CL2018001337A1 - Producción de derivados de olefina grasa vía metátesis de olefina - Google Patents
Producción de derivados de olefina grasa vía metátesis de olefinaInfo
- Publication number
- CL2018001337A1 CL2018001337A1 CL2018001337A CL2018001337A CL2018001337A1 CL 2018001337 A1 CL2018001337 A1 CL 2018001337A1 CL 2018001337 A CL2018001337 A CL 2018001337A CL 2018001337 A CL2018001337 A CL 2018001337A CL 2018001337 A1 CL2018001337 A1 CL 2018001337A1
- Authority
- CL
- Chile
- Prior art keywords
- rent
- derivative
- catalyst
- olefin
- formula
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
- C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
- B01J31/2278—Complexes comprising two carbene ligands differing from each other, e.g. Grubbs second generation catalysts
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P19/00—Pest attractants
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2217—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/21—Alkatrienes; Alkatetraenes; Other alkapolyenes
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
- C07C201/02—Preparation of esters of nitric acid
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C203/00—Esters of nitric or nitrous acid
- C07C203/02—Esters of nitric acid
- C07C203/04—Esters of nitric acid having nitrate groups bound to acyclic carbon atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C33/02—Acyclic alcohols with carbon-to-carbon double bonds
- C07C33/025—Acyclic alcohols with carbon-to-carbon double bonds with only one double bond
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/41—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by hydrogenolysis or reduction of carboxylic groups or functional derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
- C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
- C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
- C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/04—Formic acid esters
- C07C69/06—Formic acid esters of monohydroxylic compounds
- C07C69/07—Formic acid esters of monohydroxylic compounds of unsaturated alcohols
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/12—Acetic acid esters
- C07C69/14—Acetic acid esters of monohydroxylic compounds
- C07C69/145—Acetic acid esters of monohydroxylic compounds of unsaturated alcohols
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/54—Metathesis reactions, e.g. olefin metathesis
- B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/64—Molybdenum
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/66—Tungsten
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/09—Geometrical isomers
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- General Chemical & Material Sciences (AREA)
- Plant Pathology (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
EN UN ASPECTO, LA INVENCIÓN PROPORCIONA UN MÉTODO PARA LA SÍNTESIS DE UN DERIVADO DE OLEFINA GRASA. EL MÉTODO INCLUYE: A) EL CONTACTO DE UNA OLEFINA DE ACUERDO CON LA FÓRMULA I (I), CON UN COMPAÑERO DE REACCIÓN DE METÁTESIS DE ACUERDO CON LA FÓRMULA IIB (IIB), EN PRESENCIA DE UN CATALIZADOR DE METÁTESIS EN CONDICIONES SUFICIENTES PARA FORMAR UN PRODUCTO DE METÁTESIS DE ACUERDO CON LA FÓRMULA IIIB: (IIIB); Y B) LA CONVERSIÓN DEL PRODUCTO DE METÁTESIS AL DERIVADO DE OLEFINA GRASA. CADA R1 SE SELECCIONA DE MANERA INDEPENDIENTE DE H, C1–18 ALQUILO Y C2–18 ALQUENILO; R2B ES C1–8 ALQUILO; SUBÍNDICE Y ES UN NÚMERO ENTERO QUE VARÍA DE 0 A 17; Y EL SUBÍNDICE Z ES UN NÚMERO ENTERO QUE VARÍA DE 0 A 17. EN CIERTAS FORMAS DE REALIZACIÓN, EL CATALIZADOR DE METÁTESIS ES UN CATALIZADOR DE TUNGSTENO O UN CATALIZADOR DE MOLIBDENO. EN DIVERSAS FORMAS DE REALIZACIÓN, EL DERIVADO DE OLEFINA GRASA ES UNA FEROMONA DE INSECTO. SE DESCRIBEN ADEMÁS COMPOSICIONES DE FEROMONAS Y MÉTODOS PARA SU USO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201562257148P | 2015-11-18 | 2015-11-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
CL2018001337A1 true CL2018001337A1 (es) | 2018-10-26 |
Family
ID=58689813
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CL2018001337A CL2018001337A1 (es) | 2015-11-18 | 2018-05-17 | Producción de derivados de olefina grasa vía metátesis de olefina |
CL2019003183A CL2019003183A1 (es) | 2015-11-18 | 2019-11-06 | Producción de derivados de olefina grasa vía metátesis de olefina (divisional solicitud 201801337) |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CL2019003183A CL2019003183A1 (es) | 2015-11-18 | 2019-11-06 | Producción de derivados de olefina grasa vía metátesis de olefina (divisional solicitud 201801337) |
Country Status (14)
Country | Link |
---|---|
US (4) | US9776179B2 (es) |
EP (2) | EP3377465B1 (es) |
JP (2) | JP6970088B2 (es) |
CN (2) | CN115215748A (es) |
AR (2) | AR108028A1 (es) |
AU (1) | AU2016357756B2 (es) |
BR (1) | BR112018009885B1 (es) |
CA (1) | CA3005562C (es) |
CL (2) | CL2018001337A1 (es) |
HU (1) | HUE063333T2 (es) |
IL (1) | IL259459B (es) |
MX (1) | MX2018006241A (es) |
PL (1) | PL3377465T3 (es) |
WO (1) | WO2017087710A2 (es) |
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EP3662996A3 (en) | 2013-03-14 | 2020-12-16 | Verbio Vereinigte BioEnergie AG | Molybdenum and tungsten complexes as olefin metathesis catalysts and reactions using the catalysts |
EP3052229B1 (en) | 2013-10-01 | 2021-02-24 | Verbio Vereinigte BioEnergie AG | Immobilized metathesis tungsten oxo alkylidene catalysts and use thereof in olefin metathesis |
GB201406591D0 (en) | 2014-04-11 | 2014-05-28 | Ximo Ag | Compounds |
JP6970088B2 (ja) | 2015-11-18 | 2021-11-24 | プロビビ インコーポレイテッド | オレフィンメタセシスを介した脂肪族オレフィン誘導体の生成 |
WO2017087846A1 (en) | 2015-11-18 | 2017-05-26 | Provivi, Inc. | Microorganisms for the production of insect pheromones and related compounds |
CN109890832B (zh) | 2016-06-06 | 2022-08-12 | 普罗维维股份有限公司 | 脂肪醇和脂肪醛的半生物合成产生 |
JP7153937B2 (ja) * | 2017-02-17 | 2022-10-17 | プロビビ インコーポレイテッド | オレフィンメタセシスによるフェロモンおよび関連材料の合成方法 |
CN110914442A (zh) | 2017-05-17 | 2020-03-24 | 普罗维维股份有限公司 | 用于产生昆虫信息素及相关化合物的微生物 |
EP3768691A1 (en) * | 2018-03-22 | 2021-01-27 | Verbio Vereinigte BioEnergie AG | Tetraphenylphenoxy tungsten oxo alkylidene complexes, methods of making same and use thereof |
WO2020018581A1 (en) * | 2018-07-16 | 2020-01-23 | Provivi, Inc. | Synthesis of straight-chain lepidopteran pheromones through one- or two- carbon homologation of fatty alkenes |
WO2020123534A1 (en) * | 2018-12-10 | 2020-06-18 | Provivi, Inc. | Synthesis of conjugated diene pheromones and related compounds |
EP3927798A4 (en) * | 2019-02-21 | 2022-11-09 | Wilmar Trading Pte Ltd | PROCESSES FOR THE MANUFACTURE OF GLYCERIDOLIGOMERS AND PRODUCTS MADE THEREOF |
US20220227797A1 (en) | 2019-05-27 | 2022-07-21 | Verbio Vereinigte Bioenergie Ag | Tungsten imido alkylidene o-bitet and o-binol complexes and use thereof in olefin metathesis reactions |
FI128954B (en) * | 2019-09-26 | 2021-03-31 | Neste Oyj | Preparation of renewable base oil including metathesis |
FI128952B (en) | 2019-09-26 | 2021-03-31 | Neste Oyj | Preparation of renewable alkenes including metathesis |
CN115210310B (zh) * | 2019-12-11 | 2024-08-30 | 诺弗洛普有限公司 | 用于废物聚丙烯降解的组合物和方法 |
JP2023527882A (ja) * | 2020-06-01 | 2023-06-30 | プロビビ インコーポレイテッド | Z選択的オレフィンメタセシスによるフェロモン誘導体の合成方法 |
JP7475264B2 (ja) * | 2020-12-10 | 2024-04-26 | 信越化学工業株式会社 | 3-イソプロペニル-6-ヘプテナール化合物及び6-イソプロペニル-3-メチル-3,9-デカジエニル=カルボキシレート化合物の製造方法並びにその中間体 |
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