DE69015863T2 - Alkylenoxid-Katalysator mit verbesserter Aktivität und/oder Stabilität. - Google Patents
Alkylenoxid-Katalysator mit verbesserter Aktivität und/oder Stabilität.Info
- Publication number
- DE69015863T2 DE69015863T2 DE69015863T DE69015863T DE69015863T2 DE 69015863 T2 DE69015863 T2 DE 69015863T2 DE 69015863 T DE69015863 T DE 69015863T DE 69015863 T DE69015863 T DE 69015863T DE 69015863 T2 DE69015863 T2 DE 69015863T2
- Authority
- DE
- Germany
- Prior art keywords
- stability
- alkylene oxide
- oxide catalyst
- improved activity
- manganese component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/053—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US34024289A | 1989-04-18 | 1989-04-18 | |
US34039089A | 1989-04-18 | 1989-04-18 | |
US07/502,187 US5504053A (en) | 1989-04-18 | 1990-04-03 | Alkylene oxide catalysts having enhanced activity and/or stability |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69015863D1 DE69015863D1 (de) | 1995-02-23 |
DE69015863T2 true DE69015863T2 (de) | 1995-05-18 |
Family
ID=27407385
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69015863T Expired - Fee Related DE69015863T2 (de) | 1989-04-18 | 1990-04-17 | Alkylenoxid-Katalysator mit verbesserter Aktivität und/oder Stabilität. |
Country Status (14)
Country | Link |
---|---|
US (1) | US5504053A (de) |
EP (1) | EP0393785B1 (de) |
JP (1) | JP3049560B2 (de) |
KR (1) | KR950008196B1 (de) |
AT (1) | ATE116976T1 (de) |
AU (1) | AU640924B2 (de) |
BR (1) | BR9001784A (de) |
CA (2) | CA1337722C (de) |
DD (1) | DD300512A5 (de) |
DE (1) | DE69015863T2 (de) |
DK (1) | DK0393785T3 (de) |
ES (1) | ES2066101T3 (de) |
RU (1) | RU2045335C1 (de) |
ZA (1) | ZA902931B (de) |
Families Citing this family (85)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5187140A (en) * | 1989-10-18 | 1993-02-16 | Union Carbide Chemicals & Plastics Technology Corporation | Alkylene oxide catalysts containing high silver content |
AU656537B2 (en) * | 1990-10-12 | 1995-02-09 | Union Carbide Chemicals & Plastics Technology Corporation | Alkylene oxide catalysts having enhanced activity and/or stability |
EP0879640B1 (de) * | 1995-09-26 | 2003-04-02 | Kabushiki Kaisha Kobe Seiko Sho | Mittel zur entfernung von giftgas |
US5763630A (en) * | 1996-03-18 | 1998-06-09 | Arco Chemical Technology, L.P. | Propylene oxide process using alkaline earth metal compound-supported silver catalysts |
US5861519A (en) * | 1997-05-23 | 1999-01-19 | Arco Chemical Technology, L.P. | Propylene oxide process using alkaline earth metal compound-supported silver catalysts containing tungsten and potassium promoters |
TW426545B (en) * | 1997-12-25 | 2001-03-21 | Nippon Catalytic Chem Ind | Silver catalyst for production of ethylene oxide, method for production thereof, and method for production of ethylene oxide |
RU2242153C2 (ru) | 1999-04-01 | 2004-12-20 | Хилинг Спортс Лимитед. | Устройство для катания на пятке и способ |
US6509485B2 (en) | 2001-02-22 | 2003-01-21 | Sri International | Preparation of epoxides from alkanes using lanthanide-promoted silver catalysts |
US6392066B1 (en) | 2001-02-22 | 2002-05-21 | Sri International | Epoxidation of olefins using lanthanide-promoted silver catalysts |
US7193094B2 (en) * | 2001-11-20 | 2007-03-20 | Shell Oil Company | Process and systems for the epoxidation of an olefin |
US6987080B2 (en) * | 2002-03-01 | 2006-01-17 | Scientific Design Company, Inc. | Ethylene oxide catalyst carrier preparation |
JP4537848B2 (ja) * | 2002-06-28 | 2010-09-08 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒の選択性を改善する方法及びオレフィンのエポキシ化方法 |
AU2003278999A1 (en) * | 2002-09-30 | 2004-04-23 | Shell Oil Company | Calcium carbonate carrier for making silver based epoxidation catalysts |
RU2325948C2 (ru) * | 2002-10-28 | 2008-06-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения олефиноксида, способ применения олефиноксида и каталитическая композиция |
DE10251325A1 (de) * | 2002-11-05 | 2004-05-13 | Bayer Ag | Katalysator und Verfahren zur Oxidation von Kohlenwasserstoffen zu Epoxiden |
MY153179A (en) * | 2003-02-28 | 2015-01-29 | Shell Int Research | A method of manufacturing ethylene oxide |
MY136774A (en) | 2003-02-28 | 2008-11-28 | Shell Int Research | Method of improving the operation of a manufacturing process |
TWI346574B (en) * | 2003-03-31 | 2011-08-11 | Shell Int Research | A catalyst composition, a process for preparing the catalyst composition and a use of the catalyst composition |
RU2328491C2 (ru) * | 2003-04-01 | 2008-07-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ эпоксидирования олефинов и катализатор для применения в способе |
CA2524890C (en) | 2003-05-07 | 2012-09-11 | Shell Internationale Research Maatschappij B.V. | Silver-containing catalysts, the manufacture of such silvercontaining catalysts, and the use thereof |
US8148555B2 (en) * | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
CA2538989A1 (en) * | 2003-08-22 | 2005-03-17 | Union Carbide Chemicals & Plastics Technology Corporation | Modified alumina carriers and silver-based catalysts for the production of alkylene oxides |
JP4870561B2 (ja) * | 2003-08-22 | 2012-02-08 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | アルキレンオキサイドの製造用の改良されたアルミナ担体及び銀系触媒 |
BRPI0414766A (pt) * | 2003-09-29 | 2006-11-28 | Union Carbide Chem Plastic | processo para manufaturar óxido de etileno através da epoxidação de etileno |
CN101767039B (zh) | 2003-10-16 | 2015-04-01 | 陶氏技术投资有限责任公司 | 用于烯化氧制备的具有提高稳定性、效率和/或活性的催化剂 |
US7759284B2 (en) * | 2005-05-09 | 2010-07-20 | Scientific Design Company, Inc. | Calcination in an inert gas in the presence of a small concentration of an oxidizing component |
DE102005023955A1 (de) * | 2005-05-20 | 2006-11-23 | Basf Ag | Inertmaterial für den Einsatz in exothermen Reaktionen |
EP1890807B1 (de) * | 2005-06-07 | 2019-04-03 | Shell International Research Maatschappij B.V. | Katalysator, verfahren zur herstellung des katalysators und ein verfahren zur herstellung eines olefinoxids, eines 1,2-diols, eines 1,2-diolethers oder eines alkanolamins |
WO2006133187A2 (en) * | 2005-06-07 | 2006-12-14 | Saint-Gobain Ceramics & Plastics, Inc. | A catalyst carrier and a process for preparing the catalyst carrier |
TW200738332A (en) * | 2006-02-03 | 2007-10-16 | Shell Int Research | A process for treating a catalyst, the catalyst, and use of the catalyst |
CA2931674C (en) * | 2006-04-18 | 2020-12-15 | Dow Global Technologies Llc | Alkylene oxide catalyst and use thereof |
US7932408B2 (en) * | 2006-09-29 | 2011-04-26 | Scientific Design Company, Inc. | Catalyst with bimodal pore size distribution and the use thereof |
US7977274B2 (en) | 2006-09-29 | 2011-07-12 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Catalyst with bimodal pore size distribution and the use thereof |
US20100056816A1 (en) | 2006-11-01 | 2010-03-04 | Wallin Sten A | Shaped porous bodies of alpha-alumina and methods for the preparation thereof |
EP2108031B1 (de) * | 2006-11-21 | 2018-10-17 | Dow Global Technologies LLC | Verfahren zur entfernung von quecksilber aus kohlenwasserstoffeinsätzen |
EP3187493B1 (de) * | 2007-05-09 | 2019-07-10 | Shell International Research Maatschappij B.V. | Epoxidierungskatalysator, ein verfahren zur herstellung des katalysators und verfahren zur herstellung eines olefinoxids, 1,2-diols, 1,2-diolethers, 1,2-carbonats oder alkanolamins |
JP5542659B2 (ja) | 2007-05-09 | 2014-07-09 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | エポキシ化触媒、触媒を調製する方法、および酸化オレフィン、1,2−ジオール、1,2−ジオールエーテル、1,2−カーボネートまたはアルカノールアミンの製造方法 |
CN101314128B (zh) * | 2007-05-31 | 2013-02-13 | 中国科学院大连化学物理研究所 | 一种自热重整制氢催化剂及其制备方法 |
US7507845B1 (en) * | 2007-08-27 | 2009-03-24 | Sd Lizenzverwertungsgesellschaft Mbh & Co Kg | Process for production of an olefin oxide |
US7714152B2 (en) * | 2007-08-30 | 2010-05-11 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Carrier for olefin oxide catalyst |
CN102066348B (zh) * | 2008-05-07 | 2013-09-25 | 国际壳牌研究有限公司 | 环氧烷、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或链烷醇胺的制备方法 |
CA2723517C (en) * | 2008-05-07 | 2017-03-07 | Shell Internationale Research Maatschappij B.V. | A process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
CA2730550A1 (en) * | 2008-07-14 | 2010-01-21 | Velocys Inc. | Process for making ethylene oxide using microchannel process technology |
US8933254B2 (en) * | 2008-07-14 | 2015-01-13 | Basf Se | Process for making ethylene oxide |
CA2731412A1 (en) * | 2008-08-05 | 2010-02-11 | Dow Technology Investments Llc | Two-stage, gas phase process for the manufacture of alkylene glycol |
CN102458651B (zh) * | 2009-04-21 | 2015-06-10 | 陶氏技术投资有限公司 | 铼助催化的环氧化催化剂及其制造和使用方法 |
KR101704079B1 (ko) | 2009-04-21 | 2017-02-07 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 레늄-촉진된 에폭시화 촉매의 효율을 개선하는 방법 및 이를 이용한 에폭시화 방법 |
SG175771A1 (en) * | 2009-04-21 | 2011-12-29 | Dow Technology Investments Llc | Improved method of achieving and maintaining a specified alkylene oxide production parameter with a high efficiency catalyst |
SG194340A1 (en) * | 2009-04-21 | 2013-11-29 | Dow Technology Investments Llc | Epoxidation reactions and operating conditions thereof |
WO2010123842A1 (en) * | 2009-04-21 | 2010-10-28 | Dow Technology Investments Llc | Simplified method for producing alkylene oxides with a high efficiency catalyst as it ages |
CN102421724A (zh) | 2009-04-29 | 2012-04-18 | 陶氏技术投资有限公司 | 多孔体前体,成形多孔体,用于制造它们的方法及基于其的最终用途产品 |
US8524927B2 (en) * | 2009-07-13 | 2013-09-03 | Velocys, Inc. | Process for making ethylene oxide using microchannel process technology |
CN102333767B (zh) | 2009-12-28 | 2014-12-03 | 陶氏技术投资有限公司 | 控制氯化银在环氧烷生产中的银催化剂上的产生的方法 |
TWI496618B (zh) | 2010-03-17 | 2015-08-21 | Dow Technology Investments Llc | 藉由使用具有廣泛選擇性的催化劑將乙烯部分氧化來製造環氧乙烷之高效率固定床平台 |
WO2012078948A1 (en) | 2010-12-10 | 2012-06-14 | Dow Technology Investments Llc | Method of reducing the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst |
SG190901A1 (en) | 2010-12-15 | 2013-07-31 | Dow Technology Investments Llc | Method of starting-up a process of producing an alkylene oxide using a high-efficiency catalyst |
WO2012094120A1 (en) * | 2011-01-05 | 2012-07-12 | Sumitomo Chemical Company, Limited | Process for producing olefin oxide |
WO2012094121A1 (en) * | 2011-01-05 | 2012-07-12 | Sumitomo Chemical Company, Limited | Process for producing olefin oxide |
CA2836060C (en) | 2011-05-30 | 2020-06-02 | John Richard MAYER | Testing and selection methods for catalyst support structures |
EP2718009B1 (de) * | 2011-06-06 | 2021-09-08 | Dow Technology Investments LLC | Verfahren zur herstellung von epoxydationskatalysatoren |
CN107020094B (zh) | 2011-10-31 | 2019-10-11 | 陶氏技术投资有限责任公司 | 生产环氧化催化剂的方法和利用所述环氧化催化剂的环氧化方法 |
CN104080778B (zh) | 2011-12-09 | 2016-08-24 | 陶氏技术投资有限责任公司 | 在利用高效催化剂制造环氧烷的工艺中保持环氧烷生产参数值的方法 |
CN104125858B (zh) | 2011-12-19 | 2017-07-11 | 陶氏技术投资有限责任公司 | 根据催化剂参考性质配制环氧烷催化剂的方法 |
CA2867506C (en) | 2012-03-27 | 2020-08-18 | Dow Technology Investments Llc | Method of making a manganese containing supported silver catalyst intermediate |
JP6033124B2 (ja) * | 2013-02-28 | 2016-11-30 | 株式会社日本触媒 | エチレンオキシド製造用触媒およびエチレンオキシドの製造方法 |
SG11201507353RA (en) | 2013-03-15 | 2015-10-29 | Dow Technology Investments Llc | Method for the production of ethylene oxide |
TWI632138B (zh) | 2013-05-16 | 2018-08-11 | 科學設計股份有限公司 | 具有降低鈉含量之建基於銀之環氧乙烷觸媒 |
TWI632954B (zh) | 2013-05-16 | 2018-08-21 | 科學設計股份有限公司 | 改善環氧乙烷觸媒的催化效能之載體處理 |
TWI772322B (zh) | 2016-09-02 | 2022-08-01 | 美商陶氏科技投資有限公司 | 製備環氧化催化劑之方法 |
BR112019011162B1 (pt) | 2016-12-02 | 2022-08-16 | Shell Internationale Research Maatschappij B.V. | Método para o condicionamento de um catalisador de epoxidação de etileno e método para melhorar a seletividade do referido catalisador em um processo de epoxidação de etileno |
WO2018136381A1 (en) * | 2017-01-17 | 2018-07-26 | Scientific Design Company, Inc. | Silver impregnation method for producing ethylene oxide catalyst with enhanced catalytic ability |
SG11202005995SA (en) | 2017-12-28 | 2020-07-29 | Dow Technology Investments Llc | Process for preparing an epoxidation catalyst |
DK3749449T3 (da) | 2018-02-07 | 2022-04-19 | Basf Se | Fremgangsmåde til fremstilling af en sølvimprægnerings-opløsning |
US11772082B1 (en) * | 2018-06-21 | 2023-10-03 | Avn Corporation | Catalyst supports—composition and process of manufacture |
EP3639923A1 (de) | 2018-10-15 | 2020-04-22 | Basf Se | Verfahren zur herstellung von ethylenoxid durch gasphasenoxidation von ethylen |
EP3639924A1 (de) | 2018-10-15 | 2020-04-22 | Basf Se | Katalysator zur herstellung von ethylenoxid durch gasphasenoxidation |
EP3659703A1 (de) | 2018-11-28 | 2020-06-03 | Basf Se | Katalysator zur herstellung von ethylenoxid durch gasphasenoxidation |
EP3885038A1 (de) | 2020-03-27 | 2021-09-29 | Basf Se | Verfahren zur herstellung eines epoxidierungskatalysators |
WO2021260138A1 (en) | 2020-06-26 | 2021-12-30 | Basf Se | Shaped catalyst body for the production of ethylene oxide |
WO2021260140A1 (en) | 2020-06-26 | 2021-12-30 | Basf Se | Production of porous alpha-alumina supports from boehmitic derived aluminas |
WO2021259427A1 (de) | 2020-06-26 | 2021-12-30 | Basf Se | Poröser katalysatorträger-formkörper |
CN111992204B (zh) * | 2020-09-17 | 2022-07-19 | 福建省晋蓝环保科技有限公司 | 一种臭氧氧化催化剂、制备方法及臭氧催化氧化装置 |
WO2022161924A1 (en) | 2021-01-26 | 2022-08-04 | Basf Se | Epoxidation catalyst |
WO2022268348A1 (en) | 2021-06-25 | 2022-12-29 | Basf Se | High purity tableted alpha-alumina catalyst support |
CA3224814A1 (en) | 2021-07-15 | 2023-01-19 | Karena SMOLL | Alkylene oxide catalyst that can be manufactured rapidly in one step |
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US2040782A (en) * | 1936-05-12 | Manufacture of olefine oxides | ||
US2605239A (en) * | 1952-07-29 | Coprecipitated silver-beryllium | ||
US2615900A (en) * | 1949-06-23 | 1952-10-28 | Du Pont | Process and catalyst for producing ethylene oxide |
US2769016A (en) * | 1953-05-14 | 1956-10-30 | Jefferson Chem Co Inc | Catalytic process of oxidizing ethylene to ethylene oxide with ozone or hydrogen peroxide as carbon dioxide repressants |
US3844981A (en) * | 1969-12-23 | 1974-10-29 | Exxon Research Engineering Co | Method for preparation of olefin oxidation catalyst |
US3962285A (en) * | 1972-06-05 | 1976-06-08 | Exxon Research And Engineering Company | Olefin oxidation process |
GB1491447A (en) * | 1973-12-05 | 1977-11-09 | Ici Ltd | Alkylene oxide production and catalysts therefor |
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US4800070A (en) * | 1987-09-08 | 1989-01-24 | Air Products And Chemicals, Inc. | Catalysts for absorptive air separation |
-
1989
- 1989-06-29 CA CA000604427A patent/CA1337722C/en not_active Expired - Fee Related
-
1990
- 1990-04-03 US US07/502,187 patent/US5504053A/en not_active Expired - Lifetime
- 1990-04-16 KR KR1019900005228A patent/KR950008196B1/ko not_active IP Right Cessation
- 1990-04-17 DK DK90200945.5T patent/DK0393785T3/da active
- 1990-04-17 AU AU53211/90A patent/AU640924B2/en not_active Ceased
- 1990-04-17 EP EP90200945A patent/EP0393785B1/de not_active Expired - Lifetime
- 1990-04-17 DD DD339811A patent/DD300512A5/de unknown
- 1990-04-17 JP JP2099466A patent/JP3049560B2/ja not_active Expired - Lifetime
- 1990-04-17 RU SU904743878A patent/RU2045335C1/ru active
- 1990-04-17 AT AT90200945T patent/ATE116976T1/de active
- 1990-04-17 DE DE69015863T patent/DE69015863T2/de not_active Expired - Fee Related
- 1990-04-17 CA CA002014667A patent/CA2014667C/en not_active Expired - Fee Related
- 1990-04-17 ES ES90200945T patent/ES2066101T3/es not_active Expired - Lifetime
- 1990-04-17 BR BR909001784A patent/BR9001784A/pt not_active Application Discontinuation
- 1990-04-18 ZA ZA902931A patent/ZA902931B/xx unknown
Also Published As
Publication number | Publication date |
---|---|
JP3049560B2 (ja) | 2000-06-05 |
CA1337722C (en) | 1995-12-12 |
DE69015863D1 (de) | 1995-02-23 |
US5504053A (en) | 1996-04-02 |
JPH0368449A (ja) | 1991-03-25 |
KR950008196B1 (ko) | 1995-07-26 |
CA2014667A1 (en) | 1990-10-18 |
ZA902931B (en) | 1991-02-27 |
AU640924B2 (en) | 1993-09-09 |
DK0393785T3 (da) | 1995-03-27 |
EP0393785B1 (de) | 1995-01-11 |
EP0393785A1 (de) | 1990-10-24 |
DD300512A5 (de) | 1992-06-17 |
ATE116976T1 (de) | 1995-01-15 |
CA2014667C (en) | 1998-09-29 |
KR900015813A (ko) | 1990-11-10 |
BR9001784A (pt) | 1991-06-11 |
ES2066101T3 (es) | 1995-03-01 |
RU2045335C1 (ru) | 1995-10-10 |
AU5321190A (en) | 1990-10-25 |
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8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |