DD150062A5 - Verfahren zur herstellung von phosphorsaeure-estern von 5(3)-hydroxypyrazolen - Google Patents
Verfahren zur herstellung von phosphorsaeure-estern von 5(3)-hydroxypyrazolen Download PDFInfo
- Publication number
- DD150062A5 DD150062A5 DD78220135A DD22013578A DD150062A5 DD 150062 A5 DD150062 A5 DD 150062A5 DD 78220135 A DD78220135 A DD 78220135A DD 22013578 A DD22013578 A DD 22013578A DD 150062 A5 DD150062 A5 DD 150062A5
- Authority
- DD
- German Democratic Republic
- Prior art keywords
- iii
- hydroxypyrazoles
- alkyl
- same
- acid esters
- Prior art date
Links
- 150000003014 phosphoric acid esters Chemical class 0.000 title description 4
- 238000004519 manufacturing process Methods 0.000 title description 3
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 14
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 8
- 150000002367 halogens Chemical group 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 7
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 3
- 125000003545 alkoxy group Chemical group 0.000 claims abstract description 3
- 125000003282 alkyl amino group Chemical group 0.000 claims abstract description 3
- 125000004414 alkyl thio group Chemical group 0.000 claims abstract description 3
- 125000000304 alkynyl group Chemical group 0.000 claims abstract description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims abstract description 3
- 150000002148 esters Chemical class 0.000 claims abstract 2
- XBYRMPXUBGMOJC-UHFFFAOYSA-N 1,2-dihydropyrazol-3-one Chemical class OC=1C=CNN=1 XBYRMPXUBGMOJC-UHFFFAOYSA-N 0.000 claims description 12
- 150000003580 thiophosphoric acid esters Chemical class 0.000 claims description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- 125000005843 halogen group Chemical group 0.000 claims description 7
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- -1 alkali metal salt Chemical class 0.000 claims 2
- 239000002585 base Substances 0.000 claims 1
- 239000002798 polar solvent Substances 0.000 claims 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 12
- 230000000895 acaricidal effect Effects 0.000 abstract description 4
- 230000000749 insecticidal effect Effects 0.000 abstract description 3
- 230000001069 nematicidal effect Effects 0.000 abstract description 3
- 239000002917 insecticide Substances 0.000 abstract description 2
- 101100072620 Streptomyces griseus ind2 gene Proteins 0.000 abstract 2
- 101100242909 Streptococcus pneumoniae (strain ATCC BAA-255 / R6) pbpA gene Proteins 0.000 abstract 1
- 101100269618 Streptococcus pneumoniae serotype 4 (strain ATCC BAA-334 / TIGR4) aliA gene Proteins 0.000 abstract 1
- 239000000642 acaricide Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000005645 nematicide Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 description 47
- 241000238876 Acari Species 0.000 description 4
- 241000244206 Nematoda Species 0.000 description 4
- 238000000921 elemental analysis Methods 0.000 description 4
- 241000256054 Culex <genus> Species 0.000 description 3
- 241000238631 Hexapoda Species 0.000 description 3
- YYJNOYZRYGDPNH-MFKUBSTISA-N fenpyroximate Chemical compound C=1C=C(C(=O)OC(C)(C)C)C=CC=1CO/N=C/C=1C(C)=NN(C)C=1OC1=CC=CC=C1 YYJNOYZRYGDPNH-MFKUBSTISA-N 0.000 description 3
- 150000003217 pyrazoles Chemical class 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- OWFJMIVZYSDULZ-PXOLEDIWSA-N (4s,4ar,5s,5ar,6s,12ar)-4-(dimethylamino)-1,5,6,10,11,12a-hexahydroxy-6-methyl-3,12-dioxo-4,4a,5,5a-tetrahydrotetracene-2-carboxamide Chemical compound C1=CC=C2[C@](O)(C)[C@H]3[C@H](O)[C@H]4[C@H](N(C)C)C(=O)C(C(N)=O)=C(O)[C@@]4(O)C(=O)C3=C(O)C2=C1O OWFJMIVZYSDULZ-PXOLEDIWSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 241000238659 Blatta Species 0.000 description 2
- 241000256248 Spodoptera Species 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000026030 halogenation Effects 0.000 description 2
- 238000005658 halogenation reaction Methods 0.000 description 2
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical compound O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000254173 Coleoptera Species 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 206010061217 Infestation Diseases 0.000 description 1
- 241000124008 Mammalia Species 0.000 description 1
- 241000257229 Musca <genus> Species 0.000 description 1
- PKUWKAXTAVNIJR-UHFFFAOYSA-N O,O-diethyl hydrogen thiophosphate Chemical compound CCOP(O)(=S)OCC PKUWKAXTAVNIJR-UHFFFAOYSA-N 0.000 description 1
- QGLOLKPCOMUAJX-UHFFFAOYSA-N OC1=CC(Cl)=NN1C1=CC=CC=C1 Chemical compound OC1=CC(Cl)=NN1C1=CC=CC=C1 QGLOLKPCOMUAJX-UHFFFAOYSA-N 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-N Thiophosphoric acid Chemical compound OP(O)(S)=O RYYWUUFWQRZTIU-UHFFFAOYSA-N 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 125000005157 alkyl carboxy group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000012320 chlorinating reagent Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 150000002085 enols Chemical group 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 125000003226 pyrazolyl group Chemical group 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having alternatively specified atoms bound to the phosphorus atom and not covered by a single one of groups A01N57/10, A01N57/18, A01N57/26, A01N57/34
- A01N57/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having alternatively specified atoms bound to the phosphorus atom and not covered by a single one of groups A01N57/10, A01N57/18, A01N57/26, A01N57/34 containing heterocyclic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/18—One oxygen or sulfur atom
- C07D231/20—One oxygen atom attached in position 3 or 5
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
- C07F9/6509—Six-membered rings
- C07F9/650905—Six-membered rings having the nitrogen atoms in the positions 1 and 2
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
- Biochemistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT31190/77A IT1090364B (it) | 1977-12-23 | 1977-12-23 | Esteri fosforici e tiofosforici di 5(3) idrossipirazoli sostituiti in posizione 3(5) insetticidi |
| IT3119177A IT1090365B (it) | 1977-12-23 | 1977-12-23 | 5(3)-idrossi-pirazoli sostituiti in posizione 3(5) e loro procedimento di preparazione |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DD150062A5 true DD150062A5 (de) | 1981-08-12 |
Family
ID=26328917
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DD78220132A DD150056A5 (de) | 1977-12-23 | 1978-12-22 | Verfahren zur herstellung von 5(3)-hydroxypyrazolen |
| DD78210125A DD150425A5 (de) | 1977-12-23 | 1978-12-22 | Mittel zur bekaempfung von insekten,acari und nematoda |
| DD78220135A DD150062A5 (de) | 1977-12-23 | 1978-12-22 | Verfahren zur herstellung von phosphorsaeure-estern von 5(3)-hydroxypyrazolen |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DD78220132A DD150056A5 (de) | 1977-12-23 | 1978-12-22 | Verfahren zur herstellung von 5(3)-hydroxypyrazolen |
| DD78210125A DD150425A5 (de) | 1977-12-23 | 1978-12-22 | Mittel zur bekaempfung von insekten,acari und nematoda |
Country Status (26)
| Country | Link |
|---|---|
| US (3) | US4256902A (ru) |
| JP (1) | JPS5495567A (ru) |
| AR (1) | AR223157A1 (ru) |
| AU (1) | AU4276578A (ru) |
| BR (1) | BR7808414A (ru) |
| CA (1) | CA1113946A (ru) |
| CH (1) | CH639393A5 (ru) |
| CS (1) | CS207749B2 (ru) |
| DD (3) | DD150056A5 (ru) |
| DE (2) | DE2855256A1 (ru) |
| DK (1) | DK569478A (ru) |
| EG (1) | EG13746A (ru) |
| ES (1) | ES476263A1 (ru) |
| GB (1) | GB2013182B (ru) |
| GR (1) | GR71657B (ru) |
| IL (1) | IL56259A (ru) |
| IN (1) | IN149776B (ru) |
| LU (1) | LU80702A1 (ru) |
| NL (1) | NL7812293A (ru) |
| NO (1) | NO784274L (ru) |
| NZ (1) | NZ189284A (ru) |
| OA (1) | OA06140A (ru) |
| PL (1) | PL115092B1 (ru) |
| PT (1) | PT68967A (ru) |
| RO (2) | RO81226B (ru) |
| SU (2) | SU1071197A3 (ru) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2604174B1 (fr) * | 1986-09-18 | 1989-06-02 | Roussel Uclaf | Nouveaux derives de la 5-pyrazolone, leur procede de preparation et leur utilisation comme herbicides |
| US4855442A (en) * | 1988-04-13 | 1989-08-08 | Monsanto Company | Substituted 3-hydroxy pyrazoles |
| DE3931303A1 (de) * | 1989-09-20 | 1991-03-28 | Desowag Materialschutz Gmbh | Verfahren zum vorbeugenden materialschutz gegenueber staendig und/oder temporaer im boden lebenden schaedlingen, insbesondere termiten |
| DE4315384A1 (de) * | 1992-09-03 | 1994-03-10 | Bayer Ag | Phosphoryloxypyrazolderivate |
| EP1131298B1 (de) * | 1998-11-19 | 2003-09-03 | Basf Aktiengesellschaft | Verfahren zur herstellung von 1-substituierten 5-hydroxypyrazolen |
| AR075713A1 (es) | 2009-03-03 | 2011-04-20 | Du Pont | Pirazoles fungicidas |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2439098A (en) * | 1944-12-22 | 1948-04-06 | Eastman Kodak Co | Alkoxy pyrazolone couplers |
| AT184580B (de) * | 1951-04-20 | 1956-02-10 | Geigy Ag J R | Verfahren zur Herstellung neuer, heterocyclischer Phosphorsäure- bzw. Thiophosphorsäureester |
| DK109974C (da) * | 1959-03-06 | 1968-08-12 | Philips Nv | Middel til bekæmpelse af skadelige organismer. |
| US3166475A (en) * | 1959-12-29 | 1965-01-19 | Fiordalisi Fernanda Misani | Anti-convulsant pyrazolones |
| US3644374A (en) * | 1969-04-04 | 1972-02-22 | Raoul Buijle | Process for the preparation of acylated amides |
| DE2037853C3 (de) * | 1970-07-30 | 1980-02-14 | Bayer Ag, 5090 Leverkusen | Pyrazole- (thiono)-phosphor(phosphon)saureester, Verfahren zu ihrer Herstellung sowie ihre Verwendung als Insektizide und Akarizide |
| DE2060198A1 (de) * | 1970-12-08 | 1972-06-15 | Bayer Ag | Pyrazolo-(thiono)-phosphor(phosphon)-saeureester,Verfahren zu ihrer Herstellung sowie ihre Verwendung als Insektizide und Akarizide |
| BE785785A (fr) * | 1971-07-02 | 1973-01-03 | Bayer Ag | Nouveaux esters d'acides o-pyrazolothiono-phosphoriques (phosphoniques), leur preparation et leur application comme insecticides et acaricide |
| DE2219484A1 (de) * | 1972-04-21 | 1973-10-31 | Bayer Ag | 0-pyrazolo(thiono)-phosphor(phosphon)saeureester, verfahren zu ihrer herstellung und ihre verwendung als insektizide und akarizide |
| DD108536A1 (ru) * | 1972-12-21 | 1974-09-20 | ||
| DE2608643A1 (de) * | 1976-03-03 | 1977-09-08 | Bayer Ag | O,s-dialkyl-o-pyrazoldithiophosphorsaeureester, verfahren zu ihrer herstellung und ihre verwendung als insektizide und akarizide |
| DE2639258A1 (de) * | 1976-09-01 | 1978-03-02 | Bayer Ag | Tert.-butyl-substituierte pyrazolyl (thiono)(thiol)-phosphor(phosphon)-saeureester bzw. -esteramide, verfahren zu ihrer herstellung und ihre verwendung als insektizide, akarizide und nematizide |
| JPS5547695A (en) * | 1978-09-19 | 1980-04-04 | Takeda Chem Ind Ltd | Pyrazole phosphate, its preparation, and insecticide and miticide |
-
1978
- 1978-12-19 NO NO784274A patent/NO784274L/no unknown
- 1978-12-19 DK DK569478A patent/DK569478A/da not_active Application Discontinuation
- 1978-12-19 NL NL7812293A patent/NL7812293A/xx not_active Application Discontinuation
- 1978-12-20 RO RO102780A patent/RO81226B/ro unknown
- 1978-12-20 CH CH1298278A patent/CH639393A5/it not_active IP Right Cessation
- 1978-12-20 RO RO7895990A patent/RO77326A/ro unknown
- 1978-12-20 PL PL1978211969A patent/PL115092B1/pl unknown
- 1978-12-20 EG EG728/78A patent/EG13746A/xx active
- 1978-12-20 IL IL56259A patent/IL56259A/xx unknown
- 1978-12-20 AR AR274881A patent/AR223157A1/es active
- 1978-12-21 BR BR7808414A patent/BR7808414A/pt unknown
- 1978-12-21 NZ NZ189284A patent/NZ189284A/xx unknown
- 1978-12-21 IN IN1358/CAL/78A patent/IN149776B/en unknown
- 1978-12-21 AU AU42765/78A patent/AU4276578A/en active Pending
- 1978-12-21 GR GR57957A patent/GR71657B/el unknown
- 1978-12-21 GB GB7849730A patent/GB2013182B/en not_active Expired
- 1978-12-21 CS CS788758A patent/CS207749B2/cs unknown
- 1978-12-21 DE DE19782855256 patent/DE2855256A1/de active Granted
- 1978-12-21 DE DE2858748A patent/DE2858748C2/de not_active Expired - Fee Related
- 1978-12-22 ES ES476263A patent/ES476263A1/es not_active Expired
- 1978-12-22 JP JP15769878A patent/JPS5495567A/ja active Granted
- 1978-12-22 DD DD78220132A patent/DD150056A5/de unknown
- 1978-12-22 PT PT68967A patent/PT68967A/pt unknown
- 1978-12-22 DD DD78210125A patent/DD150425A5/de unknown
- 1978-12-22 DD DD78220135A patent/DD150062A5/de unknown
- 1978-12-22 CA CA318,485A patent/CA1113946A/en not_active Expired
- 1978-12-22 SU SU782699555A patent/SU1071197A3/ru active
- 1978-12-22 OA OA56696A patent/OA06140A/xx unknown
- 1978-12-22 LU LU80702A patent/LU80702A1/xx unknown
-
1979
- 1979-06-18 SU SU792776759A patent/SU1001858A3/ru active
-
1980
- 1980-03-12 US US06/129,724 patent/US4256902A/en not_active Expired - Lifetime
-
1982
- 1982-09-29 US US06/426,881 patent/US4459294A/en not_active Expired - Fee Related
-
1983
- 1983-08-18 US US06/524,229 patent/US4492690A/en not_active Expired - Fee Related
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