DE697481C - Verfahren zur Herstellung von in kaltem Wasser loeslichen hochmolekularen Polymerisationsprodukten - Google Patents
Verfahren zur Herstellung von in kaltem Wasser loeslichen hochmolekularen PolymerisationsproduktenInfo
- Publication number
- DE697481C DE697481C DE1936I0055120 DEI0055120D DE697481C DE 697481 C DE697481 C DE 697481C DE 1936I0055120 DE1936I0055120 DE 1936I0055120 DE I0055120 D DEI0055120 D DE I0055120D DE 697481 C DE697481 C DE 697481C
- Authority
- DE
- Germany
- Prior art keywords
- water
- polymerization
- soluble
- cold water
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 30
- 238000000034 method Methods 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 18
- 150000003839 salts Chemical group 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 8
- 150000001735 carboxylic acids Chemical class 0.000 claims description 8
- 150000007513 acids Chemical class 0.000 claims description 4
- 150000003857 carboxamides Chemical class 0.000 claims description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 150000003949 imides Chemical class 0.000 claims 2
- 150000001408 amides Chemical class 0.000 description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000000243 solution Substances 0.000 description 11
- 239000000047 product Substances 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 229920000591 gum Polymers 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- -1 maleic acid Chemical class 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920003176 water-insoluble polymer Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/52—Amides or imides
- C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F20/56—Acrylamide; Methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/24—Homopolymers or copolymers of amides or imides
- C09J133/26—Homopolymers or copolymers of acrylamide or methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J135/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least another carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J135/04—Homopolymers or copolymers of nitriles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Adhesives Or Adhesive Processes (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1936I0055120 DE697481C (de) | 1936-05-29 | 1936-05-29 | Verfahren zur Herstellung von in kaltem Wasser loeslichen hochmolekularen Polymerisationsprodukten |
| GB16746/36A GB475671A (en) | 1936-05-29 | 1936-06-16 | Improvements in the manufacture and production of polymerisation products |
| BE421689D BE421689A (enrdf_load_stackoverflow) | 1936-05-29 | 1937-05-22 | |
| FR822263D FR822263A (fr) | 1936-05-29 | 1937-05-26 | Procédé pour préparer des produits de polymérisation solubles dans l'eau |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1936I0055120 DE697481C (de) | 1936-05-29 | 1936-05-29 | Verfahren zur Herstellung von in kaltem Wasser loeslichen hochmolekularen Polymerisationsprodukten |
| GB16746/36A GB475671A (en) | 1936-05-29 | 1936-06-16 | Improvements in the manufacture and production of polymerisation products |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE697481C true DE697481C (de) | 1940-10-15 |
Family
ID=25981936
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1936I0055120 Expired DE697481C (de) | 1936-05-29 | 1936-05-29 | Verfahren zur Herstellung von in kaltem Wasser loeslichen hochmolekularen Polymerisationsprodukten |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE421689A (enrdf_load_stackoverflow) |
| DE (1) | DE697481C (enrdf_load_stackoverflow) |
| FR (1) | FR822263A (enrdf_load_stackoverflow) |
| GB (1) | GB475671A (enrdf_load_stackoverflow) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1049871B (de) * | 1959-02-05 | Badische Anilin- &. Soda-Fabrik Aktiengesellschaft, Ludwigshafen/Rhein | Dispergiermittel mit Schutzkolloideigenschaften | |
| US2732358A (en) * | 1956-01-24 | N-benzylacrylamide | ||
| DE749587C (de) * | 1941-01-11 | 1944-11-28 | Verfahren zur Herstellung von Polyacrylsaeureamid | |
| DE763830C (de) * | 1942-09-02 | 1954-02-15 | Roehm & Haas G M B H | Klebmittel |
| BE465267A (enrdf_load_stackoverflow) * | 1944-04-24 | |||
| US2486190A (en) * | 1946-07-22 | 1949-10-25 | Eastman Kodak Co | Imidized polyacrylamides |
| BE476083A (enrdf_load_stackoverflow) * | 1946-07-22 | |||
| US2486192A (en) * | 1947-02-08 | 1949-10-25 | Eastman Kodak Co | Gel-type imidized polyacrylamide |
| US2616818A (en) * | 1948-11-18 | 1952-11-04 | Hercules Powder Co Ltd | Paper coating |
| US2718497A (en) * | 1950-11-03 | 1955-09-20 | Union Oil Co | Drilling muds |
| DE942352C (de) * | 1951-01-23 | 1956-05-17 | Hoechst Ag | Verfahren zur Herstellung von Mischpolymerisaten |
| US2764503A (en) * | 1952-08-28 | 1956-09-25 | Du Pont | Coating fabrics |
| US2764504A (en) * | 1952-08-28 | 1956-09-25 | Du Pont | Coating process and products therefrom |
| DE1037128B (de) * | 1956-03-17 | 1958-08-21 | Basf Ag | Verfahren zur Herstellung von in Wasser loeslichen, Amid- und Estergruppen enthaltenden Mischpolymerisaten |
| DE1265116B (de) * | 1957-12-03 | 1968-04-04 | Basf Ag | Verfahren zur Herstellung stabiler, waessriger, Hydrophobiermittel enthaltender Dispersionen |
| DE1214880B (de) * | 1958-07-21 | 1966-04-21 | Goodrich Co B F | Verfahren zur Herstellung von waessrigen Loesungen von Mischpolymerisaten |
| NL242509A (enrdf_load_stackoverflow) * | 1958-08-22 | |||
| US3085853A (en) * | 1958-12-23 | 1963-04-16 | Dow Chemical Co | Method of employing dextrans |
| DE1204411B (de) * | 1959-04-07 | 1965-11-04 | Hercules Powder Co Ltd | Verfahren zur Herstellung von wasserloeslichen Polymerisaten |
| US2992943A (en) * | 1959-06-19 | 1961-07-18 | Eastman Kodak Co | Sizing compositions for textile yarns |
| DE1124244B (de) * | 1959-09-08 | 1962-02-22 | Bayer Ag | Verfahren zur Herstellung von festen wasserloeslichen Polyacrylamiden mit hohen Molekulargewichten durch Faellungspolymerisation |
| DE1220610B (de) * | 1961-03-04 | 1966-07-07 | Hoechst Ag | Verfahren zur Durchfuehrung von Umsetzungen an wasserloeslichen Polymerisaten und Copolymerisaten des Acrylsaeureamids |
| US3087890A (en) * | 1961-03-07 | 1963-04-30 | Dow Chemical Co | Method of applying acrylamide polymer flocculants |
| US3516932A (en) * | 1962-06-04 | 1970-06-23 | Monsanto Co | Clarification of water |
| US3418237A (en) * | 1963-12-22 | 1968-12-24 | American Cyanamid Co | Settling of non-argillaceous ore pulps and mineral suspensions by use of water-soluble acrylic polymers |
| US3637491A (en) * | 1969-11-03 | 1972-01-25 | Monsanto Co | Clarification of water |
-
1936
- 1936-05-29 DE DE1936I0055120 patent/DE697481C/de not_active Expired
- 1936-06-16 GB GB16746/36A patent/GB475671A/en not_active Expired
-
1937
- 1937-05-22 BE BE421689D patent/BE421689A/xx unknown
- 1937-05-26 FR FR822263D patent/FR822263A/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB475671A (en) | 1937-11-24 |
| BE421689A (enrdf_load_stackoverflow) | 1937-06-30 |
| FR822263A (fr) | 1937-12-24 |
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