DE60228000D1 - Verfahren für die Herstellung von Polypropylen - Google Patents
Verfahren für die Herstellung von PolypropylenInfo
- Publication number
- DE60228000D1 DE60228000D1 DE60228000T DE60228000T DE60228000D1 DE 60228000 D1 DE60228000 D1 DE 60228000D1 DE 60228000 T DE60228000 T DE 60228000T DE 60228000 T DE60228000 T DE 60228000T DE 60228000 D1 DE60228000 D1 DE 60228000D1
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- propylene
- loop reactor
- flow
- bulk loop
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/1812—Tubular reactors
- B01J19/1818—Tubular reactors in series
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/1812—Tubular reactors
- B01J19/1837—Loop-type reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J4/00—Feed or outlet devices; Feed or outlet control devices
- B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
- B01J4/002—Nozzle-type elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00004—Scale aspects
- B01J2219/00006—Large-scale industrial plants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00094—Jackets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/05—Transitioning, i.e. transition from one catalyst to another with use of a deactivating agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US33680101P | 2001-12-03 | 2001-12-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
DE60228000D1 true DE60228000D1 (de) | 2008-09-11 |
Family
ID=23317726
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60203472T Expired - Lifetime DE60203472T2 (de) | 2001-12-03 | 2002-11-26 | Verfahren zum Übergang zwischen Ziegler-Natta-Katalysatoren und Metallocen-Katalysatoren in einem Schlaufenreaktor für die Herstellung von Polypropylen |
DE60228000T Expired - Lifetime DE60228000D1 (de) | 2001-12-03 | 2002-11-26 | Verfahren für die Herstellung von Polypropylen |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60203472T Expired - Lifetime DE60203472T2 (de) | 2001-12-03 | 2002-11-26 | Verfahren zum Übergang zwischen Ziegler-Natta-Katalysatoren und Metallocen-Katalysatoren in einem Schlaufenreaktor für die Herstellung von Polypropylen |
Country Status (11)
Country | Link |
---|---|
US (5) | US6916892B2 (de) |
EP (2) | EP1526143B1 (de) |
JP (1) | JP4627965B2 (de) |
KR (1) | KR100920986B1 (de) |
CN (2) | CN1422875A (de) |
AT (2) | ATE402963T1 (de) |
BR (1) | BR0204898B1 (de) |
DE (2) | DE60203472T2 (de) |
ES (1) | ES2238542T3 (de) |
MX (1) | MXPA02011729A (de) |
TW (1) | TWI258483B (de) |
Families Citing this family (68)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1497243A2 (de) * | 2002-04-22 | 2005-01-19 | Chevron Phillips Chemical Company LP | Verfahren zur herstellung von hochviskosen polyalphaolefinen durch verwendung von flüssigen ionischen katalysatoren |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
CN101724110B (zh) | 2002-10-15 | 2013-03-27 | 埃克森美孚化学专利公司 | 用于烯烃聚合的多催化剂体系和由其生产的聚合物 |
US7122606B2 (en) | 2003-07-04 | 2006-10-17 | Basell Polyolefine Gmbh | Olefin polymerization process |
SG164364A1 (en) * | 2003-10-31 | 2010-09-29 | Chevron Phillips Chemical Co | Method and system to add high shear to improve an ionic liquid catalyzed chemical reaction |
EP1564221A1 (de) * | 2004-02-13 | 2005-08-17 | Total Petrochemicals Research Feluy | Oberflächenbehandlung eines Reaktors für die Polymerisation von Olefinen |
US20050272891A1 (en) * | 2004-02-13 | 2005-12-08 | Atofina Research S.A. | Double loop technology |
WO2005082962A2 (en) * | 2004-02-13 | 2005-09-09 | Total Petrochemicals Research Feluy | Catalyst grain size |
EA010378B1 (ru) * | 2004-02-13 | 2008-08-29 | Тотал Петрокемикалс Рисерч Фелюй | Способ полимеризации пропилена в присутствии противообрастающего агента |
WO2005077985A2 (en) * | 2004-02-13 | 2005-08-25 | Total Petrochemicals Research Feluy | Multiple loop reactor for olefin polymerization |
DK1660231T3 (da) | 2004-02-13 | 2007-08-13 | Total Petrochemicals Res Feluy | Fremgangsmåde og anordning til fremstilling og tilförsel af katalysatoropslemning til en polymeriseringsreaktor |
ATE464324T1 (de) * | 2004-02-13 | 2010-04-15 | Total Petrochemicals Res Feluy | Gelarme chrom-katalyse |
EP1564222A1 (de) * | 2004-02-13 | 2005-08-17 | Total Petrochemicals Research Feluy | Polyolefinproduktion mit hoher Olefin-Konzentration |
ATE489409T1 (de) * | 2004-02-13 | 2010-12-15 | Total Petrochemicals Res Feluy | Verfahren zur verbesserung der copolymerisation von ethylen und einem olefin-comonomer in einem schlaufenpolymerisationsreaktor |
US8492489B2 (en) * | 2004-02-13 | 2013-07-23 | Total Petrochemicals Research Feluy | Double loop technology |
EP1564223A1 (de) * | 2004-02-13 | 2005-08-17 | Total Petrochemicals Research Feluy | Miteinander verbundene Schlaufenreaktoren |
EP1563901A1 (de) * | 2004-02-13 | 2005-08-17 | Total Petrochemicals Research Feluy | Verfahren und Vorrichtung zur Optimisierung des Katalysatorszufuhrs für einen Polymerisationreaktor |
EP1564229A1 (de) * | 2004-02-13 | 2005-08-17 | Total Petrochemicals Research Feluy | Verfahren zur Olefinpolymerisation in Gegenwart eines Antifoulingmittels |
EP1564224A1 (de) * | 2004-02-13 | 2005-08-17 | Total Petrochemicals Research Feluy | Schlaufensuspensionreaktor |
US20050182210A1 (en) * | 2004-02-17 | 2005-08-18 | Natarajan Muruganandam | De-foaming spray dried catalyst slurries |
US7973112B2 (en) * | 2004-02-17 | 2011-07-05 | Univation Technologies, Llc | De-foaming spray dried catalyst slurries |
CA2587038C (en) * | 2004-11-09 | 2011-05-31 | Sumitomo Bakelite Company Limited | Decomposition reaction apparatus, system for producing raw material for recycled resin composition, method for producing raw material for recycled resin composition, raw material for recycled resin composition, and formed article |
US7053163B1 (en) * | 2005-02-22 | 2006-05-30 | Fina Technology, Inc. | Controlled comonomer distribution along a reactor for copolymer production |
US7678341B2 (en) * | 2005-07-29 | 2010-03-16 | Exxonmobil Chemical Patents Inc. | Loop reactor heat removal |
US7615596B2 (en) * | 2005-09-30 | 2009-11-10 | Chevron Phillips Chemical Company Lp | Multiple component feed methods and systems |
JP5013825B2 (ja) * | 2005-11-22 | 2012-08-29 | 旭化成ケミカルズ株式会社 | オレフィン重合体の製造方法 |
EP1840141A1 (de) * | 2006-03-31 | 2007-10-03 | Total Petrochemicals Research Feluy | Verfahren zur Beendung einer katalysierten Olefinpolymerization |
US7446167B2 (en) * | 2006-04-13 | 2008-11-04 | Fina Technology, Inc. | Catalyst deactivation agents and methods for use of same |
US8003739B2 (en) * | 2007-10-17 | 2011-08-23 | Fina Technology, Inc. | Multi-component catalyst systems and polymerization processes for forming in-situ heterophasic copolymers and/or varying the xylene solubles content of polyolefins |
US7378537B2 (en) * | 2006-07-25 | 2008-05-27 | Chevron Phillips Chemical Company Lp | Olefin oligomerization catalysts and methods of using same |
US7494627B2 (en) * | 2006-08-09 | 2009-02-24 | Total Petrochemicals Research Feluy | Device and method for the optimization of the injection of reactants into a reactor |
WO2008059974A1 (fr) * | 2006-11-17 | 2008-05-22 | Mitsui Chemicals, Inc. | Procédé pour produire un polypropylène syndiotactique |
JP4977579B2 (ja) * | 2007-10-31 | 2012-07-18 | 日本ポリプロ株式会社 | ポリオレフィン製造設備の触媒タンクにおける触媒切り替え方法 |
US8759446B2 (en) | 2008-06-30 | 2014-06-24 | Fina Technology, Inc. | Compatibilized polypropylene and polylactic acid blends and methods of making and using same |
US8545971B2 (en) | 2008-06-30 | 2013-10-01 | Fina Technology, Inc. | Polymeric compositions comprising polylactic acid and methods of making and using same |
US8268913B2 (en) | 2008-06-30 | 2012-09-18 | Fina Technology, Inc. | Polymeric blends and methods of using same |
US20100087602A1 (en) * | 2008-10-08 | 2010-04-08 | Fina Technology, Inc. | Long chain branched polypropylene for cast film applications |
US20100125124A1 (en) * | 2008-11-17 | 2010-05-20 | Fina Technology, Inc. | Methods of catalyst activation |
CN102741301B (zh) * | 2009-09-11 | 2014-10-08 | 巴塞尔聚烯烃意大利有限责任公司 | 烯烃的气相聚合方法 |
WO2011073369A1 (en) * | 2009-12-18 | 2011-06-23 | Total Petrochemicals Research Feluy | Method for replacing incompatible ethylene polymerization catalysts |
US8729199B2 (en) * | 2009-12-18 | 2014-05-20 | Total Research & Technology Feluy | Method for neutralizing polymerization catalyst |
KR101453636B1 (ko) | 2010-02-05 | 2014-10-22 | 토탈 리서치 앤드 테크놀로지 펠루이 | 폴리올레핀 제조 방법 |
EP2386352A1 (de) | 2010-05-12 | 2011-11-16 | Ineos Europe Limited | Reaktor |
US20140171601A1 (en) * | 2012-12-13 | 2014-06-19 | Chevron Phillips Chemical Company, Lp | Polyethylene production with multiple polymerization reactors |
PT2454291E (pt) | 2010-07-30 | 2013-02-15 | Total Res & Technology Feluy | Processo de preparação de poliolefinas |
EP2598540B1 (de) * | 2010-07-30 | 2016-06-15 | Total Research & Technology Feluy | Verfahren zur herstellung von polyolefinen |
EA023514B1 (ru) * | 2010-07-30 | 2016-06-30 | Тотал Рисерч Энд Текнолоджи Фелюй | Способ получения полиэтилена в петлевом реакторе |
CN104507975B (zh) * | 2012-07-27 | 2016-06-29 | 道达尔研究技术弗吕公司 | 未配混的粒状的由茂金属制造的聚乙烯 |
US8821800B2 (en) * | 2012-10-18 | 2014-09-02 | Chevron Phillips Chemical Company Lp | System and method for catalyst preparation |
US20140140894A1 (en) * | 2012-11-20 | 2014-05-22 | Chevron Phillips Chemical Company, Lp | Polyolefin production with multiple polymerization reactors |
US9073029B2 (en) | 2013-09-25 | 2015-07-07 | Chevron Phillips Chemical Company Lp | System and method for deterring fouling in a polymerization reactor |
EA034766B1 (ru) | 2014-12-22 | 2020-03-18 | Сабик Глоубл Текнолоджиз Б.В. | Способ перехода между несовместимыми катализаторами |
JP6967073B2 (ja) | 2016-10-28 | 2021-11-17 | フイナ・テクノロジー・インコーポレーテツドFina Technology, Incorporated | Boppに応用するためのポリプロピレン中の結晶度を下げる作用剤の使用 |
US10030086B1 (en) | 2017-07-21 | 2018-07-24 | Chevron Phillips Chemical Company Lp | Methods for determining transition metal compound concentrations in multicomponent liquid systems |
US10697889B2 (en) | 2017-07-21 | 2020-06-30 | Chevron Phillips Chemical Company Lp | Methods for determining transition metal compound concentrations in multicomponent liquid systems |
US10679734B2 (en) | 2018-03-29 | 2020-06-09 | Chevron Phillips Chemical Company Lp | Methods for determining transition metal compound concentrations in multicomponent liquid systems |
US10507445B2 (en) | 2018-03-29 | 2019-12-17 | Chevron Phillips Chemical Company Lp | Methods for determining transition metal compound concentrations in multicomponent liquid systems |
US11993699B2 (en) | 2018-09-14 | 2024-05-28 | Fina Technology, Inc. | Polyethylene and controlled rheology polypropylene polymer blends and methods of use |
US11866522B2 (en) | 2018-12-28 | 2024-01-09 | Braskem S.A. | Process for introducing catalyst in a polymerization process |
JP2022522649A (ja) | 2019-02-20 | 2022-04-20 | フイナ・テクノロジー・インコーポレーテツド | 低い反りを有するポリマー組成物 |
WO2021091725A1 (en) * | 2019-11-07 | 2021-05-14 | Exxonmobil Chemical Patents Inc. | Method for controlling gas phase reactor activity |
US11180587B2 (en) | 2019-12-13 | 2021-11-23 | Chevron Phillips Chemical Company Lp | Polymerization of propylene |
EP4376994A1 (de) * | 2021-07-26 | 2024-06-05 | Univation Technologies, LLC | Verteileranordnungen für gasphasenreaktoren und verfahren zum betrieb davon |
US20240043669A1 (en) | 2022-08-04 | 2024-02-08 | Fina Technology, Inc. | Polypropylene compositions with improved clarity |
WO2024040097A1 (en) | 2022-08-16 | 2024-02-22 | Fina Technology, Inc. | Metallocene polypropylene compositions |
US20240110048A1 (en) | 2022-09-30 | 2024-04-04 | Fina Technology, Inc. | Polypropylene peroxide masterbatch |
EP4389783A1 (de) * | 2022-12-20 | 2024-06-26 | Borealis AG | Katalysatorübergangsverfahren |
EP4389776A1 (de) * | 2022-12-20 | 2024-06-26 | Borealis AG | Verfahren |
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-
2002
- 2002-11-15 US US10/295,927 patent/US6916892B2/en not_active Expired - Lifetime
- 2002-11-25 TW TW091134200A patent/TWI258483B/zh not_active IP Right Cessation
- 2002-11-26 ES ES02080132T patent/ES2238542T3/es not_active Expired - Lifetime
- 2002-11-26 EP EP05075141A patent/EP1526143B1/de not_active Expired - Lifetime
- 2002-11-26 AT AT05075141T patent/ATE402963T1/de not_active IP Right Cessation
- 2002-11-26 EP EP02080132A patent/EP1316566B1/de not_active Expired - Lifetime
- 2002-11-26 DE DE60203472T patent/DE60203472T2/de not_active Expired - Lifetime
- 2002-11-26 DE DE60228000T patent/DE60228000D1/de not_active Expired - Lifetime
- 2002-11-26 AT AT02080132T patent/ATE292149T1/de active
- 2002-11-27 MX MXPA02011729A patent/MXPA02011729A/es unknown
- 2002-11-29 JP JP2002347474A patent/JP4627965B2/ja not_active Expired - Fee Related
- 2002-12-03 CN CN02155798A patent/CN1422875A/zh active Pending
- 2002-12-03 BR BRPI0204898-1A patent/BR0204898B1/pt not_active IP Right Cessation
- 2002-12-03 KR KR1020020076364A patent/KR100920986B1/ko not_active IP Right Cessation
- 2002-12-03 CN CNA2005100939519A patent/CN1763109A/zh active Pending
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2004
- 2004-12-10 US US11/009,803 patent/US7390860B2/en not_active Expired - Fee Related
- 2004-12-10 US US11/009,234 patent/US7056991B2/en not_active Expired - Lifetime
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2008
- 2008-01-23 US US12/018,225 patent/US7960484B2/en not_active Expired - Fee Related
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Also Published As
Publication number | Publication date |
---|---|
CN1763109A (zh) | 2006-04-26 |
ATE292149T1 (de) | 2005-04-15 |
TWI258483B (en) | 2006-07-21 |
KR20030045647A (ko) | 2003-06-11 |
US20050159563A1 (en) | 2005-07-21 |
CN1422875A (zh) | 2003-06-11 |
US8710162B2 (en) | 2014-04-29 |
EP1526143A2 (de) | 2005-04-27 |
JP4627965B2 (ja) | 2011-02-09 |
US7960484B2 (en) | 2011-06-14 |
ES2238542T3 (es) | 2005-09-01 |
US6916892B2 (en) | 2005-07-12 |
EP1316566B1 (de) | 2005-03-30 |
BR0204898A (pt) | 2004-06-15 |
JP2003192717A (ja) | 2003-07-09 |
US7056991B2 (en) | 2006-06-06 |
EP1316566A2 (de) | 2003-06-04 |
BR0204898B1 (pt) | 2011-12-27 |
TW200300765A (en) | 2003-06-16 |
US20030114608A1 (en) | 2003-06-19 |
US20080114135A1 (en) | 2008-05-15 |
EP1526143B1 (de) | 2008-07-30 |
ATE402963T1 (de) | 2008-08-15 |
US20110207898A1 (en) | 2011-08-25 |
EP1316566A3 (de) | 2003-07-09 |
DE60203472T2 (de) | 2006-04-27 |
US20050165181A1 (en) | 2005-07-28 |
KR100920986B1 (ko) | 2009-10-09 |
EP1526143A3 (de) | 2005-09-28 |
MXPA02011729A (es) | 2003-09-22 |
US7390860B2 (en) | 2008-06-24 |
DE60203472D1 (de) | 2005-05-04 |
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