JP4062647B2 - メタノールをスチーム改質するための触媒 - Google Patents
メタノールをスチーム改質するための触媒 Download PDFInfo
- Publication number
- JP4062647B2 JP4062647B2 JP25730298A JP25730298A JP4062647B2 JP 4062647 B2 JP4062647 B2 JP 4062647B2 JP 25730298 A JP25730298 A JP 25730298A JP 25730298 A JP25730298 A JP 25730298A JP 4062647 B2 JP4062647 B2 JP 4062647B2
- Authority
- JP
- Japan
- Prior art keywords
- precipitate
- solution
- alkali metal
- catalyst
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims description 75
- 239000003054 catalyst Substances 0.000 title claims description 73
- 238000000629 steam reforming Methods 0.000 title claims description 11
- 239000000243 solution Substances 0.000 claims description 56
- 239000011701 zinc Substances 0.000 claims description 40
- 239000002244 precipitate Substances 0.000 claims description 39
- 239000010949 copper Substances 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 18
- 150000003751 zinc Chemical class 0.000 claims description 16
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 15
- 150000008041 alkali metal carbonates Chemical class 0.000 claims description 15
- 238000001354 calcination Methods 0.000 claims description 14
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- -1 platinum group metals Chemical class 0.000 claims description 13
- 150000003839 salts Chemical class 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
- 150000001879 copper Chemical class 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 9
- 229910002651 NO3 Inorganic materials 0.000 claims description 8
- 150000002602 lanthanoids Chemical group 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate group Chemical group [N+](=O)([O-])[O-] NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- 239000003929 acidic solution Substances 0.000 claims description 7
- 229910001413 alkali metal ion Inorganic materials 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 7
- 230000000737 periodic effect Effects 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 229910052747 lanthanoid Inorganic materials 0.000 claims description 5
- 239000012266 salt solution Substances 0.000 claims description 5
- 238000001651 catalytic steam reforming of methanol Methods 0.000 claims description 3
- 238000001556 precipitation Methods 0.000 description 29
- 239000000203 mixture Substances 0.000 description 17
- 230000000694 effects Effects 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 11
- 229910052725 zinc Inorganic materials 0.000 description 11
- 229910017518 Cu Zn Inorganic materials 0.000 description 10
- 229910017752 Cu-Zn Inorganic materials 0.000 description 10
- 229910017943 Cu—Zn Inorganic materials 0.000 description 10
- 229910052802 copper Inorganic materials 0.000 description 10
- 229910007570 Zn-Al Inorganic materials 0.000 description 9
- 229910052596 spinel Inorganic materials 0.000 description 9
- 239000011029 spinel Substances 0.000 description 9
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 8
- 239000000725 suspension Substances 0.000 description 8
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 8
- 101150002998 LCAT gene Proteins 0.000 description 7
- 229910017773 Cu-Zn-Al Inorganic materials 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical class [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
- 239000011787 zinc oxide Substances 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
- 239000000306 component Substances 0.000 description 4
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910017604 nitric acid Inorganic materials 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000002407 reforming Methods 0.000 description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- 241000907663 Siproeta stelenes Species 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000012018 catalyst precursor Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- WMWXXXSCZVGQAR-UHFFFAOYSA-N dialuminum;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3] WMWXXXSCZVGQAR-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000002815 homogeneous catalyst Substances 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000004690 nonahydrates Chemical class 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- GWBUNZLLLLDXMD-UHFFFAOYSA-H tricopper;dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[O-]C([O-])=O.[O-]C([O-])=O GWBUNZLLLLDXMD-UHFFFAOYSA-H 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
- MQWLIFWNJWLDCI-UHFFFAOYSA-L zinc;carbonate;hydrate Chemical compound O.[Zn+2].[O-]C([O-])=O MQWLIFWNJWLDCI-UHFFFAOYSA-L 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
- C01B3/326—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1076—Copper or zinc-based catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
- Y10S502/524—Spinel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19739773A DE19739773A1 (de) | 1997-09-10 | 1997-09-10 | Verfahren und Katalysator zur Dampfreformierung von Methanol |
| DE19739773.5 | 1997-09-10 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH11169714A JPH11169714A (ja) | 1999-06-29 |
| JPH11169714A5 JPH11169714A5 (enExample) | 2005-10-13 |
| JP4062647B2 true JP4062647B2 (ja) | 2008-03-19 |
Family
ID=7841897
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP25730298A Expired - Fee Related JP4062647B2 (ja) | 1997-09-10 | 1998-09-10 | メタノールをスチーム改質するための触媒 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US6051163A (enExample) |
| EP (1) | EP0901982B1 (enExample) |
| JP (1) | JP4062647B2 (enExample) |
| DE (2) | DE19739773A1 (enExample) |
| DK (1) | DK0901982T3 (enExample) |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3624722B2 (ja) | 1998-11-18 | 2005-03-02 | 本田技研工業株式会社 | メタノール改質触媒及びそれを用いたメタノール改質触媒装置 |
| EP1063011B1 (de) * | 1999-05-22 | 2001-12-12 | OMG AG & Co. KG | Verwendung eines Katalysators für die Dampfreformierung von Methanol |
| JP2001185190A (ja) * | 1999-12-28 | 2001-07-06 | Mitsubishi Gas Chem Co Inc | 燃料電池用水素の製造方法 |
| JP2001185192A (ja) * | 1999-12-28 | 2001-07-06 | Mitsubishi Gas Chem Co Inc | 燃料電池用水素の製造方法 |
| JP3482459B2 (ja) * | 2000-03-06 | 2003-12-22 | 独立行政法人産業技術総合研究所 | メタノールの部分酸化反応による水素製造触媒及びその製造法 |
| WO2001078892A1 (en) * | 2000-04-19 | 2001-10-25 | Osaka Gas Co., Ltd. | Method for preparing catalyst for reforming methanol |
| JP3496051B2 (ja) * | 2000-06-07 | 2004-02-09 | 独立行政法人産業技術総合研究所 | メタノールの酸化的水蒸気改質反応による水素ガス製造触媒及びその製造法 |
| EP1298089B1 (en) * | 2000-06-22 | 2005-01-19 | Consejo Superior De Investigaciones Cientificas | Method for obtaining hydrogen by partial methanol oxidation |
| KR100400591B1 (ko) * | 2000-07-18 | 2003-10-08 | 미쯔이카가쿠 가부시기가이샤 | 메탄올의 수증기개질촉매 및 그것을 이용한 수소제조법 |
| JP2002079100A (ja) * | 2000-09-08 | 2002-03-19 | Hiroshima Industrial Technology Organization | メタノール水蒸気改質用球状微粒子触媒前駆体並びにメタノール水蒸気改質用球状微粒子触媒及びその製造方法 |
| JP2002079101A (ja) * | 2000-09-08 | 2002-03-19 | Hiroshima Industrial Technology Organization | メタノール水蒸気改質用触媒前駆体並びにメタノール水蒸気改質用触媒及びその製造方法 |
| DE10111197A1 (de) | 2001-03-08 | 2002-09-19 | Basf Ag | Verfahren zur Herstellung von Katalysatoren mit geringem Volumenschwund |
| DE10111198A1 (de) * | 2001-03-08 | 2002-09-19 | Basf Ag | Methanolreformierungskatalysator mit verringertem Volumenschwund |
| US7470294B2 (en) * | 2001-06-29 | 2008-12-30 | Plug Power Inc. | Fuel processor design and method of manufacture |
| US7470648B2 (en) * | 2002-02-13 | 2008-12-30 | Battelle Memorial Institute | Reforming catalysts |
| US6693057B1 (en) * | 2002-03-22 | 2004-02-17 | Sud-Chemie Inc. | Water gas shift catalyst |
| US6627572B1 (en) * | 2002-03-22 | 2003-09-30 | Sud-Chemie Inc. | Water gas shift catalyst |
| FR2852531B1 (fr) * | 2003-03-17 | 2007-06-01 | Procede de preparation d'un catalyseur a base d'aluminate de zinc et catalyseur obtenu | |
| US7208136B2 (en) * | 2003-05-16 | 2007-04-24 | Battelle Memorial Institute | Alcohol steam reforming catalysts and methods of alcohol steam reforming |
| JP4774197B2 (ja) * | 2003-05-20 | 2011-09-14 | 出光興産株式会社 | 酸素含有炭化水素の改質触媒、それを用いた水素又は合成ガスの製造方法及び燃料電池システム |
| US7722854B2 (en) * | 2003-06-25 | 2010-05-25 | Velocy's | Steam reforming methods and catalysts |
| EP1533271B1 (en) * | 2003-11-22 | 2013-01-09 | Haldor Topsoe A/S | Process for the preparation of hydrogen or synthesis gas |
| CN100492740C (zh) * | 2004-03-30 | 2009-05-27 | 加利福尼亚技术学院 | 使用固体酸电解质的直接醇类燃料电池 |
| US20050226808A1 (en) * | 2004-04-12 | 2005-10-13 | King Fahd University Of Petroleum And Minerals | Laser photo-catalytic process for the production of hydrogen |
| CN100595950C (zh) * | 2004-06-10 | 2010-03-24 | 加利福尼亚技术学院 | 制造固体酸燃料电池膜电极组件的生产工艺 |
| US7255962B2 (en) * | 2004-07-01 | 2007-08-14 | California Institute Of Technology | Eulytite solid acid electrolytes for electrochemical devices |
| US7749376B2 (en) * | 2005-08-15 | 2010-07-06 | Sud-Chemie Inc. | Process for sulfur adsorption using copper-containing catalyst |
| JP4772561B2 (ja) * | 2006-03-31 | 2011-09-14 | 株式会社東芝 | メタノール改質触媒、シフト触媒、メタノール改質触媒の製造方法およびシフト触媒の製造方法 |
| TWI462777B (zh) * | 2009-10-30 | 2014-12-01 | Atomic Energy Council | 合成甲醇及二甲醚之Ｃｕ－Ｚｎ－Ａｌ觸媒製備方法 |
| JP2011194362A (ja) * | 2010-03-23 | 2011-10-06 | Idemitsu Kosan Co Ltd | 一酸化炭素転換用触媒の製造方法 |
| CN102179251B (zh) * | 2011-03-17 | 2013-01-30 | 清华大学 | 流化床合成甲醇用催化剂及其制备方法 |
| GB201111781D0 (en) * | 2011-07-08 | 2011-08-24 | Isis Innovation | Stream reforming of methanol |
| WO2018141694A1 (de) | 2017-01-31 | 2018-08-09 | Basf Se | Verfahren zur passivierung eines katalysators |
| EP3625199B1 (de) | 2017-05-16 | 2021-09-22 | Basf Se | Hydroformylierungsverfahren dienend der grosstechnischen herstellung von aldehyden und/oder alkoholen |
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Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1296212A (enExample) * | 1969-03-04 | 1972-11-15 | ||
| GB1405012A (en) * | 1972-01-21 | 1975-09-03 | Ici Ltd | Method of making composition convertible to a catalyst precursor and catalyst and methanol synthesis using the catalyst |
| JPS58193738A (ja) * | 1982-05-06 | 1983-11-11 | Mitsubishi Heavy Ind Ltd | 水素富化ガス製造用触媒 |
| JPS59152205A (ja) * | 1983-02-14 | 1984-08-30 | Mitsubishi Gas Chem Co Inc | メタノ−ルの水蒸気改質法 |
| FR2558738B1 (fr) | 1984-01-27 | 1987-11-13 | Inst Francais Du Petrole | Procede de fabrication de catalyseurs contenant du cuivre, du zinc et de l'aluminium, utilisables pour la production de methanol a partir de gaz de synthese |
| JP2634247B2 (ja) * | 1989-07-20 | 1997-07-23 | 三菱重工業株式会社 | メタノール水蒸気改質用触媒の調製方法 |
| JP2535760B2 (ja) * | 1993-07-07 | 1996-09-18 | 工業技術院長 | メタノ―ルの水蒸気改質用触媒の製造方法 |
| DE19534434C1 (de) * | 1995-09-16 | 1997-03-06 | Daimler Benz Ag | Katalysator für einen Methanolreformierungsreaktor und Verfahren zu dessen Herstellung |
-
1997
- 1997-09-10 DE DE19739773A patent/DE19739773A1/de not_active Withdrawn
-
1998
- 1998-09-09 DE DE59802308T patent/DE59802308D1/de not_active Expired - Lifetime
- 1998-09-09 US US09/149,440 patent/US6051163A/en not_active Expired - Lifetime
- 1998-09-09 DK DK98117210T patent/DK0901982T3/da active
- 1998-09-09 EP EP98117210A patent/EP0901982B1/de not_active Expired - Lifetime
- 1998-09-10 JP JP25730298A patent/JP4062647B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0901982B1 (de) | 2001-12-05 |
| DE19739773A1 (de) | 1999-03-11 |
| DK0901982T3 (da) | 2002-03-04 |
| US6051163A (en) | 2000-04-18 |
| EP0901982A1 (de) | 1999-03-17 |
| DE59802308D1 (de) | 2002-01-17 |
| JPH11169714A (ja) | 1999-06-29 |
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