DE19739773A1 - Verfahren und Katalysator zur Dampfreformierung von Methanol - Google Patents

Verfahren und Katalysator zur Dampfreformierung von Methanol

Info

Publication number
DE19739773A1
DE19739773A1 DE19739773A DE19739773A DE19739773A1 DE 19739773 A1 DE19739773 A1 DE 19739773A1 DE 19739773 A DE19739773 A DE 19739773A DE 19739773 A DE19739773 A DE 19739773A DE 19739773 A1 DE19739773 A1 DE 19739773A1
Authority
DE
Germany
Prior art keywords
range
catalyst
salts
oxides
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE19739773A
Other languages
German (de)
English (en)
Inventor
Otto Dr Kumberger
Michael Jolyon Dr Sprague
Otto Hofstadt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DE19739773A priority Critical patent/DE19739773A1/de
Priority to DE59802308T priority patent/DE59802308D1/de
Priority to US09/149,440 priority patent/US6051163A/en
Priority to DK98117210T priority patent/DK0901982T3/da
Priority to EP98117210A priority patent/EP0901982B1/de
Priority to JP25730298A priority patent/JP4062647B2/ja
Publication of DE19739773A1 publication Critical patent/DE19739773A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • C01B3/326—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
    • Y10S502/524—Spinel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
DE19739773A 1997-09-10 1997-09-10 Verfahren und Katalysator zur Dampfreformierung von Methanol Withdrawn DE19739773A1 (de)

Priority Applications (6)

Application Number Priority Date Filing Date Title
DE19739773A DE19739773A1 (de) 1997-09-10 1997-09-10 Verfahren und Katalysator zur Dampfreformierung von Methanol
DE59802308T DE59802308D1 (de) 1997-09-10 1998-09-09 Verfahren und Katalysator zur Dampfreformierung von Methanol
US09/149,440 US6051163A (en) 1997-09-10 1998-09-09 Catalyst for steam-reforming methanol
DK98117210T DK0901982T3 (da) 1997-09-10 1998-09-09 Fremgangsmåde og katalysator til vanddampreformering af methanol
EP98117210A EP0901982B1 (de) 1997-09-10 1998-09-09 Verfahren und Katalysator zur Dampfreformierung von Methanol
JP25730298A JP4062647B2 (ja) 1997-09-10 1998-09-10 メタノールをスチーム改質するための触媒

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19739773A DE19739773A1 (de) 1997-09-10 1997-09-10 Verfahren und Katalysator zur Dampfreformierung von Methanol

Publications (1)

Publication Number Publication Date
DE19739773A1 true DE19739773A1 (de) 1999-03-11

Family

ID=7841897

Family Applications (2)

Application Number Title Priority Date Filing Date
DE19739773A Withdrawn DE19739773A1 (de) 1997-09-10 1997-09-10 Verfahren und Katalysator zur Dampfreformierung von Methanol
DE59802308T Expired - Lifetime DE59802308D1 (de) 1997-09-10 1998-09-09 Verfahren und Katalysator zur Dampfreformierung von Methanol

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE59802308T Expired - Lifetime DE59802308D1 (de) 1997-09-10 1998-09-09 Verfahren und Katalysator zur Dampfreformierung von Methanol

Country Status (5)

Country Link
US (1) US6051163A (enExample)
EP (1) EP0901982B1 (enExample)
JP (1) JP4062647B2 (enExample)
DE (2) DE19739773A1 (enExample)
DK (1) DK0901982T3 (enExample)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1238701A1 (de) * 2001-03-08 2002-09-11 Basf Aktiengesellschaft Methanolreformierungskatalysator mit verringertem Volumenschwund
US6919066B2 (en) 2001-03-08 2005-07-19 Basf Aktiengesellschaft Preparation of catalysts having low volume shrinkage
EP1733448A4 (en) * 2004-03-30 2009-02-18 California Inst Of Techn DIRECT-ALCOHOL FUEL CELLS WITH FLEECE-ACID ELECTROLYTES
CN113198471A (zh) * 2021-05-21 2021-08-03 晋中学院 一种甲醇重整制氢的铜铝尖晶石催化剂及其制法和应用
CN116199250A (zh) * 2022-12-29 2023-06-02 广西民族师范学院 一种高纯绿铜锌矿Cu2Zn3(OH)6(CO3)2的制备方法及其应用
WO2023213583A1 (en) 2022-05-02 2023-11-09 Basf Se Synthetic methanol having low deuterium content from non-fossil resources
EP4446302A1 (en) 2023-04-12 2024-10-16 Basf Se Synthetic vinyl acetate having low deuterium content from non-fossil resources
WO2024213626A1 (en) 2023-04-12 2024-10-17 Basf Se Vinyl acetate having low deuterium content
WO2025016799A1 (de) 2023-07-17 2025-01-23 Basf Se Neue kühlmittelzusammensetzungen
EP4553060A1 (en) 2023-11-09 2025-05-14 Basf Se Vinyl acetate having a natural abundance of carbon-14 from non-fossil resources
WO2025109158A1 (en) 2023-11-23 2025-05-30 Basf Se Process for the chemical recycling of plastic waste containing polyethylene or polypropylene

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JP3624722B2 (ja) 1998-11-18 2005-03-02 本田技研工業株式会社 メタノール改質触媒及びそれを用いたメタノール改質触媒装置
DE59900542D1 (de) * 1999-05-22 2002-01-24 Omg Ag & Co Kg Verwendung eines Katalysators für die Dampfreformierung von Methanol
JP2001185190A (ja) * 1999-12-28 2001-07-06 Mitsubishi Gas Chem Co Inc 燃料電池用水素の製造方法
JP2001185192A (ja) * 1999-12-28 2001-07-06 Mitsubishi Gas Chem Co Inc 燃料電池用水素の製造方法
JP3482459B2 (ja) * 2000-03-06 2003-12-22 独立行政法人産業技術総合研究所 メタノールの部分酸化反応による水素製造触媒及びその製造法
WO2001078892A1 (en) * 2000-04-19 2001-10-25 Osaka Gas Co., Ltd. Method for preparing catalyst for reforming methanol
JP3496051B2 (ja) * 2000-06-07 2004-02-09 独立行政法人産業技術総合研究所 メタノールの酸化的水蒸気改質反応による水素ガス製造触媒及びその製造法
WO2001098202A1 (es) * 2000-06-22 2001-12-27 Consejo Superior De Investigaciones Cientificas Procedimiento para la obtención de hidrógeno por oxidación parcial de metanol
KR100400591B1 (ko) * 2000-07-18 2003-10-08 미쯔이카가쿠 가부시기가이샤 메탄올의 수증기개질촉매 및 그것을 이용한 수소제조법
JP2002079100A (ja) * 2000-09-08 2002-03-19 Hiroshima Industrial Technology Organization メタノール水蒸気改質用球状微粒子触媒前駆体並びにメタノール水蒸気改質用球状微粒子触媒及びその製造方法
JP2002079101A (ja) * 2000-09-08 2002-03-19 Hiroshima Industrial Technology Organization メタノール水蒸気改質用触媒前駆体並びにメタノール水蒸気改質用触媒及びその製造方法
US7470294B2 (en) * 2001-06-29 2008-12-30 Plug Power Inc. Fuel processor design and method of manufacture
US7470648B2 (en) * 2002-02-13 2008-12-30 Battelle Memorial Institute Reforming catalysts
US6693057B1 (en) * 2002-03-22 2004-02-17 Sud-Chemie Inc. Water gas shift catalyst
US6627572B1 (en) * 2002-03-22 2003-09-30 Sud-Chemie Inc. Water gas shift catalyst
FR2852531B1 (fr) * 2003-03-17 2007-06-01 Procede de preparation d'un catalyseur a base d'aluminate de zinc et catalyseur obtenu
US7208136B2 (en) * 2003-05-16 2007-04-24 Battelle Memorial Institute Alcohol steam reforming catalysts and methods of alcohol steam reforming
JP4774197B2 (ja) * 2003-05-20 2011-09-14 出光興産株式会社 酸素含有炭化水素の改質触媒、それを用いた水素又は合成ガスの製造方法及び燃料電池システム
US20040266615A1 (en) * 2003-06-25 2004-12-30 Watson Junko M. Catalyst support and steam reforming catalyst
EP1533271B1 (en) * 2003-11-22 2013-01-09 Haldor Topsoe A/S Process for the preparation of hydrogen or synthesis gas
US20050226808A1 (en) * 2004-04-12 2005-10-13 King Fahd University Of Petroleum And Minerals Laser photo-catalytic process for the production of hydrogen
CA2569366A1 (en) * 2004-06-10 2005-12-29 California Institute Of Technology Processing techniques for the fabrication of solid acid fuel cell membrane electrode assemblies
US7255962B2 (en) * 2004-07-01 2007-08-14 California Institute Of Technology Eulytite solid acid electrolytes for electrochemical devices
US7749376B2 (en) * 2005-08-15 2010-07-06 Sud-Chemie Inc. Process for sulfur adsorption using copper-containing catalyst
JP4772561B2 (ja) * 2006-03-31 2011-09-14 株式会社東芝 メタノール改質触媒、シフト触媒、メタノール改質触媒の製造方法およびシフト触媒の製造方法
TWI462777B (zh) * 2009-10-30 2014-12-01 Atomic Energy Council 合成甲醇及二甲醚之Ｃｕ－Ｚｎ－Ａｌ觸媒製備方法
JP2011194362A (ja) * 2010-03-23 2011-10-06 Idemitsu Kosan Co Ltd 一酸化炭素転換用触媒の製造方法
CN102179251B (zh) * 2011-03-17 2013-01-30 清华大学 流化床合成甲醇用催化剂及其制备方法
GB201111781D0 (en) * 2011-07-08 2011-08-24 Isis Innovation Stream reforming of methanol
WO2018141694A1 (de) 2017-01-31 2018-08-09 Basf Se Verfahren zur passivierung eines katalysators
CN110637003B (zh) 2017-05-16 2022-11-04 巴斯夫欧洲公司 用于醛和/或醇的大规模制备的氢甲酰化方法
CN110841684B (zh) * 2019-11-25 2022-12-13 山东科技大学 一种甲醇水蒸气重整制氢催化剂用于甲醇水蒸气重整制氢
CN114192151B (zh) * 2021-12-03 2024-02-09 宁波中科科创新能源科技有限公司 Pcvd法合成的甲醇水蒸气重整制氢催化剂及其制备方法
CN116216639A (zh) * 2021-12-06 2023-06-06 中国科学院大连化学物理研究所 一种甲醇的蒸汽重整制氢的方法
CN114870859A (zh) * 2022-04-13 2022-08-09 宁波中科科创新能源科技有限公司 铜基甲醇水蒸气重整制氢催化剂及其制备方法

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GB1405012A (en) * 1972-01-21 1975-09-03 Ici Ltd Method of making composition convertible to a catalyst precursor and catalyst and methanol synthesis using the catalyst
JPS58193738A (ja) * 1982-05-06 1983-11-11 Mitsubishi Heavy Ind Ltd 水素富化ガス製造用触媒
JPS59152205A (ja) * 1983-02-14 1984-08-30 Mitsubishi Gas Chem Co Inc メタノ−ルの水蒸気改質法
FR2558738B1 (fr) * 1984-01-27 1987-11-13 Inst Francais Du Petrole Procede de fabrication de catalyseurs contenant du cuivre, du zinc et de l'aluminium, utilisables pour la production de methanol a partir de gaz de synthese
JP2634247B2 (ja) * 1989-07-20 1997-07-23 三菱重工業株式会社 メタノール水蒸気改質用触媒の調製方法
JP2535760B2 (ja) * 1993-07-07 1996-09-18 工業技術院長 メタノ―ルの水蒸気改質用触媒の製造方法
DE19534434C1 (de) * 1995-09-16 1997-03-06 Daimler Benz Ag Katalysator für einen Methanolreformierungsreaktor und Verfahren zu dessen Herstellung

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1238701A1 (de) * 2001-03-08 2002-09-11 Basf Aktiengesellschaft Methanolreformierungskatalysator mit verringertem Volumenschwund
US6919066B2 (en) 2001-03-08 2005-07-19 Basf Aktiengesellschaft Preparation of catalysts having low volume shrinkage
EP1733448A4 (en) * 2004-03-30 2009-02-18 California Inst Of Techn DIRECT-ALCOHOL FUEL CELLS WITH FLEECE-ACID ELECTROLYTES
CN113198471A (zh) * 2021-05-21 2021-08-03 晋中学院 一种甲醇重整制氢的铜铝尖晶石催化剂及其制法和应用
WO2023213583A1 (en) 2022-05-02 2023-11-09 Basf Se Synthetic methanol having low deuterium content from non-fossil resources
CN116199250A (zh) * 2022-12-29 2023-06-02 广西民族师范学院 一种高纯绿铜锌矿Cu2Zn3(OH)6(CO3)2的制备方法及其应用
EP4446302A1 (en) 2023-04-12 2024-10-16 Basf Se Synthetic vinyl acetate having low deuterium content from non-fossil resources
WO2024213626A1 (en) 2023-04-12 2024-10-17 Basf Se Vinyl acetate having low deuterium content
WO2025016799A1 (de) 2023-07-17 2025-01-23 Basf Se Neue kühlmittelzusammensetzungen
EP4553060A1 (en) 2023-11-09 2025-05-14 Basf Se Vinyl acetate having a natural abundance of carbon-14 from non-fossil resources
WO2025109158A1 (en) 2023-11-23 2025-05-30 Basf Se Process for the chemical recycling of plastic waste containing polyethylene or polypropylene

Also Published As

Publication number Publication date
DE59802308D1 (de) 2002-01-17
JPH11169714A (ja) 1999-06-29
DK0901982T3 (da) 2002-03-04
EP0901982B1 (de) 2001-12-05
JP4062647B2 (ja) 2008-03-19
EP0901982A1 (de) 1999-03-17
US6051163A (en) 2000-04-18

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