EP0947971B1 - Haftetikett - Google Patents

Haftetikett Download PDF

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Publication number
EP0947971B1
EP0947971B1 EP99113150A EP99113150A EP0947971B1 EP 0947971 B1 EP0947971 B1 EP 0947971B1 EP 99113150 A EP99113150 A EP 99113150A EP 99113150 A EP99113150 A EP 99113150A EP 0947971 B1 EP0947971 B1 EP 0947971B1
Authority
EP
European Patent Office
Prior art keywords
layer
imprint
adhesive label
adhesive
battery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP99113150A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0947971A3 (de
EP0947971A2 (de
Inventor
Hans-Peter Ast
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CCL Label Meerane GmbH
Original Assignee
Steinbeis IBL GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8011845&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0947971(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Steinbeis IBL GmbH filed Critical Steinbeis IBL GmbH
Publication of EP0947971A2 publication Critical patent/EP0947971A2/de
Publication of EP0947971A3 publication Critical patent/EP0947971A3/de
Application granted granted Critical
Publication of EP0947971B1 publication Critical patent/EP0947971B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/08—Fastening or securing by means not forming part of the material of the label itself
    • G09F3/10—Fastening or securing by means not forming part of the material of the label itself by an adhesive layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851—Intermediate layer is discontinuous or differential
    • Y10T428/24868—Translucent outer layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2848—Three or more layers

Definitions

  • the invention relates to an adhesive label for application to a peripheral surface a dry cell battery.
  • Conventional adhesive labels to be applied to the peripheral surface of a Dry cell batteries have a stretched, shrinkable, transparent Cover film, one applied directly to the underside of the cover film, Imprint visible from the top of the adhesive label and one below the Printed adhesive layer.
  • the adhesive label points along one Generation line of the peripheral surface of the battery overlapping one another first edge sections and second projecting over the end faces of the battery Edge sections on which after shrinking the cover film on the Lay on end faces.
  • the cover film forms a leak protection for the battery and also protects the underneath the label layers, especially the print mechanical damage.
  • the cover film forms an electrical one Isolation of the peripheral surface of the battery from the environment. If one the layer lying under the cover film is electrically conductive, insulates the cover film this layer against the environment.
  • FR 2 674 979 A1 is an adhesive label for application to the peripheral surface known a dry cell battery, in which the stretched, shrinkable, transparent cover film is the only film layer of the adhesive label forms.
  • the print that is visible from the top of the adhesive label is directly on the underside of this cover film facing the battery applied.
  • a metallization layer follows on the underside of the print and then the pressure sensitive adhesive layer. Between the pressure sensitive adhesive layer and the metallization layer can be provided with an oxide layer that Isolate metallization layer electrically against the battery body.
  • Similar metallized adhesive label which with a single shrink wrap comes out as an outer cover film and carries the print inside, is out Patent Abstracts of Japan, Vol. 12, No. 20 (E-575) and JP-A-62177864 known.
  • Adhesive label for the casing of a dry cell battery is from GB 2 193 834 A.
  • the shrinkable film carries the Imprint on its outside, while the metallization layer immediately is arranged on the inside of this film.
  • a layer of PVC lacquer is arranged, which is the metallization layer electrically insulate against the battery body.
  • Foil material known which, after being shaped into a tube can be used to coat dry cell batteries.
  • the film material has a single shrink film on the battery body a multicolored print is applied to the side to be turned.
  • the Imprint is due to two layers of lacquer of different composition covered.
  • Another adhesive label for battery casings is from FR 2 715 494 A1 known.
  • This label also has a single shrink wrap Cover layer, which is provided on the inside with a print that in turn an electrically non-conductive layer made of particles of a dielectric Minerals carries.
  • the pressure sensitive adhesive layer is on this particle layer arranged.
  • the adhesive label is free of electrically conductive materials, especially a metallization.
  • the object of the invention is to provide an adhesive label for the casing of a Specify dry cell battery, with the simplest construction without long-term change its appearance to be permanently glued to the battery can.
  • the imprint is preferred on the cover film in colors from the organic Solution or solvent-free photocatalytic system in the mirror image Counterprint printed, i.e. from below a mirror image of the Cover film, so that the print can be seen from the right side from above.
  • This Color systems are particularly suitable for printing on the shrinkable film, without changing during the shrinking process or from the film replace. They also have the necessary for dry cell batteries electrical properties and are chemical resistant, which in particular important with regard to the leak protection function of the battery label is.
  • the cover film is preferably made of shrinkable hard PVC, polypropylene, Polystyrene, polyamide, in particular a thickness of 25 to 60 micrometers, or Polyethylene terephthalate, or polycarbonate, in particular a thickness of 10 up to 60 microns. So that the adhesive label after shrink-fitting adheres to the battery as firmly as possible and also under unfavorable environmental conditions The adhesive label does not come off the body of the battery Cover film stretched in the circumferential direction of the dry cell battery, so that after the shrinking the adhesive label in the circumferential direction the greatest bias Has.
  • Fig. 2 shows a schematic section of a first embodiment of the Adhesive label.
  • a cover film 3 is made of stretched, shrinkable, transparent film made of hard PVC (polyvinyl chloride), PP (Polypropylene), OPP (oriented polypropylene), PET (polyethylene terephthalate), PS (polystyrene), PE (polyethylene), PC (polycarbonate) or polyamide of one thickness from 20 to 70 microns underside directly with an externally visible one Print 5.
  • PVC polyvinyl chloride
  • PP Polypropylene
  • OPP oriented polypropylene
  • PET polyethylene terephthalate
  • PS polystyrene
  • PE polyethylene
  • PC polycarbonate
  • a PP, OPP, PS or PE film is used as the cover film 3 - becomes the cover film because of the non-polar properties of the film material before applying the print 5 with an adhesion-promoting primer layer 3a provided as a pressure improver with a thickness of approx. 2 ⁇ m.
  • the primer layer 3a increases the surface tension.
  • the cover sheet 3 is the only shrinkable Plastic film layer of the adhesive label. You can top and Wear additional layers on the underside.
  • the imprint 5 and free of the imprint Partial surfaces of the cover sheet 3 are covered with a metal layer 7, in particular Aluminum, steamed or sputtered.
  • the metal layer 7 forms one of visible background for the imprint 5 and is outwardly through the Cover film 3 electrically insulated.
  • a non-metallic layer 9 applied from plastic film or paper.
  • the Metal layer 7 and the non-metallic layer 9 together form one Backing material 11 of the label 1.
  • the metal layer 7 can be separated from the cover film 3 onto the non-metallic one Layer 9 applied - for example vapor-deposited or sputtered - and that resulting from these two sub-layers 7, 9 Backing material 11 is - optionally by means of a primer layer - on the printed underside of the cover sheet 3, in particular by the action of heat attached.
  • the carrier material 11 1 is provided on the underside with pressure-sensitive adhesive 13, and that thus finished label 1 is on a non-stick, such as siliconized Carrier tape 15 is placed, from which it is later shown by means of a not shown Dispensing device is transferred to a battery body.
  • a non-stick such as siliconized Carrier tape 15
  • the imprint 5 is only schematic with spaces shown. In this as in all the versions described below, the imprint 5 can also be closed over a large area, multi-colored, multi-layer, a combination of opaque inks or / and be opaque inks. Also special metal colors, so also in solution brought particles of a flat vapor deposition form a special closed layer of paint.
  • Fig. 1 shows schematically the application of the adhesive label 1 on one cylindrical battery body 50 of a rechargeable or non-rechargeable Dry cell or device battery.
  • the adhesive label 1 is with its adhesive layer 13 on the circumference of the battery body 50 so imposed that its not printed and no substrate 11 having Longitudinal edges 17 over end faces 51, 51 of the battery body 50 protrude, in particular the stretching direction of the cover film 3 in the circumferential direction of the battery body 50 extends.
  • the adhesive label 1 around the Circumference of the battery body 50 folded around, so that end regions 19, 19 of the Adhesive labels 1 overlap each other.
  • the adhesive label 1 is under Heat shrunk on the battery body 50 so that the Longitudinal edges 17 rest on the end faces 51, 51 of the battery body 50 and additionally adhere to the end faces 51, 51 by means of the pressure-sensitive adhesive 13.
  • the outer cover layer 3 protects the underlying one Layers before damage, especially during the manufacturing process the battery from the application of the label to the packaging of the manufacture battery and also withstands mechanical stress in Battery layers of the devices used.
  • Fig. 3 shows a second embodiment of the adhesive label 1. It differs of the embodiment according to FIG. 2 in that the carrier material 11 has one layer is. If the carrier material 11 1 is made of metal, such as aluminum, it can be applied to the printed underside of the cover film 3 be sputtered or evaporated, approximately 2 to 7 ⁇ thick. Alternatively, the metal layer can be separated of the cover sheet 3 are applied to a support, not shown, from which they then apply to the surface using a thermosensitive intermediate layer Imprint 5 is transferred.
  • This carrier provides as a system-related aid preferably is a film after the transfer of the metal layer is pulled off again and rolled up, therefore no longer in the Layer structure is integrated.
  • the pressure sensitive adhesive 13 is applied directly to the Metal layer applied. Again, if necessary, the cover sheet 3 can be placed in front of the Printed with a primer layer 3a or a high-frequency treatment be subjected.
  • FIG. 4 shows a third embodiment of the adhesive label 1 similar to that in FIG. 3 with a single-layer carrier material 11.
  • the carrier material 11 is made of paper or plastic and is applied to the printed underside of the cover film 3 by means of an intermediate liner layer 21.
  • the lamination layer 21 is applied as a lacquer or adhesive in the liquid or semi-liquid phase and cures by chemical reaction of the binder and hardener constituents, by radiation or / and by the release of solvents.
  • the lamination layer 21 can be pigmented when the print is not closed over the entire area and form an optical background for the print 5.
  • the liner layer 21 improves the adhesion of the carrier material 11 to the printed underside of the cover film 3.
  • the liner layer 21 has a thickness of 3.5 to 5 ⁇ m, corresponding to 2.5-4 g / m 2, and forms a barrier against immigration of solvents from the underlying layer Adhesive layer 13 in the print and thereby its change with a long storage time.
  • the liner layer 21 is an additional barrier against migration of electrolyte and at the same time improves the electrical insulation properties of the label without the need for an additional insulation layer.
  • the cover film 3 can be provided with a primer layer 3a before printing or subjected to a high-frequency treatment.
  • Fig. 5 shows a fourth embodiment.
  • the Cover foil 3 is provided with the imprint 5 directly on its underside.
  • the cover sheet 3 takes over the sole here Carrier function of the adhesive label.
  • the imprint 5 can be closed flat, so that you cannot see the surface of the battery body underneath.
  • the imprint 5 improves the electrical insulation of the label and prevents it diffusing solvents from the adhesive layer 13 or from Electrolyte residues on the battery surface.
  • the adhesive layer 13 can be colored and then does not form an optical background for you flat closed opaque print.
  • Fig. 6 shows a fifth embodiment similar to Fig. 5, but the imprint 5 on the underside carries a lamination layer 21 similar to the embodiment of FIG. 4.
  • the lamination layer 21 is in the form of lacquer or adhesive in liquid or semi-liquid Applied and hardened by chemical reaction of binder and Hardener components, by irradiation and / or by the release of Solvents.
  • the lamination layer 21 can be closed when the surface is not closed Imprint pigmented and an optical background for form the imprint 5.
  • the lamination layer 21 has the function of Barrier against diffusion of solvents from the underside to the Laminating layer 21 applied adhesive layer 13 and of electrolytes on the surface of the battery body in the imprint 5 and protects it before change. This improves durability and shelf life of the label even under unfavorable conditions such as high temperature and Humidity.
  • the cover film 3 can also be printed here before printing a primer layer 3a or a high frequency treatment be subjected.
  • Fig. 7 shows a sixth embodiment.
  • the top layer 3, which in the case a non-polar film optionally present primer layer 3a and Imprint 5 correspond to the embodiment of Fig. 3.
  • the liner layer 21 improves the adhesion of an applied to it Metal layer 7, such as aluminum, according to the embodiment of Fig. 3.
  • This metal layer 7 is sputtered with a thickness of 2-7 ⁇ evaporated. Because of the micropartial buildup of metal particles the metal layer 7 is porous and has a significantly higher electrical Resistance as a metal foil. The metal layer 7 additionally hides unavoidable Contaminants and stains on the battery body 50.
  • the metal layer 7 can also be used as a film in the transfer process Laminating layer 21 are transferred.
  • the lamination layer 21 forms a flexible connection between the metal layer 7 and the cover sheet 3.
  • This flexible connection prevents Shrinkage of the film and labeling on tight radii of the battery body the metal layer is distorted.
  • the flexible connection takes shear forces and Tensions in the label.
  • the flexible connection forms the Barrier described above for Fig. 4, which prevents solvent from the pressure-sensitive adhesive 13 which has penetrated into the pores of the metal layer 7 can immigrate into the print and change it, and that in particular electrical insulation improved.
  • the one in the pores of the metal layer penetrated laminating adhesive 21 solidifies the metal layer.
  • the lamination layer 21 can be a varnish, which after application in liquid or semi-liquid state due to chemical reaction of binder and hardener components, radiation or / and by evaporation of Solidified solvents. Before sputtering or evaporating the Metal layer 7 can let the lamination layer 21 solidify. In the event of the storage of a metal foil, for example in the foil transfer process, can place the metal foil on the not yet solidified lamination layer 21 in order to to take advantage of the adhesive effect of the paint that has not yet solidified.
  • the lamination layer 21 may contain pigments to form an optical background for the imprint 5.
  • the adhesive layer 13 has a thickness of 10 to 25 microns and electrically isolates the metal layer 7 from the battery body 50.
  • the adhesive layer 13 be thinner than 15 ⁇ m because the lamination layer 21 is also insulating Has properties.
  • the pressure sensitive adhesive 13 which has penetrated into the pores of the metal layer 7 isolates the Pores and thus increases the electrical resistance of the metal layer 7.
  • the lamination adhesive 21 is preferably a two-component adhesive or paint with binder and hardener, and the pressure sensitive adhesive 13 provides in the Usually a permanently elastic one-component adhesive with stabilizers such as Antioxidants that harden and therefore flake off as a result prevent surface breakage while maintaining high shear force in the contact area. As a result, the lamination layer 21 adheres in the hardened state stronger than the non-curing and thus permanently elastic pressure sensitive adhesive 13.
  • the Adhesive effect of the pressure-sensitive adhesive 13 in the overlap area 19 with the cover film 3 is on the adhesive effect with the battery body 50 between the overlap areas adjusted so that the overlap 19 is prevented.
  • Fig. 8 shows a seventh embodiment, which differs from the embodiment of Fig Layer structure distinguishes between the imprint 5 and the metal layer 7, otherwise, however, the embodiment of FIG. 7 with all of its Variants are the same.
  • the lamination layer 21 applied to the imprint 5, which in its Components can correspond to the embodiment of FIG. 7 is flexible and forms a flexible connection between the cover sheet 3 and the metal layer 7, so that when the cover film 3 shrinks onto the battery body, the metal layer 7 is not damaged, such as curling or tearing.
  • This flexible Connection absorbs shear forces and tension in the label.
  • the Laminating layer 21 adheres more strongly than pressure-sensitive adhesive 13.
  • a lacquer layer 22 is applied to the underside of the lamination layer 21, which is harder and / or denser than the lamination layer 21 and which corresponds to FIG. 7 described barrier function against immigration of solvents the adhesive layer 13 or electrolytes of the battery surface in the Imprint 5 takes over.
  • the lacquer layer 22 can be good because of its strength sputter or vaporize with metal and prevents penetration of such solvents from the adhesive layer 13 and from the electrolyte Battery surface that has already penetrated the pores of the metal layer 7 to have.
  • the lamination layer 21 and / or the lacquer layer 22 can be pigmented and form an optical background for the imprint.
  • FIG. 9 shows an eighth embodiment similar to FIGS. 7 and 8, but with modified lamination layer 21, the corresponding components 7 can be formed.
  • the lamination layer 21 is applied to the imprint 5 in the liquid or semi-liquid state and then by curing the binder and hardener components, irradiation or / and solvent evaporation partially solidified such that a on the imprint 5 flexible partial layer 21a and one of the Imprint 5 forms distant, harder sub-layer 21b, which subsequently can be sputtered or vaporized particularly well with the metal layer 7.
  • the flexible sublayer 21a serves as a flexible connection between the cover film 3 and the metal layer 7, with the effect of the lamination layer 21 of the 8, and the harder sublayer 21b forms the barrier layer with effect of the lacquer layer 22 against the embodiment of FIG. 8 Immigration of solvent from the adhesive layer 13 and from Electrolytes of the battery surface through pores of the metal layer 7 in the Imprint 5.
  • the lamination layer 21 and / or the lacquer layer 22 can be pigmented to form an optical background for the imprint 5.
  • a variety of adhesive labels releasably adhere to a siliconized Carrier tape 15.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Sealing Battery Cases Or Jackets (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Valve Device For Special Equipments (AREA)
EP99113150A 1995-08-16 1996-08-14 Haftetikett Expired - Lifetime EP0947971B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE29513170U 1995-08-16
DE29513170U DE29513170U1 (de) 1995-08-16 1995-08-16 Haftetikett
EP96113097A EP0762365B1 (de) 1995-08-16 1996-08-14 Haftetikett

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
EP96113097A Division EP0762365B1 (de) 1995-08-16 1996-08-14 Haftetikett

Publications (3)

Publication Number Publication Date
EP0947971A2 EP0947971A2 (de) 1999-10-06
EP0947971A3 EP0947971A3 (de) 1999-11-10
EP0947971B1 true EP0947971B1 (de) 2002-04-03

Family

ID=8011845

Family Applications (2)

Application Number Title Priority Date Filing Date
EP99113150A Expired - Lifetime EP0947971B1 (de) 1995-08-16 1996-08-14 Haftetikett
EP96113097A Expired - Lifetime EP0762365B1 (de) 1995-08-16 1996-08-14 Haftetikett

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP96113097A Expired - Lifetime EP0762365B1 (de) 1995-08-16 1996-08-14 Haftetikett

Country Status (9)

Country Link
US (1) US6248427B1 (da)
EP (2) EP0947971B1 (da)
JP (1) JP2869963B2 (da)
CN (1) CN1107299C (da)
AT (2) ATE215721T1 (da)
CA (1) CA2183593C (da)
DE (3) DE29513170U1 (da)
DK (2) DK0762365T3 (da)
EA (1) EA000086B1 (da)

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EA199600054A1 (ru) 1997-03-31
EP0947971A3 (de) 1999-11-10
US6248427B1 (en) 2001-06-19
JPH10301496A (ja) 1998-11-13
EP0762365A1 (de) 1997-03-12
DE29513170U1 (de) 1997-01-02
ATE215721T1 (de) 2002-04-15
DK0762365T3 (da) 2000-10-30
DE59605489D1 (de) 2000-08-03
CA2183593C (en) 2000-03-28
CA2183593A1 (en) 1997-02-17
EP0947971A2 (de) 1999-10-06
HK1020634A1 (en) 2000-05-12
HK1009302A1 (en) 1999-05-28
JP2869963B2 (ja) 1999-03-10
CN1107299C (zh) 2003-04-30
EA000086B1 (ru) 1998-06-25
DK0947971T3 (da) 2002-07-08
ATE194246T1 (de) 2000-07-15
EP0762365B1 (de) 2000-06-28
DE59609038D1 (de) 2002-05-08
CN1151059A (zh) 1997-06-04

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