DE69618485T2 - Verfahren zur herstellung von epoxidierungskatalysatoren - Google Patents

Verfahren zur herstellung von epoxidierungskatalysatoren

Info

Publication number
DE69618485T2
DE69618485T2 DE69618485T DE69618485T DE69618485T2 DE 69618485 T2 DE69618485 T2 DE 69618485T2 DE 69618485 T DE69618485 T DE 69618485T DE 69618485 T DE69618485 T DE 69618485T DE 69618485 T2 DE69618485 T2 DE 69618485T2
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DE
Germany
Prior art keywords
promoter
catalyst
amount
support
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69618485T
Other languages
German (de)
English (en)
Other versions
DE69618485D1 (de
Inventor
Marek Matusz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Application granted granted Critical
Publication of DE69618485D1 publication Critical patent/DE69618485D1/de
Publication of DE69618485T2 publication Critical patent/DE69618485T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • B01J23/68Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8946Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
DE69618485T 1995-10-06 1996-10-02 Verfahren zur herstellung von epoxidierungskatalysatoren Expired - Fee Related DE69618485T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/540,233 US5739075A (en) 1995-10-06 1995-10-06 Process for preparing ethylene oxide catalysts
PCT/EP1996/004298 WO1997013579A1 (en) 1995-10-06 1996-10-02 Process for preparing epoxidation catalysts

Publications (2)

Publication Number Publication Date
DE69618485D1 DE69618485D1 (de) 2002-02-14
DE69618485T2 true DE69618485T2 (de) 2002-08-01

Family

ID=24154573

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69618485T Expired - Fee Related DE69618485T2 (de) 1995-10-06 1996-10-02 Verfahren zur herstellung von epoxidierungskatalysatoren

Country Status (8)

Country Link
US (1) US5739075A (https=)
EP (1) EP0874688B1 (https=)
JP (1) JP3961568B2 (https=)
AU (1) AU7284396A (https=)
CA (1) CA2232942C (https=)
DE (1) DE69618485T2 (https=)
ES (1) ES2166468T3 (https=)
WO (1) WO1997013579A1 (https=)

Families Citing this family (102)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2744038B1 (fr) * 1996-01-26 1998-03-06 Pechiney Recherche Supports de catalyseur en mousse de sic revetue de cerine et systemes catalytiques correspondants
US5861519A (en) * 1997-05-23 1999-01-19 Arco Chemical Technology, L.P. Propylene oxide process using alkaline earth metal compound-supported silver catalysts containing tungsten and potassium promoters
US6383974B1 (en) * 1997-08-26 2002-05-07 Japan Energy Corporation Hydrorefining catalyst and method for manufacturing hydrorefining catalyst
US6812180B2 (en) * 1997-12-10 2004-11-02 Idemitsu Kosan Co., Ltd. Method for preparing catalyst
US7504525B2 (en) * 1998-09-14 2009-03-17 Shell Oil Company Catalyst composition
RU2232049C2 (ru) * 1998-09-14 2004-07-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ удаления ионизируемых частиц с поверхности катализатора для улучшения каталитических свойств
US7232786B2 (en) * 1998-09-14 2007-06-19 Shell Oil Company Catalyst composition
US7232918B2 (en) * 2001-11-06 2007-06-19 Shell Oil Company Catalyst composition
CA2343836C (en) * 1998-09-14 2007-12-04 Shell Internationale Research Maatschappij B.V. Epoxidation catalyst carrier, preparation and use thereof
ATE391552T1 (de) * 1998-09-14 2008-04-15 Shell Int Research Verfahren zur herstellung von katalysatoren mit verbesserten katalytischen eigenschaften
US20070066480A1 (en) * 1999-10-25 2007-03-22 Moser William R Method of preparing compounds using cavitation and compounds formed therefrom
WO2001051202A1 (en) * 2000-01-14 2001-07-19 Worcester Polytechnic Institute Method of preparing compounds using cavitation and compounds formed therefrom
US6403523B1 (en) * 2000-09-18 2002-06-11 Union Carbide Chemicals & Plastics Technology Corporation Catalysts for the oxidative dehydrogenation of hydrocarbons
DE10048844A1 (de) * 2000-10-02 2002-04-11 Basf Ag Verfahren zur Herstellung von Platinmetall-Katalysatoren
US7193094B2 (en) 2001-11-20 2007-03-20 Shell Oil Company Process and systems for the epoxidation of an olefin
US6831037B2 (en) * 2002-02-25 2004-12-14 Saint-Gobain Norpro Corporation Catalyst carriers
KR100980123B1 (ko) * 2002-06-28 2010-09-03 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 촉매 선택성을 향상시키는 방법 및 올레핀 에폭시화 방법
RU2005102097A (ru) * 2002-06-28 2005-08-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Способ введения в действие способа эпоксидирования и способ эпоксидирования олефина
US20040110973A1 (en) * 2002-10-28 2004-06-10 Marek Matusz Olefin oxide catalysts
TWI346574B (en) 2003-03-31 2011-08-11 Shell Int Research A catalyst composition, a process for preparing the catalyst composition and a use of the catalyst composition
ATE376879T1 (de) * 2003-04-01 2007-11-15 Shell Int Research Olefinepoxidationsverfahren und katalysator zur verwendung bei dem verfahren
US7348444B2 (en) * 2003-04-07 2008-03-25 Shell Oil Company Process for the production of an olefin oxide
US6858560B2 (en) 2003-04-23 2005-02-22 Scientific Design Co., Inc. Ethylene oxide catalyst
US20040225138A1 (en) * 2003-05-07 2004-11-11 Mcallister Paul Michael Reactor system and process for the manufacture of ethylene oxide
AU2004238820B2 (en) 2003-05-07 2008-01-31 Shell Internationale Research Maatschappij B.V. Silver-containing catalysts, the manufacture of such silver containing catalysts, and the use thereof
US20040224841A1 (en) * 2003-05-07 2004-11-11 Marek Matusz Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof
US8148555B2 (en) * 2003-06-26 2012-04-03 Shell Oil Company Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
US20060293180A1 (en) * 2003-08-22 2006-12-28 Thorsteinson Erlind M Modified alumina carriers and silver-based catalysts for the production of alkylene oxides
CN1838991A (zh) * 2003-08-22 2006-09-27 联合碳化化学及塑料技术公司 改进的氧化铝载体和用于制造烯化氧的银基催化剂
EP1670754A2 (en) * 2003-10-10 2006-06-21 Degussa AG Process for the manufacture of methylmercaptan
EP2277622B1 (en) * 2003-10-16 2013-01-09 Dow Technology Investments LLC Method for the preparation of catalysts having enhanced stability, efficiency and/or activity for alkylene oxide production
US6939979B2 (en) * 2003-11-10 2005-09-06 Scientific Design Co., Inc. Oxidation process and catalyst
TW200613056A (en) * 2004-04-01 2006-05-01 Shell Int Research A process for preparing a silver catalyst, the catalyst, and a use of the catalyst for olefin oxidation
TW200600190A (en) * 2004-04-01 2006-01-01 Shell Int Research Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation
TW200602123A (en) * 2004-04-01 2006-01-16 Shell Int Research Process for preparing a catalyst, the catalyst, and a use of the catalyst
EP1765799A1 (en) * 2004-06-18 2007-03-28 Shell Oil Company A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
EP1765800B1 (en) * 2004-06-18 2012-04-18 Shell Internationale Research Maatschappij B.V. A process for the production of an olefin oxide, a 1,2-diol, a 1.2-diol ether, or an alkanolamine
US7521393B2 (en) * 2004-07-27 2009-04-21 Süd-Chemie Inc Selective hydrogenation catalyst designed for raw gas feed streams
US8536083B2 (en) * 2004-09-01 2013-09-17 Shell Oil Company Olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier
KR20070058576A (ko) 2004-09-01 2007-06-08 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 올레핀 에폭시화 방법, 이 방법에 사용되는 촉매, 이촉매의 제조에 사용되는 담체, 및 이 담체의 제조방법
JP2008514405A (ja) * 2004-09-24 2008-05-08 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 成形粒子を選択するプロセス、システムを取り付けるプロセス、このようなシステム内で気体原料を反応させるプロセス、コンピュータプログラム製品、およびコンピュータシステム
KR20070106772A (ko) * 2005-02-21 2007-11-05 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 올레핀의 에폭시화 방법, 그 방법에 사용하기 위한 촉매,그 촉매를 제조하는데 이용하기 위한 담체, 및 그 담체의제조방법
KR20070112870A (ko) * 2005-03-22 2007-11-27 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 반응기 시스템 및 에틸렌옥사이드의 제조방법
BRPI0611817A2 (pt) * 2005-06-07 2011-12-20 Saint Gobain Ceramics veìculo catalisador e um processo para preparação do veìculo catalisador
KR101369619B1 (ko) * 2005-06-07 2014-03-05 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 산화올레핀, 1,2-디올, 1,2-디올 에테르 또는 알칸올아민의제조방법, 이를 위한 촉매, 이 촉매의 제조방법
US8791280B2 (en) * 2005-08-10 2014-07-29 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Process for preparation of catalyst carrier and its use in catalyst preparation
US7459589B2 (en) * 2005-12-22 2008-12-02 Shell Oil Company Process for the preparation of an alkylene glycol
US20070213545A1 (en) * 2005-12-22 2007-09-13 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070203348A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070197801A1 (en) * 2005-12-22 2007-08-23 Bolk Jeroen W Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitables for such a process
US20070154377A1 (en) * 2005-12-22 2007-07-05 Rekers Dominicus M Process for the removal of combustible volatile contaminant materials from a process stream
US20070197808A1 (en) * 2005-12-22 2007-08-23 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
CN101384359A (zh) * 2005-12-22 2009-03-11 国际壳牌研究有限公司 制备再生的环氧化催化剂的方法
US20070203349A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070203350A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070203352A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070151451A1 (en) * 2005-12-22 2007-07-05 Rekers Dominicus M Process for the cooling, concentration or purification of ethylene oxide
US7704908B2 (en) * 2005-12-22 2010-04-27 Shell Oil Company Method for reusing rhenium from a donor spent epoxidation catalyst
JP2009525848A (ja) * 2006-02-03 2009-07-16 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒の処理方法、触媒、および触媒の使用
US8097557B2 (en) 2006-08-08 2012-01-17 Sd Lizenverwertungsgesellschaft Mbh & Co. Kg Two-stage calcination for catalyst production
EP2125202A2 (en) 2006-11-20 2009-12-02 Shell Internationale Research Maatschappij B.V. A process for treating a carrier, a process for preparing a catalyst, the catalyst, and use of the catalyst
US20080154052A1 (en) * 2006-12-20 2008-06-26 Jeroen Willem Bolk Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process
US20080154051A1 (en) * 2006-12-20 2008-06-26 Jeroen Willem Bolk Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process
TWI464154B (zh) * 2007-05-09 2014-12-11 Shell Int Research 製備烯烴氧化物、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或烷醇胺之方法
AR066468A1 (es) 2007-05-09 2009-08-19 Shell Int Research Un catalizador de epoxidacion, un proceso para preparar el mismo, y un proceso para producir un oxido de olefina , un 1,2- diol, un 1,2 - diol eter, un 1,2- carbonato, o una alcanolamina
EP2152681B1 (en) * 2007-05-09 2017-03-29 Shell Internationale Research Maatschappij B.V. An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
KR101485955B1 (ko) 2007-05-11 2015-01-22 베리 제이. 빌릭 산화올레핀 제조 공장에서의 고선택성 촉매의 개시 방법
WO2008144396A2 (en) 2007-05-18 2008-11-27 Shell Oil Company A reactor system, and a process for preparing an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate and an alkanolamine
US9144765B2 (en) 2007-05-18 2015-09-29 Shell Oil Company Reactor system, an absorbent and a process for reacting a feed
US8569527B2 (en) 2007-05-18 2013-10-29 Shell Oil Company Reactor system, an absorbent and a process for reacting a feed
WO2009029578A2 (en) * 2007-08-27 2009-03-05 Shell Oil Company A carrier, a process for preparing the carrier, an olefin epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
US7763096B2 (en) 2008-05-06 2010-07-27 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Recovery of rhenium
KR101629037B1 (ko) * 2008-05-07 2016-06-09 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 에폭시화 방법의 스타트업 방법, 산화에틸렌, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법
KR101629038B1 (ko) * 2008-05-07 2016-06-09 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 산화올레핀, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법
BRPI0912718B1 (pt) 2008-05-15 2017-12-26 Shell Internationale Research Maataschappij B.V Method for producing an alkylene carbonate and / or an alkylene glycol
CN102066352B (zh) 2008-05-15 2014-03-19 国际壳牌研究有限公司 制备亚烷基碳酸酯和亚烷基二醇的方法
CN102414189B (zh) * 2009-04-21 2014-09-17 陶氏技术投资有限公司 环氧化反应及其操作条件
WO2010123844A1 (en) * 2009-04-21 2010-10-28 Dow Technology Investments Llc Improved method of achieving and maintaining a specified alkylene oxide production parameter with a high efficiency catalyst
JP2012524785A (ja) * 2009-04-21 2012-10-18 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 高効率触媒を用いたアルキレンオキシド簡易製造方法
JP2012522061A (ja) * 2009-12-28 2012-09-20 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー アルキレンオキサイドの製造における銀触媒上への塩化銀の生成の制御方法
US8937031B2 (en) 2010-03-01 2015-01-20 Shell Oil Company Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide
US8648225B2 (en) * 2010-04-12 2014-02-11 Chevron Phillips Chemical Company Lp Process for hydrogenating highly unsaturated hydrocarbons and catalyst therefor
TW201208763A (en) * 2010-05-17 2012-03-01 Scient Design Co Method for making a highly selective ethylene oxide catalyst
JP2013505993A (ja) * 2010-07-10 2013-02-21 住友化学株式会社 酸化オレフィンの製造方法
US9018126B2 (en) * 2010-07-13 2015-04-28 Shell Oil Company Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide
CN102441435B (zh) * 2010-09-30 2014-01-01 中国石油化工股份有限公司 制备银催化剂用氧化铝载体的方法、由此得到的载体及其应用
US8742147B2 (en) 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
US8742146B2 (en) 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
CN103502229B (zh) 2011-04-29 2016-02-03 国际壳牌研究有限公司 用于改善环氧乙烷催化剂选择性的方法
CN102950029B (zh) * 2011-08-19 2016-03-30 中国石油化工股份有限公司 改性氧化铝载体、其制备方法、由其制成的银催化剂及其在环氧乙烷生产中的应用
WO2014105924A1 (en) * 2012-12-31 2014-07-03 Scientific Design Company, Inc. Calcination process for producing an improved ethylene oxide catalyst
RU2674990C1 (ru) 2013-12-19 2018-12-14 Сайентифик Дизайн Компани, Инк. Высококонцентрированные серебросодержащие растворы для изготовления катализаторов синтеза этиленоксида
CN108368039B (zh) 2015-12-15 2020-07-14 国际壳牌研究有限公司 从环氧乙烷制造中的循环气体流去除碘化物杂质的方法和系统
BR112018012058B1 (pt) 2015-12-15 2021-01-05 Shell Internationale Research Maatschappij B.V. processo para operar um sistema de leito de guarda
EP3390379B1 (en) 2015-12-15 2019-10-30 Shell International Research Maatschappij B.V. Processes and systems for removing a vinyl iodide impurity from a recycle gas stream in the production of ethylene oxide
RU2721603C2 (ru) 2015-12-15 2020-05-21 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способы и системы для удаления примеси алкилиодида из возвратного газового потока при получении этиленоксида
TWI772330B (zh) 2016-10-14 2022-08-01 荷蘭商蜆殼國際研究所 用於定量分析氣態製程流之方法及設備
BR112019011162B1 (pt) 2016-12-02 2022-08-16 Shell Internationale Research Maatschappij B.V. Método para o condicionamento de um catalisador de epoxidação de etileno e método para melhorar a seletividade do referido catalisador em um processo de epoxidação de etileno
CN110639518A (zh) * 2019-09-03 2020-01-03 北京氦舶科技有限责任公司 一种乙烯环氧化反应用银催化剂及其制备方法和应用
CA3204704A1 (en) 2020-12-29 2022-07-07 Shell Internationale Research Maatschappij B.V. Process for the production of ethylene oxide
EP4673492A2 (en) 2023-03-02 2026-01-07 Basf Se Environmenal friendly ethylene oxide, propylene oxide and downstream products
WO2024213626A1 (en) 2023-04-12 2024-10-17 Basf Se Vinyl acetate having low deuterium content

Family Cites Families (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3316279A (en) * 1964-06-09 1967-04-25 Union Oil Co Preparation of olefin oxides
US3844981A (en) * 1969-12-23 1974-10-29 Exxon Research Engineering Co Method for preparation of olefin oxidation catalyst
GB1325715A (en) * 1969-12-23 1973-08-08 Exxon Research Engineering Co Bimetallic catalyst manufacture and use in ethylene oxidation
US3702259A (en) * 1970-12-02 1972-11-07 Shell Oil Co Chemical production of metallic silver deposits
US4356312A (en) * 1972-01-07 1982-10-26 Shell Oil Company Ethylene oxide process
US3962136A (en) * 1972-01-07 1976-06-08 Shell Oil Company Catalyst for production of ethylene oxide
US4010115A (en) * 1972-01-07 1977-03-01 Shell Oil Company Catalyst for the oxidation of ethylene to ethylene oxide
US3962285A (en) * 1972-06-05 1976-06-08 Exxon Research And Engineering Company Olefin oxidation process
US3972829A (en) * 1974-11-07 1976-08-03 Universal Oil Products Company Method of depositing a catalytically active metallic component on a carrier material
US4005049A (en) * 1975-05-23 1977-01-25 Standard Oil Company (Indiana) Silver catalysts
US4212772A (en) * 1976-05-19 1980-07-15 Basf Aktiengesellschaft Catalyst for the manufacture of ethylene oxide
DE2861030D1 (en) * 1977-11-19 1981-11-26 Basf Ag Process for preparing an ethylene oxide catalyst
DE2844402A1 (de) * 1978-10-12 1980-04-30 Basf Ag Silber enthaltende traegerkatalysatoren, verfahren zu ihrer herstellung und verfahren zur herstellung von aethylenoxid mittels dieser katalysatoren
DE2904919A1 (de) * 1979-02-09 1980-08-21 Basf Ag Verfahren zur herstellung und regenerierung von traegerkatalysatoren sowie deren verwendung fuer die herstellung von aethylenoxid
JPS56108533A (en) * 1980-01-30 1981-08-28 Nippon Shokubai Kagaku Kogyo Co Ltd Silver catalyst for preparing ethylene oxide
JPS56149320A (en) * 1980-04-21 1981-11-19 Sumitomo Alum Smelt Co Ltd Manufacture of activated alumina molding with low density
NL8201396A (nl) * 1982-04-01 1983-11-01 Dow Chemical Nederland Zilver katalysator en een werkwijze voor de bereiding daarvan.
US4459372A (en) * 1982-08-25 1984-07-10 Uop Inc. Surface-metallated refractory inorganic oxides, method of their preparation and catalyst supported on the oxides
GB8304749D0 (en) * 1983-02-21 1983-03-23 Ici Plc Catalysts
EP0172280B1 (en) * 1983-03-14 1988-03-09 E.I. Du Pont De Nemours And Company Catalyst composition
US4579728A (en) * 1985-04-24 1986-04-01 Shell Oil Company Wide pore alumina supports
DE3669668D1 (de) * 1985-07-31 1990-04-26 Ici Plc Verfahren zur aktivierung der katalysatoren zur herstellung von alkylenoxiden.
DE3675601D1 (de) * 1985-08-16 1990-12-20 Sumitomo Chemical Co Verfahren zur vorbereitung einer festen base.
GB8611121D0 (en) * 1986-05-07 1986-06-11 Shell Int Research Silver catalyst
US4808738A (en) * 1986-10-31 1989-02-28 Shell Oil Company Ethylene oxide process
US4766105A (en) * 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4761394A (en) * 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US5057481A (en) * 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US4908343A (en) * 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
GB8716653D0 (en) * 1987-07-15 1987-08-19 Shell Int Research Silver-containing catalyst
US4897498A (en) * 1988-01-28 1990-01-30 Eastman Kodak Company Selective monoepoxidation of olefins
CN1009437B (zh) * 1988-02-03 1990-09-05 中国石油化工总公司 乙烯氧化制环氧乙烷高效银催化剂
US5072886A (en) * 1988-09-09 1991-12-17 Simon Fraser University Method of preparing a new ultra-fine particle transition alumina
US5130286A (en) * 1989-01-11 1992-07-14 Amoco Corporation Catalyst for lower alkane conversion
US5028577A (en) * 1989-01-11 1991-07-02 Amoco Corporation Lower alkane conversion catalysts
US5081324A (en) * 1989-01-11 1992-01-14 Amoco Corporation Lower alkane conversion
US4992409A (en) * 1989-01-11 1991-02-12 Amoco Corporation Catalyst and method of preparing the catalyst for lower alkane conversion
EP0383636A1 (en) * 1989-02-17 1990-08-22 Nippon Shokubai Co., Ltd. Carrier for catalyst and method for production thereof
DE3905578A1 (de) * 1989-02-23 1990-08-30 Basf Ag Verfahren zur herstellung eines silberkatalysators
US5071815A (en) * 1989-09-01 1991-12-10 British Columbia Research Corporation Method for producing catalysts
US5037794A (en) * 1989-09-12 1991-08-06 The B. F. Goodrich Company Attrition resistant catalyst support
US5081096A (en) * 1990-07-25 1992-01-14 Eastman Kodak Company Epoxidation catalyst
US5102848A (en) * 1990-09-28 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US5100859A (en) * 1991-01-22 1992-03-31 Norton Company Catalyst carrier
DE4106508A1 (de) * 1991-03-01 1992-09-03 Basf Ag Silberkatalysator
US5153165A (en) * 1991-05-09 1992-10-06 Phillips Petroleum Company Preparation of alkaline earth oxide catalysts
JP3312916B2 (ja) * 1991-06-06 2002-08-12 三菱化学株式会社 酸化エチレン製造用銀触媒
US5502020A (en) * 1993-04-14 1996-03-26 Mitsubishi Petrochemical Co., Ltd. Catalyst for production of ethylene oxide and process for producing the catalyst
US5447897A (en) * 1993-05-17 1995-09-05 Shell Oil Company Ethylene oxide catalyst and process
US5380697A (en) * 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
US5364826A (en) * 1993-09-13 1994-11-15 Shell Oil Company Process for preparing ethylene oxide catalysts
DE69520409T3 (de) * 1994-12-15 2010-02-18 Shell Internationale Research Maatschappij B.V. Verfahren zur Herstellung von Äthylenoxid-Katalysatoren

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AU7284396A (en) 1997-04-30

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