ATE429437T1 - Metallkomplexe für die metathese, atomtransferradikalreaktionen. additionspolymerisation und vinylationreaktionen, verfahren und zwischenprodukte für deren herstellung. - Google Patents

Metallkomplexe für die metathese, atomtransferradikalreaktionen. additionspolymerisation und vinylationreaktionen, verfahren und zwischenprodukte für deren herstellung.

Info

Publication number
ATE429437T1
ATE429437T1 AT06020387T AT06020387T ATE429437T1 AT E429437 T1 ATE429437 T1 AT E429437T1 AT 06020387 T AT06020387 T AT 06020387T AT 06020387 T AT06020387 T AT 06020387T AT E429437 T1 ATE429437 T1 AT E429437T1
Authority
AT
Austria
Prior art keywords
reactions
metal complexes
transfer radical
metathesis
processes
Prior art date
Application number
AT06020387T
Other languages
English (en)
Inventor
Francis Walter Cornelius Verpoort
Clercq Bob De
Original Assignee
Telene Sas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from EP02075250A external-priority patent/EP1329455A1/de
Application filed by Telene Sas filed Critical Telene Sas
Application granted granted Critical
Publication of ATE429437T1 publication Critical patent/ATE429437T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C07F15/0053—Ruthenium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B01J31/1625—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups
    • B01J31/1633—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups covalent linkages via silicon containing groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/08—Copper compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/002—Osmium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/06—Cobalt compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/28—Titanium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/7003—Bidentate ligand
    • C08F4/7019—Monoanionic ligand
    • C08F4/7022—NO
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B01J2231/125—Radical (co)polymerisation, e.g. mediators therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0286—Complexes comprising ligands or other components characterized by their function
    • B01J2531/0288—Sterically demanding or shielding ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/11—Compounds covalently bound to a solid support
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
    • C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3322—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from cyclooctene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
    • C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3324—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from norbornene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/41—Organometallic coupling reactions
    • C08G2261/418—Ring opening metathesis polymerisation [ROMP]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/41—Organometallic coupling reactions
    • C08G2261/419—Acyclic diene metathesis [ADMET]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polymerization Catalysts (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Pyrrole Compounds (AREA)
AT06020387T 2002-01-22 2003-01-22 Metallkomplexe für die metathese, atomtransferradikalreaktionen. additionspolymerisation und vinylationreaktionen, verfahren und zwischenprodukte für deren herstellung. ATE429437T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP02075250A EP1329455A1 (de) 2002-01-22 2002-01-22 Metallkarbenkomplexe, deren Herstellung und Reaktionszwischenprodukte, und deren Verwendung in Metathesereaktionen
US34995602P 2002-02-01 2002-02-01

Publications (1)

Publication Number Publication Date
ATE429437T1 true ATE429437T1 (de) 2009-05-15

Family

ID=27614617

Family Applications (2)

Application Number Title Priority Date Filing Date
AT06020387T ATE429437T1 (de) 2002-01-22 2003-01-22 Metallkomplexe für die metathese, atomtransferradikalreaktionen. additionspolymerisation und vinylationreaktionen, verfahren und zwischenprodukte für deren herstellung.
AT03731638T ATE348835T1 (de) 2002-01-22 2003-01-22 Metallkomplexe für die metathese

Family Applications After (1)

Application Number Title Priority Date Filing Date
AT03731638T ATE348835T1 (de) 2002-01-22 2003-01-22 Metallkomplexe für die metathese

Country Status (11)

Country Link
US (1) US7687635B2 (de)
EP (2) EP1468004B1 (de)
JP (2) JP4477879B2 (de)
AT (2) ATE429437T1 (de)
AU (1) AU2003236511B2 (de)
CA (1) CA2473029A1 (de)
DE (2) DE60310521T2 (de)
DK (2) DK1468004T3 (de)
ES (2) ES2279117T3 (de)
WO (1) WO2003062253A1 (de)
ZA (1) ZA200405685B (de)

Families Citing this family (107)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2003236511B2 (en) * 2002-01-22 2009-04-09 Telene S.A.S. Metal complexes for use in metathesis
WO2005035121A2 (en) * 2003-10-16 2005-04-21 Universiteit Gent Schiff base metal complexes for use as catalysts in organic synthesis
DE102004002178A1 (de) * 2004-01-15 2005-08-11 Ivoclar Vivadent Ag Dentalmeterialien auf der Basis von RÖMP-Kompositen
US20070185343A1 (en) * 2004-02-26 2007-08-09 Universiteit Gent Metal complexes for use in olefin metathesis and atom group transfer reactions
WO2005082819A2 (en) * 2004-02-26 2005-09-09 Universiteit Gent Metal complexes for use in olefin metathesis and atom group transfer reactions
JP2006016606A (ja) * 2004-05-31 2006-01-19 Nippon Zeon Co Ltd 環状オレフィンの付加重合用触媒、およびこれを用いた環状オレフィン付加重合体の製造方法
DE102004039277A1 (de) * 2004-08-13 2006-02-23 Merck Patent Gmbh Am Zentralatom substituierte, immoblisierbare Ruthenium(II)-Katalysatoren, Verfahren zu deren Herstellung und Verwendung
PL1757613T3 (pl) 2005-08-22 2011-06-30 Rimtec Corp Wielokoordynacyjne kompleksy metalu do zastosowania w reakcjach metatezy
GB0517137D0 (en) 2005-08-22 2005-09-28 Viacatt N V Multicoordinated metal complexes for use in metalthesis reactions
US8933276B2 (en) * 2006-01-19 2015-01-13 Agency For Science, Technology And Research Heterogeneous chiral catalyst
US8592336B2 (en) 2006-04-11 2013-11-26 Agency For Science, Technology And Research Catalysts for ring-closing metathesis
US8648003B2 (en) 2006-04-11 2014-02-11 Agency For Science, Technology And Research Catalysts for ring-closing metathesis
CN100465195C (zh) * 2006-04-29 2009-03-04 中国科学院长春应用化学研究所 一种β-羟基丙烯亚胺钒烯烃聚合催化剂及制备方法和应用
CN100424100C (zh) * 2006-05-25 2008-10-08 中国科学院长春应用化学研究所 一种β-酮亚胺钒烯烃聚合催化剂及制备方法和应用
CN101594937B (zh) * 2006-11-21 2014-04-30 加州理工学院 含有亚噻唑-2-基配体的烯烃复分解反应引发剂
WO2008067443A1 (en) * 2006-11-29 2008-06-05 Board Of Governors For Higher Education, Aerobic oxidative coupling for the formation biaryls
KR101015435B1 (ko) * 2006-12-05 2011-02-22 주식회사 엘지화학 중합체 제조방법
FR2910004A1 (fr) * 2006-12-14 2008-06-20 Rhodia Recherches & Tech Procede d'oligomerisation et/ou polymerisation du composes insatures
WO2008115154A1 (en) * 2007-03-22 2008-09-25 Agency For Science, Technology And Research Catalyst immobilization on siliceous mesocellular foam via click chemistry
US8492552B2 (en) * 2007-06-20 2013-07-23 Agency For Science, Technology And Research N-heterocyclic carbene metallacycle catalysts and methods
WO2009002726A1 (en) * 2007-06-25 2008-12-31 Sun Chemical Corporation Process for preparation of oligomeric or polymeric compounds using selective michael addition
WO2009009597A1 (en) * 2007-07-09 2009-01-15 The Regents Of The University Of California Water soluble olefin metathesis
US8263712B2 (en) 2007-09-04 2012-09-11 Exxonmobil Research And Engineering Company Production of elastomeric functionalized olefin polymers
EP2042537B1 (de) * 2007-09-28 2014-05-14 Rimtec Corporation Polycycloolefin-Duroplast-Verband und Verfahren zu seiner Herstellung
WO2009085040A1 (en) * 2007-12-27 2009-07-09 Dcb-Usa Llc Protein kinase inhibitors
US8080681B2 (en) 2007-12-28 2011-12-20 Chevron Phillips Chemical Company Lp Nano-linked metallocene catalyst compositions and their polymer products
US7863210B2 (en) 2007-12-28 2011-01-04 Chevron Phillips Chemical Company Lp Nano-linked metallocene catalyst compositions and their polymer products
US8012900B2 (en) 2007-12-28 2011-09-06 Chevron Phillips Chemical Company, L.P. Nano-linked metallocene catalyst compositions and their polymer products
DE102009017498A1 (de) 2009-04-16 2010-10-28 Süd-Chemie AG Verwendung einer Katalysatorzusammensetzung zur Olefinmetathese in der Gasphase und Verfahren zur Olefinmetathese in der Gasphase
KR101147809B1 (ko) * 2009-04-28 2012-05-18 한국과학기술연구원 폴리알킬티오펜 블록 공중합체 및 개환 메타세시스 중합 반응을 통한 이의 제조 방법
US7919639B2 (en) 2009-06-23 2011-04-05 Chevron Phillips Chemical Company Lp Nano-linked heteronuclear metallocene catalyst compositions and their polymer products
EP2280017B1 (de) * 2009-07-21 2013-01-02 Rimtec Corporation Katalytischer Komplex für Olefin-Metathesenreaktionen, Herstellungsverfahren und Verwendung davon
US20110263870A1 (en) * 2010-04-23 2011-10-27 Helvetica Industries (P) Limited Novel pyrrole derivatives and their synthesis
WO2012026980A2 (en) 2010-08-23 2012-03-01 Materia, Inc. Vartm flow modifications for low viscosity resin systems
JP5738097B2 (ja) * 2010-09-10 2015-06-17 昭和電工株式会社 ノルボルネン系重合体の製造方法
JP5949551B2 (ja) 2010-09-22 2016-07-06 日本ゼオン株式会社 有機電解液系蓄電デバイス用の粘着フィルム
US8937207B2 (en) * 2010-12-22 2015-01-20 Richard Dehn Use of supported ruthenium-carbene complexes in continuously operated reactors
US20120289617A1 (en) * 2011-05-10 2012-11-15 Saudi Arabian Oil Company Hybrid Catalyst for Olefin Metathesis
US10457597B2 (en) 2011-06-17 2019-10-29 Materia, Inc. Adhesion promoters and gel-modifiers for olefin metathesis compositions
KR20140054030A (ko) 2011-07-12 2014-05-08 바스프 에스이 시클로헵텐의 제조 방법
US8993819B2 (en) 2011-07-12 2015-03-31 Basf Se Process for preparing cycloheptene
WO2013036546A2 (en) 2011-09-07 2013-03-14 Dow Corning Corporation Titanium containing complex and condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
US9228061B2 (en) 2011-09-07 2016-01-05 Dow Corning Corporation Zirconium containing complex and condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
CN103842441B (zh) 2011-10-04 2015-12-23 道康宁公司 含铁(iii)络合物和缩合反应催化剂、制备该催化剂的方法及含有该催化剂的组合物
US9139699B2 (en) * 2012-10-04 2015-09-22 Dow Corning Corporation Metal containing condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
KR20140094507A (ko) 2011-11-18 2014-07-30 가부시키가이샤 아데카 신규 화합물 및 이 신규 화합물을 담지한 담지체
GB201204715D0 (en) 2012-03-18 2012-05-02 Croda Int Plc Metathesis of olefins using ruthenium-based catalytic complexes
JP6290195B2 (ja) 2012-06-13 2018-03-07 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 大環状ケトンの製造方法
EP2867243B1 (de) 2012-06-29 2016-04-13 Apeiron Synthesis S.A. Metallkomplexe, deren verwendung und verfahren zur ausführung von metathesereaktionen
EP2695901B1 (de) 2012-08-10 2016-09-14 Basf Se Aliphatische langkettige Polykondensate
EP2902428B1 (de) 2012-09-26 2020-08-12 Rimtec Corporation Polymerisierbare zusammensetzung und verfahren eines harzformartikels
TWI485145B (zh) 2012-10-26 2015-05-21 財團法人工業技術研究院 Ｐ型有機半導體材料與光電元件
US9527982B2 (en) 2012-12-19 2016-12-27 Materia, Inc. Storage stable adhesion promoter compositions for cyclic olefin resin compositions
WO2014134333A1 (en) * 2013-02-27 2014-09-04 Materia, Inc. Metal carbene olefin metathesis two catalyst composition
US9598531B2 (en) 2013-02-27 2017-03-21 Materia, Inc. Olefin metathesis catalyst compositions comprising at least two metal carbene olefin metathesis catalysts
JP6342985B2 (ja) 2013-03-15 2018-06-13 マテリア， インコーポレイテッド Ｒｏｍｐポリマーのインモールドコーティング
US9663440B2 (en) 2013-04-09 2017-05-30 Materia, Inc. Cross metathesis of poly-branched poly-olefins
AU2014302626B2 (en) 2013-06-24 2017-09-28 ExxonMobil Product Solutions Company Thermal insulation
US9751975B2 (en) 2013-07-03 2017-09-05 Materia, Inc. Liquid molding compositions
US9890239B2 (en) * 2013-09-04 2018-02-13 California Institute Of Technology Functionalized linear and cyclic polyolefins
KR20160061362A (ko) 2013-09-27 2016-05-31 림텍 가부시키가이샤 노르보르넨계 가교 중합체 및 그 제조 방법
WO2015098636A1 (ja) 2013-12-26 2015-07-02 Rimtec株式会社 複合成形体の製造方法
US10633484B2 (en) 2014-01-10 2020-04-28 Materia, Inc. Method and composition for improving adhesion of metathesis compositions to substrates
ES3073605T3 (en) 2014-02-27 2026-07-14 Exxonmobil Product Solutions Co Adhesion promoter compositions for cyclic olefin resin compositions
RU2674471C2 (ru) * 2014-07-03 2018-12-11 Гуан Мин Инновейшн Компани (Ухань) Катализаторы на основе переходного металла 8 группы, способ их получения и способ их применения в реакции метатезиса
JP6618290B2 (ja) 2014-07-24 2019-12-11 日本ポリエチレン株式会社 オレフィン重合触媒及びオレフィン重合体の製造方法
PL2982709T3 (pl) 2014-08-07 2017-12-29 Telene Sas Kompozycja utwardzalna i wytwór formowany zawierający kompozycję
US9856352B2 (en) 2014-08-07 2018-01-02 Ppg Industries Ohio, Inc. Glass fiber sizing compositions, sized glass fibers, and polyolefin composites
TWI688609B (zh) 2014-11-13 2020-03-21 美商道康寧公司 含硫聚有機矽氧烷組成物及相關態樣
WO2016130743A1 (en) 2015-02-12 2016-08-18 Materia, Inc. Cyclic olefin resin compositions comprising functional elastomers
US10344118B2 (en) 2015-02-14 2019-07-09 Materia, Inc. Romp polymers having improved resistance to hydrocarbon fluids
EP3153227A1 (de) * 2015-10-07 2017-04-12 Evonik Degussa GmbH Verfahren zur herstellung von polyalkenameren für verpackungsanwendungen
EP3202813A1 (de) 2016-02-05 2017-08-09 Telene SAS Härtbare zusammensetzung und geformter artikel mit der zusammensetzung
WO2017134673A1 (en) 2016-02-07 2017-08-10 Stratasys Ltd. Three-dimensional printing combining ring-opening metathesis polymerization and free radical polymerization
JP6920218B2 (ja) 2016-02-10 2021-08-18 Rimtec株式会社 重合性組成物及び複合材料
EP3448661B1 (de) 2016-04-26 2024-03-27 Stratasys Ltd. Dreidimensionales tintenstrahldrucken mit ringöffnungs-metathesenpolymerisierung
JPWO2017204051A1 (ja) 2016-05-27 2019-03-22 Rimtec株式会社 複合材料成形体の製造方法
CN109982995B (zh) 2016-09-23 2022-09-30 优美科股份公司及两合公司 氨基酸和氨基酸衍生物的制备
WO2018150379A2 (en) 2017-02-17 2018-08-23 Provivi, Inc. Synthesis of pheromones and related materials via olefin metathesis
JP6794311B2 (ja) 2017-05-11 2020-12-02 公益財団法人鉄道総合技術研究所 超電導コイル装置及びその製造方法
US10245583B1 (en) * 2017-09-12 2019-04-02 Chevron Phillips Chemical Company, Lp Use of charge-containing molecules linked with covalent bonds to enhance acetylene hydrogenation catalysts
EP3781309A1 (de) 2018-04-20 2021-02-24 ARLANXEO Deutschland GmbH Hydrierkatalysatorzusammensetzungen und ihre verwendung zur hydrierung von nitrilkautschuk
CN108559083B (zh) * 2018-04-26 2020-07-14 大连理工大学 一种结晶性聚单硫代碳酸酯的制备方法
JP7285252B2 (ja) 2018-06-07 2023-06-01 Rimtec株式会社 複合材料および複合材料成形体
CN109046463B (zh) * 2018-08-16 2021-05-04 中山大学 双齿氮杂卡宾锰催化剂及其制备方法和烷基化合成应用
CN111068774B (zh) * 2018-10-18 2022-11-04 中国石油化工股份有限公司 2,6-萘二甲酸合成所用催化剂和其应用
JP7541511B2 (ja) 2019-04-23 2024-08-28 Rimtec株式会社 シクロオレフィン樹脂加飾成形品の製造方法
JP7659496B2 (ja) 2019-08-06 2025-04-09 Rimtec株式会社 重合性組成物、シクロオレフィン系重合体および金属樹脂複合体
EP4140570B1 (de) 2020-04-24 2025-02-19 RIMTEC Corporation Verfahren zur herstellung einer polymerisierungsreaktiven flüssigkeitsformulierung
EP4190836A4 (de) 2020-08-03 2024-08-07 RIMTEC Corporation Gehärtetes produkt auf basis von cycloolefinharz
JP7737380B2 (ja) 2020-08-28 2025-09-10 Rimtec株式会社 酸素バリア性シクロオレフィン系樹脂硬化物
CN112250843B (zh) * 2020-10-16 2023-05-30 湘潭大学 四种D-A’-(π-A)2型聚合烷基化水杨醛席夫碱衍生物合金属配合物及其制备方法与用途
EP4257627A4 (de) 2020-12-03 2024-10-30 RIMTEC Corporation Polymerisierbare zusammensetzung und harzimprägnierte supraleitende spule
WO2022230803A1 (ja) 2021-04-30 2022-11-03 Rimtec株式会社 金属樹脂積層体及び金属樹脂積層体の製造方法
CN115518689B (zh) * 2021-06-24 2023-10-31 中国石油化工股份有限公司 一种环氧烷烃水合制二醇催化剂及其制备方法和应用
US11780864B2 (en) * 2021-07-07 2023-10-10 The Hong Kong University Of Science And Technology Rhenium(V) alkylidyne complexes and methods of use and preparation thereof
CN113666956B (zh) * 2021-08-25 2023-04-25 上海橡实化学有限公司 一种水杨醛亚胺硅烷偶联剂及其制备方法和应用
US20250303398A1 (en) * 2022-05-12 2025-10-02 Yale University Catalyst, system and method for mineralization of organic pollutants
CN115463655B (zh) * 2022-06-23 2024-05-14 浙江恒逸石化研究院有限公司 一种可一步法制备高顺反比2,2,4,4-四甲基-1,3-环丁二醇的催化剂及其应用
CN116351472B (zh) * 2023-02-22 2024-06-25 万华化学集团股份有限公司 一种催化精馏生产异氰酸酯的制备方法和系统
JPWO2024224997A1 (de) 2023-04-26 2024-10-31
CN116970148A (zh) * 2023-06-15 2023-10-31 天津大学 一种高性能宽加工窗口的环烯烃共聚物及其制备方法
CN116693812B (zh) * 2023-06-16 2026-05-01 北京大学 含有离去基团的烯丙基化合物作为封端剂的应用
JPWO2025013577A1 (de) 2023-07-10 2025-01-16
CN121135989B (zh) * 2025-11-18 2026-03-06 湖南工程学院 共价有机框架材料及其制备方法和应用
CN121182370B (zh) * 2025-11-24 2026-03-03 合肥绿拓新材料科技有限公司 一种金属螯合成膜剂及其制备方法、应用
CN121648964B (zh) * 2026-02-06 2026-05-05 鲁东大学 改性分子筛催化剂、制备方法及其在降解聚氨酯中的用途

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4035032C1 (de) 1990-11-03 1992-04-30 Degussa Ag, 6000 Frankfurt, De
EP0563730A3 (en) * 1992-03-28 1994-07-27 Hoechst Ag Alkenylaminoalkylene phosphonic acid esters and process for the preparation of copolymers comprising alkenylaminoalkylene phosphonates and ethylenic unsaturated compounds
US6541580B1 (en) * 1995-03-31 2003-04-01 Carnegie Mellon University Atom or group transfer radical polymerization
US5763548A (en) * 1995-03-31 1998-06-09 Carnegie-Mellon University (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization
US6410664B1 (en) * 1997-03-24 2002-06-25 Cryovac, Inc. Catalyst compositions and processes for olefin polymers and copolymers
US6284852B1 (en) * 1997-10-30 2001-09-04 California Institute Of Technology Acid activation of ruthenium metathesis catalysts and living ROMP metathesis polymerization in water
DE19748468A1 (de) 1997-11-03 1999-05-06 Hoechst Ag Beschichtete Gestricke als katalytische Füllungen für Destillationskolonnen
US5977393A (en) * 1997-11-21 1999-11-02 California Institute Of Technology Schiff base derivatives of ruthenium and osmium olefin metathesis catalysts
US6696597B2 (en) 1998-09-01 2004-02-24 Tilliechem, Inc. Metathesis syntheses of pheromones or their components
JP2002020417A (ja) 2000-07-04 2002-01-23 Mitsui Chemicals Inc オレフィンの重合方法
AU2003236511B2 (en) 2002-01-22 2009-04-09 Telene S.A.S. Metal complexes for use in metathesis
WO2005035121A2 (en) 2003-10-16 2005-04-21 Universiteit Gent Schiff base metal complexes for use as catalysts in organic synthesis
WO2005082819A2 (en) 2004-02-26 2005-09-09 Universiteit Gent Metal complexes for use in olefin metathesis and atom group transfer reactions
US20070185343A1 (en) * 2004-02-26 2007-08-09 Universiteit Gent Metal complexes for use in olefin metathesis and atom group transfer reactions
GB0517137D0 (en) * 2005-08-22 2005-09-28 Viacatt N V Multicoordinated metal complexes for use in metalthesis reactions

Also Published As

Publication number Publication date
WO2003062253A1 (en) 2003-07-31
ES2323803T3 (es) 2009-07-24
US7687635B2 (en) 2010-03-30
AU2003236511B2 (en) 2009-04-09
JP2005515260A (ja) 2005-05-26
ES2279117T3 (es) 2007-08-16
CA2473029A1 (en) 2003-07-31
DK1743899T3 (da) 2009-06-22
JP5100728B2 (ja) 2012-12-19
JP4477879B2 (ja) 2010-06-09
ZA200405685B (en) 2005-10-26
DK1468004T3 (da) 2007-04-30
DE60327378D1 (de) 2009-06-04
US20050043541A1 (en) 2005-02-24
JP2010077128A (ja) 2010-04-08
EP1743899B1 (de) 2009-04-22
DE60310521T2 (de) 2007-11-08
EP1468004A1 (de) 2004-10-20
EP1468004B1 (de) 2006-12-20
DE60310521D1 (de) 2007-02-01
EP1743899A1 (de) 2007-01-17
ATE348835T1 (de) 2007-01-15

Similar Documents

Publication Publication Date Title
DE60327378D1 (de) Metallkomplexe für die Metathese, Atomtransferradikalreaktionen. Additionspolymerisation und Vinylationreaktionen, Verfahren und Zwischenprodukte für deren Herstellung.
MY127285A (en) Ruthenium complexes as (pre)catalysts for metathesis reactions
DE69227793D1 (de) Verfahren und Verbindungen für die Festphase-Synthese von Oligonukleotiden und Analogen
MXPA04001348A (es) NUEVOS COMPUESTOS DE FOSFITOS Y SUS COMPLEJOS METaLICOS.
UA93225C2 (ru) 3'-алкоксиспироциклопентилзамещенные производные тетрамовой кислоты и гербицидное средство ha их ochobe
DE50305049D1 (de) Galactosyl-isomalt, verfahren zu seiner herstellung und verwendung
DE60012349D1 (de) Verfahren zur herstellung einer katalysatorkomponente für olefinpolymerisation
PL356486A1 (en) Catalysts for hydrosilylation reactions
WO2005076744A3 (en) Method for the preparation of peptide-oligonucleotide conjugates
MY157193A (en) Process for production of olefin
WO2007039851A3 (en) Oligomerisation of olefinic compounds in the presence of an oligomerisation catalyst, and a catalyst activator including a halogenated organic group
PT1509517E (pt) Nova síntese de irbesartan
DE10347385A1 (de) Umgelagerte Pentanole, ein Verfahren zu ihrer Herstellung und ihre Verwendung als Entzündungshemmer
WO2005048954A3 (en) Continuous process for producing hydroxyazapirones by oxidation
DE50106631D1 (de) Verfahren zur metathesereaktion ungesättigter organischer verbindungen
DE60128112D1 (de) Aminoalkoxybenzoyl-benzofurane oder benzothiophene, verfahren zu ihrer herstellung und die enthaltenden zusammensetzungen
EP0965574A3 (de) Verfahren zur enantioselektiven Hydrierung
IL175253A0 (en) A process for preparing pyrrole derivatives
DE10340485A1 (de) Verfahren zur Herstellung von Oxazolidinon-Chinolon Hybriden
EP1426379A4 (de) Übergangsmetallkomplex, katalysator für die polymerisierung von olefinen und verfahren zur herstellung von olefinpolymeren unter anwendung desselben
MXPA03002029A (es) Metodo para intensificar el aclarado de la piel.
ATE325137T1 (de) Verfahren zur kontinuierlichen herstellung von polymerzusammensetzungen sowie verwendung
DE602006019870D1 (de) Verfahren zur synthese von triazolen
MY207749A (en) Catalyst composition comprising the combination of a monophopsphine, a tetraphosphine ligand and a hydroformylation process using it
DE502004010308D1 (de) Verfahren zur herstellung von isocyanatoorganosilanen

Legal Events

Date Code Title Description
UEP Publication of translation of european patent specification

Ref document number: 1743899

Country of ref document: EP