HUP0103400A2 - Csökkentett mennyiségű brómozott égésgátlót tartalmazó tűzálló polisztirolhab - Google Patents
Csökkentett mennyiségű brómozott égésgátlót tartalmazó tűzálló polisztirolhab Download PDFInfo
- Publication number
- HUP0103400A2 HUP0103400A2 HU0103400A HUP0103400A HUP0103400A2 HU P0103400 A2 HUP0103400 A2 HU P0103400A2 HU 0103400 A HU0103400 A HU 0103400A HU P0103400 A HUP0103400 A HU P0103400A HU P0103400 A2 HUP0103400 A2 HU P0103400A2
- Authority
- HU
- Hungary
- Prior art keywords
- styrene polymer
- polymer
- phosphate
- polymer composition
- foam
- Prior art date
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 63
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims description 238
- 229920000642 polymer Polymers 0.000 title claims description 173
- 239000006260 foam Substances 0.000 title abstract description 75
- 230000009970 fire resistant effect Effects 0.000 title description 3
- 239000000203 mixture Substances 0.000 claims abstract description 85
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical class N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 62
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 claims abstract description 55
- -1 phosphate compound Chemical class 0.000 claims abstract description 30
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 11
- 239000004088 foaming agent Substances 0.000 claims abstract description 10
- 239000004793 Polystyrene Substances 0.000 claims abstract description 8
- 229920002223 polystyrene Polymers 0.000 claims abstract description 8
- 239000010452 phosphate Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910001868 water Inorganic materials 0.000 claims abstract description 4
- 150000001298 alcohols Chemical class 0.000 claims abstract description 3
- 150000001875 compounds Chemical class 0.000 claims abstract description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 27
- 239000011574 phosphorus Substances 0.000 claims description 27
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical group C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 19
- 239000004604 Blowing Agent Substances 0.000 claims description 13
- 235000021317 phosphate Nutrition 0.000 claims description 9
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 claims description 4
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 4
- 150000003018 phosphorus compounds Chemical class 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 2
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 claims description 2
- RCRYBQKHEDNBDN-UHFFFAOYSA-N 6-methylheptyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCCCCCC(C)C)OC1=CC=CC=C1 RCRYBQKHEDNBDN-UHFFFAOYSA-N 0.000 claims description 2
- RYUJRXVZSJCHDZ-UHFFFAOYSA-N 8-methylnonyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCCCCCCCC(C)C)OC1=CC=CC=C1 RYUJRXVZSJCHDZ-UHFFFAOYSA-N 0.000 claims description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical class OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 2
- GTVWRXDRKAHEAD-UHFFFAOYSA-N Tris(2-ethylhexyl) phosphate Chemical compound CCCCC(CC)COP(=O)(OCC(CC)CCCC)OCC(CC)CCCC GTVWRXDRKAHEAD-UHFFFAOYSA-N 0.000 claims description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 claims description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
- VOWPVJACXJNHBC-UHFFFAOYSA-N methyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OC)OC1=CC=CC=C1 VOWPVJACXJNHBC-UHFFFAOYSA-N 0.000 claims description 2
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 claims description 2
- CMPQUABWPXYYSH-UHFFFAOYSA-N phenyl phosphate Chemical compound OP(O)(=O)OC1=CC=CC=C1 CMPQUABWPXYYSH-UHFFFAOYSA-N 0.000 claims description 2
- 150000003003 phosphines Chemical class 0.000 claims description 2
- 150000004714 phosphonium salts Chemical class 0.000 claims description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 2
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 claims description 2
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 claims description 2
- RXPQRKFMDQNODS-UHFFFAOYSA-N tripropyl phosphate Chemical compound CCCOP(=O)(OCCC)OCCC RXPQRKFMDQNODS-UHFFFAOYSA-N 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 12
- 238000001125 extrusion Methods 0.000 abstract description 9
- 239000000654 additive Substances 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 7
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract description 6
- 238000005187 foaming Methods 0.000 abstract description 6
- 229930195733 hydrocarbon Natural products 0.000 abstract description 6
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 6
- 239000001569 carbon dioxide Substances 0.000 abstract description 5
- 229920006327 polystyrene foam Polymers 0.000 abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 238000009472 formulation Methods 0.000 abstract 1
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 18
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 11
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 10
- 229910052794 bromium Inorganic materials 0.000 description 10
- 239000000463 material Substances 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000003607 modifier Substances 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- WXGNWUVNYMJENI-UHFFFAOYSA-N 1,1,2,2-tetrafluoroethane Chemical compound FC(F)C(F)F WXGNWUVNYMJENI-UHFFFAOYSA-N 0.000 description 4
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 150000003440 styrenes Chemical class 0.000 description 2
- XMNDMAQKWSQVOV-UHFFFAOYSA-N (2-methylphenyl) diphenyl phosphate Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 XMNDMAQKWSQVOV-UHFFFAOYSA-N 0.000 description 1
- ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 description 1
- NODLCKUQQWRUIU-UHFFFAOYSA-N 1-(1-phenylethylsulfonyl)ethylbenzene Chemical compound C=1C=CC=CC=1C(C)S(=O)(=O)C(C)C1=CC=CC=C1 NODLCKUQQWRUIU-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- SZGBUFROANKUNE-UHFFFAOYSA-N [1-(1-phenylcyclohexyl)cyclohexyl]benzene Chemical group C1CCCCC1(C1(CCCCC1)C=1C=CC=CC=1)C1=CC=CC=C1 SZGBUFROANKUNE-UHFFFAOYSA-N 0.000 description 1
- MJIRQUDRSKNXSM-UHFFFAOYSA-N [1-(1-phenylcyclopentyl)cyclopentyl]benzene Chemical group C1CCCC1(C1(CCCC1)C=1C=CC=CC=1)C1=CC=CC=C1 MJIRQUDRSKNXSM-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000007824 aliphatic compounds Chemical class 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- MWSVUOSVPYCABB-UHFFFAOYSA-N bis(2-bromobutan-2-yl)diazene Chemical compound CCC(C)(Br)N=NC(C)(Br)CC MWSVUOSVPYCABB-UHFFFAOYSA-N 0.000 description 1
- FJDFMHRXSYNDIR-UHFFFAOYSA-N bis(2-chlorobutan-2-yl)diazene Chemical compound CCC(C)(Cl)N=NC(C)(Cl)CC FJDFMHRXSYNDIR-UHFFFAOYSA-N 0.000 description 1
- ZGXHUGQEDPPKGZ-UHFFFAOYSA-N bis(2-methylbutan-2-yl)diazene Chemical compound CCC(C)(C)N=NC(C)(C)CC ZGXHUGQEDPPKGZ-UHFFFAOYSA-N 0.000 description 1
- 229940006460 bromide ion Drugs 0.000 description 1
- PZGVVCOOWYSSGB-UHFFFAOYSA-L but-2-enedioate;dioctyltin(2+) Chemical compound CCCCCCCC[Sn]1(CCCCCCCC)OC(=O)C=CC(=O)O1 PZGVVCOOWYSSGB-UHFFFAOYSA-L 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002896 organic halogen compounds Chemical class 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0038—Use of organic additives containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0019—Use of organic additives halogenated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/04—Foams characterised by their properties characterised by the foam pores
- C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US9821698P | 1998-08-28 | 1998-08-28 | |
| PCT/US1999/019408 WO2000012593A1 (en) | 1998-08-28 | 1999-08-26 | Fire resistant styrene polymer foams with reduced brominated fire retardant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HUP0103400A2 true HUP0103400A2 (hu) | 2002-01-28 |
Family
ID=22268086
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HU0103400A HUP0103400A2 (hu) | 1998-08-28 | 1999-08-26 | Csökkentett mennyiségű brómozott égésgátlót tartalmazó tűzálló polisztirolhab |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US6579911B1 (https=) |
| EP (1) | EP1112308A1 (https=) |
| JP (1) | JP2002523586A (https=) |
| KR (1) | KR20010072979A (https=) |
| CN (1) | CN1317031A (https=) |
| AU (1) | AU5900699A (https=) |
| BR (1) | BR9914313A (https=) |
| CA (1) | CA2339258A1 (https=) |
| HU (1) | HUP0103400A2 (https=) |
| IL (1) | IL141265A0 (https=) |
| TR (1) | TR200100601T2 (https=) |
| WO (1) | WO2000012593A1 (https=) |
| ZA (1) | ZA200100800B (https=) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1164158A4 (en) | 1999-10-27 | 2004-04-07 | Kaneka Corp | EXTRUDED POLYSTYRENE FOAM AND PRODUCTION METHOD THEREFOR |
| CA2398123A1 (en) * | 1999-12-03 | 2001-06-07 | The Dow Chemical Company | Halogenated fire-retardant compositions and foams and fabricated articles therefrom |
| CA2436828A1 (en) | 2000-12-22 | 2002-07-04 | Kaneka Corporation | Extruded styrene resin foam and process for producing the same |
| CN100384916C (zh) * | 2000-12-22 | 2008-04-30 | 钟渊化学工业株式会社 | 苯乙烯类树脂挤出泡沫体及其制造方法 |
| ATE416823T1 (de) * | 2001-05-25 | 2008-12-15 | Us Health | Flammenunterdrückendes mittel, flammenunterdrückendes system und ihre verwendung |
| US7144925B2 (en) | 2002-05-09 | 2006-12-05 | Dow Global Technologies Inc. | Fire resistance acoustic foam |
| JP4755399B2 (ja) * | 2004-02-26 | 2011-08-24 | 第一工業製薬株式会社 | 難燃性スチレン系樹脂組成物 |
| PL1786853T3 (pl) * | 2004-07-19 | 2009-09-30 | Bromine Compounds Ltd | Nowe ognioodporne polistyreny |
| KR101197972B1 (ko) * | 2004-07-19 | 2012-11-05 | 브로민 콤파운드 리미티드 | 방향족 폴리할로겐화 할로메틸 화합물의 합성 |
| JP4395840B2 (ja) * | 2004-09-01 | 2010-01-13 | 第一工業製薬株式会社 | プラスチック用臭素系難燃剤組成物 |
| DE102004044380A1 (de) * | 2004-09-10 | 2006-03-30 | Basf Ag | Halogenfreie, flammgeschützte Polymerschaumstoffe |
| JP4914000B2 (ja) * | 2004-11-12 | 2012-04-11 | 株式会社ジェイエスピー | ポリスチレン系樹脂押出発泡板 |
| JP2008525573A (ja) * | 2004-12-22 | 2008-07-17 | アルベマール・コーポレーシヨン | 難燃性押出し加工ポリスチレンフォーム組成物 |
| ITMO20050135A1 (it) * | 2005-06-03 | 2006-12-04 | Coopbox Europ S P A | Procedimento per la produzione di polistirolo espanso. |
| EP1951798A4 (en) | 2005-11-21 | 2011-03-02 | Bromine Compounds Ltd | BROMOBENZYLE FIRE RETARDANT SYSTEMS |
| US20080090920A1 (en) * | 2006-09-26 | 2008-04-17 | Albemarle Corporation | Flame retardant extruded polystyrene foam compositions |
| US8084511B2 (en) * | 2007-03-08 | 2011-12-27 | Chemtura Corporation | Flame retardants for use in styrenic foams |
| RU2010114598A (ru) * | 2007-09-13 | 2011-10-20 | Дау Глобал Текнолоджиз, Инк. (Us) | Вспененные стирольные полимеры, содержащие ароматические фосфонатные ап-добавки |
| ATE524514T1 (de) * | 2007-11-02 | 2011-09-15 | Dow Global Technologies Llc | Extrudierte polymerschaumstoffe mit bromierten flammenresistenten zusätzen auf fettsäurebasis |
| CN102333816A (zh) * | 2009-02-26 | 2012-01-25 | Icl-Ip美国公司 | 苯乙烯聚合物组合物 |
| JP5471013B2 (ja) * | 2009-04-27 | 2014-04-16 | 株式会社カネカ | スチレン系樹脂押出発泡体及びその製造方法 |
| KR101824268B1 (ko) * | 2009-12-16 | 2018-01-31 | 바스프 에스이 | 난연제 |
| CN102127269B (zh) | 2010-01-12 | 2014-01-29 | 盛亚军 | 一种阻燃聚合物泡沫材料及其制备方法 |
| CN102250447B (zh) * | 2010-05-21 | 2014-10-22 | 台燿科技股份有限公司 | 无卤素的阻燃性环氧树脂组合物及由其制成的预浸材和印刷电路板 |
| ES2535972T3 (es) | 2011-06-08 | 2015-05-19 | Italmatch Chemicals S.P.A. | Espumas de poliestireno extruidas de combustión lenta |
| EP2692786A1 (de) * | 2012-08-02 | 2014-02-05 | Basf Se | Flammgeschützter und wärmeformbeständiger Extrusionsschaumstoff aus Styrolcopolymeren |
| JP6185607B2 (ja) * | 2013-02-26 | 2017-08-23 | ダウ グローバル テクノロジーズ エルエルシー | 熱可塑性ポリマー発泡体の管断熱材 |
| MX2018013641A (es) | 2016-05-11 | 2019-04-25 | Owens Corning Intellectual Capital Llc | "espuma polimerica que comprende bajos niveles de retardante de flama brominado y su metodo de elaboracion". |
| KR20190046823A (ko) * | 2016-08-29 | 2019-05-07 | 아이씨엘-아이피 아메리카 아이엔씨. | 난연성 폴리아미드 조성물 |
| KR102000183B1 (ko) | 2017-08-11 | 2019-07-15 | 손민일 | 건축용 단열재 및 이를 포함하는 건축물의 바닥 시공구조 |
| KR102160266B1 (ko) | 2018-04-25 | 2020-09-25 | 손민일 | Cpvc를 이용한 난연성 건축자재 및 그 제조방법 |
| KR102160267B1 (ko) | 2018-04-25 | 2020-09-25 | 손민일 | 폐플라스틱을 이용한 난연성 건축자재 |
| CN112280204A (zh) * | 2020-10-31 | 2021-01-29 | 三益(玉田)新材料科技有限公司 | 一种聚苯乙烯挤塑板及其制备工艺 |
| TWI907671B (zh) | 2021-03-22 | 2025-12-11 | 義大利商佛沙里斯股份有限公司 | 反應性聚合物混合物、混成聚合物發泡體及其製造方法 |
| EP4384568A1 (en) | 2021-08-09 | 2024-06-19 | Italmatch Chemicals SpA | Flame retardant nucleating compositions and corresponding formulations for polystyrene foams |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL127714C (https=) | 1965-04-01 | |||
| DE1244396B (de) * | 1965-11-30 | 1967-07-13 | Basf Ag | Styrolpolymerisate enthaltende Formmassen zur Herstellung selbstverloeschender Formkoerper |
| GB1182964A (en) | 1967-09-01 | 1970-03-04 | Monsanto Chemicals | Process for the Production of Foamed or Foamable Resin Compositions. |
| AT316879B (de) | 1972-05-18 | 1974-07-25 | Isovolta | Schwer entflammbar ausgerüsteter Strukturschaum aus Polystyrol und Verfahren zu seiner Herstellung |
| DD130482B1 (de) | 1977-04-21 | 1982-03-31 | Gruetzmacher | Verfahren zur herstellung von schwerentflammbaren schaumfaehigen styrolpolymerisaten |
| DE2861556D1 (en) | 1977-11-09 | 1982-03-04 | Basf Wyandotte Corp | Particles of expandable polystyrene with improved flame-retardant properties |
| CS201748B1 (cs) * | 1978-08-11 | 1980-11-28 | Zdenek Horak | Lehcený polymerní materiál se sníženou hořlavostí |
| JPS5712048A (en) | 1980-06-26 | 1982-01-21 | Teijin Chem Ltd | Flame-retardant, expandable styrene resin bead composition |
| JPH01247434A (ja) | 1988-03-30 | 1989-10-03 | Sekisui Plastics Co Ltd | 難燃性スチレン系樹脂発泡体の製造方法 |
| JPH0277435A (ja) * | 1988-09-14 | 1990-03-16 | Sekisui Plastics Co Ltd | 難燃性スチレン系樹脂板状発泡体の製造方法 |
| HUT65242A (en) * | 1990-06-14 | 1994-05-02 | Dow Chemical Co | Process for producing of fire resistant alkenilaromatic foams and fire resistant alkenylaromatic foams |
| JPH089678B2 (ja) | 1990-10-31 | 1996-01-31 | 積水化成品工業株式会社 | スチレン系樹脂発泡体の製造方法 |
| JPH07106591B2 (ja) | 1990-11-26 | 1995-11-15 | 積水化成品工業株式会社 | スチレン系樹脂発泡体 |
| JPH04307228A (ja) * | 1991-04-03 | 1992-10-29 | Kanegafuchi Chem Ind Co Ltd | ポリスチレン系樹脂押出発泡体 |
| CA2123984A1 (en) | 1991-12-13 | 1993-06-24 | William G. Stobby | Fire resistant alkenylaromatic foams |
| JP3198676B2 (ja) | 1992-11-19 | 2001-08-13 | 三菱化学フォームプラスティック株式会社 | 鋳造原型用熱可塑性樹脂発泡粒子 |
| DE4240109A1 (de) | 1992-11-28 | 1994-06-01 | Basf Ag | Feinteilige, expandierbare Styrolpolymerisate, insbesondere für das Recycling von Polystyrol-Partikelschaumstoffen |
| JPH06329824A (ja) | 1993-05-26 | 1994-11-29 | Kanegafuchi Chem Ind Co Ltd | 切削加工性に優れたポリスチレン系樹脂発泡体 |
| DE19508935A1 (de) * | 1995-03-13 | 1996-09-19 | Basf Ag | Flammgeschützte thermoplastische Formmassen, enthaltend als wesentliche Komponenten |
| DE19508939A1 (de) | 1995-03-13 | 1996-09-19 | Basf Ag | Verfahren zur Herstellung von flammgeschützten, Polystyrolschaum-Recyclat enthaltenden Polystyrol-Partikelschaumstoffen |
| DE19624827A1 (de) | 1996-06-21 | 1998-01-02 | Basf Ag | Flammgeschützte Polystyrolschaumstoffe |
| DE19632439A1 (de) | 1996-08-12 | 1998-02-19 | Basf Ag | Durch Extrusion hergestellte Schaumstoffplatten |
-
1999
- 1999-08-26 BR BR9914313-5A patent/BR9914313A/pt not_active Application Discontinuation
- 1999-08-26 CA CA002339258A patent/CA2339258A1/en not_active Abandoned
- 1999-08-26 CN CN99810541A patent/CN1317031A/zh active Pending
- 1999-08-26 WO PCT/US1999/019408 patent/WO2000012593A1/en not_active Ceased
- 1999-08-26 US US09/744,005 patent/US6579911B1/en not_active Expired - Fee Related
- 1999-08-26 TR TR2001/00601T patent/TR200100601T2/xx unknown
- 1999-08-26 JP JP2000567601A patent/JP2002523586A/ja active Pending
- 1999-08-26 AU AU59006/99A patent/AU5900699A/en not_active Abandoned
- 1999-08-26 EP EP99946638A patent/EP1112308A1/en not_active Withdrawn
- 1999-08-26 KR KR1020017002426A patent/KR20010072979A/ko not_active Withdrawn
- 1999-08-26 IL IL14126599A patent/IL141265A0/xx unknown
- 1999-08-26 HU HU0103400A patent/HUP0103400A2/hu unknown
-
2001
- 2001-01-29 ZA ZA200100800A patent/ZA200100800B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2000012593A1 (en) | 2000-03-09 |
| TR200100601T2 (tr) | 2001-06-21 |
| EP1112308A1 (en) | 2001-07-04 |
| CN1317031A (zh) | 2001-10-10 |
| CA2339258A1 (en) | 2000-03-09 |
| KR20010072979A (ko) | 2001-07-31 |
| AU5900699A (en) | 2000-03-21 |
| BR9914313A (pt) | 2001-06-19 |
| IL141265A0 (en) | 2002-03-10 |
| JP2002523586A (ja) | 2002-07-30 |
| US6579911B1 (en) | 2003-06-17 |
| ZA200100800B (en) | 2001-08-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| HUP0103400A2 (hu) | Csökkentett mennyiségű brómozott égésgátlót tartalmazó tűzálló polisztirolhab | |
| EP1352921B1 (en) | Extruded styrene resin foam and process for producing the same | |
| JP4914000B2 (ja) | ポリスチレン系樹脂押出発泡板 | |
| KR100610392B1 (ko) | 열가소성 수지계 난연성 발포체 및 그 제조방법 | |
| WO2010141400A1 (en) | Infrared attenuated polymeric foam insulation with flame retardant performance | |
| KR20150022844A (ko) | 난연성 폴리올레핀 발포체 및 그의 제조 | |
| US20070257241A1 (en) | Novel Flame-Retardant Polystyrenes | |
| JP2013124281A (ja) | ポリスチレン系樹脂押出発泡体の製造方法 | |
| JP4901026B2 (ja) | ポリスチレン系樹脂押出発泡板の製造方法及びポリスチレン系樹脂押出発泡板 | |
| JP3981945B2 (ja) | ポリスチレン系樹脂押出発泡板の製造方法及びポリスチレン系樹脂押出発泡板 | |
| JP6099495B2 (ja) | 難燃剤溶融混練物及びこれを用いたポリスチレン系樹脂押出発泡体の製造方法 | |
| JP7390170B2 (ja) | 熱可塑性樹脂押出発泡板及びその製造方法 | |
| JP4261995B2 (ja) | ポリスチレン系樹脂押出発泡板の製造方法及びポリスチレン系樹脂押出発泡板 | |
| JP5337208B2 (ja) | ポリスチレン系樹脂押出発泡板の製造方法 | |
| JP4784113B2 (ja) | スチレン系樹脂押出発泡体の製造方法 | |
| JP3913460B2 (ja) | スチレン系樹脂発泡体およびその製造方法 | |
| JP4222916B2 (ja) | 難燃性ポリスチレン系樹脂押出発泡体及びその製造方法 | |
| JP6211442B2 (ja) | ポリスチレン系樹脂押出発泡体の製造方法 | |
| JP7667730B2 (ja) | ポリスチレン系樹脂押出発泡板の製造方法 | |
| MXPA01002166A (en) | Fire resistant styrene polymer foams with reduced brominated fire retardant | |
| JP5105700B2 (ja) | スチレン系樹脂発泡体およびその製造方法 | |
| JP2025158933A (ja) | ポリスチレン系樹脂押出発泡板の製造方法 | |
| JP2024157337A (ja) | ポリスチレン系樹脂押出発泡板の製造方法 | |
| JP2024173093A (ja) | ポリスチレン系樹脂押出発泡板の製造方法 | |
| JP4474733B2 (ja) | スチレン系樹脂発泡体の製造方法 |