DE1542529A1 - Verfahren zur Herstellung von Katalysatoren zur stereospezifischen Polymerisation konjungierter Diolefine - Google Patents

Verfahren zur Herstellung von Katalysatoren zur stereospezifischen Polymerisation konjungierter Diolefine

Info

Publication number
DE1542529A1
DE1542529A1 DE19641542529 DE1542529A DE1542529A1 DE 1542529 A1 DE1542529 A1 DE 1542529A1 DE 19641542529 DE19641542529 DE 19641542529 DE 1542529 A DE1542529 A DE 1542529A DE 1542529 A1 DE1542529 A1 DE 1542529A1
Authority
DE
Germany
Prior art keywords
cerium
catalyst
aluminum
iii
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19641542529
Other languages
German (de)
English (en)
Inventor
Von Dohlen Werner Claus
Caflisch Edward George
Wilson Thomas Putnam
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of DE1542529A1 publication Critical patent/DE1542529A1/de
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/37—Lanthanum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/38—Lanthanides other than lanthanum

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE19641542529 1963-02-28 1964-02-26 Verfahren zur Herstellung von Katalysatoren zur stereospezifischen Polymerisation konjungierter Diolefine Pending DE1542529A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US261875A US3297667A (en) 1963-02-28 1963-02-28 Production of cis-1, 4-polydienes by polymerization of 1, 3-dienes

Publications (1)

Publication Number Publication Date
DE1542529A1 true DE1542529A1 (de) 1970-07-23

Family

ID=22995253

Family Applications (2)

Application Number Title Priority Date Filing Date
DE19641542529 Pending DE1542529A1 (de) 1963-02-28 1964-02-26 Verfahren zur Herstellung von Katalysatoren zur stereospezifischen Polymerisation konjungierter Diolefine
DE19641302264D Pending DE1302264B (forum.php) 1963-02-28 1964-02-26

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE19641302264D Pending DE1302264B (forum.php) 1963-02-28 1964-02-26

Country Status (6)

Country Link
US (1) US3297667A (forum.php)
BE (1) BE644291A (forum.php)
DE (2) DE1542529A1 (forum.php)
FR (1) FR1390509A (forum.php)
GB (1) GB1061002A (forum.php)
NL (1) NL6401996A (forum.php)

Families Citing this family (73)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1030932A (en) * 1963-10-30 1966-05-25 Mitsui Chemical Ind Co Ltd Method for polymerizing conjugated diolefines
IT1085663B (it) 1977-08-01 1985-05-28 Snam Progetti Procedimento per la polimerizzazione e copolimerizzazione di diolefine e mezzi adatti allo scopo
DE2848964A1 (de) * 1978-11-11 1980-05-22 Bayer Ag Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien
IT1151542B (it) * 1982-04-15 1986-12-24 Anic Spa Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo
US4556647A (en) * 1984-09-13 1985-12-03 Phillips Petroleum Company Olefin polymerization
US4544718A (en) * 1984-09-13 1985-10-01 Phillips Petroleum Company Olefin polymerization
US4575538A (en) * 1984-12-20 1986-03-11 Phillips Petroleum Company Olefin polymerization
DE4334045A1 (de) * 1993-10-06 1995-04-13 Bayer Ag Katalysator, dessen Herstellung und Verwendung zur Gasphasenpolymerisation von konjugierten Dienen
DE19512116A1 (de) * 1995-04-04 1996-10-10 Bayer Ag Gasphasenpolymerisation von konjugierten Dienen in Gegenwart von Allylverbindungen der seltenen Erden
US6001478A (en) * 1997-08-08 1999-12-14 Union Carbide Chemicals & Plastics Technology Corporation Resin particle produced by diene polymerization with rare earth and transition metal catalysts
DE19806931A1 (de) * 1998-02-19 1999-08-26 Bayer Ag Verfahren zur Herstellung von Polydienen mit geregelter Mooney-Viskosität
WO2000059955A1 (fr) * 1999-04-06 2000-10-12 Mitsui Chemicals, Incorporated Catalyseur de polymerisation, nouveau compose de metaux de transition, procede de polymerisation et copolymere dans lequel ils sont utilises
US6992147B1 (en) * 1999-11-12 2006-01-31 Bridgestone Corporation Modified polymers prepared with lanthanide-based catalysts
US6977281B1 (en) * 1999-11-12 2005-12-20 Bridgestone Corporation Modified polymers prepared with lanthanide-based catalysts
ES2412979T3 (es) 2000-11-10 2013-07-15 Bridgestone Corporation Cis-1,4-polibutadieno altamente funcionalizado preparado usando nuevos agentes de funcionalización
DE10135314A1 (de) * 2001-07-19 2003-01-30 Bayer Ag Aufarbeitung von Polymersyntheselösungen
US9226876B2 (en) * 2001-10-19 2016-01-05 The Goodyear Tire & Rubber Company Rubber for baby bottle nipples, pacifiers, and syringe plungers
US6871751B2 (en) * 2001-10-19 2005-03-29 The Goodyear Tire & Rubber Company Rubber for baby bottle nipples, pacifiers, & syringe plungers
US6699813B2 (en) 2001-11-07 2004-03-02 Bridgestone Corporation Lanthanide-based catalyst composition for the manufacture of polydienes
US6780948B2 (en) 2002-03-28 2004-08-24 The Goodyear Tire & Rubber Company Synthesis of polyisoprene with neodymium catalyst
US7008899B2 (en) * 2003-08-11 2006-03-07 Bridgestone Corporation Lanthanide-based catalyst composition for producing cis-1,4-polydienes
US7094849B2 (en) * 2003-12-15 2006-08-22 Bridgestone Corporation Bulk polymerization process for producing polydienes
US7091150B2 (en) * 2003-12-19 2006-08-15 The Goodyear Tire & Rubber Company Synthetic polyisoprene rubber
JP5111101B2 (ja) 2004-03-02 2012-12-26 株式会社ブリヂストン バルク重合プロセス
DE102004022676A1 (de) * 2004-05-07 2005-12-15 Bayer Ag Hydrierte Copolymerisate aus nicht substituierten und substituierten konjugierten Dienen
JP4294011B2 (ja) * 2004-07-21 2009-07-08 日信工業株式会社 炭素系材料及びその製造方法、複合材料の製造方法
JP4279220B2 (ja) * 2004-09-09 2009-06-17 日信工業株式会社 複合材料及びその製造方法、複合金属材料及びその製造方法
US7879952B2 (en) * 2005-12-28 2011-02-01 Bridgestone Corporation Functionalized polymers
US7671138B2 (en) * 2006-05-26 2010-03-02 Bridgestone Corporation Polymers functionized with hydrobenzamides
US20080006833A1 (en) * 2006-06-02 2008-01-10 Semiconductor Energy Laboratory Co., Ltd. Lighting device and liquid crystal display device
JP2007323544A (ja) * 2006-06-05 2007-12-13 Sony Corp 情報処理システム、情報処理装置、および方法、並びにコンピュータ・プログラム
US7795354B2 (en) 2006-06-16 2010-09-14 Georgia-Pacific Chemicals Llc Formaldehyde free binder
US7732534B2 (en) * 2006-08-28 2010-06-08 Bridgestone Corporation Polymers functionalized with nitro compounds
US8088868B2 (en) 2006-12-19 2012-01-03 Bridgestone Corporation Polymers functionalized with protected oxime compounds
US7879958B2 (en) * 2007-08-07 2011-02-01 Bridgestone Corporation Polyhydroxy compounds as polymerization quenching agents
US7825201B2 (en) * 2007-12-31 2010-11-02 Bridgestone Corporation Process for producing polydienes
US8268933B2 (en) * 2007-12-31 2012-09-18 Bridgestone Corporation Polymers functionalized with polyimine compounds
US7741418B2 (en) * 2007-12-31 2010-06-22 Bridgestone Corporation Process for producing polydienes
RU2515980C2 (ru) * 2007-12-31 2014-05-20 Бриджстоун Корпорейшн Способ получения полидиенов полимеризацией в объеме
US7807763B2 (en) 2008-04-07 2010-10-05 Bridgestone Corporation Method for bulk polymerization
US7906592B2 (en) * 2008-07-03 2011-03-15 Bridgestone Corporation Polymers functionalized with imide compounds containing a protected amino group
US8188195B2 (en) 2008-12-31 2012-05-29 Bridgestone Corporation Polymers functionalized with nitroso compounds
EP2382240B1 (en) 2009-01-23 2014-04-16 Bridgestone Corporation Polymers functionalized with nitrile compounds containing a protected amino group
US8785566B2 (en) 2009-01-23 2014-07-22 Bridgestone Corporation Polymers functionalized with polycyano compounds
US7902309B2 (en) 2009-02-23 2011-03-08 Bridgestone Corporation Process and catalyst system for polydiene production
FR2944800B1 (fr) * 2009-04-28 2012-10-26 Michelin Soc Tech Systemes catalytiques a base d'un complexe de terres rares pour la polymerisation stereospecifique des dienes conjugues
US8623975B2 (en) 2009-06-24 2014-01-07 Bridgestone Corporation Process for producing polydienes
WO2011047021A1 (en) 2009-10-14 2011-04-21 Bridgestone Corporation Processes for preparation of cyclic acyclic diene copolymer and rubber composition
US8338544B2 (en) * 2009-12-21 2012-12-25 Bridgestone Corporation Polymers functionalized with polyoxime compounds and methods for their manufacture
RU2692101C2 (ru) 2010-09-23 2019-06-21 Бриджстоун Корпорейшн Способ получения полидиенов
US8748531B2 (en) 2010-12-10 2014-06-10 Bridgestone Corporation Polymers functionalized with oxime compounds containing an acyl group
US9000107B2 (en) 2011-01-31 2015-04-07 Bridgestone Corporation Process for producing polydienes
US8962766B2 (en) 2011-09-15 2015-02-24 Bridgestone Corporation Polymers functionalized with polyhydrazone compounds
CN104039843B (zh) 2011-11-17 2016-05-18 株式会社普利司通 制备聚二烯的方法
SG11201404817VA (en) 2012-02-27 2014-09-26 Bridgestone Corp Processes for the preparation of high-cis polydienes
US8685513B1 (en) 2012-02-29 2014-04-01 Carolyn M. Dry Inflatable articles comprising a self-repairing laminate
US9694629B1 (en) 2012-02-29 2017-07-04 Carolyn Dry Self-repairing inflatable articles incorporating an integrated self-repair system
WO2013138270A1 (en) 2012-03-14 2013-09-19 Bridgestsone Corporation Process for producing polydienes
JP6069044B2 (ja) * 2013-03-12 2017-01-25 住友ゴム工業株式会社 ベーストレッド用ゴム組成物及び空気入りタイヤ
EP3077455B1 (en) 2013-12-03 2020-08-12 Bridgestone Corporation Process for preparing blends of cis-1,4-polybutadiene and syndiotactic 1,2-polybutadiene
TWI522378B (zh) 2013-12-13 2016-02-21 奇美實業股份有限公司 改質的高順式丁二烯－異戊二烯系共聚物、其製造方法及含有前述聚合物的輪胎
TWI508979B (zh) 2013-12-18 2015-11-21 Chi Mei Corp 改質的高順式異戊二烯聚合物、其製造方法及含有前述聚合物的輪胎
EP3204430B1 (en) 2014-10-10 2019-06-26 Bridgestone Corporation Polymerization catalyst composition and method of employing same
CN104557994B (zh) * 2014-12-15 2017-02-22 黑龙江大学 单分子磁体[Dy2(saph)2(NO3)2(CH3OH)4]的制备方法
EP3237526B1 (en) 2014-12-23 2022-05-18 Bridgestone Americas Tire Operations, LLC Tire comprising an oil-containing rubber composition
US10202474B2 (en) 2015-09-11 2019-02-12 Bridgestone Corporation Process for producing polydienes
US10730985B2 (en) 2016-12-19 2020-08-04 Bridgestone Corporation Functionalized polymer, process for preparing and rubber compositions containing the functionalized polymer
CN111630075B (zh) 2017-12-15 2023-04-28 株式会社普利司通 官能化聚合物、用于制备该官能化聚合物的方法和含有该官能化聚合物的橡胶组合物
EP3732210A4 (en) 2017-12-30 2021-08-11 Bridgestone Corporation COMPOSITION INCLUDING MULTIPLE POLYMERS WITH TERMINAL FUNCTIONALIZATION
JP7238154B2 (ja) 2019-03-10 2023-03-13 株式会社ブリヂストン 変性高シスポリジエンポリマー、関連する方法及びゴム組成物
US11767388B1 (en) 2019-09-18 2023-09-26 The Goodyear Tire & Rubber Company Silicon-functionalized rubber
EP3838932B1 (en) 2019-12-20 2022-08-10 The Goodyear Tire & Rubber Company Synthesis of isoprene-butadiene copolymer rubbers
US11584808B2 (en) 2019-12-30 2023-02-21 Bridgestone Corporation Polymerization catalyst composition and method of employing same

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3094514A (en) * 1958-02-13 1963-06-18 Goodrich Gulf Chem Inc Polymerization process for aliphatic, conjugated dienes
IN57789B (forum.php) * 1955-07-29
GB865248A (en) * 1956-12-28 1961-04-12 Hoechst Ag Process for the polymerisation of olefines
AT213051B (de) * 1958-04-24 1961-01-25 Montedison Spa Verfahren zum Polymerisieren von Diolefinen mit wenigstens einer Vinyldoppelbindung
NL257561A (forum.php) * 1959-11-18
FR1281516A (fr) * 1959-12-31 1962-01-12 Bridgestone Tire Co Ltd Procédé de préparation de cis-1, 4 polybutadiène et catalyseur pour sa mise en oeuvre et produits obtenus

Also Published As

Publication number Publication date
NL6401996A (forum.php) 1964-08-31
US3297667A (en) 1967-01-10
GB1061002A (en) 1967-03-08
DE1302264B (forum.php) 1970-11-12
BE644291A (forum.php) 1964-06-15
FR1390509A (fr) 1965-02-26

Similar Documents

Publication Publication Date Title
DE1542529A1 (de) Verfahren zur Herstellung von Katalysatoren zur stereospezifischen Polymerisation konjungierter Diolefine
DE2027327C3 (de) Verfahren zur Herstellung einer Dialkylmagnesiumverbindung
DE1117576B (de) Verfahren zur Herstellung von Aluminiumtrialkylen
DE60004437T2 (de) Verfahren zur Herstellung von Neodymium Neodecanoat und Verwendung davon als Katalysatorbestandteil für die Lösungspolymerisation von Butadien
DE2324766A1 (de) Verfahren zur polymerisation von olefinen
DE1217952B (de) Verfahren zur Herstellung cyclomatischer Metallverbindungen
DE60023080T2 (de) Geträgerter fester Katalysator für die Polymerisation von konjugierten Dienen, Verfahren zu seiner Herstellung und Polymerisationsverfahren unter Verwendung desselben
DE1668544C3 (de) Verfahren zur Dimerisation acyclischer konjugierter Dienkohlenwasserstoffe und Komplexkatalysator zur Durchführung dieses Verfahrens
DE2826498C2 (de) Verfahren zur Herstellung eines in Kohlenwasserstoffen löslicher Organomagnesiumkomplexes
DE2543219A1 (de) Verfahren zum herstellen einer uebergangsmetall-katalysatorkomponente fuer ziegler-katalysatoren zur polymerisation von olefinen
DE1142702B (de) Verfahren zur Herstellung von kristallinen 1,3-Butadienpolymeren mit im wesentlichensyndiotaktischer 1,2-Struktur
DE2533511A1 (de) Verfahren zur herstellung von festem titantrichlorid und dessen verwendung als katalysator zur polymerisation von alpha-olefinen
DE1542225A1 (de) Polymerisationsverfahren
EP1926697B1 (de) Magnesiumalkoxidgranulat, verfahren zu dessen herstellung und verwendung des magnesiumalkoxidgranulates
WO2007026016A1 (de) Aktiviertes erdalkalimetall, insbesondere magnesium, zur herstellung von organo-erdalkalimetall-verbindungen
DE2543272A1 (de) Verfahren zum herstellen von olefinpolymerisaten
DE2828627A1 (de) Polymerisationskatalysatoren auf der basis von titantrihalogeniden, verfahren zu ihrer herstellung und ihre verwendung
DE2615351C2 (de) Organomagnesiumkomplexe und Verfahren zu ihrer Herstellung
DE1113823B (de) Verfahren zur Herstellung von trans-1, 4-Polydienen
DE2560411C2 (de) Verfahren zur Herstellung von festem purpurfarbenem, feingranuliertem Titantrichlorid und seine Verwendung zur Polymerisation von α-Olefinen
DE1210191B (de) Verfahren zur Polymerisation von Butadien-(1, 3) oder dessen niederen Alkylderivatenoder zur Mischpolymerisation von Gemischen dieser Verbindungen
DE1570916B2 (de) Verfahren zur Polymerisation von konjugierten Diolefinen
AT208076B (de) Verfahren zur Herstellung von Polypropylen
EP0003300B1 (de) Katalysator, dessen Herstellung und Verwendung bei der Polymerisation von Butadien
DE1158715B (de) Verfahren zur Herstellung von festem Polybutadien mit hohem Anteil an cis-1, 4-Konfiguration