ATE391552T1 - Verfahren zur herstellung von katalysatoren mit verbesserten katalytischen eigenschaften - Google Patents
Verfahren zur herstellung von katalysatoren mit verbesserten katalytischen eigenschaftenInfo
- Publication number
- ATE391552T1 ATE391552T1 AT99947318T AT99947318T ATE391552T1 AT E391552 T1 ATE391552 T1 AT E391552T1 AT 99947318 T AT99947318 T AT 99947318T AT 99947318 T AT99947318 T AT 99947318T AT E391552 T1 ATE391552 T1 AT E391552T1
- Authority
- AT
- Austria
- Prior art keywords
- carrier
- catalytic properties
- improved catalytic
- producing catalysts
- depositing
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- 230000003197 catalytic effect Effects 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000151 deposition Methods 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- 238000005470 impregnation Methods 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- 230000008021 deposition Effects 0.000 abstract 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/06—Washing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10019598P | 1998-09-14 | 1998-09-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE391552T1 true ATE391552T1 (de) | 2008-04-15 |
Family
ID=22278557
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT99947318T ATE391552T1 (de) | 1998-09-14 | 1999-09-09 | Verfahren zur herstellung von katalysatoren mit verbesserten katalytischen eigenschaften |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US6656874B2 (de) |
| EP (1) | EP1115486B1 (de) |
| JP (1) | JP4518673B2 (de) |
| KR (1) | KR100572967B1 (de) |
| CN (1) | CN1145526C (de) |
| AT (1) | ATE391552T1 (de) |
| AU (1) | AU757495B2 (de) |
| BR (1) | BR9913599A (de) |
| CA (1) | CA2343784C (de) |
| DE (1) | DE69938503T2 (de) |
| ES (1) | ES2301248T3 (de) |
| GC (1) | GC0000067A (de) |
| ID (1) | ID29419A (de) |
| MX (1) | MX259780B (de) |
| MY (1) | MY121431A (de) |
| RU (1) | RU2234370C2 (de) |
| TR (1) | TR200100751T2 (de) |
| TW (1) | TWI224027B (de) |
| WO (1) | WO2000015334A1 (de) |
| ZA (1) | ZA200101903B (de) |
Families Citing this family (69)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7504525B2 (en) * | 1998-09-14 | 2009-03-17 | Shell Oil Company | Catalyst composition |
| US7232786B2 (en) * | 1998-09-14 | 2007-06-19 | Shell Oil Company | Catalyst composition |
| ID28790A (id) * | 1998-09-14 | 2001-07-05 | Shell Int Research | Bahan pembawa katalis epoksidasi, pembuatan dan penggunaannya |
| US7232918B2 (en) | 2001-11-06 | 2007-06-19 | Shell Oil Company | Catalyst composition |
| US7425647B2 (en) | 2001-03-30 | 2008-09-16 | Shell Oil Company | Process for preparing a group V111-metal containing catalyst, use thereof for preparing an alkenyl carboxylate |
| US7193094B2 (en) | 2001-11-20 | 2007-03-20 | Shell Oil Company | Process and systems for the epoxidation of an olefin |
| US6831037B2 (en) | 2002-02-25 | 2004-12-14 | Saint-Gobain Norpro Corporation | Catalyst carriers |
| JP4421201B2 (ja) | 2002-03-27 | 2010-02-24 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒を調製する方法、触媒、および触媒の使用 |
| EP1493486B1 (de) * | 2002-04-08 | 2008-02-20 | Sued-Chemie Catalysts Japan, Inc. | Behandlungsmittel für eine metallhydridverbindung enthaltendes abgas und verfahren zur behandlung von eine metallhydridverbindung enthaltendem abgas |
| US6750173B2 (en) | 2002-04-08 | 2004-06-15 | Scientific Design Company, Inc. | Ethylene oxide catalyst |
| MX245604B (es) | 2002-06-28 | 2007-05-04 | Shell Int Research | Metodo para iniciar un proceso de epoxidacion y proceso de epoxidacion de una olefina. |
| AU2003243757A1 (en) | 2002-06-28 | 2004-01-19 | Shell Oil Company | A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| DE10240128A1 (de) * | 2002-08-30 | 2004-03-11 | Basf Ag | Silberkatalysator für die Epoxidation von Propylen |
| TWI346574B (en) | 2003-03-31 | 2011-08-11 | Shell Int Research | A catalyst composition, a process for preparing the catalyst composition and a use of the catalyst composition |
| MXPA05010375A (es) | 2003-04-01 | 2005-11-17 | Shell Int Research | Proceso de epoxidacion de olefina y catalizador para utilizar en el proceso. |
| US7348444B2 (en) | 2003-04-07 | 2008-03-25 | Shell Oil Company | Process for the production of an olefin oxide |
| US6846774B2 (en) * | 2003-04-23 | 2005-01-25 | Scientific Design Co., Inc. | Ethylene oxide catalyst |
| CA2524890C (en) | 2003-05-07 | 2012-09-11 | Shell Internationale Research Maatschappij B.V. | Silver-containing catalysts, the manufacture of such silvercontaining catalysts, and the use thereof |
| US20040224841A1 (en) | 2003-05-07 | 2004-11-11 | Marek Matusz | Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof |
| US20040225138A1 (en) | 2003-05-07 | 2004-11-11 | Mcallister Paul Michael | Reactor system and process for the manufacture of ethylene oxide |
| US8148555B2 (en) | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| CN101757914A (zh) | 2003-10-16 | 2010-06-30 | 陶氏技术投资有限责任公司 | 用于烯化氧制备的具有提高稳定性、效率和/或活性的催化剂 |
| TW200600190A (en) | 2004-04-01 | 2006-01-01 | Shell Int Research | Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation |
| TW200613056A (en) * | 2004-04-01 | 2006-05-01 | Shell Int Research | A process for preparing a silver catalyst, the catalyst, and a use of the catalyst for olefin oxidation |
| TW200602123A (en) * | 2004-04-01 | 2006-01-16 | Shell Int Research | Process for preparing a catalyst, the catalyst, and a use of the catalyst |
| MY140566A (en) | 2004-06-18 | 2009-12-31 | Shell Int Research | A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine |
| WO2006028544A2 (en) | 2004-06-18 | 2006-03-16 | Shell International Research Maatschappij B.V. | A process for the production of an olefin oxide, a 1,2-diol, a 1.2-diol ether, or an alkanolamine |
| MX2007002386A (es) | 2004-09-01 | 2007-04-23 | Shell Int Research | Proceso para epoxidacion de olefinas, catalizador para uso en el proceso, soporte para uso en la preparacion del catalizador, y proceso para preparar el soporte. |
| US8536083B2 (en) | 2004-09-01 | 2013-09-17 | Shell Oil Company | Olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier |
| RU2007115405A (ru) | 2004-09-24 | 2008-10-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) | Способ выбора формированных частиц, способ сборки системы, способ реагирования газообразного сырья в такой системе, компьютерный программный продукт и компьютерная система |
| US20060204414A1 (en) * | 2005-03-11 | 2006-09-14 | Saint-Gobain Ceramics & Plastics, Inc. | Bed support media |
| US7566428B2 (en) * | 2005-03-11 | 2009-07-28 | Saint-Gobain Ceramics & Plastics, Inc. | Bed support media |
| JP5101498B2 (ja) | 2005-06-07 | 2012-12-19 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒、触媒の製造方法、およびオレフィンオキシド、1,2−ジオール、1,2−ジオールエーテル、またはアルカノールアミンの製造方法 |
| TWI334363B (en) | 2005-06-07 | 2010-12-11 | Saint Gobain Ceramics | A catalyst carrier |
| US7655596B2 (en) * | 2005-12-22 | 2010-02-02 | Saudi Basic Industries Corporation | Catalyst for epoxidation of an alkene to an alkene oxide, method of making and method of using thereof |
| TW200738332A (en) * | 2006-02-03 | 2007-10-16 | Shell Int Research | A process for treating a catalyst, the catalyst, and use of the catalyst |
| JP4175387B2 (ja) * | 2006-05-31 | 2008-11-05 | トヨタ自動車株式会社 | 排ガス浄化触媒製造方法 |
| US8501664B2 (en) * | 2006-11-20 | 2013-08-06 | Shell Oil Company | Process for treating a carrier, a process for preparing a catalyst, the catalyst, and use of the catalyst |
| TWI446964B (zh) | 2007-05-09 | 2014-08-01 | Shell Int Research | 環氧化催化劑,製備該催化劑之方法及製備烯烴氧化物、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或烷醇胺之方法 |
| US7713903B2 (en) | 2007-08-27 | 2010-05-11 | Shell Oil Company | Carrier, a process for preparing the carrier, an olefin epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, A 1,2-diol, A 1,2-diol ether, or an alkanolamine |
| JP5868703B2 (ja) | 2008-05-07 | 2016-02-24 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | オレフィンオキシド、1,2−ジオール、1,2−ジオールエーテル、1,2−カーボネートまたはアルカノールアミンの製造方法 |
| CN102056909B (zh) | 2008-05-07 | 2014-03-05 | 国际壳牌研究有限公司 | 环氧化工艺的开车方法及环氧乙烷、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或链烷醇胺的制备方法 |
| US8987482B2 (en) | 2011-10-28 | 2015-03-24 | Basf Se | Process for producing a supported silver catalyst |
| WO2013148417A1 (en) * | 2012-03-27 | 2013-10-03 | Dow Technology Investments Llc | Method of making a manganese containing supported silver catalyst intermediate |
| TWI632954B (zh) | 2013-05-16 | 2018-08-21 | 科學設計股份有限公司 | 改善環氧乙烷觸媒的催化效能之載體處理 |
| TWI632138B (zh) | 2013-05-16 | 2018-08-11 | 科學設計股份有限公司 | 具有降低鈉含量之建基於銀之環氧乙烷觸媒 |
| RU2674990C1 (ru) | 2013-12-19 | 2018-12-14 | Сайентифик Дизайн Компани, Инк. | Высококонцентрированные серебросодержащие растворы для изготовления катализаторов синтеза этиленоксида |
| TWI723100B (zh) | 2015-12-15 | 2021-04-01 | 荷蘭商蜆殼國際研究所 | 從環氧乙烷製造中的循環氣體流移除烷基碘雜質之方法及系統 |
| KR102687888B1 (ko) | 2015-12-15 | 2024-07-25 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | 에틸렌 옥사이드의 제조 시 재순환 가스 스트림으로부터 요오드화물 불순물을 제거하기 위한 방법 및 시스템 |
| TWI740863B (zh) | 2015-12-15 | 2021-10-01 | 荷蘭商蜆殼國際研究所 | 防護床系統及方法 |
| KR102687885B1 (ko) | 2015-12-15 | 2024-07-25 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | 에틸렌 옥사이드의 제조 시 재순환 가스 스트림으로부터 요오드화비닐 불순물을 제거하기 위한 방법 및 시스템 |
| TWI772330B (zh) | 2016-10-14 | 2022-08-01 | 荷蘭商蜆殼國際研究所 | 用於定量分析氣態製程流之方法及設備 |
| EP3548471B1 (de) | 2016-12-02 | 2021-05-19 | Shell Internationale Research Maatschappij B.V. | Verfahren zur konditionierung eines ethylenepoxidationskatalysators und zugehörige verfahren zur herstellung von ethylenoxid |
| CN111655368A (zh) | 2018-02-07 | 2020-09-11 | 巴斯夫欧洲公司 | 制备银浸渍溶液的方法 |
| EP3639924A1 (de) | 2018-10-15 | 2020-04-22 | Basf Se | Katalysator zur herstellung von ethylenoxid durch gasphasenoxidation |
| EP3639923A1 (de) | 2018-10-15 | 2020-04-22 | Basf Se | Verfahren zur herstellung von ethylenoxid durch gasphasenoxidation von ethylen |
| EP3659703A1 (de) | 2018-11-28 | 2020-06-03 | Basf Se | Katalysator zur herstellung von ethylenoxid durch gasphasenoxidation |
| EP3885038A1 (de) | 2020-03-27 | 2021-09-29 | Basf Se | Verfahren zur herstellung eines epoxidierungskatalysators |
| US20230256420A1 (en) | 2020-06-26 | 2023-08-17 | Basf Se | Shaped catalyst body for the production of ethylene oxide |
| JP7805320B2 (ja) | 2020-06-26 | 2026-01-23 | ビーエーエスエフ ソシエタス・ヨーロピア | 多孔質アルファ-アルミナ触媒支持体を生成する方法 |
| WO2021260140A1 (en) | 2020-06-26 | 2021-12-30 | Basf Se | Production of porous alpha-alumina supports from boehmitic derived aluminas |
| CN114377721A (zh) * | 2020-10-22 | 2022-04-22 | 湘潭大学 | 一种介孔催化剂的制备方法及其在烯烃环氧化反应中的应用 |
| WO2022144866A1 (en) | 2020-12-29 | 2022-07-07 | Shell Internationale Research Maatschappij B.V. | Process for the production of ethylene oxide |
| CN116723893A (zh) | 2021-01-26 | 2023-09-08 | 巴斯夫欧洲公司 | 环氧化催化剂 |
| CN117545552A (zh) | 2021-06-25 | 2024-02-09 | 巴斯夫欧洲公司 | 高纯度压片阿尔法氧化铝催化剂载体 |
| CN117696051A (zh) * | 2022-09-07 | 2024-03-15 | 中国石油化工股份有限公司 | 一种银催化剂及其合成方法和应用 |
| EP4601789A1 (de) | 2022-10-12 | 2025-08-20 | Basf Se | Epoxidierungskatalysator |
| CN115739112B (zh) * | 2022-11-22 | 2024-06-21 | 北京化工大学 | 一种CoRhCs三金属催化剂的合成方法及其应用 |
| WO2026027443A1 (en) | 2024-07-29 | 2026-02-05 | Basf Se | Blended catalyst mix for epoxidation |
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| US5935894A (en) * | 1997-07-02 | 1999-08-10 | Laroche Industries, Inc. | Alumina based adsorbent containing alkali metal compounds |
| FR2770421B1 (fr) * | 1997-10-31 | 1999-12-10 | Inst Francais Du Petrole | Procede de preparation de catalyseurs utilisables dans les reactions de transformation de composes organiques |
| JP4698835B2 (ja) * | 1998-09-14 | 2011-06-08 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒特性改良のため触媒表面からイオン化可能種を除去する方法 |
-
1999
- 1999-09-09 RU RU2001110170/04A patent/RU2234370C2/ru not_active IP Right Cessation
- 1999-09-09 CA CA002343784A patent/CA2343784C/en not_active Expired - Fee Related
- 1999-09-09 AU AU60814/99A patent/AU757495B2/en not_active Ceased
- 1999-09-09 AT AT99947318T patent/ATE391552T1/de not_active IP Right Cessation
- 1999-09-09 WO PCT/EP1999/006722 patent/WO2000015334A1/en not_active Ceased
- 1999-09-09 JP JP2000569913A patent/JP4518673B2/ja not_active Expired - Fee Related
- 1999-09-09 DE DE69938503T patent/DE69938503T2/de not_active Expired - Lifetime
- 1999-09-09 KR KR1020017003172A patent/KR100572967B1/ko not_active Expired - Fee Related
- 1999-09-09 BR BR9913599-0A patent/BR9913599A/pt not_active Application Discontinuation
- 1999-09-09 TR TR2001/00751T patent/TR200100751T2/xx unknown
- 1999-09-09 ES ES99947318T patent/ES2301248T3/es not_active Expired - Lifetime
- 1999-09-09 CN CNB998109029A patent/CN1145526C/zh not_active Expired - Lifetime
- 1999-09-09 EP EP99947318A patent/EP1115486B1/de not_active Revoked
- 1999-09-09 ID IDW20010577A patent/ID29419A/id unknown
- 1999-09-13 GC GCP1999280 patent/GC0000067A/xx active
- 1999-09-14 MY MYPI99003963A patent/MY121431A/en unknown
- 1999-10-19 TW TW088118045A patent/TWI224027B/zh not_active IP Right Cessation
-
2001
- 2001-03-07 ZA ZA200101903A patent/ZA200101903B/en unknown
- 2001-03-12 MX MXPA01002586 patent/MX259780B/es not_active IP Right Cessation
- 2001-03-13 US US09/805,317 patent/US6656874B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| RU2234370C2 (ru) | 2004-08-20 |
| ID29419A (id) | 2001-08-30 |
| CA2343784C (en) | 2007-11-13 |
| DE69938503T2 (de) | 2009-06-10 |
| CN1145526C (zh) | 2004-04-14 |
| MX259780B (en) | 2008-08-20 |
| CA2343784A1 (en) | 2000-03-23 |
| ZA200101903B (en) | 2002-09-23 |
| BR9913599A (pt) | 2001-05-22 |
| TR200100751T2 (tr) | 2001-09-21 |
| AU757495B2 (en) | 2003-02-20 |
| KR100572967B1 (ko) | 2006-04-24 |
| WO2000015334A1 (en) | 2000-03-23 |
| EP1115486B1 (de) | 2008-04-09 |
| JP4518673B2 (ja) | 2010-08-04 |
| US6656874B2 (en) | 2003-12-02 |
| CN1317991A (zh) | 2001-10-17 |
| EP1115486A1 (de) | 2001-07-18 |
| MXPA01002586A (es) | 2001-08-01 |
| ES2301248T3 (es) | 2008-06-16 |
| AU6081499A (en) | 2000-04-03 |
| DE69938503D1 (de) | 2008-05-21 |
| KR20010079797A (ko) | 2001-08-22 |
| MY121431A (en) | 2006-01-28 |
| US20020010094A1 (en) | 2002-01-24 |
| GC0000067A (en) | 2004-06-30 |
| JP2002524246A (ja) | 2002-08-06 |
| TWI224027B (en) | 2004-11-21 |
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