DE69941219D1 - Katalysatorkomplex mit phenylindenyliden-ligand - Google Patents
Katalysatorkomplex mit phenylindenyliden-ligandInfo
- Publication number
- DE69941219D1 DE69941219D1 DE69941219T DE69941219T DE69941219D1 DE 69941219 D1 DE69941219 D1 DE 69941219D1 DE 69941219 T DE69941219 T DE 69941219T DE 69941219 T DE69941219 T DE 69941219T DE 69941219 D1 DE69941219 D1 DE 69941219D1
- Authority
- DE
- Germany
- Prior art keywords
- ligand
- complexes
- phenylindenyliden
- catalyst complex
- alkylidene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
- B01J31/2278—Complexes comprising two carbene ligands differing from each other, e.g. Grubbs second generation catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
- B01J31/2269—Heterocyclic carbenes
- B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
- C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/46—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with hetero atoms directly attached to the ring nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
- C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
- C07D223/04—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with only hydrogen atoms, halogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D225/00—Heterocyclic compounds containing rings of more than seven members having one nitrogen atom as the only ring hetero atom
- C07D225/02—Heterocyclic compounds containing rings of more than seven members having one nitrogen atom as the only ring hetero atom not condensed with other rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D313/00—Heterocyclic compounds containing rings of more than six members having one oxygen atom as the only ring hetero atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D498/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D498/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
- C07D498/04—Ortho-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/002—Osmium compounds
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/0046—Ruthenium compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
- B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/54—Metathesis reactions, e.g. olefin metathesis
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/54—Metathesis reactions, e.g. olefin metathesis
- B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/825—Osmium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US9972298P | 1998-09-10 | 1998-09-10 | |
US11535899P | 1999-01-08 | 1999-01-08 | |
PCT/US1999/020629 WO2000015339A1 (en) | 1998-09-10 | 1999-09-09 | Catalyst complex with carbene ligand |
Publications (1)
Publication Number | Publication Date |
---|---|
DE69941219D1 true DE69941219D1 (de) | 2009-09-17 |
Family
ID=26796425
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69941219T Expired - Lifetime DE69941219D1 (de) | 1998-09-10 | 1999-09-09 | Katalysatorkomplex mit phenylindenyliden-ligand |
Country Status (9)
Country | Link |
---|---|
US (8) | US7622590B1 (de) |
EP (2) | EP2116302B1 (de) |
JP (5) | JP5066656B2 (de) |
AT (1) | ATE438462T1 (de) |
AU (1) | AU5817599A (de) |
CA (1) | CA2343798C (de) |
DE (1) | DE69941219D1 (de) |
TW (1) | TW536427B (de) |
WO (1) | WO2000015339A1 (de) |
Families Citing this family (63)
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---|---|---|---|---|
US7285593B1 (en) | 1998-05-19 | 2007-10-23 | Advanced Polymer Technologies, Inc. | Polyolefin compositions optionally having variable toughness and/or hardness |
US6696597B2 (en) | 1998-09-01 | 2004-02-24 | Tilliechem, Inc. | Metathesis syntheses of pheromones or their components |
US6900347B2 (en) | 1998-09-01 | 2005-05-31 | Tilliechem, Inc. | Impurity inhibition in olefin metathesis reactions |
US7622590B1 (en) | 1998-09-10 | 2009-11-24 | University Of New Orleans Foundation | Catalyst complex with carbene ligand |
WO2000046257A1 (en) | 1999-02-05 | 2000-08-10 | Materia, Inc. | Metathesis-active adhesion agents and methods for enhancing polymer adhesion to surfaces |
US20140088260A1 (en) | 1999-02-05 | 2014-03-27 | Materia, Inc. | Metathesis-active adhesion agents and methods for enhancing polymer adhesion to surfaces |
IL144549A0 (en) | 1999-02-05 | 2002-05-23 | Materia Inc | Polyolefin compositions having variable density and methods for their production and use |
US7329758B1 (en) * | 1999-05-24 | 2008-02-12 | California Institute Of Technology | Imidazolidine-based metal carbene metathesis catalysts |
JP2001278962A (ja) * | 2000-03-30 | 2001-10-10 | Hitachi Chem Co Ltd | 樹脂組成物及びそれを用いた硬化物の製造方法 |
JP2002020395A (ja) * | 2000-07-04 | 2002-01-23 | Sekisui Chem Co Ltd | 新規な高メタセシス活性の有機金属錯体化合物、これを含有してなるメタセシス反応触媒、この触媒を用いた重合方法、並びにこの重合方法により得られた樹脂組成物 |
WO2002014376A2 (en) | 2000-08-10 | 2002-02-21 | Trustees Of Boston College | Recyclable metathesis catalysts |
US6610626B2 (en) | 2000-09-05 | 2003-08-26 | Cymetech, Llp | Highly active metathesis catalysts generated in situ from inexpensive and air stable precursors |
US6440942B1 (en) * | 2000-12-22 | 2002-08-27 | Enanta Pharmaceuticals, Inc. | 14-membered macrolides derived from leucomycins |
US6759537B2 (en) | 2001-03-23 | 2004-07-06 | California Institute Of Technology | Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts |
US6838489B2 (en) | 2001-03-23 | 2005-01-04 | Cymetech, Llc | High activity metal carbene metathesis catalysts generated using a thermally activated N-heterocyclic carbene precursor |
KR100869981B1 (ko) | 2001-03-26 | 2008-11-24 | 다우 글로벌 테크놀로지스 인크. | 불포화 지방산 에스테르 또는 불포화 지방산과 저급 올레핀과의 상호교환반응 |
WO2002083742A2 (en) * | 2001-04-16 | 2002-10-24 | California Institute Of Technology | Group 8 transition metal carbene complexes as enantioselective olefin metathesis catalysts |
DE10137051A1 (de) | 2001-07-31 | 2003-02-20 | Bayer Ag | Neue Übergangsmetall-Komplexe und deren Einsatz in Übergangsmetall-katalysierten Reaktionen |
US6818586B2 (en) | 2001-08-01 | 2004-11-16 | Cymetech, Llp | Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts |
WO2003027079A1 (fr) | 2001-09-20 | 2003-04-03 | Zeon Corporation | Complexes de ruthenium, leur procede de preparation, et procedes de production de polymeres a anneau ouvert de cycloolefines et de produits d'hydrogenation associes, au moyen desdits complexes en tant que catalyseurs |
EP1489106B1 (de) * | 2002-03-11 | 2012-05-09 | Japan Science and Technology Agency | Auf polymeren immobilisierte aren-ruthenium-komplexe, katalysatoren aus diesen komplexen und verfahren für organische synthesen damit |
US7576227B2 (en) | 2002-04-29 | 2009-08-18 | Union Carbide Chemicals & Plastics Technology Corporation | Integrate chemical processes for industrial utilization of seed oils |
BRPI0406756A (pt) * | 2003-01-13 | 2005-12-20 | Cargill Inc | Método para fabricação de agentes quìmicos industriais |
US7094898B2 (en) * | 2003-05-29 | 2006-08-22 | University Of Ottawa | Ruthenium compounds, their production and use |
BRPI0415176B1 (pt) | 2003-10-09 | 2014-04-15 | Dow Global Technologies Llc | Processo de preparação de um álcool insaturado e composição |
WO2007081987A2 (en) * | 2006-01-10 | 2007-07-19 | Elevance Renewable Sciences, Inc. | Method of making hydrogenated metathesis products |
EP2046719B1 (de) | 2006-07-12 | 2013-09-04 | Elevance Renewable Sciences, Inc. | Ringöffnungs-kreuzmetathese zyklischer olefine mit samenölen und dergleichen |
US8067610B2 (en) | 2006-07-13 | 2011-11-29 | Yann Schrodi | Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis |
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CN102123979A (zh) | 2006-10-13 | 2011-07-13 | 埃莱文斯可更新科学公司 | 通过烯烃复分解由内烯烃合成末端烯烃的方法 |
EP3281931A1 (de) | 2006-10-13 | 2018-02-14 | Elevance Renewable Sciences, Inc. | Verfahren zur herstellung von organischen verbindungen durch metathese |
US8492552B2 (en) * | 2007-06-20 | 2013-07-23 | Agency For Science, Technology And Research | N-heterocyclic carbene metallacycle catalysts and methods |
EP2027920B1 (de) | 2007-08-21 | 2014-10-08 | LANXESS Deutschland GmbH | Katalysatoren für Metathese-Reaktionen |
DE102007039527A1 (de) | 2007-08-21 | 2009-02-26 | Lanxess Deutschland Gmbh | Katalysatoren für Metathese-Reaktionen |
DE102007039695A1 (de) | 2007-08-22 | 2009-02-26 | Lanxess Deutschland Gmbh | Katalysatoren für Metathese-Reaktionen |
US8241575B2 (en) | 2008-01-28 | 2012-08-14 | The Johns Hopkins University | Molecularly imprinted polymer sensor device |
EP2350159A1 (de) | 2008-10-31 | 2011-08-03 | Dow Global Technologies LLC | Olefinmetatheseverfahren unter verwendung eines bimetallischen rutheniumkomplexes mit verbrückenden hydrido-liganden |
EP2210870A1 (de) | 2009-01-23 | 2010-07-28 | Evonik Degussa GmbH | Hydroxy- und aldehydfunktionale Verbindungen |
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EP2280017B1 (de) | 2009-07-21 | 2013-01-02 | Rimtec Corporation | Katalytischer Komplex für Olefin-Metathesenreaktionen, Herstellungsverfahren und Verwendung davon |
PL2506972T3 (pl) * | 2009-12-03 | 2019-09-30 | Umicore Ag & Co. Kg | Nośnikowe katalizatory metatezy olefin |
GB201004732D0 (en) | 2010-03-22 | 2010-05-05 | Univ Aberdeen | Ruthenium complexes for use in olefin metathesis |
KR101033506B1 (ko) | 2010-09-13 | 2011-05-09 | 주식회사 이너트론 | 커플링 소자를 구비한 광대역 공진 필터 |
EP2684905A1 (de) | 2011-03-08 | 2014-01-15 | Zeon Corporation | Polymerisierbare zusammensetzung, formharz und laminat |
BR112014003140A2 (pt) * | 2011-08-15 | 2017-06-13 | Lanxess Deutschland Gmbh | catalisador de complexo á base de rutênio e processo de hidrogenação de substratos que possuem pelo menos uma dupla ligação carbono-carbono |
GB201116719D0 (en) | 2011-09-28 | 2011-11-09 | Univ St Andrews | Ruthenium polymerisation catalysts |
CN103974772B (zh) * | 2011-10-21 | 2017-03-29 | 阿朗新科德国有限责任公司 | 包括钌或锇卡宾络合物和末端烯烃的催化剂组合物及其用于氢化丁腈橡胶的用途 |
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US9266914B2 (en) | 2013-06-26 | 2016-02-23 | The United States of America, as requested by the Secretary of the Air Force | Backfluorinated NHC carbenes and complexes |
CN107250142B (zh) | 2014-07-03 | 2020-10-30 | 光明创新(武汉)有限公司 | 第8族过渡金属催化剂及其制备方法和其在复分解反应中的应用 |
US9828347B2 (en) | 2014-10-09 | 2017-11-28 | The United States Of America As Represented By The Secretary Of The Air Force | Backfunctionalized imidazolinium salts and NHC carbene-metal complexes |
BR112018005823A2 (pt) | 2015-09-24 | 2018-10-16 | Umicore Ag & Co Kg | catalisadores de metátese de metal-carbeno-olefina |
US9776179B2 (en) | 2015-11-18 | 2017-10-03 | Provivi, Inc. | Production of fatty olefin derivatives via olefin metathesis |
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US5146033A (en) | 1990-01-04 | 1992-09-08 | Massachusetts Institute Of Technology | Homogeneous rhenium catalysts for metathesis of olefins |
US5077414A (en) * | 1990-03-29 | 1991-12-31 | E. I. Du Pont De Nemours And Company | Preparation of 1,3-disubstituted imidazolium salts |
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-
1999
- 1999-09-09 US US09/392,869 patent/US7622590B1/en not_active Expired - Fee Related
- 1999-09-09 AT AT99945604T patent/ATE438462T1/de not_active IP Right Cessation
- 1999-09-09 EP EP09010060.3A patent/EP2116302B1/de not_active Expired - Lifetime
- 1999-09-09 WO PCT/US1999/020629 patent/WO2000015339A1/en active Application Filing
- 1999-09-09 DE DE69941219T patent/DE69941219D1/de not_active Expired - Lifetime
- 1999-09-09 JP JP2000569918A patent/JP5066656B2/ja not_active Expired - Fee Related
- 1999-09-09 AU AU58175/99A patent/AU5817599A/en not_active Abandoned
- 1999-09-09 EP EP99945604A patent/EP1115491B1/de not_active Expired - Lifetime
- 1999-09-09 CA CA2343798A patent/CA2343798C/en not_active Expired - Lifetime
- 1999-11-09 TW TW088115620A patent/TW536427B/zh not_active IP Right Cessation
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2004
- 2004-05-17 US US10/847,978 patent/US20040210055A1/en not_active Abandoned
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2009
- 2009-11-19 US US12/622,225 patent/US7902389B2/en not_active Expired - Fee Related
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2010
- 2010-03-09 JP JP2010051468A patent/JP2010188341A/ja active Pending
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2011
- 2011-03-07 US US13/041,573 patent/US20120004418A1/en not_active Abandoned
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2012
- 2012-12-03 JP JP2012264339A patent/JP2013099739A/ja active Pending
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- 2013-01-25 US US13/750,265 patent/US8859779B2/en not_active Expired - Fee Related
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- 2014-12-12 JP JP2014252051A patent/JP2015096261A/ja active Pending
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CA2343798C (en) | 2010-11-23 |
EP2116302B1 (de) | 2017-02-22 |
US20160243535A1 (en) | 2016-08-25 |
JP2016135485A (ja) | 2016-07-28 |
JP2010188341A (ja) | 2010-09-02 |
CA2343798A1 (en) | 2000-03-23 |
US9233365B2 (en) | 2016-01-12 |
JP2015096261A (ja) | 2015-05-21 |
JP2013099739A (ja) | 2013-05-23 |
US20100160642A1 (en) | 2010-06-24 |
US20120004418A1 (en) | 2012-01-05 |
EP2116302A1 (de) | 2009-11-11 |
US20150018557A1 (en) | 2015-01-15 |
EP1115491A4 (de) | 2002-11-20 |
EP1115491B1 (de) | 2009-08-05 |
JP5066656B2 (ja) | 2012-11-07 |
US8859779B2 (en) | 2014-10-14 |
US20040210055A1 (en) | 2004-10-21 |
EP1115491A1 (de) | 2001-07-18 |
ATE438462T1 (de) | 2009-08-15 |
US7902389B2 (en) | 2011-03-08 |
WO2000015339A1 (en) | 2000-03-23 |
US7622590B1 (en) | 2009-11-24 |
US9339805B2 (en) | 2016-05-17 |
TW536427B (en) | 2003-06-11 |
JP5993104B2 (ja) | 2016-09-14 |
AU5817599A (en) | 2000-04-03 |
JP2002524250A (ja) | 2002-08-06 |
US20130261296A1 (en) | 2013-10-03 |
US20150202610A1 (en) | 2015-07-23 |
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