ES2040161B1 - Herramienta de corte con revestimiento cvd y pvd enriquecido con aglutinante. - Google Patents
Herramienta de corte con revestimiento cvd y pvd enriquecido con aglutinante.Info
- Publication number
- ES2040161B1 ES2040161B1 ES9101313A ES9101313A ES2040161B1 ES 2040161 B1 ES2040161 B1 ES 2040161B1 ES 9101313 A ES9101313 A ES 9101313A ES 9101313 A ES9101313 A ES 9101313A ES 2040161 B1 ES2040161 B1 ES 2040161B1
- Authority
- ES
- Spain
- Prior art keywords
- pvd
- cutting tool
- binder
- enriched
- cvd coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011230 binding agent Substances 0.000 title abstract 2
- 239000011248 coating agent Substances 0.000 title abstract 2
- 238000000576 coating method Methods 0.000 title abstract 2
- 239000000126 substance Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
- C23C28/044—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material coatings specially adapted for cutting tools or wear applications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23B—TURNING; BORING
- B23B27/00—Tools for turning or boring machines; Tools of a similar kind in general; Accessories therefor
- B23B27/14—Cutting tools of which the bits or tips or cutting inserts are of special material
- B23B27/148—Composition of the cutting inserts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23P—METAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
- B23P15/00—Making specific metal objects by operations not covered by a single other subclass or a group in this subclass
- B23P15/28—Making specific metal objects by operations not covered by a single other subclass or a group in this subclass cutting tools
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
- C23C28/048—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material with layers graded in composition or physical properties
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
- C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T407/00—Cutters, for shaping
- Y10T407/27—Cutters, for shaping comprising tool of specific chemical composition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Chemical Vapour Deposition (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Physical Vapour Deposition (AREA)
- Polishing Bodies And Polishing Tools (AREA)
- Milling Processes (AREA)
- Milling, Broaching, Filing, Reaming, And Others (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Paper (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/583,544 US5250367A (en) | 1990-09-17 | 1990-09-17 | Binder enriched CVD and PVD coated cutting tool |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2040161A1 ES2040161A1 (es) | 1993-10-01 |
| ES2040161B1 true ES2040161B1 (es) | 1994-05-16 |
Family
ID=24333547
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES9101313A Expired - Fee Related ES2040161B1 (es) | 1990-09-17 | 1991-05-30 | Herramienta de corte con revestimiento cvd y pvd enriquecido con aglutinante. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5250367A (https=) |
| EP (1) | EP0549585B1 (https=) |
| JP (2) | JP2847325B2 (https=) |
| KR (1) | KR0182289B1 (https=) |
| CN (1) | CN1022609C (https=) |
| AT (1) | ATE161211T1 (https=) |
| AU (1) | AU651832B2 (https=) |
| CA (1) | CA2090312C (https=) |
| DE (2) | DE69128480T2 (https=) |
| ES (1) | ES2040161B1 (https=) |
| IL (1) | IL98431A (https=) |
| MX (1) | MX173642B (https=) |
| RU (1) | RU2071869C1 (https=) |
| WO (1) | WO1992005009A1 (https=) |
Families Citing this family (106)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5232318A (en) * | 1990-09-17 | 1993-08-03 | Kennametal Inc. | Coated cutting tools |
| US5325747A (en) * | 1990-09-17 | 1994-07-05 | Kennametal Inc. | Method of machining using coated cutting tools |
| US5516588A (en) * | 1991-03-27 | 1996-05-14 | Widia Gmbh | Composite body, its use and a process for its production |
| US5139537A (en) * | 1991-06-13 | 1992-08-18 | Julien D Lynn | Titanium-nitride coated grinding wheel and method therefor |
| CA2092932C (en) * | 1992-04-17 | 1996-12-31 | Katsuya Uchino | Coated cemented carbide member and method of manufacturing the same |
| US5576093A (en) * | 1992-10-22 | 1996-11-19 | Mitsubishi Materials Corporation | Multilayer coated hard alloy cutting tool |
| DE4239234A1 (de) * | 1992-11-21 | 1994-06-09 | Krupp Widia Gmbh | Werkzeug und Verfahren zur Beschichtung eines Werkzeuggrundkörpers |
| US5374471A (en) * | 1992-11-27 | 1994-12-20 | Mitsubishi Materials Corporation | Multilayer coated hard alloy cutting tool |
| US5681651A (en) * | 1992-11-27 | 1997-10-28 | Mitsubishi Materials Corporation | Multilayer coated hard alloy cutting tool |
| US5651295A (en) * | 1993-03-29 | 1997-07-29 | Kennametal Inc. | Method of machining of aluminum |
| EP0653499B1 (en) * | 1993-05-31 | 2002-07-24 | Sumitomo Electric Industries, Ltd. | Coated cutting tool and method for producing the same |
| SE501913C2 (sv) * | 1993-10-21 | 1995-06-19 | Sandvik Ab | Skär för skärande verktyg |
| DE4402287A1 (de) * | 1994-01-27 | 1995-08-03 | Winter Cvd Technik Gmbh | Zahnradförmige Diamantabrichtrolle |
| US5597272A (en) * | 1994-04-27 | 1997-01-28 | Sumitomo Electric Industries, Ltd. | Coated hard alloy tool |
| EP0784713A4 (en) * | 1994-10-11 | 2000-03-01 | Gelest Inc | Uniform TITANIUM BASE FILMS AND THEIR PRODUCTION |
| JPH08141804A (ja) * | 1994-11-22 | 1996-06-04 | Hitachi Zosen Corp | 切削工具およびその寿命検出装置 |
| US5541006A (en) * | 1994-12-23 | 1996-07-30 | Kennametal Inc. | Method of making composite cermet articles and the articles |
| US5762843A (en) * | 1994-12-23 | 1998-06-09 | Kennametal Inc. | Method of making composite cermet articles |
| US5679445A (en) * | 1994-12-23 | 1997-10-21 | Kennametal Inc. | Composite cermet articles and method of making |
| SE514283C2 (sv) * | 1995-04-12 | 2001-02-05 | Sandvik Ab | Belagt hårmetallskär med bindefasadanrikad ytzon samt sätt för dess tillverkning |
| SE514177C2 (sv) * | 1995-07-14 | 2001-01-15 | Sandvik Ab | Belagt hårdmetallskär för intermittent bearbetning i låglegerat stål |
| US5722803A (en) * | 1995-07-14 | 1998-03-03 | Kennametal Inc. | Cutting tool and method of making the cutting tool |
| SE9502687D0 (sv) * | 1995-07-24 | 1995-07-24 | Sandvik Ab | CVD coated titanium based carbonitride cutting tool insert |
| US5879823A (en) * | 1995-12-12 | 1999-03-09 | Kennametal Inc. | Coated cutting tool |
| US5750247A (en) * | 1996-03-15 | 1998-05-12 | Kennametal, Inc. | Coated cutting tool having an outer layer of TiC |
| AT1542U1 (de) * | 1996-08-30 | 1997-07-25 | Metall Kofler Kg | Fliesenschneidrad |
| US5976707A (en) * | 1996-09-26 | 1999-11-02 | Kennametal Inc. | Cutting insert and method of making the same |
| US5955186A (en) | 1996-10-15 | 1999-09-21 | Kennametal Inc. | Coated cutting insert with A C porosity substrate having non-stratified surface binder enrichment |
| US5752155A (en) * | 1996-10-21 | 1998-05-12 | Kennametal Inc. | Green honed cutting insert and method of making the same |
| US5701578A (en) * | 1996-11-20 | 1997-12-23 | Kennametal Inc. | Method for making a diamond-coated member |
| DE19719195A1 (de) * | 1997-05-09 | 1998-11-12 | Widia Gmbh | Schneideinsatz zum Zerspanen und Verfahren zur Herstellung dieses Schneideinsatzes |
| JP3402146B2 (ja) * | 1997-09-02 | 2003-04-28 | 三菱マテリアル株式会社 | 硬質被覆層がすぐれた密着性を有する表面被覆超硬合金製エンドミル |
| RU2198243C2 (ru) * | 1998-08-05 | 2003-02-10 | Верещака Алексей Анатольевич | Многослойно-композиционное износостойкое покрытие |
| DE19907749A1 (de) | 1999-02-23 | 2000-08-24 | Kennametal Inc | Gesinterter Hartmetallkörper und dessen Verwendung |
| US6217992B1 (en) | 1999-05-21 | 2001-04-17 | Kennametal Pc Inc. | Coated cutting insert with a C porosity substrate having non-stratified surface binder enrichment |
| MXPA02009350A (es) * | 2000-03-24 | 2003-09-22 | Kennametal Inc | Herramienta de carburo cementado y metodo de realizacion. |
| US20010051215A1 (en) * | 2000-04-13 | 2001-12-13 | Gelest, Inc. | Methods for chemical vapor deposition of titanium-silicon-nitrogen films |
| US6908688B1 (en) | 2000-08-04 | 2005-06-21 | Kennametal Inc. | Graded composite hardmetals |
| RU2200209C2 (ru) * | 2001-01-11 | 2003-03-10 | Уральский электрохимический комбинат | Покрытие для режущего инструмента |
| US6988858B2 (en) * | 2001-02-28 | 2006-01-24 | Kennametal Inc. | Oxidation-resistant cutting assembly |
| EP1311712A2 (de) * | 2001-03-27 | 2003-05-21 | Widia GmbH | Verfahren zur erhöhung der druckspannung oder zur erniedrigung der zugeigenspannung einer schicht |
| SE0101241D0 (sv) * | 2001-04-05 | 2001-04-05 | Sandvik Ab | Tool for turning of titanium alloys |
| RU2214890C1 (ru) * | 2002-02-08 | 2003-10-27 | Ульяновский государственный технический университет | Режущий инструмент с многослойным покрытием |
| RU2214891C1 (ru) * | 2002-02-08 | 2003-10-27 | Ульяновский государственный технический университет | Режущий инструмент с покрытием |
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| US20050268768A1 (en) * | 2002-06-19 | 2005-12-08 | Johnson David N | Circular saw blade for cutting ferous materials |
| US6976810B2 (en) * | 2002-07-19 | 2005-12-20 | The Boeing Company | Rotatable cutting wheel |
| US20070157525A1 (en) * | 2004-01-15 | 2007-07-12 | Egan David P | Method for coating abrasives |
| SE528427C2 (sv) * | 2004-07-09 | 2006-11-07 | Seco Tools Ab | Ett belagt skär för metallbearbetning och sätt att tillverka detta |
| SE528109C2 (sv) * | 2004-07-12 | 2006-09-05 | Sandvik Intellectual Property | Fasningsskär, speciellt för fasfräsning av stålplåt för oljerör, samt sätt att tillverka detsamma |
| JP4593994B2 (ja) * | 2004-07-23 | 2010-12-08 | 住友電工ハードメタル株式会社 | 表面被覆切削工具 |
| US20090211414A1 (en) * | 2004-07-29 | 2009-08-27 | Kyocera Corporation | Cutting Tool |
| US7207374B2 (en) * | 2004-10-26 | 2007-04-24 | United Technologies Corporation | Non-oxidizable coating |
| EP1806193B1 (en) * | 2004-10-29 | 2013-05-08 | Sumitomo Electric Hardmetal Corp. | Surface-coated cutting tool |
| JP4739234B2 (ja) * | 2004-12-03 | 2011-08-03 | 住友電工ハードメタル株式会社 | 刃先交換型切削チップおよびその製造方法 |
| EP1825943B2 (en) * | 2004-12-14 | 2025-08-20 | Sumitomo Electric Hardmetal Corp. | Coated cutting tool |
| US7803464B2 (en) * | 2004-12-27 | 2010-09-28 | Sumitomo Electric Hardmetal Corp. | Surface-coated cutting tool |
| KR100665266B1 (ko) * | 2005-03-24 | 2007-01-09 | 대구텍 주식회사 | 복수피복층이 형성된 초경합금 절삭공구 |
| WO2006109457A1 (ja) * | 2005-04-07 | 2006-10-19 | Sumitomo Electric Hardmetal Corp. | 刃先交換型切削チップ |
| US8637127B2 (en) | 2005-06-27 | 2014-01-28 | Kennametal Inc. | Composite article with coolant channels and tool fabrication method |
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| US8512882B2 (en) * | 2007-02-19 | 2013-08-20 | TDY Industries, LLC | Carbide cutting insert |
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| US8272816B2 (en) | 2009-05-12 | 2012-09-25 | TDY Industries, LLC | Composite cemented carbide rotary cutting tools and rotary cutting tool blanks |
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| EP2454393B1 (de) * | 2009-07-14 | 2016-09-28 | MSM Krystall GBR | Verfahren zur herstellung von wendeschneidplatten |
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| US8440314B2 (en) | 2009-08-25 | 2013-05-14 | TDY Industries, LLC | Coated cutting tools having a platinum group metal concentration gradient and related processes |
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| CN102335814A (zh) * | 2011-08-03 | 2012-02-01 | 四川欧曼机械有限公司 | 一种制造切削刀片的方法 |
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| US9016406B2 (en) | 2011-09-22 | 2015-04-28 | Kennametal Inc. | Cutting inserts for earth-boring bits |
| US9656335B2 (en) * | 2013-03-08 | 2017-05-23 | United Technologies Corporation | Broach tool rake face with a tailored surface topography |
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| CN109482915B (zh) * | 2018-10-29 | 2020-06-02 | 厦门金鹭特种合金有限公司 | 一种涂层的可转位刀片及其制作方法 |
| CN110408829B (zh) * | 2019-08-26 | 2021-07-16 | 广东技术师范大学 | 一种梯度多层涂层与梯度硬质合金相结合的刀具及其制备方法 |
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| CN111910172B (zh) * | 2020-07-24 | 2022-10-18 | 株洲钻石切削刀具股份有限公司 | 复合式涂层pcbn切削刀具及其制备方法 |
| CN113829455B (zh) * | 2021-10-08 | 2022-08-26 | 南京海强机械刀具有限公司 | 一种硬质合金涂层新型长材刨片机刀片 |
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-
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-
1991
- 1991-05-15 WO PCT/US1991/003397 patent/WO1992005009A1/en not_active Ceased
- 1991-05-15 KR KR1019930700795A patent/KR0182289B1/ko not_active Expired - Fee Related
- 1991-05-15 RU RU93005050/08A patent/RU2071869C1/ru not_active IP Right Cessation
- 1991-05-15 EP EP19910910756 patent/EP0549585B1/en not_active Revoked
- 1991-05-15 JP JP51062291A patent/JP2847325B2/ja not_active Expired - Fee Related
- 1991-05-15 AU AU80846/91A patent/AU651832B2/en not_active Ceased
- 1991-05-15 DE DE69128480T patent/DE69128480T2/de not_active Revoked
- 1991-05-15 DE DE91910756T patent/DE549585T1/de active Pending
- 1991-05-15 AT AT91910756T patent/ATE161211T1/de not_active IP Right Cessation
- 1991-05-15 CA CA 2090312 patent/CA2090312C/en not_active Expired - Fee Related
- 1991-05-30 ES ES9101313A patent/ES2040161B1/es not_active Expired - Fee Related
- 1991-06-10 IL IL9843191A patent/IL98431A/en not_active IP Right Cessation
- 1991-06-17 MX MX026265A patent/MX173642B/es unknown
- 1991-08-27 CN CN91108504A patent/CN1022609C/zh not_active Expired - Fee Related
-
1995
- 1995-11-01 JP JP32094695A patent/JP3038535B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| KR930702114A (ko) | 1993-09-08 |
| CA2090312C (en) | 1995-08-29 |
| US5250367A (en) | 1993-10-05 |
| AU651832B2 (en) | 1994-08-04 |
| DE69128480T2 (de) | 1998-06-04 |
| DE69128480D1 (de) | 1998-01-29 |
| JPH06502352A (ja) | 1994-03-17 |
| ES2040161A1 (es) | 1993-10-01 |
| ATE161211T1 (de) | 1998-01-15 |
| CA2090312A1 (en) | 1992-03-18 |
| EP0549585A1 (en) | 1993-07-07 |
| KR0182289B1 (ko) | 1999-05-01 |
| MX173642B (es) | 1994-03-18 |
| DE549585T1 (de) | 1993-10-14 |
| JP2847325B2 (ja) | 1999-01-20 |
| IL98431A0 (en) | 1992-07-15 |
| RU2071869C1 (ru) | 1997-01-20 |
| JPH08318410A (ja) | 1996-12-03 |
| CN1059858A (zh) | 1992-04-01 |
| CN1022609C (zh) | 1993-11-03 |
| WO1992005009A1 (en) | 1992-04-02 |
| IL98431A (en) | 1994-08-26 |
| EP0549585A4 (https=) | 1995-08-02 |
| AU8084691A (en) | 1992-04-15 |
| EP0549585B1 (en) | 1997-12-17 |
| JP3038535B2 (ja) | 2000-05-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 20040531 |