EA201890300A1 - Способ получения карбонильного соединения ацеталя - Google Patents

Способ получения карбонильного соединения ацеталя

Info

Publication number
EA201890300A1
EA201890300A1 EA201890300A EA201890300A EA201890300A1 EA 201890300 A1 EA201890300 A1 EA 201890300A1 EA 201890300 A EA201890300 A EA 201890300A EA 201890300 A EA201890300 A EA 201890300A EA 201890300 A1 EA201890300 A1 EA 201890300A1
Authority
EA
Eurasian Patent Office
Prior art keywords
acetal
carbonyl
ethylene glycol
raw material
carbonylation
Prior art date
Application number
EA201890300A
Other languages
English (en)
Other versions
EA035211B1 (ru
Inventor
Юмин Ни
Вэньлян Чжу
Юн Лю
Хончао Лю
Чжунминь Лю
Мяо Ян
Пэн Тянь
Original Assignee
Далянь Инститьют Оф Кемикал Физикс, Чайниз Академи Оф Сайэнс
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Далянь Инститьют Оф Кемикал Физикс, Чайниз Академи Оф Сайэнс filed Critical Далянь Инститьют Оф Кемикал Физикс, Чайниз Академи Оф Сайэнс
Publication of EA201890300A1 publication Critical patent/EA201890300A1/ru
Publication of EA035211B1 publication Critical patent/EA035211B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
    • C07C69/708—Ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/10—Constitutive chemical elements of heterogeneous catalysts of Group I (IA or IB) of the Periodic Table
    • B01J2523/17—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/10—Constitutive chemical elements of heterogeneous catalysts of Group I (IA or IB) of the Periodic Table
    • B01J2523/18—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/30—Constitutive chemical elements of heterogeneous catalysts of Group III (IIIA or IIIB) of the Periodic Table
    • B01J2523/32—Gallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/80—Constitutive chemical elements of heterogeneous catalysts of Group VIII of the Periodic Table
    • B01J2523/82—Metals of the platinum group
    • B01J2523/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/80—Constitutive chemical elements of heterogeneous catalysts of Group VIII of the Periodic Table
    • B01J2523/82—Metals of the platinum group
    • B01J2523/828—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/80—Constitutive chemical elements of heterogeneous catalysts of Group VIII of the Periodic Table
    • B01J2523/84—Metals of the iron group
    • B01J2523/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/80—Constitutive chemical elements of heterogeneous catalysts of Group VIII of the Periodic Table
    • B01J2523/84—Metals of the iron group
    • B01J2523/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/80—Constitutive chemical elements of heterogeneous catalysts of Group VIII of the Periodic Table
    • B01J2523/84—Metals of the iron group
    • B01J2523/847—Nickel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
    • C07C2529/85—Silicoaluminophosphates (SAPO compounds)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Настоящая заявка обеспечивает способ получения карбонильного соединения ацеталя, используемого в качестве промежуточного соединения для получения этиленгликоля, который предусматривает стадию, на которой сырьевой материал ацеталь и сырьевой газообразный монооксид углерода проходят через реактор, загруженный катализатором, содержащим кислотное микропористое кремнийалюмофосфатное молекулярное сито, для проведения реакции карбонилирования. В способе настоящего изобретения скорость конверсии сырьевого материала ацеталя высока, и селективность карбонилирования ацеталя высока, и срок службы катализатора длинный, и никакого дополнительного растворителя не требуется в процессе реакции, и условия реакции относительно умеренные, а процесс непрерывный, что показывает потенциал для промышленного применения. Кроме того, продукт - карбонильное соединение ацеталя - можно использовать для получения этиленгликоля путем гидрирования с последующим гидролизом.
EA201890300A 2015-07-20 2015-12-08 Способ получения карбонильного соединения ацеталя EA035211B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201510426676.1A CN106365992B (zh) 2015-07-20 2015-07-20 一种制备缩醛羰化物的方法
PCT/CN2015/096647 WO2017012245A1 (zh) 2015-07-20 2015-12-08 一种制备缩醛羰化物的方法

Publications (2)

Publication Number Publication Date
EA201890300A1 true EA201890300A1 (ru) 2018-08-31
EA035211B1 EA035211B1 (ru) 2020-05-15

Family

ID=57833585

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201890300A EA035211B1 (ru) 2015-07-20 2015-12-08 Способ получения карбонильного соединения ацеталя

Country Status (6)

Country Link
US (1) US10508073B2 (ru)
EP (1) EP3326995B1 (ru)
JP (1) JP6523548B2 (ru)
CN (1) CN106365992B (ru)
EA (1) EA035211B1 (ru)
WO (1) WO2017012245A1 (ru)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019061358A1 (zh) * 2017-09-29 2019-04-04 中国科学院大连化学物理研究所 一种合成气直接生产乙酸甲酯和/或乙酸的方法
CN109833905A (zh) * 2017-11-29 2019-06-04 中国科学院大连化学物理研究所 分子筛催化剂及其制备方法和应用
CN114345401B (zh) * 2022-01-10 2023-06-02 万华化学集团股份有限公司 一种对羟基苯氧乙醇的制备方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58152841A (ja) * 1982-03-08 1983-09-10 Toa Nenryo Kogyo Kk アルコキシ酢酸エステルの製造方法
US4792620A (en) * 1983-10-14 1988-12-20 Bp Chemicals Limited Carbonylation catalysts
US6127432A (en) * 1998-01-29 2000-10-03 Union Carbide Chemicals & Plastics Technology Corporation Processes for preparing oxygenates and catalysts therefor
US6812372B2 (en) 2001-03-01 2004-11-02 Exxonmobil Chemical Patents Inc. Silicoaluminophosphate molecular sieve
UA95663C2 (ru) * 2006-12-15 2011-08-25 Зе Регентс Оф Зе Юніверситі Оф Каліфорнія Способ получения с1-с3-алифатической карбоновой кислоты и/или соответствующего сложного эфира путем карбонилирования
US7772423B2 (en) * 2008-10-23 2010-08-10 The Regents Of The University Of California Process for the production of alkyl alkoxyacetates
CN103172516B (zh) * 2011-12-20 2014-11-26 中国科学院大连化学物理研究所 一种负载型杂多酸催化剂用于甲缩醛气相羰基化生产甲氧基乙酸甲酯的方法
CN103172517B (zh) * 2011-12-20 2015-05-27 中国科学院大连化学物理研究所 一种生产甲氧基乙酸甲酯的方法
CN103831124A (zh) 2012-11-26 2014-06-04 上海碧科清洁能源技术有限公司 一种用于二甲醚羰基化合成乙酸甲酯的含磷沸石催化剂以及使用该催化剂的方法
CN104119228B (zh) * 2013-04-26 2016-04-20 中国科学院大连化学物理研究所 一种合成甲氧基乙酸甲酯的方法
CN104725224B (zh) * 2013-12-23 2017-04-12 中国科学院大连化学物理研究所 制备聚甲氧基二甲醚羰化物及甲氧基乙酸甲酯的方法
EA029435B1 (ru) 2013-12-23 2018-03-30 Далянь Инститьют Оф Кемикал Физикс, Чайниз Академи Оф Сайенсез Способ получения карбонильного соединения диметилового эфира полиоксиметилена и метилметоксиацетата
US9908783B2 (en) * 2014-01-22 2018-03-06 California Institute Of Technology Methods for producing crystalline microporous solids with the RTH topology and compositions derived from the same

Also Published As

Publication number Publication date
WO2017012245A1 (zh) 2017-01-26
US20180201567A1 (en) 2018-07-19
JP6523548B2 (ja) 2019-06-05
EA035211B1 (ru) 2020-05-15
CN106365992B (zh) 2019-01-01
EP3326995A4 (en) 2018-08-15
EP3326995B1 (en) 2019-07-31
US10508073B2 (en) 2019-12-17
EP3326995A1 (en) 2018-05-30
CN106365992A (zh) 2017-02-01
JP2018522010A (ja) 2018-08-09

Similar Documents

Publication Publication Date Title
EA201890301A1 (ru) Способ получения метилацетата
CY1120779T1 (el) Διαδικασια για την παραγωγη ακρυλικων ενωσεων απο εποξειδια
WO2014008232A3 (en) Process for acrylate production
EA201890795A1 (ru) Способ прямого получения диметилового эфира гликоля и совместного получения этиленгликоля из монометилового эфира этиленгликоля
EA201892204A2 (ru) Способ получения промежуточных соединений для получения азоксистробина
EA201890300A1 (ru) Способ получения карбонильного соединения ацеталя
EA201691233A1 (ru) Способ получения карбонильного соединения диметилового эфира полиоксиметилена и метилметоксиацетата
MX2015007902A (es) Recuperacion y uso de acidos carboxilicos procedentes de un caldo de fermentacion.
MY195498A (en) Novel method to produce acrylic acid with acetaldehyde as the main by-product
RU2016145670A (ru) Улучшенные каталитические характеристики в способах получения уксусной кислоты
ZA202002840B (en) Method for producing aldehyde and method for producing alcohol
EA201890652A1 (ru) Способ получения уксусной кислоты карбонилированием метанола
RU2016146790A (ru) Способ совместного получения уксусной кислоты и диметилового эфира
EA201890299A1 (ru) Способ получения алкилового эфира низшей жирной кислоты
EA200801410A1 (ru) Способ производства диалкилкарбоната и диола в промышленном масштабе
MY170265A (en) Polythiols as cis/trans isomerization catalysts for unsaturated compounds
WO2015029059A3 (en) A process for preparation of unsaturated ketone
MY170264A (en) Nitrogen monoxide as cis/trans isomerization catalysts for unsaturated compounds
GB2529007A8 (en) Process for making esters
MY182164A (en) Process for producing acetic acid by introducing a lithium compound
EA201790194A1 (ru) Способ модернизации комплекса по производству карбамида
EA201691848A1 (ru) Способ запуска и эксплуатации реактора фишера-тропша
Masalitina et al. Catalytic ammonia oxidation to nitrogen (I) oxide
BR112015026740A2 (pt) método para sintetizar derivados de furano, e, método para preparar derivados de furano
EA201500756A1 (ru) Способ получения формилвалериановой кислоты и адипиновой кислоты

Legal Events

Date Code Title Description
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ