DK1743899T3 - Metalkomplekser til anvendelse i metatese, radikalreaktioner med atomoverförsel, additionspolymeriserings og vinyleringsreaktioner, fremgangsmåder og mellemprodukter til fremstilling - Google Patents

Metalkomplekser til anvendelse i metatese, radikalreaktioner med atomoverförsel, additionspolymeriserings og vinyleringsreaktioner, fremgangsmåder og mellemprodukter til fremstilling

Info

Publication number
DK1743899T3
DK1743899T3 DK06020387T DK06020387T DK1743899T3 DK 1743899 T3 DK1743899 T3 DK 1743899T3 DK 06020387 T DK06020387 T DK 06020387T DK 06020387 T DK06020387 T DK 06020387T DK 1743899 T3 DK1743899 T3 DK 1743899T3
Authority
DK
Denmark
Prior art keywords
reactions
metal complexes
metathesis
intermediates
preparation
Prior art date
Application number
DK06020387T
Other languages
English (en)
Inventor
Francis Walter Cornelius Verpoort
Clercq Bob De
Original Assignee
Telene Sas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from EP02075250A external-priority patent/EP1329455A1/en
Application filed by Telene Sas filed Critical Telene Sas
Application granted granted Critical
Publication of DK1743899T3 publication Critical patent/DK1743899T3/da

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C07F15/0053—Ruthenium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B01J31/1625—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups
    • B01J31/1633—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups covalent linkages via silicon containing groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/08—Copper compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/002—Osmium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/06—Cobalt compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/28—Titanium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/7003—Bidentate ligand
    • C08F4/7019—Monoanionic ligand
    • C08F4/7022—NO
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B01J2231/125—Radical (co)polymerisation, e.g. mediators therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0286—Complexes comprising ligands or other components characterized by their function
    • B01J2531/0288—Sterically demanding or shielding ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/11—Compounds covalently bound to a solid support
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
    • C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3322—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from cyclooctene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
    • C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3324—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from norbornene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/41—Organometallic coupling reactions
    • C08G2261/418—Ring opening metathesis polymerisation [ROMP]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/41—Organometallic coupling reactions
    • C08G2261/419—Acyclic diene metathesis [ADMET]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polymerization Catalysts (AREA)
  • Pyrrole Compounds (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
DK06020387T 2002-01-22 2003-01-22 Metalkomplekser til anvendelse i metatese, radikalreaktioner med atomoverförsel, additionspolymeriserings og vinyleringsreaktioner, fremgangsmåder og mellemprodukter til fremstilling DK1743899T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP02075250A EP1329455A1 (en) 2002-01-22 2002-01-22 Metal carbene complexes, methods and intermediates for making them and their use in metathesis reactions
US34995602P 2002-02-01 2002-02-01

Publications (1)

Publication Number Publication Date
DK1743899T3 true DK1743899T3 (da) 2009-06-22

Family

ID=27614617

Family Applications (2)

Application Number Title Priority Date Filing Date
DK06020387T DK1743899T3 (da) 2002-01-22 2003-01-22 Metalkomplekser til anvendelse i metatese, radikalreaktioner med atomoverförsel, additionspolymeriserings og vinyleringsreaktioner, fremgangsmåder og mellemprodukter til fremstilling
DK03731638T DK1468004T3 (da) 2002-01-22 2003-01-22 Metalkomplekser til anvendelse i metatese

Family Applications After (1)

Application Number Title Priority Date Filing Date
DK03731638T DK1468004T3 (da) 2002-01-22 2003-01-22 Metalkomplekser til anvendelse i metatese

Country Status (11)

Country Link
US (1) US7687635B2 (da)
EP (2) EP1468004B1 (da)
JP (2) JP4477879B2 (da)
AT (2) ATE348835T1 (da)
AU (1) AU2003236511B2 (da)
CA (1) CA2473029A1 (da)
DE (2) DE60310521T2 (da)
DK (2) DK1743899T3 (da)
ES (2) ES2279117T3 (da)
WO (1) WO2003062253A1 (da)
ZA (1) ZA200405685B (da)

Families Citing this family (98)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003062253A1 (en) 2002-01-22 2003-07-31 Universiteit Gent Metal complexes for use in metathesis
WO2005035121A2 (en) * 2003-10-16 2005-04-21 Universiteit Gent Schiff base metal complexes for use as catalysts in organic synthesis
DE102004002178A1 (de) * 2004-01-15 2005-08-11 Ivoclar Vivadent Ag Dentalmeterialien auf der Basis von RÖMP-Kompositen
JP4997096B2 (ja) * 2004-02-26 2012-08-08 テレーヌ ソシエテ パル アクシオン サンプリフィエー オレフィンメタセシスおよび原子またはグループ移動反応に使用するための金属錯体
US20070185343A1 (en) * 2004-02-26 2007-08-09 Universiteit Gent Metal complexes for use in olefin metathesis and atom group transfer reactions
JP2006016606A (ja) * 2004-05-31 2006-01-19 Nippon Zeon Co Ltd 環状オレフィンの付加重合用触媒、およびこれを用いた環状オレフィン付加重合体の製造方法
DE102004039277A1 (de) * 2004-08-13 2006-02-23 Merck Patent Gmbh Am Zentralatom substituierte, immoblisierbare Ruthenium(II)-Katalysatoren, Verfahren zu deren Herstellung und Verwendung
GB0517137D0 (en) 2005-08-22 2005-09-28 Viacatt N V Multicoordinated metal complexes for use in metalthesis reactions
DE602006019673D1 (de) 2005-08-22 2011-03-03 Telene S A S Vielfachkoordinierte Metal-Komplexe zur Verwendung in Metathese-Reaktionen
JP5116694B2 (ja) * 2006-01-19 2013-01-09 エージェンシー フォー サイエンス，テクノロジー アンド リサーチ 不均一キラル触媒
WO2007117221A1 (en) 2006-04-11 2007-10-18 Agency For Science, Technology And Research Catalysts for ring closing metathesis
US8592336B2 (en) 2006-04-11 2013-11-26 Agency For Science, Technology And Research Catalysts for ring-closing metathesis
CN100465195C (zh) * 2006-04-29 2009-03-04 中国科学院长春应用化学研究所 一种β-羟基丙烯亚胺钒烯烃聚合催化剂及制备方法和应用
CN100424100C (zh) * 2006-05-25 2008-10-08 中国科学院长春应用化学研究所 一种β-酮亚胺钒烯烃聚合催化剂及制备方法和应用
EP2104566B1 (en) * 2006-11-21 2016-01-27 California Institute Of Technology Olefin metathesis initiators bearing thiazol-2-ylidene ligands
WO2008067443A1 (en) * 2006-11-29 2008-06-05 Board Of Governors For Higher Education, Aerobic oxidative coupling for the formation biaryls
KR101015435B1 (ko) * 2006-12-05 2011-02-22 주식회사 엘지화학 중합체 제조방법
FR2910004A1 (fr) * 2006-12-14 2008-06-20 Rhodia Recherches & Tech Procede d'oligomerisation et/ou polymerisation du composes insatures
US8148287B2 (en) * 2007-03-22 2012-04-03 Agency For Science, Technology And Research Catalyst immobilization on siliceous mesocellular foam via click chemistry
CN102027001A (zh) * 2007-06-20 2011-04-20 新加坡科技研究局 N-杂环卡宾金属环催化剂和方法
US8524958B2 (en) 2007-06-25 2013-09-03 Sun Chemical Corporation Process for preparation of oligomeric or polymeric compounds using selective Michael addition
WO2009009597A1 (en) * 2007-07-09 2009-01-15 The Regents Of The University Of California Water soluble olefin metathesis
US8263712B2 (en) 2007-09-04 2012-09-11 Exxonmobil Research And Engineering Company Production of elastomeric functionalized olefin polymers
EP2042537B1 (en) * 2007-09-28 2014-05-14 Rimtec Corporation Polycycloolefin (PCO) thermoset assembly and process for its preparation
WO2009085040A1 (en) * 2007-12-27 2009-07-09 Dcb-Usa Llc Protein kinase inhibitors
US8080681B2 (en) 2007-12-28 2011-12-20 Chevron Phillips Chemical Company Lp Nano-linked metallocene catalyst compositions and their polymer products
US7863210B2 (en) 2007-12-28 2011-01-04 Chevron Phillips Chemical Company Lp Nano-linked metallocene catalyst compositions and their polymer products
US8012900B2 (en) 2007-12-28 2011-09-06 Chevron Phillips Chemical Company, L.P. Nano-linked metallocene catalyst compositions and their polymer products
DE102009017498A1 (de) 2009-04-16 2010-10-28 Süd-Chemie AG Verwendung einer Katalysatorzusammensetzung zur Olefinmetathese in der Gasphase und Verfahren zur Olefinmetathese in der Gasphase
KR101147809B1 (ko) * 2009-04-28 2012-05-18 한국과학기술연구원 폴리알킬티오펜 블록 공중합체 및 개환 메타세시스 중합 반응을 통한 이의 제조 방법
US7919639B2 (en) 2009-06-23 2011-04-05 Chevron Phillips Chemical Company Lp Nano-linked heteronuclear metallocene catalyst compositions and their polymer products
EP2280017B1 (en) 2009-07-21 2013-01-02 Rimtec Corporation Catalytic complex for olefin metathesis reactions, process for the preparation thereof and use thereof
US20110263870A1 (en) * 2010-04-23 2011-10-27 Helvetica Industries (P) Limited Novel pyrrole derivatives and their synthesis
EP2608949B1 (en) 2010-08-23 2023-03-29 Materia, Inc. Vartm flow modifications for low viscosity resin systems
JP5738097B2 (ja) * 2010-09-10 2015-06-17 昭和電工株式会社 ノルボルネン系重合体の製造方法
US20130183519A1 (en) 2010-09-22 2013-07-18 Zeon Corporation Adhesive film for organic electrolyte-type energy storage device
US8937207B2 (en) * 2010-12-22 2015-01-20 Richard Dehn Use of supported ruthenium-carbene complexes in continuously operated reactors
US20120289617A1 (en) * 2011-05-10 2012-11-15 Saudi Arabian Oil Company Hybrid Catalyst for Olefin Metathesis
PL2721106T3 (pl) 2011-06-17 2021-03-08 Materia, Inc. Promotory przyczepności i modyfikatory żelowania dla kompozycji do metatezy olefin
US8993819B2 (en) 2011-07-12 2015-03-31 Basf Se Process for preparing cycloheptene
KR20140054030A (ko) 2011-07-12 2014-05-08 바스프 에스이 시클로헵텐의 제조 방법
EP2753655B1 (en) 2011-09-07 2019-12-04 Dow Silicones Corporation Titanium containing complex and condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
CN103781850B (zh) 2011-09-07 2016-10-26 道康宁公司 含锆络合物和缩合反应催化剂、制备该催化剂的方法以及包含该催化剂的组合物
US9139699B2 (en) * 2012-10-04 2015-09-22 Dow Corning Corporation Metal containing condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
EP2764052B1 (en) 2011-10-04 2018-07-18 Dow Silicones Corporation Iron(iii) containing complex and condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
US9530571B2 (en) 2011-11-18 2016-12-27 Adeka Corporation Compound and support material supporting this novel compound
GB201204715D0 (en) 2012-03-18 2012-05-02 Croda Int Plc Metathesis of olefins using ruthenium-based catalytic complexes
WO2013186238A1 (de) 2012-06-13 2013-12-19 Basf Se Verfahren zur herstellung makrocyclischer ketone
JP6092379B2 (ja) 2012-06-29 2017-03-08 アペイロン シンセシス エス アー 金属錯体、その適用、及びメタセシス反応の実施方法
EP2695901B1 (de) 2012-08-10 2016-09-14 Basf Se Aliphatische langkettige Polykondensate
KR102054752B1 (ko) 2012-09-26 2019-12-11 림텍 가부시키가이샤 중합성 조성물 및 수지 성형체의 제조 방법
TWI485145B (zh) 2012-10-26 2015-05-21 Ind Tech Res Inst Ｐ型有機半導體材料與光電元件
US9527982B2 (en) 2012-12-19 2016-12-27 Materia, Inc. Storage stable adhesion promoter compositions for cyclic olefin resin compositions
US9598531B2 (en) 2013-02-27 2017-03-21 Materia, Inc. Olefin metathesis catalyst compositions comprising at least two metal carbene olefin metathesis catalysts
BR112015019868B1 (pt) * 2013-02-27 2020-06-09 Materia Inc composição de polimerização de metátese de abertura de anel (romp) e métodos para a produção de um artigo
US20160017089A1 (en) 2013-03-15 2016-01-21 Materia, Inc. In-mold coating of romp polymers
US9663440B2 (en) 2013-04-09 2017-05-30 Materia, Inc. Cross metathesis of poly-branched poly-olefins
WO2014210076A1 (en) 2013-06-24 2014-12-31 Materia, Inc. Thermal insulation
CN105492489B (zh) 2013-07-03 2017-06-13 马特里亚公司 液体模制组合物
EP3041812B1 (en) 2013-09-04 2022-08-10 California Institute of Technology Functionalized linear and cyclic polyolefins
US20160244540A1 (en) * 2013-09-27 2016-08-25 Rimtec Corporation Norbornene cross-linked polymer and method for producing same
KR102287912B1 (ko) 2013-12-26 2021-08-06 림텍 가부시키가이샤 복합 성형체의 제조 방법
WO2015130802A1 (en) 2014-02-27 2015-09-03 Materia, Inc. Adhesion promoter compositions for cyclic olefin resin compositions
CN107250142B (zh) * 2014-07-03 2020-10-30 光明创新（武汉）有限公司 第8族过渡金属催化剂及其制备方法和其在复分解反应中的应用
US10301401B2 (en) 2014-07-24 2019-05-28 Japan Polyethylene Corporation Olefin polymerization catalyst and method for producing olefin polymer
US9856352B2 (en) 2014-08-07 2018-01-02 Ppg Industries Ohio, Inc. Glass fiber sizing compositions, sized glass fibers, and polyolefin composites
ES2639302T3 (es) 2014-08-07 2017-10-26 Telene Sas Composición curable y artículo moldeado que comprende la composición
TWI688609B (zh) 2014-11-13 2020-03-21 美商道康寧公司 含硫聚有機矽氧烷組成物及相關態樣
CN107207679A (zh) 2015-02-12 2017-09-26 马特里亚公司 包含官能弹性体的环烯烃树脂组合物
CA2975259C (en) 2015-02-14 2023-03-14 Materia, Inc. Romp polymers having improved resistance to hydrocarbon fluids
EP3153227A1 (de) * 2015-10-07 2017-04-12 Evonik Degussa GmbH Verfahren zur herstellung von polyalkenameren für verpackungsanwendungen
EP3202813A1 (en) 2016-02-05 2017-08-09 Telene SAS Curable composition and molded article comprising the composition
EP3411218A1 (en) 2016-02-07 2018-12-12 Stratasys Ltd. Three-dimensional printing combining ring-opening metathesis polymerization and free radical polymerization
US11053366B2 (en) 2016-02-10 2021-07-06 Rimtec Corporation Polymerizable composition and composite material
US11118004B2 (en) 2016-04-26 2021-09-14 Stratasys Ltd. Three-dimensional inkjet printing using ring-opening metathesis polymerization
US20190210305A1 (en) 2016-05-27 2019-07-11 Rimtec Corporation Method for manufacturing composite material molding
WO2018057290A1 (en) 2016-09-23 2018-03-29 Materia, Inc. Preparation of amino acids and amino acid derivatives
JP6794311B2 (ja) 2017-05-11 2020-12-02 公益財団法人鉄道総合技術研究所 超電導コイル装置及びその製造方法
US10245583B1 (en) * 2017-09-12 2019-04-02 Chevron Phillips Chemical Company, Lp Use of charge-containing molecules linked with covalent bonds to enhance acetylene hydrogenation catalysts
WO2019201730A1 (en) 2018-04-20 2019-10-24 Arlanxeo Deutschland Gmbh Hydrogenation catalyst compositions and their use for hydrogenation of nitrile rubber
CN108559083B (zh) * 2018-04-26 2020-07-14 大连理工大学 一种结晶性聚单硫代碳酸酯的制备方法
CN112204087A (zh) 2018-06-07 2021-01-08 Rimtec株式会社 复合材料和复合材料成型体
CN109046463B (zh) * 2018-08-16 2021-05-04 中山大学 双齿氮杂卡宾锰催化剂及其制备方法和烷基化合成应用
CN111068774B (zh) * 2018-10-18 2022-11-04 中国石油化工股份有限公司 2,6-萘二甲酸合成所用催化剂和其应用
EP3960414A4 (en) * 2019-04-23 2023-01-18 RIMTEC Corporation PROCESS FOR MAKING A CYCLOOLEFIN RESIN DECORATIVE MOLDING ARTICLE
WO2021024956A1 (ja) 2019-08-06 2021-02-11 Rimtec株式会社 重合性組成物、シクロオレフィン系重合体および金属樹脂複合体
TW202208055A (zh) 2020-04-24 2022-03-01 日商Ｒｉｍｔｅｃ股份有限公司 聚合反應性調配液之製造方法及聚合物之製造方法
US20240002585A1 (en) 2020-08-03 2024-01-04 Rimtec Corporation Cycloolefin resin cured product
CN116157262A (zh) 2020-08-28 2023-05-23 Rimtec株式会社 阻氧性环烯烃系树脂固化物
CN112250843B (zh) * 2020-10-16 2023-05-30 湘潭大学 四种D-A’-(π-A)2型聚合烷基化水杨醛席夫碱衍生物合金属配合物及其制备方法与用途
JPWO2022118614A1 (da) 2020-12-03 2022-06-09
WO2022230803A1 (ja) 2021-04-30 2022-11-03 Rimtec株式会社 金属樹脂積層体及び金属樹脂積層体の製造方法
CN115518689B (zh) * 2021-06-24 2023-10-31 中国石油化工股份有限公司 一种环氧烷烃水合制二醇催化剂及其制备方法和应用
US11780864B2 (en) * 2021-07-07 2023-10-10 The Hong Kong University Of Science And Technology Rhenium(V) alkylidyne complexes and methods of use and preparation thereof
CN113666956B (zh) * 2021-08-25 2023-04-25 上海橡实化学有限公司 一种水杨醛亚胺硅烷偶联剂及其制备方法和应用
WO2023220706A2 (en) * 2022-05-12 2023-11-16 Yale University Catalyst, system and method for mineralization of organic pollutants
CN115463655B (zh) * 2022-06-23 2024-05-14 浙江恒逸石化研究院有限公司 一种可一步法制备高顺反比2,2,4,4-四甲基-1,3-环丁二醇的催化剂及其应用
CN116970148A (zh) * 2023-06-15 2023-10-31 天津大学 一种高性能宽加工窗口的环烯烃共聚物及其制备方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4035032C1 (da) 1990-11-03 1992-04-30 Degussa Ag, 6000 Frankfurt, De
EP0563730A3 (en) * 1992-03-28 1994-07-27 Hoechst Ag Alkenylaminoalkylene phosphonic acid esters and process for the preparation of copolymers comprising alkenylaminoalkylene phosphonates and ethylenic unsaturated compounds
US5763548A (en) 1995-03-31 1998-06-09 Carnegie-Mellon University (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization
US6541580B1 (en) 1995-03-31 2003-04-01 Carnegie Mellon University Atom or group transfer radical polymerization
US6410664B1 (en) * 1997-03-24 2002-06-25 Cryovac, Inc. Catalyst compositions and processes for olefin polymers and copolymers
US6284852B1 (en) 1997-10-30 2001-09-04 California Institute Of Technology Acid activation of ruthenium metathesis catalysts and living ROMP metathesis polymerization in water
DE19748468A1 (de) 1997-11-03 1999-05-06 Hoechst Ag Beschichtete Gestricke als katalytische Füllungen für Destillationskolonnen
US5977393A (en) 1997-11-21 1999-11-02 California Institute Of Technology Schiff base derivatives of ruthenium and osmium olefin metathesis catalysts
US6696597B2 (en) 1998-09-01 2004-02-24 Tilliechem, Inc. Metathesis syntheses of pheromones or their components
JP2002020417A (ja) 2000-07-04 2002-01-23 Mitsui Chemicals Inc オレフィンの重合方法
WO2003062253A1 (en) 2002-01-22 2003-07-31 Universiteit Gent Metal complexes for use in metathesis
WO2005035121A2 (en) 2003-10-16 2005-04-21 Universiteit Gent Schiff base metal complexes for use as catalysts in organic synthesis
US20070185343A1 (en) 2004-02-26 2007-08-09 Universiteit Gent Metal complexes for use in olefin metathesis and atom group transfer reactions
JP4997096B2 (ja) 2004-02-26 2012-08-08 テレーヌ ソシエテ パル アクシオン サンプリフィエー オレフィンメタセシスおよび原子またはグループ移動反応に使用するための金属錯体
GB0517137D0 (en) 2005-08-22 2005-09-28 Viacatt N V Multicoordinated metal complexes for use in metalthesis reactions

Also Published As

Publication number Publication date
JP2010077128A (ja) 2010-04-08
ES2279117T3 (es) 2007-08-16
DE60327378D1 (de) 2009-06-04
US7687635B2 (en) 2010-03-30
CA2473029A1 (en) 2003-07-31
EP1468004B1 (en) 2006-12-20
DE60310521T2 (de) 2007-11-08
WO2003062253A1 (en) 2003-07-31
ATE348835T1 (de) 2007-01-15
AU2003236511B2 (en) 2009-04-09
EP1743899B1 (en) 2009-04-22
DE60310521D1 (de) 2007-02-01
JP5100728B2 (ja) 2012-12-19
ES2323803T3 (es) 2009-07-24
US20050043541A1 (en) 2005-02-24
JP2005515260A (ja) 2005-05-26
EP1468004A1 (en) 2004-10-20
ZA200405685B (en) 2005-10-26
EP1743899A1 (en) 2007-01-17
JP4477879B2 (ja) 2010-06-09
ATE429437T1 (de) 2009-05-15
DK1468004T3 (da) 2007-04-30

Similar Documents

Publication Publication Date Title
DK1743899T3 (da) Metalkomplekser til anvendelse i metatese, radikalreaktioner med atomoverförsel, additionspolymeriserings og vinyleringsreaktioner, fremgangsmåder og mellemprodukter til fremstilling
WO2005035121A3 (en) Schiff base metal complexes for use as catalysts in organic synthesis
MY127285A (en) Ruthenium complexes as (pre)catalysts for metathesis reactions
BR0211167A (pt) Derivados de 2-pirrolidona como agonistas de prostanóides
LT2006017A (en) 2-(quinoxalin-5-ylsulfonylamino)-benzamide compounds as cck2 modulators
WO2006010139A3 (en) Olefin polymerization catalyst system and process for use thereof
TW200738741A (en) Antiviral compounds
TW200738742A (en) Antiviral compounds
NO20031687D0 (no) Veksthormonsekretagoger
ATE272066T1 (de) Metallkomplexe als hyrdosilylierungskatalysatoren
EA200602179A1 (ru) Замещенные производные арила и гетероарила в качестве модуляторов метаболизма и для профилактики и лечения связанных с ним расстройств
NO20075973L (no) Dipeptidyl-peptidase-IV-inhibitorer
WO2005076744A3 (en) Method for the preparation of peptide-oligonucleotide conjugates
DE60217186D1 (de) Dpiv-inhibitoren auf glutaminbasis
NO20064032L (no) DPP-IV inhibitorer
FR2870245B1 (fr) Synthese de copolymeres en forme d'etoile mikto par polymerisation radicalaire controlee
GB0520085D0 (en) Oligomerisation of olefinic compounds in the presence of an oligomerisation catalyst, and a catalyst activator including a halogenated -AR group
IL175253A0 (en) A process for preparing pyrrole derivatives
ATE275562T1 (de) Neue form vom irbesartan, verfahren um diese form zu erhalten und sie enthaltende pharmazeutische zusammensetzungen
DE602004014321D1 (de) Neue synthese von irbesartan
TW200503686A (en) Cannabinoid receptor modulator
BR0117002B1 (pt) método de produção de um pó através de uma reação de redução contìnua.
PL1836151T3 (pl) Modulatory receptora witaminy D
DE502004006312D1 (de) Frequenzsynthesizer nach dem direkten digitalen synthese-verfahren
DK1756046T3 (da) Arylalkylsulfonamider som terapeutiske midler til behandling af knoglelidelser