MX2018006241A - Produccion de derivados de olefina grasa via metatesis de olefina. - Google Patents
Produccion de derivados de olefina grasa via metatesis de olefina.Info
- Publication number
- MX2018006241A MX2018006241A MX2018006241A MX2018006241A MX2018006241A MX 2018006241 A MX2018006241 A MX 2018006241A MX 2018006241 A MX2018006241 A MX 2018006241A MX 2018006241 A MX2018006241 A MX 2018006241A MX 2018006241 A MX2018006241 A MX 2018006241A
- Authority
- MX
- Mexico
- Prior art keywords
- olefin
- fatty
- metathesis
- production
- catalyst
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
- C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
- B01J31/2278—Complexes comprising two carbene ligands differing from each other, e.g. Grubbs second generation catalysts
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P19/00—Pest attractants
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2217—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/21—Alkatrienes; Alkatetraenes; Other alkapolyenes
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
- C07C201/02—Preparation of esters of nitric acid
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C203/00—Esters of nitric or nitrous acid
- C07C203/02—Esters of nitric acid
- C07C203/04—Esters of nitric acid having nitrate groups bound to acyclic carbon atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C33/02—Acyclic alcohols with carbon-to-carbon double bonds
- C07C33/025—Acyclic alcohols with carbon-to-carbon double bonds with only one double bond
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/41—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by hydrogenolysis or reduction of carboxylic groups or functional derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
- C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
- C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
- C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/04—Formic acid esters
- C07C69/06—Formic acid esters of monohydroxylic compounds
- C07C69/07—Formic acid esters of monohydroxylic compounds of unsaturated alcohols
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/12—Acetic acid esters
- C07C69/14—Acetic acid esters of monohydroxylic compounds
- C07C69/145—Acetic acid esters of monohydroxylic compounds of unsaturated alcohols
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/54—Metathesis reactions, e.g. olefin metathesis
- B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/64—Molybdenum
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/66—Tungsten
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/09—Geometrical isomers
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- General Chemical & Material Sciences (AREA)
- Plant Pathology (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
En un aspecto, la invención proporciona un método para la síntesis de un derivado de olefina grasa. El método incluye: a) el contacto de una olefina de acuerdo con la Fórmula I (ver Fórmula) con un compañero de reacción de metátesis de acuerdo con la Fórmula IIb (ver Fórmula) en presencia de un catalizador de metátesis en condiciones suficientes para formar un producto de metátesis de acuerdo con la Fórmula llIb: (ver Fórmula) b) la conversión del producto de metátesis al derivado de olefina grasa. Cada R1 se selecciona de manera independiente de H, C1-18 alquilo y C2-18 alquenilo; R2b es C1-8 alquilo; subíndice y es un número entero que varía de 0 a 17; y el subíndice z es un número entero que varía de 0 a 17. En ciertas formas de realización, el catalizador de metátesis es un catalizador de tungsteno o un catalizador de molibdeno. En diversas formas de realización, el derivado de olefina grasa es una feromona de insecto. Se describen además composiciones de feromonas y métodos para su uso.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201562257148P | 2015-11-18 | 2015-11-18 | |
PCT/US2016/062595 WO2017087710A2 (en) | 2015-11-18 | 2016-11-17 | Production of fatty olefin derivatives via olefin metathesis |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2018006241A true MX2018006241A (es) | 2018-11-09 |
Family
ID=58689813
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2018006241A MX2018006241A (es) | 2015-11-18 | 2016-11-17 | Produccion de derivados de olefina grasa via metatesis de olefina. |
Country Status (14)
Country | Link |
---|---|
US (4) | US9776179B2 (es) |
EP (2) | EP4234522A3 (es) |
JP (2) | JP6970088B2 (es) |
CN (2) | CN108473390B (es) |
AR (2) | AR108028A1 (es) |
AU (1) | AU2016357756B2 (es) |
BR (1) | BR112018009885B1 (es) |
CA (1) | CA3005562A1 (es) |
CL (2) | CL2018001337A1 (es) |
HU (1) | HUE063333T2 (es) |
IL (1) | IL259459B (es) |
MX (1) | MX2018006241A (es) |
PL (1) | PL3377465T3 (es) |
WO (1) | WO2017087710A2 (es) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9919299B2 (en) | 2013-03-14 | 2018-03-20 | Ximo Ag | Metathesis catalysts and reactions using the catalysts |
WO2015049047A1 (en) | 2013-10-01 | 2015-04-09 | Ximo Ag | Immobilized metathesis tungsten oxo alkylidene catalysts and use thereof in olefin metathesis |
GB201406591D0 (en) * | 2014-04-11 | 2014-05-28 | Ximo Ag | Compounds |
EP4234522A3 (en) | 2015-11-18 | 2023-10-25 | Provivi, Inc. | Production of fatty olefin derivatives via olefin metathesis |
DK3376859T3 (da) | 2015-11-18 | 2021-03-29 | Provivi Inc | Mikroorganismer til fremstilling af insektferomoner og relaterede forbindelser |
AR110606A1 (es) | 2016-06-06 | 2019-04-17 | Provivi Inc | Producción semi-biosintética de alcoholes grasos y aldehídos grasos |
EP3583088A4 (en) * | 2017-02-17 | 2021-03-31 | Provivi, Inc. | SYNTHESIS OF PHEROMONES AND RELATED MATERIALS BY OLEFIN METATHESIS |
EP3635124A4 (en) | 2017-05-17 | 2021-03-31 | Provivi, Inc. | MICRO-ORGANISMS INTENDED FOR THE PRODUCTION OF INSECT PHEROMONES AND ASSOCIATED COMPOUNDS |
JP2021520339A (ja) * | 2018-03-22 | 2021-08-19 | フェルビオ フェルアイニクテ ビオエネルギー アクチェンゲゼルシャフト | テトラフェニルフェノキシタングステンオキソアルキリデン複合体、その製造方法及びその使用 |
WO2020018581A1 (en) | 2018-07-16 | 2020-01-23 | Provivi, Inc. | Synthesis of straight-chain lepidopteran pheromones through one- or two- carbon homologation of fatty alkenes |
CN113272267A (zh) * | 2018-12-10 | 2021-08-17 | 普罗维维公司 | 共轭二烯信息素及相关化合物的合成 |
EP3927798A4 (en) * | 2019-02-21 | 2022-11-09 | Wilmar Trading Pte Ltd | PROCESSES FOR THE MANUFACTURE OF GLYCERIDOLIGOMERS AND PRODUCTS MADE THEREOF |
CN114174310A (zh) | 2019-05-27 | 2022-03-11 | 韦尔比奥联合生物能源股份公司 | 钨亚氨基亚烷基O-bitet和O-binol配合物及其在烯烃复分解反应中的用途 |
FI128954B (en) * | 2019-09-26 | 2021-03-31 | Neste Oyj | Preparation of renewable base oil including metathesis |
FI128952B (en) | 2019-09-26 | 2021-03-31 | Neste Oyj | Preparation of renewable alkenes including metathesis |
EP4073157A1 (en) * | 2019-12-11 | 2022-10-19 | Novoloop, Inc. | Compositions and methods for the degradation of waste polypropylene |
EP4157814A1 (en) * | 2020-06-01 | 2023-04-05 | Provivi, Inc. | Synthesis of pheromone derivatives via z-selective olefin metathesis |
JP7475264B2 (ja) | 2020-12-10 | 2024-04-26 | 信越化学工業株式会社 | 3-イソプロペニル-6-ヘプテナール化合物及び6-イソプロペニル-3-メチル-3,9-デカジエニル=カルボキシレート化合物の製造方法並びにその中間体 |
Family Cites Families (76)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4231947A (en) | 1979-01-02 | 1980-11-04 | Massachusetts Institute Of Technology | Tantalum and niobium catalysts or catalyst precursors |
US4245131A (en) | 1979-07-02 | 1981-01-13 | Massachusetts Institute Of Technology | Dimerization of olefins using tantalum and niobium catalysts |
HU180386B (en) * | 1980-10-24 | 1983-02-28 | Egyt Gyogyszervegyeszeti Gyar | Process for producing 11-dodecen-1-ol and 11-dodecen-1-yl-acetate of insect-feromone activity |
US4427595A (en) | 1981-07-16 | 1984-01-24 | Massachusetts Institute Of Technology | Catalyst composition to effect metathesis of acetylenes |
US4560792A (en) * | 1982-07-20 | 1985-12-24 | Phillips Petroleum Company | Disproportionation of functional olefins |
DE129474T1 (de) | 1983-06-15 | 1985-08-29 | Societe Nationale Elf Aquitaine, Courbevoie | Katalysator fuer die metathese von olefinen. |
US4792620A (en) * | 1983-10-14 | 1988-12-20 | Bp Chemicals Limited | Carbonylation catalysts |
US4727215A (en) | 1985-09-25 | 1988-02-23 | Massachusetts Institute Of Technology | Catalyst composition for effecting metathesis of olefins |
US4681956A (en) | 1985-09-25 | 1987-07-21 | Massachusetts Institute Of Technology | Catalyst composition for effecting metathesis of olefins |
US4837358A (en) | 1986-02-26 | 1989-06-06 | Phillips Petroleum Company | Preparation of 9-alkenyl ester compounds |
US5081287A (en) * | 1989-06-30 | 1992-01-14 | Fmc Corporation | Pesticidal polyhalo alkenoic acid esters |
US5087710A (en) | 1990-01-04 | 1992-02-11 | Massachusetts Institute Of Technology | Homogeneous rhenium catalysts for metathesis of olefins |
US5146033A (en) | 1990-01-04 | 1992-09-08 | Massachusetts Institute Of Technology | Homogeneous rhenium catalysts for metathesis of olefins |
US5142073A (en) | 1991-04-30 | 1992-08-25 | Massachusetts Institute Of Technology | Synthesis of molybdenum and tungsten complexes |
DE4434640C1 (de) * | 1994-09-28 | 1996-02-01 | Hoechst Ag | Verfahren zur Herstellung verbrückter Metallocene |
SG72861A1 (en) | 1997-09-30 | 2000-05-23 | Kuraray Co | Process for producing 7-octen-1-al |
US6121473A (en) | 1998-02-19 | 2000-09-19 | Massachusetts Institute Of Technology | Asymmetric ring-closing metathesis reactions |
ES2198886T3 (es) | 1998-04-01 | 2004-02-01 | Firmenich Sa | Reduccion de compuestos carbonilados por un silano en presencia de un catalizador de zinc. |
DE19815275B4 (de) | 1998-04-06 | 2009-06-25 | Evonik Degussa Gmbh | Alkylidenkomplexe des Rutheniums mit N-heterozyklischen Carbenliganden und deren Verwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese |
US6346652B1 (en) | 1998-07-13 | 2002-02-12 | Massachusetts Institute Of Technology | Asymmetric ring-closing metathesis reactions involving achiral and meso substrates |
US6696597B2 (en) * | 1998-09-01 | 2004-02-24 | Tilliechem, Inc. | Metathesis syntheses of pheromones or their components |
US6215019B1 (en) | 1998-09-01 | 2001-04-10 | Tilliechem, Inc. | Synthesis of 5-decenyl acetate and other pheromone components |
DE69941219D1 (de) | 1998-09-10 | 2009-09-17 | Univ New Orleans Foundation | Katalysatorkomplex mit phenylindenyliden-ligand |
US6478081B1 (en) * | 1999-08-04 | 2002-11-12 | Apv North America Inc. | Plate heat exchanger |
IL149720A0 (en) * | 1999-11-18 | 2002-11-10 | Metathesis syntheses of pheremones or their components | |
EP1373170A4 (en) * | 2001-03-30 | 2007-03-21 | California Inst Of Techn | CROSS-METATHESIS REACTION OF FUNCTIONALIZED AND SUBSTITUTED OLEFINS USING GROUP 8 METAL TRANSITION CARBENE COMPLEXES AS METATHESIS CATALYSTS |
JP2004035452A (ja) * | 2002-07-03 | 2004-02-05 | Honshu Chem Ind Co Ltd | 脂環式モノオレフィンメタノールの製造方法 |
US20050261451A1 (en) | 2004-03-29 | 2005-11-24 | California Institute Of Technology | Latent, high-activity olefin metathesis catalysts containing an N-heterocyclic carbene ligand |
GB0514612D0 (en) | 2005-07-15 | 2005-08-24 | Sasol Technology Uk Ltd | The use of a phosphorus containing ligand and a cyclic organic ligand in a metathesis catalyst |
US8008224B2 (en) | 2005-12-16 | 2011-08-30 | Materia, Inc. | Organometallic ruthenium complexes and related methods for the preparation of tetra-substituted and other hindered olefins |
PL379879A1 (pl) | 2006-06-07 | 2007-12-10 | Umicore Ag & Co.Kg. | Kompleksy rutenu i osmu, sposób ich wytwarzania oraz ich zastosowanie jako (pre)katalizatorów reakcji metatezy |
DE102006043704A1 (de) | 2006-09-18 | 2008-03-27 | Umicore Ag & Co. Kg | Neue Metathesekatalysatoren |
EP2121546B1 (en) * | 2006-10-13 | 2017-12-13 | Elevance Renewable Sciences, Inc. | Methods of making alpha, omega-dicarboxylic acid alkene derivatives by metathesis |
US7932397B2 (en) | 2006-11-22 | 2011-04-26 | Massachusetts Institute Of Technology | Olefin metathesis catalysts and related methods |
FR2909382B1 (fr) | 2006-11-30 | 2009-01-23 | Enscr | Complexes catalytiques a base de ruthenium et utilisation de tels complexes pour la metathese d'olefines |
DE102007020694A1 (de) | 2007-05-03 | 2008-11-06 | Evonik Degussa Gmbh | Schwefelhaltige Metathesekatalysatoren |
CN102015106B (zh) | 2008-01-25 | 2014-04-02 | 波士顿学院董事会 | 用于包括对映选择性烯烃复分解的复分解反应的催化剂及相关方法 |
CN101990543B (zh) | 2008-04-08 | 2014-11-12 | 赢创德固赛有限公司 | 制备钌卡宾络合物的方法 |
CN102083798B (zh) | 2008-04-09 | 2016-10-26 | 马特里亚公司 | 带有具有取代骨架的n-杂环卡宾配体的钌烯烃易位催化剂 |
JP5535217B2 (ja) | 2008-10-04 | 2014-07-02 | ユミコア・アクチエンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト | ルテニウム−インデニリデンカルベン触媒の製造方法 |
US8222469B2 (en) | 2009-07-15 | 2012-07-17 | Massachusetts Institute Of Technology | Catalysts and processes for the formation of terminal olefins by ethenolysis |
US8362311B2 (en) * | 2009-09-30 | 2013-01-29 | Massachusetts Institute Of Technology | Highly Z-selective olefins metathesis |
PL2488474T3 (pl) | 2009-10-12 | 2017-07-31 | Elevance Renewable Sciences, Inc. | Sposoby rafinacji i wytwarzania paliw z surowców na bazie olejów naturalnych |
EP2506972B1 (en) | 2009-12-03 | 2019-04-17 | Umicore AG & Co. KG | Supported olefin metathesis catalysts |
EP2361683A1 (en) | 2010-01-29 | 2011-08-31 | Umicore AG & Co. KG | Process for preparation of ruthenium-based carbene catalysts with chelating alkylidene ligands |
US8598400B2 (en) | 2010-02-08 | 2013-12-03 | Massachusetts Institute Of Technology | Efficient methods for Z- or cis-selective cross-metathesis |
US8546500B2 (en) * | 2011-05-27 | 2013-10-01 | Massachusetts Institute Of Technology | Complexes for use in metathesis reactions |
JP6266509B2 (ja) | 2011-06-03 | 2018-01-24 | マサチューセッツ インスティテュート オブ テクノロジー | Z選択的閉環メタセシス反応 |
PL216649B1 (pl) | 2011-06-06 | 2014-04-30 | Univ Warszawski | Nowe kompleksy rutenu, sposób ich wytwarzania oraz zastosowanie w reakcji metatezy olefin |
US9085595B2 (en) | 2011-11-07 | 2015-07-21 | Massachusetts Institute Of Technology | Tungsten oxo alkylidene complexes for Z selective olefin metathesis |
EP2838359A4 (en) * | 2012-03-05 | 2015-12-09 | California Inst Of Techn | SYNTHESIS OF Z-OLEFIN-CONTAINING PHEROMONES OF LEPIDOPTERA INSECTS |
EP2639219B1 (en) | 2012-03-14 | 2016-08-10 | Umicore AG & Co. KG | Ruthenium-based metathesis catalysts and precursors for their preparation |
IN2014DN08906A (es) | 2012-04-24 | 2015-05-22 | Elevance Renewable Sciences | |
GB201208589D0 (en) | 2012-05-16 | 2012-06-27 | Givaudan Sa | Improvements in or relating to organic compounds |
PL2679593T3 (pl) | 2012-06-26 | 2018-08-31 | Umicore Ag & Co. Kg | Sposób otrzymywania indenylidenowego kompleksu rutenu |
WO2014018578A1 (en) * | 2012-07-24 | 2014-01-30 | Heliae Development, Llc | Methods of converting mixtures of palmitoleic and oleic acid esters to high value products |
WO2014052310A1 (en) | 2012-09-25 | 2014-04-03 | Modine Manufacturing Company | System and method for recovering waste heat |
EP2725030A1 (en) | 2012-10-29 | 2014-04-30 | Umicore AG & Co. KG | Ruthenium-based metathesis catalysts, precursors for their preparation and their use |
JP6271595B2 (ja) | 2013-02-27 | 2018-01-31 | マテリア, インコーポレイテッド | 金属カルベンオレフィンメタセシス2種の触媒組成物 |
US9919299B2 (en) * | 2013-03-14 | 2018-03-20 | Ximo Ag | Metathesis catalysts and reactions using the catalysts |
JP6431034B2 (ja) | 2013-03-14 | 2018-11-28 | エレヴァンス リニューアブル サイエンシズ インコーポレイテッドElevance Renewable Sciences, Inc. | 処理されたメタセシス基質物質、その製造及び利用方法 |
US20160039737A1 (en) * | 2013-03-14 | 2016-02-11 | Materia, Inc. | Use of soluble metal salts in metathesis reactions |
EP2961756B1 (en) | 2013-03-15 | 2022-02-16 | Goussev, Dmitri | Complex catalysts based on amino-phosphine ligands for hydrogenation and dehydrogenation processes |
GB201305858D0 (en) | 2013-03-28 | 2013-05-15 | Ximo Ag | Catalyst composition |
WO2014169014A1 (en) | 2013-04-09 | 2014-10-16 | Massachusetts Institute Of Technology | Metathesis catalysts and methods thereof |
US9206211B2 (en) | 2013-04-17 | 2015-12-08 | Massachusetts Institute Of Technology | Metathesis catalysts and methods thereof |
US20140330018A1 (en) | 2013-05-01 | 2014-11-06 | Massachusetts Institute Of Technology | Metathesis catalysts and methods thereof |
WO2014201300A1 (en) | 2013-06-12 | 2014-12-18 | Trustees Of Boston College | Catalysts for efficient z-selective metathesis |
US9441059B2 (en) * | 2013-06-20 | 2016-09-13 | Massachusetts Institute Of Technology | Metathesis catalysts and methods thereof |
EP3019510B1 (en) | 2013-07-12 | 2020-12-02 | Verbio Vereinigte BioEnergie AG | Use of immobilized molybden- und tungsten-containing catalysts in olefin cross metathesis |
CN103319704B (zh) | 2013-07-12 | 2015-06-17 | 南开大学 | 一种用10-十一碳烯酸和香草酸制备聚酯的方法 |
EP3019511B1 (en) | 2013-07-12 | 2019-01-02 | XiMo AG | Immobilized metathesis tungsten catalysts and use thereof in olefin metathesis |
EP3107655B1 (en) | 2014-02-21 | 2024-05-08 | Massachusetts Institute of Technology | Catalysts and methods for ring opening metathesis polymerization |
GB201404468D0 (en) | 2014-03-13 | 2014-04-30 | Givaudan Sa | Process |
GB201406591D0 (en) * | 2014-04-11 | 2014-05-28 | Ximo Ag | Compounds |
EP4234522A3 (en) | 2015-11-18 | 2023-10-25 | Provivi, Inc. | Production of fatty olefin derivatives via olefin metathesis |
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