CY1120779T1 - Διαδικασια για την παραγωγη ακρυλικων ενωσεων απο εποξειδια - Google Patents

Διαδικασια για την παραγωγη ακρυλικων ενωσεων απο εποξειδια

Info

Publication number
CY1120779T1
CY1120779T1 CY181100899T CY181100899T CY1120779T1 CY 1120779 T1 CY1120779 T1 CY 1120779T1 CY 181100899 T CY181100899 T CY 181100899T CY 181100899 T CY181100899 T CY 181100899T CY 1120779 T1 CY1120779 T1 CY 1120779T1
Authority
CY
Cyprus
Prior art keywords
alpha
beta unsaturated
beta
reaction zone
epoxies
Prior art date
Application number
CY181100899T
Other languages
English (en)
Inventor
Richard V Porcelli
Jay J Farmer
Robert E Lapointe
Original Assignee
Novomer Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novomer Inc filed Critical Novomer Inc
Publication of CY1120779T1 publication Critical patent/CY1120779T1/el

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/475—Preparation of carboxylic acid esters by splitting of carbon-to-carbon bonds and redistribution, e.g. disproportionation or migration of groups between different molecules
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D305/00—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms
    • C07D305/02—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings
    • C07D305/10—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings having one or more double bonds between ring members or between ring members and non-ring members
    • C07D305/12—Beta-lactones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C08G63/08—Lactones or lactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/81—Preparation processes using solvents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Οι μέθοδοι της παρούσας εφεύρεσης περιλαμβάνουν τις βαθμίδες: παροχή ενός ρεύματος τροφοδοσίας πρώτης ύλης που περιλαμβάνει ένα εποξείδιο και μονοξείδιο του άνθρακα, επαφή του ρεύματος τροφοδοσίας πρώτης ύλης με ένα καρβονύλιο μετάλλου σε μια πρώτη ζώνη αντίδρασης για επιτέλεση της μετατροπής τουλάχιστον ενός τμήματος του παρεχόμενου εποξειδίου σε μια βήτα λακτόνη, κατεύθυνση της εκροής από την πρώτη ζώνη αντίδρασης σε μια δεύτερη ζώνη αντίδρασης όπου η βήτα λακτόνη υποβάλλεται σε συνθήκες που τη μετατρέπουν σε μια ένωση που επιλέγεται από την ομάδα που αποτελείται από: ένα άλφα βήτα ακόρεστο οξύ, έναν άλφα βήτα ακόρεστο εστέρα, ένα άλφα βήτα ακόρεστο αμίδιο και ένα προαιρετικά υποκαθιστώμενο πολυμερές πολυπροπιολακτόνης, καθώς και απομόνωση ενός τελικού προϊόντος που περιλαμβάνει το άλφα-βήτα ακόρεστο καρβοξυλικό οξύ, τον άλφα-βήτα ακόρεστο εστέρα, το άλφα-βήτα ακόρεστο αμίδιο ή την πολυπροπιολακτόνη.
CY181100899T 2011-10-26 2018-08-28 Διαδικασια για την παραγωγη ακρυλικων ενωσεων απο εποξειδια CY1120779T1 (el)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161551496P 2011-10-26 2011-10-26
PCT/US2012/061791 WO2013063191A1 (en) 2011-10-26 2012-10-25 Process for production of acrylates from epoxides

Publications (1)

Publication Number Publication Date
CY1120779T1 true CY1120779T1 (el) 2019-12-11

Family

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CY181100899T CY1120779T1 (el) 2011-10-26 2018-08-28 Διαδικασια για την παραγωγη ακρυλικων ενωσεων απο εποξειδια

Country Status (16)

Country Link
US (3) US9096510B2 (el)
EP (2) EP2771307B1 (el)
JP (3) JP6219834B2 (el)
KR (1) KR101894709B1 (el)
CN (2) CN107382699B (el)
CY (1) CY1120779T1 (el)
DK (1) DK2771307T3 (el)
ES (1) ES2684970T3 (el)
HK (1) HK1245240B (el)
HR (1) HRP20181284T1 (el)
HU (1) HUE039449T2 (el)
LT (1) LT2771307T (el)
PL (1) PL2771307T3 (el)
PT (1) PT2771307T (el)
SI (1) SI2771307T1 (el)
WO (1) WO2013063191A1 (el)

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DK2771307T3 (en) 2018-08-13
EP2771307B1 (en) 2018-05-30
JP6219834B2 (ja) 2017-10-25
HRP20181284T1 (hr) 2018-10-05
KR20140084257A (ko) 2014-07-04
JP2014532650A (ja) 2014-12-08
EP3375769B1 (en) 2022-03-09
US20170247309A1 (en) 2017-08-31
WO2013063191A1 (en) 2013-05-02
LT2771307T (lt) 2018-09-25
EP2771307A4 (en) 2015-06-24
EP2771307A1 (en) 2014-09-03
US9096510B2 (en) 2015-08-04
US9914689B2 (en) 2018-03-13
JP2017171681A (ja) 2017-09-28
HUE039449T2 (hu) 2018-12-28
EP3375769A1 (en) 2018-09-19
JP6486992B2 (ja) 2019-03-20
CN107382699A (zh) 2017-11-24
PL2771307T3 (pl) 2019-06-28
JP2018119010A (ja) 2018-08-02
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HK1245240B (zh) 2020-04-09
US20150299083A1 (en) 2015-10-22
CN107382699B (zh) 2019-02-22
CN103987682B (zh) 2017-06-16
SI2771307T1 (sl) 2018-10-30
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US20140309399A1 (en) 2014-10-16
CN103987682A (zh) 2014-08-13

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