EP1720073B1 - Verfahren zur Herstellung eines Artikels - Google Patents

Verfahren zur Herstellung eines Artikels Download PDF

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Publication number
EP1720073B1
EP1720073B1 EP06252280A EP06252280A EP1720073B1 EP 1720073 B1 EP1720073 B1 EP 1720073B1 EP 06252280 A EP06252280 A EP 06252280A EP 06252280 A EP06252280 A EP 06252280A EP 1720073 B1 EP1720073 B1 EP 1720073B1
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EP
European Patent Office
Prior art keywords
liquid
substrate
projection system
space
confinement structure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP06252280A
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English (en)
French (fr)
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EP1720073A1 (de
Inventor
Alexander Straaijer
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ASML Netherlands BV
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ASML Netherlands BV
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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70—Microphotolithographic exposure; Apparatus therefor
    • G03F7/70216—Mask projection systems
    • G03F7/70341—Details of immersion lithography aspects, e.g. exposure media or control of immersion liquid supply
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/20—Exposure; Apparatus therefor
    • G03F7/2041—Exposure; Apparatus therefor in the presence of a fluid, e.g. immersion; using fluid cooling means
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70—Microphotolithographic exposure; Apparatus therefor
    • G03F7/708—Construction of apparatus, e.g. environment aspects, hygiene aspects or materials
    • G03F7/7095—Materials, e.g. materials for housing, stage or other support having particular properties, e.g. weight, strength, conductivity, thermal expansion coefficient

Definitions

  • the present invention relates to a method for manufacturing a device.
  • a lithographic apparatus is a machine that applies a desired pattern onto a substrate, usually onto a target portion of the substrate.
  • a lithographic apparatus can be used, for example, in the manufacture of integrated circuits (ICs).
  • a patterning device which is alternatively referred to as a mask or a reticle, may be used to generate a circuit pattern to be formed on an individual layer of the IC.
  • This pattern can be transferred onto a target portion (e.g. comprising part of, one, or several dies) on a substrate (e.g. a silicon wafer). Transfer of the pattern is typically via imaging onto a layer of radiation-sensitive material (resist) provided on the substrate.
  • resist radiation-sensitive material
  • a single substrate will contain a network of adjacent target portions that are successively patterned.
  • lithographic apparatus include so-called steppers, in which each target portion is irradiated by exposing an entire pattern onto the target portion at one time, and so-called scanners, in which each target portion is irradiated by scanning the pattern through a radiation beam in a given direction (the "scanning"-direction) while synchronously scanning the substrate parallel or anti-parallel to this direction. It is also possible to transfer the pattern from the patterning device to the substrate by imprinting the pattern onto the substrate.
  • liquid supply system to provide liquid on only a localized area of the substrate and in between the final element of the projection system and the substrate using a liquid confinement system (the substrate generally has a larger surface area than the final element of the projection system).
  • a liquid confinement system the substrate generally has a larger surface area than the final element of the projection system.
  • liquid is supplied by at least one inlet IN onto the substrate, preferably along the direction of movement of the substrate relative to the final element, and is removed by at least one outlet OUT after having passed under the projection system. That is, as the substrate is scanned beneath the element in a -X direction, liquid is supplied at the +X side of the element and taken up at the -X side.
  • Figure 2 shows the arrangement schematically in which liquid is supplied via inlet IN and is taken up on the other side of the element by outlet OUT which is connected to a low pressure source.
  • the liquid is supplied along the direction of movement of the substrate relative to the final element, though this does not need to be the case.
  • Figure 3 shows the arrangement schematically in which liquid is supplied via inlet IN and is taken up on the other side of the element by outlet OUT which is connected to a low pressure source.
  • the liquid is supplied along the direction of movement of the substrate relative to the final element, though this does not need to be the case.
  • Figure 3 shows the arrangement schematically in which liquid is supplied via inlet IN and is taken up on the other side of the element by outlet OUT which is connected to a low pressure source.
  • the advantage provided by immersion lithography is dependent upon the refractive index of the immersion liquid - the higher the refractive index, the greater the benefit.
  • Most existing proposals have used ultra pure water, which has a refractive index of 1.437 at 193 nm, as the immersion fluid but other fluids with higher refractive indexes have also been proposed. These include certain hydro-carbons that have a refractive index of greater than 1.6 at 193 nm, and certain perfluoropolyethers, which have a refractive index greater than 1.3 at 157 nm.
  • liquids are possibly suitable for immersion lithography - for example, they have good stability, transmissivity and are compatible with projection system materials and resists - their fluid properties are very different than those of water and so existing designs of liquid containment system may not effectively localize these fluids between the projection system and the substrate.
  • These fluids are nonpolar and have very low surface tension so they easily spread out across the entire substrate and substrate table. Arrangements using gas knives that have been shown to successfully confine water, may not be able to confine these nonpolar fluids.
  • WO2004/105106 discloses an immersion lithographic apparatus that can selectively supply one of two different immersion liquids to a space between the projection system and the substrate.
  • Figure 1 schematically depicts a lithographic apparatus usable in an embodiment of the invention.
  • the apparatus comprises:
  • the illumination system may include various types of optical components, such as refractive, reflective, magnetic, electromagnetic, electrostatic or other types of optical components, or any combination thereof, for directing, shaping, or controlling radiation.
  • optical components such as refractive, reflective, magnetic, electromagnetic, electrostatic or other types of optical components, or any combination thereof, for directing, shaping, or controlling radiation.
  • the support structure holds the patterning device in a manner that depends on the orientation of the patterning device, the design of the lithographic apparatus, and other conditions, such as for example whether or not the patterning device is held in a vacuum environment.
  • the support structure can use mechanical, vacuum, electrostatic or other clamping techniques to hold the patterning device.
  • the support structure may be a frame or a table, for example, which may be fixed or movable as required.
  • the support structure may ensure that the patterning device is at a desired position, for example with respect to the projection system. Any use of the terms "reticle” or “mask” herein may be considered synonymous with the more general term "patterning device.”
  • patterning device used herein should be broadly interpreted as referring to any device that can be used to impart a radiation beam with a pattern in its cross-section such as to create a pattern in a target portion of the substrate. It should be noted that the pattern imparted to the radiation beam may not exactly correspond to the desired pattern in the target portion of the substrate, for example if the pattern includes phase-shifting features or so called assist features. Generally, the pattern imparted to the radiation beam will correspond to a particular functional layer in a device being created in the target portion, such as an integrated circuit.
  • the patterning device may be transmissive or reflective.
  • Examples of patterning devices include masks, programmable mirror arrays, and programmable LCD panels.
  • Masks are well known in lithography, and include mask types such as binary, alternating phase-shift, and attenuated phase-shift, as well as various hybrid mask types.
  • An example of a programmable mirror array employs a matrix arrangement of small mirrors, each of which can be individually tilted so as to reflect an incoming radiation beam in different directions. The tilted mirrors impart a pattern in a radiation beam which is reflected by the mirror matrix.
  • projection system used herein should be broadly interpreted as encompassing any type of projection system, including refractive, reflective, catadioptric, magnetic, electromagnetic and electrostatic optical systems, or any combination thereof, as appropriate for the exposure radiation being used, or for other factors such as the use of an immersion liquid or the use of a vacuum. Any use of the term “projection lens” herein may be considered as synonymous with the more general term “projection system”.
  • the apparatus is of a transmissive type (e.g . employing a transmissive mask).
  • the apparatus may be of a reflective type (e.g. employing a programmable mirror array of a type as referred to above, or employing a reflective mask).
  • the lithographic apparatus may be of a type having two (dual stage) or more substrate tables (and/or two or more mask tables). In such "multiple stage” machines the additional tables may be used in parallel, or preparatory steps may be carried out on one or more tables while one or more other tables are being used for exposure.
  • the illuminator IL receives a radiation beam from a radiation source SO.
  • the source and the lithographic apparatus may be separate entities, for example when the source is an excimer laser. In such cases, the source is not considered to form part of the lithographic apparatus and the radiation beam is passed from the source SO to the illuminator IL with the aid of a beam delivery system BD comprising, for example, suitable directing mirrors and/or a beam expander. In other cases the source may be an integral part of the lithographic apparatus, for example when the source is a mercury lamp.
  • the source SO and the illuminator IL, together with the beam delivery system BD if required, may be referred to as a radiation system.
  • the illuminator IL may comprise an adjuster AD for adjusting the angular intensity distribution of the radiation beam.
  • an adjuster AD for adjusting the angular intensity distribution of the radiation beam.
  • the illuminator IL may comprise various other components, such as an integrator IN and a condenser CO.
  • the illuminator may be used to condition the radiation beam, to have a desired uniformity and intensity distribution in its cross-section.
  • the radiation beam B is incident on the patterning device (e.g. , mask MA), which is held on the support structure (e.g. , mask table MT), and is patterned by the patterning device. Having traversed the mask MA, the radiation beam B passes through the projection system PS, which focuses the beam onto a target portion C of the substrate W.
  • the substrate table WT can be moved accurately, e.g. so as to position different target portions C in the path of the radiation beam B.
  • the first positioner PM and another position sensor can be used to accurately position the mask MA with respect to the path of the radiation beam B, e.g. after mechanical retrieval from a mask library, or during a scan.
  • movement of the mask table MT may be realized with the aid of a long-stroke module (coarse positioning) and a short-stroke module (fine positioning), which form part of the first positioner PM.
  • movement of the substrate table WT may be realized using a long-stroke module and a shortstroke module, which form part of the second positioner PW.
  • the mask table MT may be connected to a short-stroke actuator only, or may be fixed.
  • Mask MA and substrate W may be aligned using mask alignment marks M1, M2 and substrate alignment marks P1, P2.
  • the substrate alignment marks as illustrated occupy dedicated target portions, they may be located in spaces between target portions (these are known as scribe-lane alignment marks).
  • the mask alignment marks may be located between the dies.
  • the depicted apparatus could be used in at least one of the following modes:
  • a immersion lithography solution not defined in the claims with a localized liquid supply system is shown in Figure 4 .
  • Liquid is supplied by two groove inlets IN on either side of the projection system PL and is removed by a plurality of discrete outlets OUT arranged radially outwardly of the inlets IN.
  • the inlets IN and OUT can be arranged in a plate with a hole in its centre and through which the projection beam is projected.
  • Liquid is supplied by one groove inlet IN on one side of the projection system PL and removed by a plurality of discrete outlets OUT on the other side of the projection system PL, causing a flow of a thin film of liquid between the projection system PL and the substrate W.
  • the choice of which combination of inlet IN and outlets OUT to use can depend on the direction of movement of the substrate W (the other combination of inlet IN and outlets OUT being inactive).
  • the immersion lithography solution according to the invention with a localized liquid supply system solution which has been proposed is to provide the liquid supply system with a liquid confinement structure which extends along at least a part of a boundary of the space between the final element of the projection system and the substrate table.
  • a solution is illustrated in Figure 5 .
  • the liquid confinement structure is substantially stationary relative to the projection system in the XY plane though there may be some relative movement in the Z direction (in the direction of the optical axis).
  • a seal is formed between the liquid confinement structure and the surface of the substrate.
  • the seal is a contactless seal such as a gas seal.
  • Such a system is disclosed in United States patent application publication no. US 2004-0207824 and European patent application publication no. EP 1420298 , and illustrated in Figure 5 .
  • a liquid supply system is used to supply liquid to the space between the final element of the projection system and the substrate.
  • the reservoir 10 forms a contactless seal to the substrate around the image field of the projection system so that liquid is confined to fill a space between the substrate surface and the final element of the projection system.
  • the reservoir is formed by a liquid confinement structure 12 positioned below and surrounding the final element of the projection system PL.
  • a first liquid 11 is brought into the space below the projection system and within the liquid confinement structure 12 through supply 13 and removed by exhaust 17.
  • the liquid confinement structure 12 extends a little above the final element of the projection system and the liquid level rises above the final element so that a buffer of liquid is provided.
  • the liquid confinement structure 12 has an inner periphery that at the upper end, in an embodiment, closely conforms to the shape of the projection system or the final element thereof and may, e.g. , be round. At the bottom, the inner periphery may be circular or closely conform to the shape of the image field, e.g. , rectangular.
  • the first liquid 11 is confined in the reservoir by a second liquid 19, with which it is substantially immiscible, that is supplied via supply 18.
  • the second liquid 19 is confined by a gas seal 16 between the bottom of the liquid confinement structure 12 and the surface of the substrate W.
  • the gas seal is formed by gas, e.g. air, synthetic air, N2 or an inert gas, provided under pressure via inlet 15 to the gap between liquid confinement structure 12 and substrate and extracted via first outlet 14.
  • the overpressure on the gas inlet 15, vacuum level on the first outlet 14 and geometry of the gap are arranged so that there is a high-velocity gas flow inwards that confines the liquid.
  • Other arrangements to confine a liquid while the body of liquid is moved over a substrate or the substrate is moved relative to the body of liquid are known and may be used to confine the second liquid and therefore also the first liquid.
  • the first, or immersion, liquid is primarily selected on the basis of its optical properties, significantly its refractive index at the wavelength of the exposure radiation.
  • Other useful properties of the second liquid are compatibility with the material of the final projection system element and with the resist, transmissivity and stability over time and under irradiation.
  • deficiencies in these properties can in many cases be ameliorated by a coating on the final projection system element and/or the resist, by increasing the power of the radiation source and/or by increasing the refresh rate of the second liquid.
  • Suitable compounds for the first liquids are cycloalkanes, such as cyclooctane, decalin, bicyclohexyl, exo-tetrahydro-dicyclopentadiene and cyclohexane, other high-index hydrocarbons, perfluoropolyethers, such as perfluoro-N-methylmorpholine and Perfluoro E2, perfluoroalkanes, such as perfluorohexane, and hydrofluoroethers.
  • cycloalkanes such as cyclooctane, decalin, bicyclohexyl, exo-tetrahydro-dicyclopentadiene and cyclohexane
  • other high-index hydrocarbons such as perfluoropolyethers, such as perfluoro-N-methylmorpholine and Perfluoro E2
  • perfluoroalkanes such as perfluorohexane
  • significant fluid properties are those that enable it to be confined, such as surface tension, viscosity and interaction with surfaces of the liquid confinement structure, and its immiscibility with the second liquid.
  • a suitable compound for the second liquid is water. Although a high refractive index is desirable, this and other optical properties of the liquid are relatively unimportant so that additives that increase the desirable properties of the first liquid can be chosen quite freely.
  • the two liquids are substantially immiscible and the functioning may be improved the less miscible are the two liquids.
  • a sufficient degree of immiscibility can be obtained by selecting a non-polar liquid as the first liquid and a polar liquid as the second liquid. If the refractive index of the first and second liquids are not too different, a substantial amount of intermixing can be tolerated. For example, with water (refractive index 1.437) and a hydro-carbon of refractive index greater than 1.6, 1% by volume of water mixed with the hydro-carbon will only reduce the refractive index by only about 1 part in 1000.
  • the liquid confinement arrangement of this embodiment can be appreciated more clearly from Figure 6 which shows in plan, the outlines of the exposure field EF, the inner periphery 12a of the liquid confinement structure 12, the extent of the second liquid 19 and the outer periphery 12b of the liquid confinement structure 12.
  • the inner periphery of the liquid confinement structure 12a may be shaped, textured and or provided with coatings to stabilize the interface between the first and second liquids.
  • a hydrophilic coating may be provided on the surface of the liquid confinement structure facing the substrate and a hydrophobic coating on the surface of the liquid confinement structure facing the space between the final element of the projection system and the substrate.
  • water-related terms such as hydrophilic, hydrophobic, humidity, etc. may be used herein, these terms should be understood to encompass the similar properties for other liquids.
  • lithographic apparatus in the manufacture of ICs
  • the lithographic apparatus described herein may have other applications, such as the manufacture of integrated optical systems, guidance and detection patterns for magnetic domain memories, flat-panel displays, liquid-crystal displays (LCDs), thin-film magnetic heads, etc.
  • LCDs liquid-crystal displays
  • any use of the terms “wafer” or “die” herein may be considered as synonymous with the more general terms “substrate” or "target portion”, respectively.
  • the substrate referred to herein may be processed, before or after exposure, in for example a track (a tool that typically applies a layer of resist to a substrate and develops the exposed resist), a metrology tool and/or an inspection tool. Where applicable, the disclosure herein may be applied to such and other substrate processing tools. Further, the substrate may be processed more than once, for example in order to create a multi-layer IC, so that the term substrate used herein may also refer to a substrate that already contains multiple processed layers.
  • UV radiation e.g. having a wavelength of or about 365, 248, 193, 157 or 126 nm.
  • lens may refer to any one or combination of various types of optical components, including refractive and reflective optical components.
  • the invention may take the form of a computer program containing one or more sequences of machine-readable instructions describing a method as disclosed above, or a data storage medium (e . g . semiconductor memory, magnetic or optical disk) having such a computer program stored therein.
  • a data storage medium e . g . semiconductor memory, magnetic or optical disk
  • a liquid supply system as contemplated herein should be broadly construed. In certain embodiments, it may be a mechanism or combination of structures that provides a liquid to a space between the projection system and the substrate and/or substrate table. It may comprise a combination of one or more structures, one or more liquid inlets, one or more gas inlets, one or more gas outlets, and/or one or more liquid outlets that provide liquid to the space.
  • a surface of the space may be a portion of the substrate and/or substrate table, or a surface of the space may completely cover a surface of the substrate and/or substrate table, or the space may envelop the substrate and/or substrate table.
  • the liquid supply system may optionally further include one or more elements to control the position, quantity, quality, shape, flow rate or any other features of the liquid.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Epidemiology (AREA)
  • Public Health (AREA)
  • Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
  • Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)

Claims (8)

  1. Ein Verfahren zur Herstellung einer Vorrichtung, das Folgendes beinhaltet:
    Projizieren eines Bildes eines Musters durch eine erste Flüssigkeit (11) auf einen Zielabschnitt eines Substrats (W) unter Verwendung eines Projektionssystems (PS); Zuführen der ersten Flüssigkeit (11) von einer ersten Flüssigkeitsquelle zu einem Raum zwischen dem Projektionssystem (PS) und dem Substrat, wobei die Flüssigkeitsbegrenzungsstruktur (12) mindestens einen Teil einer Grenze des Raums im Wesentlichen umgibt und sich im Wesentlichen daran entlang erstreckt, so dass der Raum innerhalb der Flüssigkeitsbegrenzungsstruktur (12) liegt; und
    Begrenzen der ersten Flüssigkeit (11) innerhalb des Raumes durch Zuführen einer zweiten Flüssigkeit (19) von einer zweiten Flüssigkeitsquelle zu einem Volumen um den Raum zwischen der Flüssigkeitsbegrenzungsstruktur (12) und dem Substrat (W), wobei die Flüssigkeitsbegrenzungsstruktur (12) angepasst ist, um die zweite Flüssigkeit (19) auf das Volumen zu begrenzen;
    wobei die erste Flüssigkeit (11) mit der zweiten Flüssigkeit (19) im Wesentlichen nicht mischbar ist.
  2. Verfahren gemäß Anspruch 1, wobei die erste Flüssigkeit (11) unpolar ist und die zweite Flüssigkeit (19) polar ist.
  3. Verfahren gemäß Anspruch 2, wobei die erste Flüssigkeit (11) aus der Gruppe ausgewählt ist, die Folgendes beinhaltet: Cycloalkane, andere Kohlenwasserstoffe mit hohem Index, Perfluorpolyether, Perfluoralkane und Hydrofluorether; und die zweite Flüssigkeit (19) Wasser beinhaltet.
  4. Verfahren gemäß Anspruch 1, wobei die erste Flüssigkeit (11) aus der Gruppe ausgewählt ist, die Folgendes beinhaltet: Cyclooctan, Decalin, Bicyclohexyl, Exo-tetrahydro-dicyclopentadien und Cyclohexan.
  5. Verfahren gemäß Anspruch 1, wobei die erste Flüssigkeit (11) Perfluor-N-methylmorpholin oder Perfluor-E2 ist.
  6. Verfahren gemäß Anspruch 1, wobei die erste Flüssigkeit (11) Perfluorhexan ist.
  7. Verfahren gemäß einem der Ansprüche 1 bis 6, wobei die Flüssigkeitsbegrenzungsstruktur (12) eine hydrophile Oberfläche, die an das Volumen angrenzt, und eine hydrophobe Oberfläche, die an den Raum angrenzt, aufweist.
  8. Verfahren gemäß einem der Ansprüche 1 bis 7, wobei das Volumen ringförmig ist.
EP06252280A 2005-05-03 2006-04-28 Verfahren zur Herstellung eines Artikels Not-in-force EP1720073B1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US11/120,198 US7317507B2 (en) 2005-05-03 2005-05-03 Lithographic apparatus and device manufacturing method

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EP1720073A1 EP1720073A1 (de) 2006-11-08
EP1720073B1 true EP1720073B1 (de) 2012-01-18

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US (1) US7317507B2 (de)
EP (1) EP1720073B1 (de)
JP (1) JP4543003B2 (de)
KR (1) KR100706921B1 (de)
CN (1) CN1858655B (de)
SG (1) SG126921A1 (de)
TW (1) TWI331705B (de)

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