementing agents containing partial phosphonic orphosphonic acid esters |
US4150012A (en) | 1977-01-21 | 1979-04-17 | Minnesota Mining And Manufacturing Company | Discernible dental sealant |
US4292029A (en) | 1978-05-15 | 1981-09-29 | University Of Michigan | Hydrophobic composite restorative materials and their use in tooth treatment |
US4387240A (en) | 1978-06-02 | 1983-06-07 | Minnesota Mining And Manufacturing Company | Oligomeric methacryl substituted alkylsiloxanes |
US4216288A (en) | 1978-09-08 | 1980-08-05 | General Electric Company | Heat curable cationically polymerizable compositions and method of curing same with onium salts and reducing agents |
DE2850917A1 (de) | 1978-11-24 | 1980-06-04 | Bayer Ag | Dentalwerkstoffe auf basis von organischen kunststoffen in pastoeser form |
EP0013491B1 (en) | 1979-01-05 | 1982-10-20 | Imperial Chemical Industries Plc | Dispersions of siliceous solids in liquid organic media |
US4327014A (en) | 1979-04-11 | 1982-04-27 | Kanebo Ltd. | Resin-forming material, implant material and compositions for restorative material suitable for medical or dental use |
US4250053A (en) | 1979-05-21 | 1981-02-10 | Minnesota Mining And Manufacturing Company | Sensitized aromatic iodonium or aromatic sulfonium salt photoinitiator systems |
DE3065482D1 (en) * | 1979-11-22 | 1983-12-08 | Espe Pharm Praep | Use of silicec acid pellets as fillers for dental materials |
US4379695A (en) | 1980-06-02 | 1983-04-12 | Scientific Pharmaceuticals, Inc. | Dental material comprising dimethyacrylate adducts of glycidyl methacrylate with diesters of bis(hydroxymethyl) tricyclo[5.2.1.02,6 ]decane and dicarboxylic acids |
US4348462A (en) † | 1980-07-11 | 1982-09-07 | General Electric Company | Abrasion resistant ultraviolet light curable hard coating compositions |
JPS5828878B2 (ja) | 1980-08-20 | 1983-06-18 | 三金工業株式会社 | 環状ピロ燐酸エステル誘導体 |
JPS5774369A (en) | 1980-10-28 | 1982-05-10 | Mitsui Petrochem Ind Ltd | Coating composition |
DE3170993D1 (en) | 1981-03-24 | 1985-07-25 | Blendax Werke Schneider Co | Dental filling material |
US4491508A (en) | 1981-06-01 | 1985-01-01 | General Electric Company | Method of preparing curable coating composition from alcohol, colloidal silica, silylacrylate and multiacrylate monomer |
US4512743A (en) | 1982-02-05 | 1985-04-23 | Johnson & Johnson Dental Products Company | Method for masking discoloration on teeth |
EP0094915B1 (de) | 1982-05-19 | 1987-01-21 | Ciba-Geigy Ag | Härtbare, Metallocenkomplexe enthaltende Zusammensetzungen, daraus erhältliche aktivierte Vorstufen und deren Verwendung |
US5089536A (en) | 1982-11-22 | 1992-02-18 | Minnesota Mining And Manufacturing Company | Energy polmerizable compositions containing organometallic initiators |
DE3316851A1 (de) | 1983-05-07 | 1984-11-08 | Bayer Ag, 5090 Leverkusen | Polymerisierbare dentalmassen und hieraus hergestellte dentalformkoerper |
US5073476A (en) | 1983-05-18 | 1991-12-17 | Ciba-Geigy Corporation | Curable composition and the use thereof |
US4545924A (en) | 1983-06-13 | 1985-10-08 | Owens-Corning Fiberglas Corporation | Production of a magnesium chloride gel system useful in ceramics and fiber production |
US4442240A (en) | 1983-07-14 | 1984-04-10 | Bisco, Inc. | Dental filling materials |
US4612138A (en) | 1983-08-04 | 1986-09-16 | Nalco Chemical Company | Stable acidic and alkaline metal oxide sols |
DE3341888A1 (de) | 1983-11-19 | 1985-05-30 | Bayer Ag, 5090 Leverkusen | Anorganisch-organische fuellstoffe, verfahren zu deren herstellung sowie deren verwendung in polymerisierbaren massen |
DE3342601C1 (de) | 1983-11-25 | 1985-03-14 | Blendax-Werke R. Schneider Gmbh & Co, 6500 Mainz | Verwendung von bromierten aromatischen Diacrylsaeure- bzw. Dimethacrylsaeureestern in dentalen Fuellungsmaterialien |
US4544359A (en) | 1984-01-13 | 1985-10-01 | Pentron Corporation | Dental restorative material |
DE3403040A1 (de) | 1984-01-30 | 1985-08-08 | Blendax-Werke R. Schneider Gmbh & Co, 6500 Mainz | Dentales fuellungsmaterial |
US4503169A (en) | 1984-04-19 | 1985-03-05 | Minnesota Mining And Manufacturing Company | Radiopaque, low visual opacity dental composites containing non-vitreous microparticles |
US5177120A (en) | 1984-07-31 | 1993-01-05 | Dentsply Research & Development Corp. | Chain extended urethane diacrylate and dental impression formation |
US5137448A (en) | 1984-07-31 | 1992-08-11 | Dentsply Research & Development Corp. | Dental impression method with photocuring of impression material in light transmissive tray |
US4547531A (en) | 1984-08-02 | 1985-10-15 | Pentron Corporation | Two component (paste-paste) self-curing dental restorative material |
US4746685A (en) | 1984-08-31 | 1988-05-24 | Nippon Oil And Fats Co., Ltd. | Light curable dental composition |
DE3443221A1 (de) | 1984-11-27 | 1986-06-05 | ESPE Fabrik pharmazeutischer Präparate GmbH, 8031 Seefeld | Bisacylphosphinoxide, ihre herstellung und verwendung |
US4661540A (en) | 1984-12-06 | 1987-04-28 | Berger, Jenson & Nicholson Limited | Water reducible coating compositions |
DE3502594A1 (de) | 1985-01-26 | 1986-07-31 | Etablissement Dentaire Ivoclar, Schaan | Roentgenopaker dentalwerkstoff |
US4642126A (en) | 1985-02-11 | 1987-02-10 | Norton Company | Coated abrasives with rapidly curable adhesives and controllable curvature |
US4619817A (en) | 1985-03-27 | 1986-10-28 | Battelle Memorial Institute | Hydrothermal method for producing stabilized zirconia |
US5276068A (en) | 1985-03-29 | 1994-01-04 | Jeneric/Pentron, Inc. | Dental resin materials |
US4652274A (en) | 1985-08-07 | 1987-03-24 | Minnesota Mining And Manufacturing Company | Coated abrasive product having radiation curable binder |
US4772530A (en) | 1986-05-06 | 1988-09-20 | The Mead Corporation | Photosensitive materials containing ionic dye compounds as initiators |
US4772511A (en) | 1985-11-22 | 1988-09-20 | Minnesota Mining And Manufacturing Company | Transparent non-vitreous zirconia microspheres |
JPH0729771B2 (ja) | 1986-01-14 | 1995-04-05 | 悦朗 加藤 | 単斜ジルコニア超微結晶の高分散ゾルまたはゲルおよび製造方法 |
JPS62260718A (ja) | 1986-05-06 | 1987-11-13 | Shigeyuki Somiya | 水熱法による高純度ジルコニア−アルミナ系超微粉末の製造方法 |
US4719091A (en) | 1986-07-01 | 1988-01-12 | Corning Glass Works | Preparation of mono-sized zirconia powders by forced hydrolysis |
US4778671A (en) | 1986-07-14 | 1988-10-18 | Corning Glass Works | Preparation of unagglomerated metal oxide particles with uniform particle size |
EP0262579B1 (en) | 1986-09-27 | 1992-04-01 | Nissan Chemical Industries Ltd. | Process for manufacturing fine zirconium oxide powder |
DE3642290C1 (de) | 1986-12-11 | 1987-07-02 | Dentaire Ivoclar Ets | Verfahren zur Verbesserung der Haftung von Kunststoffen auf Metallen |
US4874450A (en) | 1987-01-29 | 1989-10-17 | The Mead Corporation | Laminating transparent or translucent materials using ionic dye-counter ion complexes |
EP0280673B1 (en) | 1987-02-25 | 1991-07-31 | Nippon Shokubai Kagaku Kogyo Co., Ltd | Method for production of inorganic minute globular particles |
CA1323949C (en) * | 1987-04-02 | 1993-11-02 | Michael C. Palazzotto | Ternary photoinitiator system for addition polymerization |
US4781940A (en) * | 1987-06-26 | 1988-11-01 | Johnson & Johnson Consumer Products, Inc. | Method for producing filler for microfilled dental composite material |
US4792577A (en) | 1987-07-16 | 1988-12-20 | Johnson & Johnson Consumer Products, Inc. | Stain-resistant no-mix orthodontic adhesive |
US4886624A (en) | 1987-08-19 | 1989-12-12 | Rhone-Poulenc, Inc. | Colloidal alcohol-dispersible association complexes of ceric dioxide and a hydroxyphenyl carboxylic acid |
US4859716A (en) | 1987-11-06 | 1989-08-22 | Den-Mat Corporation | Microfilled dental composite and method for making it |
FR2629071B1 (fr) | 1988-03-22 | 1991-03-15 | Produits Refractaires | Oxyde de zirconium reactif et sa preparation |
US4885332A (en) | 1988-04-11 | 1989-12-05 | Minnesota Mining And Manufacturing Company | Photocurable abrasion resistant coatings comprising silicon dioxide dispersions |
US4985340A (en) | 1988-06-01 | 1991-01-15 | Minnesota Mining And Manufacturing Company | Energy curable compositions: two component curing agents |
US5234870A (en) | 1988-07-21 | 1993-08-10 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Zirconia sol and method for production thereof |
US4954414A (en) | 1988-11-08 | 1990-09-04 | The Mead Corporation | Photosensitive composition containing a transition metal coordination complex cation and a borate anion and photosensitive materials employing the same |
JPH0667816B2 (ja) | 1988-11-11 | 1994-08-31 | 株式会社クラレ | 歯科用修復材 |
US5275759A (en) | 1989-02-10 | 1994-01-04 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Zirconia sol, method for production thereof, porous ceramic-producing slurry, and porous ceramic product obtained by use thereof |
US5219899A (en) | 1989-04-22 | 1993-06-15 | Degussa Aktiengesellschaft | Pasty dental material which is an organopolysilane filler combined with a polymerizable bonding agent |
DE3913250A1 (de) | 1989-04-22 | 1990-10-25 | Degussa | Dentalmaterial (ii) |
US5248706A (en) | 1989-04-22 | 1993-09-28 | Degussa Aktiengesellschaft | Process for preparing a pasty dental material which is an organopolysiloxane filler combined with a polymerizable bonding agent |
US5013585A (en) * | 1989-06-13 | 1991-05-07 | Shin-Etsu Chemical Co., Ltd. | Method for the preparation of surface-modified silica particles |
US5057393A (en) | 1989-07-10 | 1991-10-15 | The Mead Corporation | Dye branched-alkyl borate photoinitiators |
US5126394A (en) | 1989-10-18 | 1992-06-30 | Dow Corning Corporation | Radiation curable abrasion resistant coatings from colloidal silica and acrylate monomer |
US5190583A (en) | 1989-12-04 | 1993-03-02 | Transfer-Electric Gesellschaft Fur | Aqueous coating composition and the use thereof for coating to be protected from light, especially ultraviolet radiation |
EP0434334B1 (en) * | 1989-12-21 | 1994-02-02 | Minnesota Mining And Manufacturing Company | Dental compositions, a method of making shaped dental articals via photoiniferter polymerization of the dental compositions, and shaped dental articles produced thereby |
US5084586A (en) | 1990-02-12 | 1992-01-28 | Minnesota Mining And Manufacturing Company | Novel initiators for cationic polymerization |
US5124417A (en) | 1990-02-12 | 1992-06-23 | Minnesota Mining And Manufacturing Company | Initiators for cationic polymerization |
US5037579A (en) | 1990-02-12 | 1991-08-06 | Nalco Chemical Company | Hydrothermal process for producing zirconia sol |
US5055372A (en) | 1990-04-23 | 1991-10-08 | The Mead Corporation | Photohardenable composition containing borate salts and ketone initiators |
US5332779A (en) * | 1990-06-04 | 1994-07-26 | Kawasaki Steel Corporation | Polymerizable silica sol, adamantane derivative for use in the sol and cured resin prepared using the same |
DE9103321U1 (ja) * | 1991-03-19 | 1992-08-27 | Thera Patent Gmbh & Co Kg Gesellschaft Fuer Industrielle Schutzrechte, 8031 Seefeld, De | |
US5332429A (en) | 1991-05-31 | 1994-07-26 | Minnesota Mining And Manufacturing Company | Method for treating fluoroaluminosilicate glass |
JP2732968B2 (ja) * | 1991-09-06 | 1998-03-30 | 鐘紡株式会社 | 歯科用充填組成物 |
FR2689876B1 (fr) † | 1992-04-08 | 1994-09-02 | Hoechst France | Dispersions silico-acryliques, leur procédé d'obtention, leur application en stéréophotolithographie et procédé de préparation d'objets en résine. |
DE4212633A1 (de) * | 1992-04-15 | 1993-10-21 | Inst Neue Mat Gemein Gmbh | Verfahren zur Herstellung oberflächenmodifizierter nanoskaliger keramischer Pulver |
US5502087A (en) * | 1993-06-23 | 1996-03-26 | Dentsply Research & Development Corp. | Dental composition, prosthesis, and method for making dental prosthesis |
WO1995027680A1 (fr) * | 1994-04-11 | 1995-10-19 | Ube Nitto Kasei Co., Ltd. | Particules fines de silices a enrobage de resine reticule et leur procede de production |
TW343961B (en) * | 1994-06-17 | 1998-11-01 | Nissan Chemical Ind Ltd | Aqueous zirconia sol and method of preparing same |
JP3214982B2 (ja) * | 1994-07-04 | 2001-10-02 | 株式会社トクヤマ | 無機組成物 |
US5856373A (en) * | 1994-10-31 | 1999-01-05 | Minnesota Mining And Manufacturing Company | Dental visible light curable epoxy system with enhanced depth of cure |
JP3542425B2 (ja) * | 1994-11-17 | 2004-07-14 | キヤノン株式会社 | インクジェット記録用水系分散インク、これを用いるインクジェット記録方法、インクカートリッジ、記録ユニットおよび記録装置 |
DE19515820A1 (de) * | 1995-04-29 | 1996-10-31 | Inst Neue Mat Gemein Gmbh | Verfahren zur Herstellung schwach agglomerierter nanoskaliger Teilchen |
US5648407A (en) * | 1995-05-16 | 1997-07-15 | Minnesota Mining And Manufacturing Company | Curable resin sols and fiber-reinforced composites derived therefrom |
WO1997015526A1 (en) * | 1995-10-27 | 1997-05-01 | E.I. Du Pont De Nemours And Company | Hydrothermal process for making ultrafine metal oxide powders |
US5820978A (en) * | 1995-11-09 | 1998-10-13 | Minnesota Mining And Manufacturing Company | Durability improved colloidal silica coating |
US5886069A (en) * | 1995-11-13 | 1999-03-23 | E. I. Du Pont De Nemours And Company | Titanium dioxide particles having substantially discrete inorganic particles dispersed on their surfaces |
JP3495171B2 (ja) * | 1996-01-25 | 2004-02-09 | サンメディカル株式会社 | 歯科用充填組成物 |
ES2202511T3 (es) * | 1996-04-22 | 2004-04-01 | Merck Patent Gmbh | Particulas de sio2 recubiertas. |
DE19617931C5 (de) * | 1996-04-26 | 2010-07-22 | Ivoclar Vivadent Ag | Verwendung eines gefüllten und polymerisierbaren Materials als Dentalmaterial |
US5942559A (en) * | 1996-08-26 | 1999-08-24 | Ivoclar Ag | Dental light-curing opaquer |
EP0836845B1 (de) * | 1996-08-26 | 2004-05-26 | Ivoclar Vivadent AG | Dentaler lichthärtender Opaker |
US5760126A (en) * | 1996-12-20 | 1998-06-02 | Minnesota Mining And Manufacturing Company | Aqueous fluorochemical compositions and abrasion-resistant coatings therefrom |
US6025406A (en) * | 1997-04-11 | 2000-02-15 | 3M Innovative Properties Company | Ternary photoinitiator system for curing of epoxy resins |
US6413638B1 (en) * | 1997-05-23 | 2002-07-02 | Agfa Gevaert Ag | Coated particles containing a monomeric, polyfunctional organosilane coating |
US5879715A (en) * | 1997-09-02 | 1999-03-09 | Ceramem Corporation | Process and system for production of inorganic nanoparticles |
US6693143B2 (en) * | 1997-10-03 | 2004-02-17 | Dentsply Detrey Gmbh | Dental materials having a nanoscale filler |
EP0969789B2 (en) * | 1997-10-03 | 2015-08-19 | DENTSPLY International Inc. | Dental materials having a nanoscale filler |
DE19806572B4 (de) * | 1998-02-17 | 2007-01-25 | 3M Espe Ag | Adhäsive Befestigung von dentalen Füllungsmaterialien |
US6030606A (en) * | 1998-06-22 | 2000-02-29 | 3M Innovative Properties Company | Dental restoratives comprising Bis-EMA6 |
US6210790B1 (en) * | 1998-07-15 | 2001-04-03 | Rensselaer Polytechnic Institute | Glass-like composites comprising a surface-modified colloidal silica and method of making thereof |
US6051672A (en) * | 1998-08-24 | 2000-04-18 | Dow Corning Corporation | Method for making hydrophobic non-aggregated colloidal silica |
US6306926B1 (en) * | 1998-10-07 | 2001-10-23 | 3M Innovative Properties Company | Radiopaque cationically polymerizable compositions comprising a radiopacifying filler, and method for polymerizing same |
US6098906A (en) * | 1998-12-04 | 2000-08-08 | Kerr Corporation | Vibratory mill and method of use for low contamination grinding |
US6417246B1 (en) * | 1999-09-21 | 2002-07-09 | Jenerica/Pentron Incorporated | Dental composite materials |
US6376590B2 (en) * | 1999-10-28 | 2002-04-23 | 3M Innovative Properties Company | Zirconia sol, process of making and composite material |
US6572693B1 (en) * | 1999-10-28 | 2003-06-03 | 3M Innovative Properties Company | Aesthetic dental materials |
US6387981B1 (en) * | 1999-10-28 | 2002-05-14 | 3M Innovative Properties Company | Radiopaque dental materials with nano-sized particles |
US6586483B2 (en) * | 2001-01-08 | 2003-07-01 | 3M Innovative Properties Company | Foam including surface-modified nanoparticles |
-
2000
- 2000-02-25 EP EP05014234.8A patent/EP1586294B2/en not_active Expired - Lifetime
- 2000-02-25 WO PCT/US2000/005089 patent/WO2001030307A1/en active IP Right Grant
- 2000-02-25 DE DE60042038T patent/DE60042038D1/de not_active Expired - Lifetime
- 2000-02-25 AU AU35054/00A patent/AU3505400A/en not_active Abandoned
- 2000-02-25 JP JP2001532727A patent/JP4800535B2/ja not_active Expired - Lifetime
- 2000-02-25 DE DE60022667T patent/DE60022667T2/de not_active Expired - Lifetime
- 2000-02-25 EP EP00913648A patent/EP1227781B9/en not_active Expired - Lifetime
- 2000-02-25 CA CA2387215A patent/CA2387215C/en not_active Expired - Lifetime
-
2002
- 2002-04-15 US US10/122,767 patent/US6899948B2/en not_active Expired - Lifetime
-
2011
- 2011-05-12 JP JP2011107644A patent/JP5255092B2/ja not_active Expired - Lifetime
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP2003512407A5 (ja) | ||
Klapdohr et al. | New inorganic components for dental filling composites | |
CA2473861A1 (en) | Dental pastes, dental articles, and methods | |
Moszner et al. | Nanotechnology for dental composites | |
KR930000381A (ko) | 침전 실리카의 제조 방법, 침전 실리카 및 그의 강화 엘라스토머에의 용도 | |
JP2003529386A5 (ja) | ||
JP2003501503A5 (ja) | ||
JP2005509050A5 (ja) | ||
WO2002092022A3 (en) | Dental composite containing discrete nanoparticles | |
RU2557961C2 (ru) | Стоматологические композиции, заготовки для стоматологического протезирования и способы | |
WO2007005249A3 (en) | Nanoparticles and dendritic-polymer-based hydrogels comprising them | |
JP2018507241A5 (ja) | ||
EP2841220A1 (de) | Verfahren zur herstellung von formen und kernen für den metallguss sowie nach diesem verfahren hergestellte formen und kerne | |
JP2003512405A5 (ja) | ||
JP2005517688A5 (ja) | ||
CN104507413A (zh) | 牙科用研磨坯料的制造方法 | |
EP1249735A3 (en) | Dry toner, toner production process, image forming method and process cartridge | |
JP2014218500A5 (ja) | ||
JPWO2017154850A1 (ja) | 歯科用ミルブランク及びその製造方法 | |
JPWO2019131756A1 (ja) | 歯科用ミルブランクおよびその製造方法 | |
CN108105298A (zh) | 一种散热快、热稳定性能好的汽车刹车片 | |
ATE484487T1 (de) | Verfahren zur herstellung eines mesostrukturierten materials aus nanopartikeln | |
JP2019111407A (ja) | ワックスパターン表面処理剤、歯科用補綴物の製造方法 | |
WO2001004217A3 (en) | A matting agent for radiation curing coatings | |
JP2001139843A (ja) | 歯科用表面改質フィラー |