ES2151819A1 - Difenilaminas noniladas. - Google Patents
Difenilaminas noniladas.Info
- Publication number
- ES2151819A1 ES2151819A1 ES009801159A ES9801159A ES2151819A1 ES 2151819 A1 ES2151819 A1 ES 2151819A1 ES 009801159 A ES009801159 A ES 009801159A ES 9801159 A ES9801159 A ES 9801159A ES 2151819 A1 ES2151819 A1 ES 2151819A1
- Authority
- ES
- Spain
- Prior art keywords
- mixture
- diphenylamines
- nonylated
- nonylated diphenylamines
- oxidative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 230000015556 catabolic process Effects 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 230000000087 stabilizing effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C211/54—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to two or three six-membered aromatic rings
- C07C211/55—Diphenylamines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Lubricants (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paper (AREA)
Abstract
La presente invención se refiere a una mezcla de difenilaminas noniladas, en especial de difenilamina dinonilada, y a un procedimiento metodológico técnicamente ventajoso para obtener dicha mezcla mediante el uso de una pequeña cantidad de catalizadores ácidos. Se emplea la mezcla como aditivo para estabilizar productos orgánicos que están sometidos a una degradación oxidante, térmica y/o inducida por la luz.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH137797 | 1997-06-06 |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2151819A1 true ES2151819A1 (es) | 2001-01-01 |
ES2151819B1 ES2151819B1 (es) | 2001-08-16 |
Family
ID=4209007
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES009801159A Expired - Lifetime ES2151819B1 (es) | 1997-06-06 | 1998-06-04 | Difenilaminas noniladas. |
Country Status (19)
Country | Link |
---|---|
US (1) | US6315925B1 (es) |
JP (3) | JP4833387B2 (es) |
KR (1) | KR100624206B1 (es) |
CN (1) | CN1135221C (es) |
BE (1) | BE1013124A3 (es) |
BR (1) | BR9802365A (es) |
CA (1) | CA2240971C (es) |
CZ (1) | CZ294662B6 (es) |
DE (1) | DE19824790B4 (es) |
ES (1) | ES2151819B1 (es) |
FR (1) | FR2764887B1 (es) |
GB (1) | GB2325929B (es) |
IT (1) | ITMI981274A1 (es) |
NL (1) | NL1009331C2 (es) |
RU (1) | RU2198870C2 (es) |
SG (1) | SG65759A1 (es) |
SK (1) | SK285027B6 (es) |
TW (1) | TW555733B (es) |
ZA (1) | ZA984871B (es) |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SG65759A1 (en) * | 1997-06-06 | 1999-06-22 | Ciba Sc Holding Ag | Nonylated diphenylamines |
US6684759B1 (en) | 1999-11-19 | 2004-02-03 | Vladimir Gorokhovsky | Temperature regulator for a substrate in vapor deposition processes |
US6871700B2 (en) | 2000-11-17 | 2005-03-29 | G & H Technologies Llc | Thermal flux regulator |
US7189875B2 (en) * | 2003-04-04 | 2007-03-13 | Crompton Corporation | Diphenylamine alkylated with olefin mixtures containing fractions with varying degrees of activity |
US6930183B2 (en) * | 2003-04-17 | 2005-08-16 | Crompton Corporation | Alkylated iminodibenzyls as antioxidants |
SK14562003A3 (sk) * | 2003-11-25 | 2005-06-02 | Duslo,A.S. | Antioxidačné kompozície oktylovaných difenylamínov a spôsob ich výroby |
PL1730101T3 (pl) * | 2004-04-01 | 2016-05-31 | Basf Se | Kompozycje alkilowanej PANA i DPA |
US7816308B2 (en) * | 2004-04-14 | 2010-10-19 | Crompton Corporation | Ketone diarylamine condensates |
US8202829B2 (en) * | 2004-11-04 | 2012-06-19 | Afton Chemical Corporation | Lubricating composition |
BRPI0612016A2 (pt) * | 2005-06-02 | 2010-10-13 | Albemarle Corp | método para alquilação de arilaminas, composição para catalização da alquilação de arilamina com agente alquilante em uma massa de reação, mistura de arilamina alquilada produzida pela criação de uma massa de reação de materiais, método de estabilizar um fluido sujeito a degradação oxidativa, térmica e/ou induzida por luz, método para nonilação de difenilamina |
US7390928B2 (en) | 2005-12-14 | 2008-06-24 | Chemtura Corporation | Alkylation of N′-phenyl-N-alkylphenylenediamines in ionic liquid, N′-phenyl-N-alkyl (alkylphenylene) diamines produced thereby, and lubricant compositions containing same |
US7145038B1 (en) | 2005-12-14 | 2006-12-05 | Chemtura Corporation | Alkylation of a diphenylamine compound in ionic liquid |
US8003583B2 (en) * | 2005-12-21 | 2011-08-23 | Chevron Oronite Company Llc | Benzo[b]perhydroheterocyclic arylamines and lubricating oil compositions |
US7285518B2 (en) * | 2005-12-21 | 2007-10-23 | Chevron Oronite Company Llc | Dibenzo[b]perhydroheterocyclic amines and lubricating oil compositions |
US7501386B2 (en) * | 2005-12-21 | 2009-03-10 | Chevron Oronite Company, Llc | Synergistic lubricating oil composition containing a mixture of a benzo[b]perhydroheterocyclic arylamine and a diarylamine |
US8828916B2 (en) * | 2006-12-28 | 2014-09-09 | Chevron Oronite Company Llc | Method to prepare nonylated diphenylamine using recycle sequential temperatures |
US8999903B2 (en) | 2007-06-08 | 2015-04-07 | Infineum International Limited | Additives and lubricating oil compositions containing same |
US7683017B2 (en) * | 2007-06-20 | 2010-03-23 | Chevron Oronite Company Llc | Synergistic lubricating oil composition containing a mixture of a nitro-substituted diarylamine and a diarylamine |
US8110532B2 (en) * | 2008-11-24 | 2012-02-07 | Chemtura Corporation | Antioxidant compositions |
RU2476587C2 (ru) * | 2010-11-12 | 2013-02-27 | Российская Федерация, От Имени Которой Выступает Министерство Промышленности И Торговли Российской Федерации | Смазочная композиция высокотемпературного масла для теплонапряженных газотурбинных двигателей сверхзвуковой авиации |
CN102659606B (zh) * | 2012-05-07 | 2014-04-09 | 常州大学 | 一种色泽稳定的烷基化二苯胺抗氧剂的制备方法 |
US9617201B2 (en) | 2013-10-14 | 2017-04-11 | Chemtura Corporation | Fixed bed process for clay catalyzed alkylation of aromatic amines |
GB2523756B (en) | 2014-03-03 | 2017-01-11 | Addivant Switzerland Gmbh | Antioxidant compositions |
US9890346B2 (en) | 2014-07-21 | 2018-02-13 | Lanxess Solutions Us Inc. | Selective alkylation method for producing p, p′-di-alkylated diphenylamine antioxidants |
US9744531B2 (en) | 2015-03-03 | 2017-08-29 | Lanxess Solutions Us Inc. | Regeneration of clay catalysts for alkylation of aromatic rings |
KR20180030831A (ko) | 2015-07-15 | 2018-03-26 | 란세스 솔루션즈 유에스 인코퍼레이티드 | 분지형 올레핀으로부터 제조된 디아릴 아민 항산화제 |
CN110114448B (zh) | 2016-12-27 | 2022-03-04 | 路博润公司 | 具有烷基化萘胺的润滑组合物 |
US20190367833A1 (en) | 2016-12-27 | 2019-12-05 | The Lubrizol Corporation | Lubricating composition including n-alkylated dianiline |
CN106699677B (zh) * | 2016-12-28 | 2019-07-09 | 利安隆(中卫)新材料有限公司 | 紫外线吸收剂uv-571的制备方法 |
US20230416631A1 (en) * | 2020-11-17 | 2023-12-28 | Songwon Industrial Co., Ltd. | Compositions comprising alkylated diphenylamines with improved properties |
CN115254088B (zh) * | 2022-08-30 | 2023-11-21 | 华东理工大学 | 一种生产烷基二苯胺的催化剂及其制备方法和应用 |
WO2024158648A1 (en) | 2023-01-24 | 2024-08-02 | The Lubrizol Corporation | Lubricating composition with phenolic antioxidant and low active sulfur |
WO2024206388A1 (en) | 2023-03-31 | 2024-10-03 | Lanxess Corporation | Efficient, low-energy, low waste alkylation and arylation method for producing safe, enviromentally-friendly disubstituted diphenylamine antioxidants |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2943112A (en) * | 1957-11-06 | 1960-06-28 | Pennsalt Chemicals Corp | Alkylation of diphenylamine |
GB1143250A (en) * | 1966-02-17 | 1969-02-19 | American Cyanamid Co | The preparation of mono- and di-alkyl-diphenylamines |
JPS58108296A (ja) * | 1981-12-21 | 1983-06-28 | Sumitomo Chem Co Ltd | 燃料油用液状酸化防止剤 |
JPS6197378A (ja) * | 1984-10-18 | 1986-05-15 | Toyoda Gosei Co Ltd | エアダクト用シ−ラント |
EP0387979A1 (en) * | 1989-01-13 | 1990-09-19 | Nippon Oil Company, Limited | Use of a p,p'-Dinonyldiphenylamine in a composition having a reduced tendency to form sludge in oil |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2776994A (en) | 1954-03-03 | 1957-01-08 | Goodrich Co B F | Preparation of a solid diphenylamine antioxidant |
CA1083606A (en) * | 1975-04-18 | 1980-08-12 | Vipin M. Kothari | Process of preparing para styrenated diphenylamine. |
GB8332797D0 (en) * | 1983-12-08 | 1984-01-18 | Ciba Geigy Ag | Antioxidant production |
JPS60202845A (ja) * | 1984-03-28 | 1985-10-14 | Seikou Kagaku Kk | 白度または透明度の高いp−置換ジフエニルアミン類の製造法 |
US4739121A (en) | 1984-05-24 | 1988-04-19 | The B. F. Goodrich Company | Process for otho- and para-alkylating diphenylamines |
US4769164A (en) * | 1987-05-22 | 1988-09-06 | The Lubrizol Corporation | Anti-oxidant products |
US4798684A (en) * | 1987-06-09 | 1989-01-17 | The Lubrizol Corporation | Nitrogen containing anti-oxidant compositions |
JPH0959227A (ja) * | 1995-08-11 | 1997-03-04 | Seiko Kagaku Kk | スチレン化ジフェニルアミンの製造方法 |
US5672752A (en) * | 1995-09-13 | 1997-09-30 | The Bfgoodrich Company | Liquid alkylated diphenylamine antioxidant |
US5750787A (en) * | 1995-09-13 | 1998-05-12 | B. F. Goodrich Company | Liquid alkylated diphenylamine antioxidant |
SG65759A1 (en) * | 1997-06-06 | 1999-06-22 | Ciba Sc Holding Ag | Nonylated diphenylamines |
-
1998
- 1998-05-21 SG SG1998001100A patent/SG65759A1/en unknown
- 1998-06-01 GB GB9811583A patent/GB2325929B/en not_active Expired - Fee Related
- 1998-06-02 RU RU98110273/04A patent/RU2198870C2/ru not_active IP Right Cessation
- 1998-06-03 CZ CZ19981716A patent/CZ294662B6/cs not_active IP Right Cessation
- 1998-06-03 DE DE19824790A patent/DE19824790B4/de not_active Expired - Fee Related
- 1998-06-04 SK SK743-98A patent/SK285027B6/sk not_active IP Right Cessation
- 1998-06-04 ES ES009801159A patent/ES2151819B1/es not_active Expired - Lifetime
- 1998-06-04 JP JP17230998A patent/JP4833387B2/ja not_active Expired - Fee Related
- 1998-06-04 TW TW087108805A patent/TW555733B/zh not_active IP Right Cessation
- 1998-06-04 CA CA002240971A patent/CA2240971C/en not_active Expired - Fee Related
- 1998-06-04 FR FR9806996A patent/FR2764887B1/fr not_active Expired - Fee Related
- 1998-06-05 KR KR1019980020780A patent/KR100624206B1/ko not_active IP Right Cessation
- 1998-06-05 BR BR9802365-9A patent/BR9802365A/pt not_active Application Discontinuation
- 1998-06-05 BE BE9800425A patent/BE1013124A3/fr active
- 1998-06-05 CN CNB981096557A patent/CN1135221C/zh not_active Expired - Fee Related
- 1998-06-05 ZA ZA984871A patent/ZA984871B/xx unknown
- 1998-06-05 NL NL1009331A patent/NL1009331C2/nl not_active IP Right Cessation
- 1998-06-05 IT IT98MI001274A patent/ITMI981274A1/it unknown
-
2000
- 2000-02-14 US US09/503,264 patent/US6315925B1/en not_active Expired - Lifetime
-
2009
- 2009-06-08 JP JP2009137187A patent/JP2009197026A/ja active Pending
-
2012
- 2012-07-27 JP JP2012167148A patent/JP5650692B2/ja not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2943112A (en) * | 1957-11-06 | 1960-06-28 | Pennsalt Chemicals Corp | Alkylation of diphenylamine |
GB1143250A (en) * | 1966-02-17 | 1969-02-19 | American Cyanamid Co | The preparation of mono- and di-alkyl-diphenylamines |
JPS58108296A (ja) * | 1981-12-21 | 1983-06-28 | Sumitomo Chem Co Ltd | 燃料油用液状酸化防止剤 |
JPS6197378A (ja) * | 1984-10-18 | 1986-05-15 | Toyoda Gosei Co Ltd | エアダクト用シ−ラント |
EP0387979A1 (en) * | 1989-01-13 | 1990-09-19 | Nippon Oil Company, Limited | Use of a p,p'-Dinonyldiphenylamine in a composition having a reduced tendency to form sludge in oil |
Non-Patent Citations (2)
Title |
---|
BASE DE DATOS WPI, Derwent, AN 1983-726633 [31]. & JP 58108296 A (SUMITOMO CHEM) 28.06.1983 * |
BASE DE DATOS WPI, Derwent, AN 1986-165254 [25]. & JP 61097378 A (TOYODA GOSEI) 15.05.1986 * |
Also Published As
Publication number | Publication date |
---|---|
JPH1112234A (ja) | 1999-01-19 |
DE19824790B4 (de) | 2013-06-20 |
KR19990006677A (ko) | 1999-01-25 |
NL1009331C2 (nl) | 2001-05-08 |
CN1201781A (zh) | 1998-12-16 |
ES2151819B1 (es) | 2001-08-16 |
JP2009197026A (ja) | 2009-09-03 |
GB9811583D0 (en) | 1998-07-29 |
SG65759A1 (en) | 1999-06-22 |
SK285027B6 (sk) | 2006-04-06 |
FR2764887B1 (fr) | 2004-04-02 |
GB2325929A (en) | 1998-12-09 |
BR9802365A (pt) | 2000-03-28 |
BE1013124A3 (fr) | 2001-10-02 |
NL1009331A1 (nl) | 1998-12-08 |
RU2198870C2 (ru) | 2003-02-20 |
JP5650692B2 (ja) | 2015-01-07 |
TW555733B (en) | 2003-10-01 |
JP2012197462A (ja) | 2012-10-18 |
KR100624206B1 (ko) | 2006-12-05 |
ITMI981274A1 (it) | 1999-12-05 |
CN1135221C (zh) | 2004-01-21 |
GB2325929B (en) | 2001-08-29 |
CZ171698A3 (cs) | 1998-12-16 |
JP4833387B2 (ja) | 2011-12-07 |
US6315925B1 (en) | 2001-11-13 |
CA2240971A1 (en) | 1998-12-06 |
CZ294662B6 (cs) | 2005-02-16 |
ZA984871B (en) | 1998-12-07 |
DE19824790A1 (de) | 1999-04-15 |
SK74398A3 (en) | 1999-04-13 |
CA2240971C (en) | 2008-02-12 |
FR2764887A1 (fr) | 1998-12-24 |
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Legal Events
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