HUE027461T2 - Fungicid szubsztituált 2-[2.halogénalkil-4-(fenoxi-fenil]-1-[1,2,4]triazol-1-il-etanol vegyületek - Google Patents

Fungicid szubsztituált 2-[2.halogénalkil-4-(fenoxi-fenil]-1-[1,2,4]triazol-1-il-etanol vegyületek Download PDF

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HUE027461T2
HUE027461T2 HUE12735512A HUE12735512A HUE027461T2 HU E027461 T2 HUE027461 T2 HU E027461T2 HU E12735512 A HUE12735512 A HU E12735512A HU E12735512 A HUE12735512 A HU E12735512A HU E027461 T2 HUE027461 T2 HU E027461T2
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Jochen Dietz
Richard Riggs
Nadege Boudet
Jan Klaas Lohmann
Ian Robert Craig
Egon Haden
Erica May Wilson Lauterwasser
Bernd Mueller
Wassilios Grammenos
Thomas Grote
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Basf Agro Bv
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/257—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings
    • C07C43/263—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings the aromatic rings being non-condensed
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/257—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings
    • C07C43/29—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
    • C07C47/575—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/20—Unsaturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/255—Unsaturated compounds containing keto groups bound to acyclic carbon atoms containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/84—Ketones containing a keto group bound to a six-membered aromatic ring containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Claims (10)

  1. Fangicid szakszó? aák 2~[2jjak;geiiMkil 4-(feiox5- feai:n--l-[! í2!.4]tríazoi--í -íl-etanal vegyietek S^aástói 1. í:
    képleté vegyületeL ahol: R jelentése CF3; R! jelentése lá&amp;ögéjaato^ {1 -6 szénatömos)--atki>,: (2-6 s2ÍaaÉopáö#^lkefíiL (2-6 szénatcasosFalkmík (3-S szsaaíoaaosl-eíkfeaikll, (3-8 s^énaísmöSÍ-65:kÍoaÍkll42-4 szénstomös^Ml fesi, £esÍ4M %ώ&amp;* m>mm^dísÉ,:f«tóí^2^-s^míc»^|NÍÉi^Ö vagy iMl-(2-4: sxssátdíBos>^ffiikícgoporS:; R;' jelentésé (! -6 ;szákík<»ös)--alkií,: :(£-&amp;'saékáíoPsöakaikenü. (2-6 sséaaíöS^sjhsikimi (3-8 szénatomosFcikioaíkü. fejűi íenü-(i-4 sís&amp;aítűttóslrélki, ferűH'2-4 szénatomos}~alkaűi vagy i?ni~(2-4 az R; és/vagy R2 alifás csoportok 1. 2. 3· vagy a leható ma- xÉítális számú azonos vagy egymástól eltérő R:5 csoportokat tartalmazhatnak, melyek egymástól fág-gétÉmM az aláOfelak kiaülvilasztoaak: R® kálogésatora, CN, mtro, -(1 -4 s»ésiatomos}-sátel:1$ *P*4 ahol az R: és.· vagy R" cikloalkil és/vagy feűlgyőkdfe ,2,.¾4, 5 Vágy "4 lehető ttmkirttills számú SZO~ nes vagy egymástól ekérő R8 csoportokat tart^ÍB®®É»ÉE^.melyeR«gyjptóől idggetletnil m alábbiak hfeu! választottak: R8 halogénatom, CN, niiro, -(1-4 szésatOínosRalkil -(1-4 szésatomösj-alkokL -(1 -4 ssesstornosj-Mogéuaikü és -(1-4 saériaiontos)~halogőaalkotticsoportQk: R2 jieletkéseMlögénaiom, CN, nitro, -(1-4 ^Étálomosí-klMl ~(1 -4 széisatomosl-halagénalki], -(1-4 szánatmmtsj-álkoxi vagy 4' n egy együttható és értéke 0, 1, 2 vagy 3; R4 jalmtesetl^gá^Rasa, GN, ráíró, -(1-4 széMíc«»ö:sJ«alMI, -(1-4 széaaícmtssi-lsaloiéoalkil, -(1-4 szénaípmos'l-aikoxi vagy -(1-4 szésatomoS:i4salogéítallt)xies0|Kírt; ϊχϊ égj? ^yötíkató és értéke 0, 1, 2,3, 4 vagy 5; mzzék Halálai és mezogazdss%ílag élttgailiaío sók
  2. 2. Az |, igénypont szerinti vegyüleíek, ahol E:* jetagesphiérogépsíop, (.1 -4 szénirtoffiosl-aíkil., aüil, |2ri sgfeaípt^ ciklofropÜ, férni henzil íenjleteml vagy ibaiMmileseport,
  3. 3. Az 1. vagy 2. igénypont szerinti vegyüietek, ahol R ; jelentése Ikfcogénatom, {1-4 szénatömos)-alkil allíi, propargil vagy benzilcsoport.
  4. 4. Az 1-3* tg&amp;spaatok· hám^lke'saeíiöp'is^yölelek, ahol m- érték© 1* 2 vagy 3 és E4 F és Okozol választop.
  5. 5. Az 1. igénypont szedni! vegyhietek, ahol a“:Ö, Rk jelentése Mdrögénaiotn, É4» jelentése 4-0 és R1 jelentése 1| Oh, O^OOTj, CHA>C-01:.? CH-OCR ízopropil mkloprapii és CF.;kö zül választott, és az olyan vogynieték, ahol ís«%; Er jelentése CH2, Kijelentése 4-0 és R* jdfesíteii OI3, Oí^Oh, izoptopil és cMopropiesoport ahol n=«ó, E4 jelentése II RÍ jelentése 2.4-Ch és R! jéiéhí ékeik: és az olyat) vegyület. ahol n~t>, le jelentése H, R4,r, jelentése 4-F és: RJ jéléhíésé Clí;}, és az olyatt vegyőletek, ahol n~0, R: j döntése ÖR, RÍ j elentése 4-€1 és R* O-FOF, és CH2CH«CM2kiüi| y*?|3i!01et^,iWiig?% R?:.j^esíéfcf metii-proparg;lesöpört, Ríjelentése4-C1 és R; CH2CH*, és CHA'sOlf közül választott
  6. 6. Eljárás az 1-3 . Igéttyponíofc bárntelylke szerinti 1 képleté vegyületek előállítására, melynek során egy Ma:
    képleté vegye letek, :alo!: R, Rá és tt itó 1-5. igénypontok Mrmdyikibéh megadott katalizátor jdedéíéied :Izöpropttosgnézlníp4sloge«yáe1:5 májé ezt feőveiéeh R*€CIO vegytiettd reagáltatnnk, áltól K ' az 1-5. Igénypontokban megadott; és a kapott ¥ííl:
    képletü vegyüleiet,. sholR, R*, R* és a m 1-3. igé&amp;ypeMok feán&amp;elytkébes aiegadöti* Mzlktts körülmények kézéit egy II;
    képleté -vegyöteitd koaeertáljzk, ahol Rá és .m zz !-5. tgértypemak báiradyikébez «egasföít; és a keletkezett Va:
    kégletü vegytllsteí, abol R, R5X Re R4 m és a az I -5. %é®ypoaiok bármelyikébea: raepdöít, tríffietilszul^öxiomöm-halogemdáel reagáltalak; majd a kde· kezeit, IX:
    kepkuí v«s>'u5er^ aho· R' R>R'R > ® 082 1-5. igéxvyponíok báraselyikébea megadott, feázikos és adott esetben a kapott! A;
    képleté vegyüleíeí, ahol R, R\ ΒΛ R4, rr> és n az 1 -5. igénypontokbármelyikéban megadott, bázikss körülmények között R2-I,e vegyileM émmhMI&amp;k, ahol LG rmkleofíi körülmények közön, cserélhető kilépő csoport, az .1 képletö ttegykletek elMlktásara.
  7. 7. Eljárás az 1-5. igértypoatok báptatlylfee szerinti I képletö vogyüietek előállítására, melynek során eg}·'IX:
    képiem vegyületst, ától,!1,:m és n az 1-5. igénypontok bármelyikében megadott, savas körülmények között R2-OH vegyülettel reagáltatok, ahol R' áz 1. vagy 3. igénypontban megadott: és a ka pott X:
    képletű vepéisteí, ahol R, Εί;.,:Ε\ %?, R4». *».£*·« a* 1-5. igéa^ijosíoli teáíSjeljíIMbSíK megadott, fealögéae2Ös»ííTs! v^f':S2:ö:llwálSssserf«!' resgálGtpk; és á istóke^eit S:
    képleté vegyiletet éket R, R\ E" , ll<:j IC*-88# &amp; a? 1-5:. igékypoktök Mmetylkééea megsáöÉ és LG mskleofil kWtoésyek közoEsseíé&amp;etp kilép® csokit. lIM^^^ríaxolíál reagálta*! tik as I képleté vegyitet eéesliítésára. t AWmVa, VI, Vűls íX;
    keplető vsp^lsísk, s&amp;sl K, R', &amp;, ts és k és 1¾, jstemérak esetek. see 1-5. tgékypektok feármeíyákébep megadott és akd Xs jelentése I vagy Br, ami a íékélelkt, hogy a 1¾ ikepletfcpm ,:¼ X! Br és R CF? és a értéke 0, m mm- 0 és R\ kém 4-Br, 3-€Fjs 4# vagy 2.-Q; és as Va képleÉsem ha Rl Mdimgésstma és R CF* és íf| R^ mm 3Cf| vagy 3-0^-0. $. Agrokémiai ÉéÉálsaéay, Islszkméoy egy segédanyagot és legalább egy 1-5. igéíwjpöoíok bár melyiké szériái I kepletü xegyiletei, mmk N-öxid^ vagy mezőgazdaságilag efegadbati tóját tartalmazza. 10. A 9. Igézypom szerződ késxirffiésvyek. mélyek további Mbábyágot is tartalmaxaak.
  8. 11, Legalább egy I, Igéoygopt szériáit vegyülstet taraümaaó készitmésyek, melyek további, az alábbi: A) - 0} csoportok közűi választott további hatóanyagot tanalm.azn.ak: A) Légzésgáílék - Komplex Hl gátlók a Qo helyen (például strobiluríook}: azoxistrobüi,ccsarűctoxi$Srobin, eoztmoxlsiidbm, dimoxistrobkg ériesdx^árim Aáiatóíitstrobiii, Íbíoxastrohin, kresoxtro-nietji, meieembbstrebía. orvsasírobiri, picoklströbbi, pirsaíöstnkáa, ^irnnetostrobin, piraoxtstrobin, tASoxiStzbbiu, 2-[2-i2,5tóime5il-ienöxkbetil)-íeiül]-3-rsetoxi-átóisav-mettlászfer és metexnnxno-N-mettlseeiap^trielopirfk^^ §®óxad;<me, feamidooe: - Komplex Ili gátlók a Ql belyeo; eyagoíatód, mstoxi-pindin-2-kan:>oíiil)amisoj-ő-mail4,9-dioxO“l,5-<liöxO0ari-?-íl] 2-metilpropanoát, |p:Si!6S!7R,8R)-8-benzlb3-Í|3~(acetoxp3setóxi}'4-meiöxbpMdtók2-katóoöSmbio|-6'ffi^i-4,9-dtoxo-l}5-áloxoe80i-7^I|2rrnmipeípaooát, [{3S,6S,7.R,kR.l~8~benz5:b3-i[(3-'!ZObiitöxlk;aj'boniloxi-4-metoxi-gsKdm-2-kaibonb}asimo|-6-meííi4,:#-dloxo-1 ?5 -dioxoo®íi-l-íi| 2-meilÍpropasoát, í í 3S}6S,7I^SP^-Ítóözíl-3-[r3-(L3-beozodioxcé-5-iMétoxi)~4-roetóxi-pÍrídÍh-2-lar:boíb!]ammo|~6-meti.Mí9ltóáoxö-i,5-dibkonatw-üj 2-merilpropanoái: (3S,6SJR-isK)0~[[(3-tódroxM-melöX{-2-piridiíii!)kartoái|®B3É^|» 6-oietil-4,9tóioxo-S-(fenilmeul)-],5<li.oxor!an-7-il 2-a:íerilpropao:í>át; - KOtóplek iligálbk (példM karboxamidok): bemxian-1, bixafesy hoscakd, k&amp;rboxüy ífciíaram., íluopiram, Hutolaml, AoxaplroxasL lámmetpÍr, Izóplrazam,. mypomL oxikabboxliö^ peii&amp;lesaJ; peoilöpiraA :sedáx3ísés lecteilaiam, t · riuxamiA metil-lif-pirazol-á^rboxam d, N-4-u V^nrietd-xabV-renri) 1A dmteul X-tluor ü prta/ol 4 kaífeoxamld, N-P4dCkíéMtetikne>-1,2 A,4-teirábí:dtó-l A-xpetaitooallalen-S-ill^^dillticmoeUIVl·' meAl-IÉ-pimzoM-fearboxamid^ 3-(difiimrmetil)-l-íí^il-KKLiv34rímetilkidait^4-íl}pirazol-4~ kaZboxamid,JAiriStsormelij:)--!-metlbMAI,l34nmetiMs»it0»4-ii)pimzol-44cad3oxamid, K3^ÉéÜM$i. 3 AtrifKormet-ü)-! ,5-dimsi!~K-( 1,13-bimstiMod<m~4-:ií}pimzöl-4-karbox3niid, 3~(#t1^-®^l)”lJ^i^'íKN41A3~tómeíiiste-4Al^i*aTOÍ*4!· karboxaaád,; - más légzés gátlók (például komplex I, uneoaplerak): dlrinmeterlm, (5,8-di fiyorkixsazolm-A-il)- (2-[2-inor-444-íní]aomiet::ipiPáío;-2-aioxi}-fenílj-etal] -aoiin; nitreíemi származékok: binapacríl, dínobutort, dlsoeajz, áttazipspi; feamzope;: szerves fémvegySletek: fealm sok, példáéi ίδ^|ρ.4»®^,;:·ΐ0ί08 kloád tvtsgy leoltó bldrpjsld; ametoctísdlp; és isiliiofám;; Sl'É&amp;etol hioszktézis gátlók (SSÍ fengteidek) - 04 dentsiiáz iaMfetomk (DMí 'topdi^O'^a^^ses^^gescI, dtóeonazöbM, epodconazel ftnbraxonazok ílö^slbeoaaaötj: iasÉazol. íbxtá&amp;f^ksásmímm% HmteteoBaz-cá, ipbösBaz©!, mstcööaoöl, yyéiobutaídi, ekpocon&amp;zok padöbiitadk peüoosazd, pröpieoBa®l,;|sröd:oconazo], ámewazd, tebhcoíiazoL tetraconazoL Iriadi&amp;SPí&amp;a, íáadsmeaók. trfbco&amp;azol,. raucona/ol: l~ ík!é#emI,b24-^”dii1uoríeaíi}<íx|ráa3meüI]^5^íöeíaBat®~! H~Il!2,4|íákKbli 2-^/-(253^)-342-Mó£^n.íi)-2-(23~dfíü^rÉa21)^irátólmdill-2lrl-|i ,2,4|tnazol-3-H{>l :«á3j«fezolok: imazalií. peibKszeáí, proehioraz, tritkirmzok pinrnidinek, píridínek és piperazinok: teaarirnoi, auarimol, f írsfemx, triíbrin; - DeteH-redtdcíáz: iahibiíosrok: idjpraplmorph, tndemcapk, feeptopidia, piperéiké sprbxatók: - 3-keto rednktáz inhibilorok: íenkexankd; C|N4IÍdP^^-$zMázís inhibitorok' - feffilapaidbk vagy aeil aannosav íkagkldek: beualaxiL bsaalaxi!-M, kiralaxik melalaxiL metakxü-M <s^írsree> - egyebek: feymesazoh oetikapne, oxbias&amp;ynb^ S-ihpEéitpzio, 5-fíuor-2-<P- tb!slpeyxi)plrimi^^ 5-í]«or-2-(4-fl«eaierdteietoxi)puinxidii^-4-aodo; D) Sencisztédás és cyíoskeietoa mhibitarok - Sdxahn dhiMtofok, pd#ei beszbpldazolok, tlolsrátpfc: beae^lh k&amp;rbeadazlpa, Ibberidazok babeodazo), bí^banate-ssebl;; ínazolopidakdbxek;: 3-blbr“744^ipetiipipefidm-1 -íl)-é-( 2,4,&amp;-tóSaorfenil^kÁd^tria^^ - tbás ss|toaztbdbS Mabiorok:: dteioferdzsrh, ©i&amp;bbxáía, pmdtamoi dnopleolide., xosandd, radraíenone, pikoishohe;: E| ádÉBÓsak és protéípskihtézis iobibhorok - ipetipbíe szintézis irddbitbrok (amilno-plriimilihék);: cyprcklai!* asepampiriap pklaxetani; - protela sMsíézlx Inhibitorok: biasucidin-S, IssagamyéHii^gaiJpemibíÉoeM^á^lbfea^ miidiorpyekg -s*re^g&amp;E^>í<áí^*:--id^^^cik^in. polpxia, validamycin Λ; f) Jehraasgdíkelo iahíb h oxbk - M&amp;P / bíptyin-fcináz iaMhiyxpfc Stjerimld, :iptpdS:ca5o? fppíclordk íludioxoail; - G protein labibitorak: qoiaoxilea; G) J.-ipid és membrán szintézis inhibitorok - iöszíbilpkf biosziatezls ihhibiarbk: ediíenphos, Ipr&amp;eníbs,: pir&amp;kxphbs* izoprobefene; - lipid peroxidácld: Mám®? -ψΜιβφ^. leenazade* tokiblbadbdii, blleidl, kiörkÉg eiddlazcd; - Jfcxs^fbl ipid bíoszlhléxis é$ sejtik! leiskódás: dnaetomorpig ílmborph, mandipropamkj, piritnorph, heptiavaUtearb, iprpvaliknrb, yaiiíépglate es· 'N-{l4í;*í karbasriinsa.v~(4-í|ppkeyí)esder; - sejtmembrán permeabilitást és zsírsavakat befolyásoló vegyiileiek: proparnokarb, propansokarb-hidrochlorid; - zsírsavaiméi hidrotáz inhibitorok: i-i;4d4~[5-(2,6^it]noiteoM}^5-dshidro-3-iz0xazobl]~24iszolil]-I·- piperidinil j-2spmMM-{MinonmáI)“iM 41]etanoxs H) Multisite hatású inhibitorok - szervetlen hatóanyagok: Bordeaux elegy, rézaeeiát, rézhidroxid, réxoxichloride., bázikus rézszuiíai, kén; - tio- és dibofcarbamáíok: férbam, maaoozeb, snaneb, métám, meiirarn, propinb, tbam, zinb. ziram; - organoehlorin vegyületek (például itaiimidok, suliaroidok, klórnitrilek): amlazín, chloroíhalosil, eapkJol eaptan, folpet, diddöíluanid, dlkÉíffen., íiusaliamid, hexaklőrbermd, pemaehlorfenoí és sói, phíaliáe, toiilOuanid, M444;!or#4útxo-fei!|4Xred^^ - guanidínek és egyebek; guanídin, dodip, dodia tree base, guazatía, guazatk-aeetlí, iminoctadin, iminoeiadíxi-íríacetát, ditiaaoa; 2,6-dimetiI-l íl,5íí~[l ^idbipopJ-ccS^" c’ldipirrol-l ,3,5,7(2H,6M}-tetraon; I) SepMsxiníézk inhibitorok' - glukáa szintézis inhibitorok: vaMamycin, polyoxia B; melanin szintézis inhibitorok; piroqoilos, triciklazoi, carproparnid, dicikknnet, fenoxamk Jbblavsayvédekezés induMtorok - aeibenzblar^S-Süeii, probenazol, izobaoll, íiadinii,; prohexadion^-eaicium:; fezibsátök: ibsetíi, Ibsidibalnpdaiun, pbospborotís acid és sóik; ^|s;=Í^EaaedSS*|éa&amp;- - btoaopol, chinomeüomu, cyűaffenamid, cymoxami,; dMomel, dehakarb, dicfcmezin, difemtoqaat, di.femo^3at-níetílsuliate, difenilamia, fenpírazasnm, fiumetover, iMöi&amp;mld, Itíiápl,; melasulíbkarh, niirapirim nitrothai-ízopropil, oxitHtöpper, proquínazid, tebuíioqum, tedoítalam, íriazoxíde, 2-butoxi-ódodo-Siúropikk^ N^dkiopropiJmmodnni&amp;o^bdifioer^n^^ 2-fenil aeetamki N'~(4"(4-fclór-34rit]oormetíÍ-foox!}~2,5-i;limeíii*fenil}-N~eí jl~i\:-nieiil tbrmamMin, b^,44^4-l]uor-34πfm0r-nϊetit-feöOxi)'2,5-dίmeti!d½rf!)-¾:-eti:^'^i'«κ:t:ίi formainkba, N'-(2~metil-5-Mi:apmíkiW43-t^^iSzilaod-propox^-tenil}d5í-etild4-metil íbrmamidio, N ’*i(5-difhíonnéííl-2-mepi^|3drh^ilszilaml^ropoxi}-fcnil|^-eiil^mtkil fens:atrndia, 2-|l-|2d:5-ateblk34dtlaorn3^ii-pirazoI-l4i)-amil|^ip®ridlar44lHiaze4*4*kai|}onsay métíHl,2?3;!;44eb^í^ |kP^S-ateíil-34riitkrtheíiÍ~pirázobi4l|keetil|‘pipeíidÍ5i-44lk4lszói-4"fcatboasáy Pietii-lRbi,2,3,4-tettahidjo^kÉáléa-ldi^anüd, 144-'i4-[5-(2,ö-difliiorfenij)-4,5-diliidrO"3~ízoxazoHi]-2“tiazclii]-l'· pjperidbüI|P-|3 -raelil-3 dtöflnonnePi)-! ii^pirázöl-l: difetanon, metoxi-eeetsav Ó-tere^hutii-S-Suor-2 J4tee4l43noiinr44l észter, 3ν4^0ΐΐΡ-|ϊ“|(5-ηη43ΐ-34τίΒηοπ£κχΙ1-1 B-pirazol-1 4i)~aeetü] -piperidin^-iil-M-ll 11:)-1,23,44etrahidmnaialea-l 41j^4iaxolkarboxamid, 3vp4^’^®tilie3pi|-2,3-dtmetii4zoxazoIidm-3-ü}-piridin, 3-f54:4~klórt'ex»l)*2,3”dimeul~izoxazolidin-3-il]-'pindin (pPÍzoxazpl|s :M-(Óns®toxi-pMdín--341| eiklopropánkatbonsav amid, S-klór-l 44,órdiö5etoxi-pirimidinr· 2-0>-2-meti 1-1 M-beíiííc*i_miíia2:o 1, 2-(4-klór-fenM)~N44XA4Gimet0xi-iéüil)-Loxs2öbS4!jO-prop~2~ imloxi-aeetamtd; Q'íS^i^íéa^ biakoniroll szerek, növény bioaaktivátorok' Ampeh>myces qinrimaM (például AQ H/\ IptáseiemMe ΟηΰΤΓΧ; Co. KG, Gennm\y}f AspergilhíSÍhviiS (például AFLAGUARD*, Syngenta. CB), /1 ureobasidium puHulam (például BOIIGTORL Mö~fern*GmbiLGeímaBy), Badi- B-30Ö87 a SONATA* és BALLAD*1 Flux, AgraQuest Inc., USA), Badllux subtiiis (például NRRL-Nr. B-2166I izolátor» a RHAPSODY®1, SERENADE* MAX IsILiGNABS*1 termékekben ÁSÓ, AgraQuest Inc., USA). Badílus subidis var. midoiiquej'ddem EZB24^IpéldMlTALGRO^, Mmmspbé BMe^ olophila 1-82 (például ASPIRE*, Eeogeu Inc., USA), Candida saüomm (például BIOCURE* Oizozimntel keverékben) és BIÖCÖAT*, Micro Flo Company, USA (BASE :SE) Is Arysta), Chiiosan (pékiáal APMOUB-ZBN, BotElM ΐΜ., NZ), Clonostad^ rmm E mtemdate, más néven iMixdadmm míemémm$pM$M 11446 izolátom: PRESTOP*, (például CONTANS*. Frppbyta, Gemajsy), End&amp;tmpmasiiica, CMCM, France), Crypíamcam aibMm (például ÁTÉL© PLUS* Anchor BitoTeetaplogies, South Africa), Mmariim (mspanm (például BIÖFOX* : SJAPA., Italy, FUSACLEAN®, Batumi Plant Protection, France), Mdmknda\uajh(víicoÍ0d^^Síá SBEMERx Apogteen, rErnsram (például AiffiBOT'’', Agra u sin, France),EkieMapsdgtgwdm:(piidSuLl®rS(3FL Verdera, Finland), EMmiezymapovcniam (például SFOROÍEíX*, Plant Erodncfs Co. Ltd, Canada), .Pytmm aitgandrum DV?4 (például PGLWERSUM*, Rsmesks SSRO, Bloprep&amp;raiy, (például RIGAIJA*1, Mmmm BioEmoyatioss, USA). T&amp;iwvwycesfiwm'Wl !'%4|íliteiFFRii(tÍL^ Fropltyla, Germany), Tricboderma lisperdium SKT-1 (példátd ECÖTLÖPB^LKnmiái: Chemical Industry Co,, Ltd,, Japan), 7 -Mraviridc LC32 (például SENTIKL* 144Pl|, T. hamamrn:T“22 (például PLANTSH1ELD s, BloWefks:lne.pDSA), ROOT FRO5* Myconírúl Líd., isméi), L harziamm T-39 (például TEICHODEX*1 és TRICHODERMA 2C)00* Mycontrol Ltd, Israel és Makbtesbbn lid., Israel), T. hmdanum ér 7; viride (például TR1CHÖPEL, Agrimm Teeiinologies Ltd, NZ), 7 harzianum lCC012es 7. viride 1CC080 (például REMEB1ER# WF, Lsagro Rieerea, Italy), 7. pefysponm és 7 kardamim (például B1NAB* BfNAB Bip-lnnovaipu AB, Sweden), Jl stromatiasim (például TRIOOYABA GXUP.L.A.C, Brazil), L vimmfjL-21 (peldial SOILGARD* Curtis LLG, USA), T vmie (például TMECQ* Eeosertse Labs. (India) Pvt Ltd., Indies, BID-CURE* F, T, Stanes &amp; Co. Lid., Indie»), 7. viride TV! (például T. viddeW), ApiMotec sri, Italy), Ubcbsámmmtdemomii 118X13 IpBdlni BGTRYbZEN*, Botry~ Zen Ltd, NZ); M)lTdueLedis szabályozók abselsip:asíd,: amidochlor, aacyrnidol, 6~benzilamiriopurm, hrassinolide, butralio, cblormequai (ébioraálpM llpAd), ebolínklpÁi, cskianilide, darniuoAde, dikegulac, dimetipin, 2,0-dmvetílpurídia, etepbpn, ilutnetralit?, iTarprlmidol. flutiscet, forcblorl'enuroa, gibberellic acid, ipabenflde, indol-3- eeetsav,, :<ρ%^|Β^|0Ρφϊ9αβ£ kloridk uarialinesetsav, N-h~beari:lsdenia5; paeiobirintapL gpfegP&amp;eo&amp; (profesxaá&amp;se^aimj^), praydr^smoa, tidiazurím, tmpmttaök. tributíl phosphorotritioát, 23,3-trijodbenzoesav. trinxapac-eül és uniconaaol: 1¾ líerbicidek ~ aeeíamsáök: acetochlor, alaehlor, butachlor, dimetacMor, dkneteitatrad, flufeaacel, tueífeimeet, raeiolachior. meíazachior. .napropamid, naproaaüide, petoxamki péiilaehlpt: ptsfpcbte fe - a5piuaKi.vsaámíaaél«>k: híi&amp;aaío». glypkosaie, glufosinate, sulfbsate; - arifoxifenöxípropiouátüfe dodinafop, cyhalofop-butil, feaoxaprop, finaaifop, imloxiiop, ixteiamiíop, propaqmzaíop, quizskribp, qmxslofbp-P-tefarik - BigáMtlek: diqnai, paraquat: - $o)karbamstsk: ásulam, butdal®J kafbéfamM,:ílesö5ediplsaaí; diatepiperaíe, ep» |ÉP1C|, esptBkam, m&amp;ie, ortefkarb, femedipbam. píPsulf ©karit, prKbfriikarit ílobsákarit triai&amp;te; - ctkiohexándionok: babs>xidün, ektodim,, dkloxidiíS., proíoxidÚB, setoxídim* tepmloxidírn, traikoxidim; - diaitroafvilinek: beariaiPin. ©talriuralm, oryxalin. pendinietalin, prodiamía, fxífluralm; - difenil éterek: aeMuoribn, adoulles, bifenox, dirioibp, efoxiim, fomesafeu, iacíofcn, oxiriuorfen; * kidimíbeazositrílek:: bpmpxlrii, dicbioheati, foxini; ~ IsridaxbiíPdaöl:; imaaaPtetabeöx,: immmex* Imaxapfe, imax&amp;pír, ímax&amp;quííi,: rmaxetapár;; - fcaöxíeeétsa^ak: elomeprop, 2d~diklóríeuoxjaéd|c acid (2,4-1¾. 2pd3®, dieMr^rrqívMCPik, MCPA-tioef.il, MCPS, Meeoprop; r· p&amp;pKiaqfc: eblpridaagn, Svi&amp;spir-eril, Íuííaeei, noEfíu-rszem, plridate; - píridmek: aírápoplralid, clopírald., iáiÉuleaikaa, dífiopk, iurtdoae, Baroxlpk, pleloram, pibolisafés, iá&amp;sopir; - sM&amp;mdkarhamidök: amldsisul&amp;s'ou, axkösul&amp;rob. beba«í|f4:öB, cbieaxuuubu-etiL. eltlorsulriupu, ciaosulfuroa, eikiosubbtnmou, eluxiauláiírid,; HaaasulÉdriP, Iliredosui&amp;ros, ÉPpiraulfiiroa, bmmvM-mm, balosolfeotg iiuaaoaai&amp;Km, idlbsilltesü*. ruesosulfem, metaaosalluröa, sjetsuifeöu-meíik nicosbllaun, oxasulfcotg jdbbiSdifeon, prösblitron, pbazosuiforoo, rimsuifutx^» StdfofbetbbbL sulíosuJ faron, táfensulfuroa. íriasulfuroo, trihenuron, friloxisalferoti, m fiúsa!furort, Mfosuiferon., l:-{{24dór-b-p:r(>pil:-imida^o|l,24i]p5ridaa3u~3-il)sxu1.tbaÍ!^3-(4,6-ditTietoxi-piritnidirf-2^ iljkarharnid; - triadapk: ameíryu. appds, claoaxm, dimebsifigiyi, ^íe^^.;bostó»<me*.«tóa^&amp;s%.:a^^dÉ!«zk> prometryn, si maxin. terhublaxán. íerbtáryn, (riazifiasn; - MfeaföMpk: klőrtölurom daimuron, diuroa, inomduroa, izcproturoa, liBtíron.metabeuxtiaxuron, tebutiuron; - más acetolaktát srintáx inhibitorok; bispiribac-scxiiura. oloraasutea^ebl. diclosulani, ílorasakm, ílukarbazone, inmsisulam roetosulam, oriho-sdíatnurofí, penoxsuiatn, propoxikarbazone, pííibe&amp;zoxbá, piríSaid, fitíÉiöíiÉac-meti^itóöiSíííím,. plikbbac, pbmaxuifbsse, plröxsú'íam; egvcbeií átlíkaítesSö^ atóa©i«áz©í,. aaiöíbs, beÖbb8íáíní4, ^SaSsÉI% btefcgÉs^sje,b©af&amp;íesa:l8,: benzoíeaap, beaíazone, beíMÉaeiktoa, biCÉI©pü?ö5i©, bramaci* bíbfbbbbdde:, bumferiacü, Imaauibs. eaisBtíöl, á<mmmm dubllamb* ©pr©ksiabid, iieaísba,: SíéW^iÉ^ ®pfb$z©pm; Dreehdm® epdothak etofumesalév©b^m^d, feabx3$sfipí% ífeppm^&amp;id, üiurdekaaopexitíl, flumíoxazia, fiurocMoíidoae, fhatamona. ladanö&amp;a, izoxaben, izoxafiutöl, lenacil propanü, pröppasbd, quinciorae, ppiamerac, mesoiriose, mőtil arsoasav, naptakin. ©xadisrgl,,^pxadiaxon, ©saaibiMelpap, peptösazpa^ piraílaíeri-edl, pijssöltbiöl, psrazöxllba, pIsMblpPie, quí«oclaasin, sailafenaoil, suícotríone. siúíestrazone, íerbacil, tefuriítríose, lemboíríorse, tieakarhazone, topramezone, {3-[2-kk>:r-4-llüor-5-(3·· m.etJ'^2,ó-dκ>xo-4-!Γd1üoπr!et.^l-3.6-d:hiá;ö-2H-piFm5ids:!-i“3lPferiO>:i]~ρsΓ;ud5Ώ·2~ilαx!}·ecetSvav etilészíer, 6'an5Íno-5-k]őr-2<ik!opropd-píri-r:idír!-4-karb<.ffisav nxeülászter, 6-klór-3-{2-cik.lopropi J-6~ meíil-fenoxj)-pirida2Ín-4-<.>.l, 4-atním>-34:lör-644-klór-fen5l)-5-Űaor-pirid5a-2-karbon$3.v. 4~amiöö~3~ kld:NK4-ldb^24É«^3^eí0XÍ4ea^^ sísplészaep és 4-amin.o-3-k]0r-'6~p4-klér-3- <lin.5etilainin0-24lvior4eTii!)-piridÍ0-24arbonsav iaeiilésxter, ö) laszckucidck - organo{tvo}foszfáÍí.ik: soephate, azaraeíipbos, azmphos-meti!, cblorpmfos, cktorpinfos-a-cti!. ddor&amp;nvirsphos, diazino^. áieliörsm» idÉe®gÉe§&amp;©s·, di®as&amp;z% d!s©!fbií>ft, «dm, feaizpböp, festi©®*, kmatka, maMicm, metamidopfem psbdabosx medl-paraboa, isempbos, sssaiöpfsáopbas, oxideaxetoa-öxetib psiaaxos, paratím íes&amp;oát, pbösak®©, pbpsmet pbosphsmídm pkerate, ptextm, pábaaipbas-metM:,: prouofos, mlpropfeos,. íbtoeÉte|öpfe©s? ísírbuips,. tdazopibs, tnchiorfon; ~ karbaraátok: alaaykarb, aldíkarb, beadkakarb, bestprakarb,: karbariL; k&amp;rbotbdap* ksd>©spl&amp;©,, íesoxík&amp;rb, ibradokarb, msdökarb, xaetomP, öxa®bt, pídpikarb, prepdxar, böiikarb,: tóazamaíe; - plrmotdok: alleíria. bifeíbr:©.. cyfktkm, eybaíoÉaiS, b^fébotk^ eypadbebm atpbs^efpédbekm beía-cypermeí'mi, zela-cypbrmeuia. PcbamPínK, ©s^dkaleratc. etofenprox. fenprupathna, íPnbalexai©, itóp^ítór^Jambda^ykalöátóa, peapasetiia, prdfctóÉk |&amp;#in I cs. IL rcsrnelna, xilafluufm fa®.* laxabrsate. teíluihna, teíramMa, íxailemetóa, feaastlatkd®, profiutbrin, dundliPhria: - rovamövekedés szabályözbfe: a) kPia-szteézís ipiibbiarok; beazoilkarhamidpk; eblpdlpazuroa, cymscmm, dlÉabeazair©», Ömktexurm flalbaoxarsa,: bessfiumurm bddsíam ao^aiaroa, isSsbeszaron, íriöa&amp;moa; impíofeMv dlöfeolm, bexyfiazox, etexaaal, ciofmtóa; bkeedysope astagöaíslák: Mbfsmdie* m€tefcep3Í^telmfatoai4e» azadimébiiB; cljípenoidok: pMprpxIfeb ®eföpres®evlsn0xílarb; d) Upid te@§Étó^;,|3ÉúlHtondí: isÉ&amp;dcpid, dametoxaai, ö#€ap^^:^^stóp«iá,: físcloptód, 3,34lbsed!-[l ,\5 Jtnazmáa; - Cl ÁB A antagonists vegyítetek: emlosuiíán, etiprol, píripnoL 5-am.mo- - matociMasos lakion mszetó^áWb. abameerim easamecim, íaíiaemectls, lepimecbn, splsosad; spirteam; - miokoadPális élekte(sníraKX^pí5Á :líÉÍ3tfíöf (MÉH) I akaríesfek: fena^atpta, pribabem íeboienpirad, tollfesprad, iafenemr;; ~ METIII és III v^gyületek: accpuinoeil iaacypdrn, hidrametilnom - Pngeoplerek: chioríenapir; * exislatív íoszíoríláeió iahibítofisi; pbepám, tíeíepípes, fe#atatm oxide, propargite; * :v$itósmeg8zakító vegyületek: erybPáÉbs ·« 'vegyes Siákeiójó oxidáz p|pea|c^# -- páirmmesatoím bloklolék; índcssakarb, metaftumizoae; epebek: beadplaz, j^p^^...ílotucamid. plridallk gywírozip sal&amp;r, tloelklarp iyfeeediaggéL eldeiagijaasIlpM, lepppir (HG W 86), eyseopaa&amp;p, iíapímaoíds, plumetple©, aaiidotlamet, és pinfinqukuiZö&amp;
  9. 12, Az I -5, igéóypmíok bármelyike szerinti I képlett! ysgybleiek, M~ox)d|aík is mezőgazdaságilag; elfogadható sóik vagy a34L IgésypoPok bármelyike szenmí Mszitmeoyek alkalmazása Élefeie®lE gombák leküzdésére. 1 S,i§árás iiopamgén gombák leküzdésem, melynek során a gombákat vagy a gombák támadásával símben védendő apagőkai, növényeket, a taia|t vagy magokat legalább ep, az 1-3. iglaypoaíok bármelyike szerinti legalább egy I· képieb! vegyibb vagy a 9-í :t. Igéppesríok bármelyike szerinti készítmény hatásos nmonyiséiével :kezepk„
  10. 14.. Az 1-5. igénypontok bármelyike szerinti legalább egy 1 képiéit vegyítettek vagy a 9-11. igéxvy-pattok bármelyike szetlídlkészltmébsyel (1,1 - 10 kg; 100 kgMeipylségben bevop mag.
HUE12735512A 2011-07-13 2012-07-12 Fungicid szubsztituált 2-[2.halogénalkil-4-(fenoxi-fenil]-1-[1,2,4]triazol-1-il-etanol vegyületek HUE027461T2 (hu)

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