CN1866603B - 电解质、电池和形成钝化层的方法 - Google Patents

电解质、电池和形成钝化层的方法 Download PDF

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Publication number
CN1866603B
CN1866603B CN200610071187XA CN200610071187A CN1866603B CN 1866603 B CN1866603 B CN 1866603B CN 200610071187X A CN200610071187X A CN 200610071187XA CN 200610071187 A CN200610071187 A CN 200610071187A CN 1866603 B CN1866603 B CN 1866603B
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electrolyte
battery
additive
lithium
carbonic acid
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CN1866603A (zh
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K·詹布纳坦
G·丹特辛
W·J·小卡斯蒂尔
S·V·伊瓦诺弗
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Air Products and Chemicals Inc
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0567—Liquid materials characterised by the additives
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/60—Other road transportation technologies with climate change mitigation effect
    • Y02T10/70—Energy storage systems for electromobility, e.g. batteries

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
CN200610071187XA 2005-01-11 2006-01-11 电解质、电池和形成钝化层的方法 Expired - Fee Related CN1866603B (zh)

Applications Claiming Priority (4)

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US64281505P 2005-01-11 2005-01-11
US60/642815 2005-01-11
US11/300,287 US20060216612A1 (en) 2005-01-11 2005-12-15 Electrolytes, cells and methods of forming passivation layers
US11/300287 2005-12-15

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CN1866603B true CN1866603B (zh) 2010-12-08

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US (2) US20060216612A1 (https=)
EP (1) EP1679760A1 (https=)
JP (1) JP4610490B2 (https=)
KR (1) KR100828532B1 (https=)
CN (1) CN1866603B (https=)
TW (1) TWI323951B (https=)

Families Citing this family (102)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7785740B2 (en) 2004-04-09 2010-08-31 Air Products And Chemicals, Inc. Overcharge protection for electrochemical cells
US7641992B2 (en) 2004-10-29 2010-01-05 Medtronic, Inc. Medical device having lithium-ion battery
US20080044728A1 (en) * 2004-10-29 2008-02-21 Medtronic, Inc. Lithium-ion battery
US7635541B2 (en) * 2004-10-29 2009-12-22 Medtronic, Inc. Method for charging lithium-ion battery
US7662509B2 (en) 2004-10-29 2010-02-16 Medtronic, Inc. Lithium-ion battery
US8980453B2 (en) 2008-04-30 2015-03-17 Medtronic, Inc. Formation process for lithium-ion batteries
US7337010B2 (en) 2004-10-29 2008-02-26 Medtronic, Inc. Medical device having lithium-ion battery
US9065145B2 (en) 2004-10-29 2015-06-23 Medtronic, Inc. Lithium-ion battery
US7563541B2 (en) 2004-10-29 2009-07-21 Medtronic, Inc. Lithium-ion battery
CN101048898B (zh) 2004-10-29 2012-02-01 麦德托尼克公司 锂离子电池及医疗装置
US7927742B2 (en) 2004-10-29 2011-04-19 Medtronic, Inc. Negative-limited lithium-ion battery
US7811705B2 (en) 2004-10-29 2010-10-12 Medtronic, Inc. Lithium-ion battery
US9077022B2 (en) 2004-10-29 2015-07-07 Medtronic, Inc. Lithium-ion battery
US7582387B2 (en) 2004-10-29 2009-09-01 Medtronic, Inc. Lithium-ion battery
US8105714B2 (en) 2004-10-29 2012-01-31 Medtronic, Inc. Lithium-ion battery
US20060216612A1 (en) * 2005-01-11 2006-09-28 Krishnakumar Jambunathan Electrolytes, cells and methods of forming passivation layers
US20080026297A1 (en) * 2005-01-11 2008-01-31 Air Products And Chemicals, Inc. Electrolytes, cells and methods of forming passivaton layers
US20070072085A1 (en) * 2005-09-26 2007-03-29 Zonghai Chen Overcharge protection for electrochemical cells
CN100576624C (zh) * 2006-01-18 2009-12-30 松下电器产业株式会社 组合电池、电源系统及组合电池的制造方法
US8168330B2 (en) * 2006-04-11 2012-05-01 Enerdel, Inc. Lithium titanate cell with reduced gassing
KR20140083054A (ko) * 2006-06-02 2014-07-03 미쓰비시 가가꾸 가부시키가이샤 비수계 전해액 및 비수계 전해액 전지
KR100977974B1 (ko) * 2007-01-16 2010-08-24 주식회사 엘지화학 공융혼합물을 포함하는 전해질 및 이를 이용하는 이차 전지
KR100793011B1 (ko) * 2007-02-16 2008-01-08 에스케이에너지 주식회사 리튬이차전지의 제조방법
US8758945B2 (en) * 2007-03-06 2014-06-24 Air Products And Chemicals, Inc. Overcharge protection by coupling redox shuttle chemistry with radical polymerization additives
AU2008222726A1 (en) 2007-03-08 2008-09-12 Board of Governors for Higher Education, State of Rhode Island and the Providence Plantations Novel electrolyte for lithium ion batteries
EP2158635B1 (en) * 2007-06-11 2013-07-31 LG Chem, Ltd. Non-aqueous electrolyte and secondary battery comprising the same
JP5177361B2 (ja) * 2007-07-23 2013-04-03 ソニー株式会社 二次電池用負極および二次電池
US9755269B2 (en) * 2007-11-30 2017-09-05 Air Products And Chemicals, Inc. Dodecaborate salt radical anion compositions and methods for making and using such compositions
JP2009164082A (ja) * 2008-01-10 2009-07-23 Sanyo Electric Co Ltd 非水電解質二次電池及びその製造方法
WO2009131700A2 (en) 2008-04-25 2009-10-29 Envia Systems, Inc. High energy lithium ion batteries with particular negative electrode compositions
KR101025278B1 (ko) * 2008-05-29 2011-03-29 삼성에스디아이 주식회사 음극활물질, 이를 구비하는 음극 및 리튬이차전지
JP2011527090A (ja) * 2008-07-03 2011-10-20 ボード オブ ガバナーズ フォー ハイヤー エデュケーション， ステート オブ ロード アイランド アンド プロヴィデンス プランテーションズ 電解質添加物によるリチウムイオン電池電解質の酸化の抑制
US8795905B2 (en) 2008-07-10 2014-08-05 Uchicago Argonne, Llc Electrolytes for lithium ion batteries
KR101002566B1 (ko) * 2008-07-29 2010-12-17 삼성에스디아이 주식회사 리튬 이온 이차 전지용 전해액 및 이를 포함하는 리튬 이온이차 전지
US9012073B2 (en) * 2008-11-11 2015-04-21 Envia Systems, Inc. Composite compositions, negative electrodes with composite compositions and corresponding batteries
JP5300468B2 (ja) * 2008-12-26 2013-09-25 昭和電工株式会社 非水電解液
US8450404B2 (en) * 2009-06-16 2013-05-28 Honeywell Federal Manufacturing & Technologies, Llc Compositions containing borane or carborane cage compounds and related applications
TW201133983A (en) 2009-11-03 2011-10-01 Envia Systems Inc High capacity anode materials for lithium ion batteries
KR20120095975A (ko) 2009-11-16 2012-08-29 다우 글로벌 테크놀로지스 엘엘씨 인-황 화합물을 함유하는 배터리 전해질 용액
US8993177B2 (en) 2009-12-04 2015-03-31 Envia Systems, Inc. Lithium ion battery with high voltage electrolytes and additives
US11876180B2 (en) * 2019-11-06 2024-01-16 Enevate Corporation Silicon-based energy storage devices with metal sulfide containing electrolyte additives
EP2541654B1 (en) * 2010-02-24 2014-11-19 LG Chem, Ltd. High-capacity positive electrode active material and lithium secondary battery comprising same
JP2011175821A (ja) * 2010-02-24 2011-09-08 Sanyo Electric Co Ltd リチウム二次電池及びその製造方法
JP5145367B2 (ja) * 2010-03-11 2013-02-13 株式会社日立製作所 非水電解液及びこれを用いたリチウム二次電池
EP2609647B1 (en) 2010-08-24 2017-03-15 Sion Power Corporation Electrolyte materials for use in electrochemical cells
DE102010043111A1 (de) * 2010-10-29 2012-05-03 Robert Bosch Gmbh Ex-situ-Herstellung einer Lithiumanodenschutzschicht
KR101147239B1 (ko) 2010-11-02 2012-05-18 삼성에스디아이 주식회사 리튬 이차 전지의 양극 보호막용 조성물, 상기 양극 보호막을 포함하는 리튬 이차 전지 및 그 제조 방법
US8092942B1 (en) 2010-12-07 2012-01-10 E.I. Du Pont De Nemours And Company Multifunctional sulfone/fluorinated ester solvents
TWI453971B (zh) * 2011-02-22 2014-09-21 Univ Nat Taiwan Science Tech 鋰電池及其製造方法
US9601228B2 (en) 2011-05-16 2017-03-21 Envia Systems, Inc. Silicon oxide based high capacity anode materials for lithium ion batteries
FR2976735B1 (fr) * 2011-06-14 2014-06-20 Commissariat Energie Atomique Electrolyte liquide pour accumulateur au lithium, comprenant un melange ternaire de solvants organiques non aqueux.
US9287580B2 (en) 2011-07-27 2016-03-15 Medtronic, Inc. Battery with auxiliary electrode
JP6178317B2 (ja) 2011-09-02 2017-08-09 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ リチウムイオン電池
CN102306835B (zh) * 2011-09-02 2014-12-17 广州天赐高新材料股份有限公司 一种锰系材料为正极的锂离子电池用耐高电压高温安全型电解液及其用途
CA2844466C (en) 2011-09-02 2021-08-17 E. I. Du Pont De Nemours And Company Fluorinated electrolyte compositions
US20130149560A1 (en) 2011-12-09 2013-06-13 Medtronic, Inc. Auxiliary electrode for lithium-ion battery
US9139441B2 (en) 2012-01-19 2015-09-22 Envia Systems, Inc. Porous silicon based anode material formed using metal reduction
US9780358B2 (en) 2012-05-04 2017-10-03 Zenlabs Energy, Inc. Battery designs with high capacity anode materials and cathode materials
US10553871B2 (en) 2012-05-04 2020-02-04 Zenlabs Energy, Inc. Battery cell engineering and design to reach high energy
JP5960503B2 (ja) * 2012-05-18 2016-08-02 トヨタ自動車株式会社 非水二次電池の製造方法
US10044066B2 (en) 2012-06-01 2018-08-07 Solvary SA Fluorinated electrolyte compositions
JP6319305B2 (ja) 2012-06-01 2018-05-09 ソルベー エスアー リチウムイオンバッテリ
JP6216154B2 (ja) 2012-06-01 2017-10-18 株式会社半導体エネルギー研究所 蓄電装置用負極及び蓄電装置
EP2869389B1 (en) * 2012-06-29 2019-11-13 Mitsubishi Chemical Corporation Nonaqueous electrolytic solution and nonaqueous electrolytic solution cell using same
US20140091748A1 (en) * 2012-09-28 2014-04-03 Quantumscape Corporation Battery control systems
US9577289B2 (en) 2012-12-17 2017-02-21 Sion Power Corporation Lithium-ion electrochemical cell, components thereof, and methods of making and using same
TWI501444B (zh) 2012-12-20 2015-09-21 Ind Tech Res Inst 鋰離子二次電池用的電解液添加劑
US10686220B2 (en) 2013-04-04 2020-06-16 Solvay Sa Nonaqueous electrolyte compositions
US10020491B2 (en) 2013-04-16 2018-07-10 Zenlabs Energy, Inc. Silicon-based active materials for lithium ion batteries and synthesis with solution processing
US10886526B2 (en) 2013-06-13 2021-01-05 Zenlabs Energy, Inc. Silicon-silicon oxide-carbon composites for lithium battery electrodes and methods for forming the composites
US10411299B2 (en) 2013-08-02 2019-09-10 Zenlabs Energy, Inc. Electrolytes for stable cycling of high capacity lithium based batteries
WO2015024004A1 (en) 2013-08-16 2015-02-19 Envia Systems, Inc. Lithium ion batteries with high capacity anode active material and good cycling for consumer electronics
EP3091603B1 (en) * 2014-03-27 2020-01-29 Daikin Industries, Ltd. Electrolytic solution and electrochemical device
KR102272271B1 (ko) * 2014-09-16 2021-07-02 삼성에스디아이 주식회사 리튬 이차 전지
WO2016160703A1 (en) 2015-03-27 2016-10-06 Harrup Mason K All-inorganic solvents for electrolytes
CN107017433B (zh) * 2016-01-28 2019-02-22 宁德新能源科技有限公司 非水电解液及锂离子电池
US10707531B1 (en) 2016-09-27 2020-07-07 New Dominion Enterprises Inc. All-inorganic solvents for electrolytes
KR102290316B1 (ko) * 2016-10-18 2021-08-18 삼성에스디아이 주식회사 리튬 이차 전지
US11038207B2 (en) * 2016-12-02 2021-06-15 Semiconductor Energy Laboratory Co., Ltd. Power storage device and electronic device
CN106597305B (zh) * 2016-12-09 2019-01-22 合肥国轩高科动力能源有限公司 一种锂离子电池的循环寿命预测方法
JP6740147B2 (ja) * 2017-02-01 2020-08-12 トヨタ自動車株式会社 非水電解液および非水電解液二次電池の製造方法
CN109148959B (zh) * 2017-06-28 2023-07-25 松下知识产权经营株式会社 锂二次电池
EP3656004A1 (en) 2017-07-21 2020-05-27 QuantumScape Corporation Active and passive battery pressure management
US11094925B2 (en) 2017-12-22 2021-08-17 Zenlabs Energy, Inc. Electrodes with silicon oxide active materials for lithium ion cells achieving high capacity, high energy density and long cycle life performance
US20200220223A1 (en) * 2019-01-09 2020-07-09 GM Global Technology Operations LLC Ionic liquid electrolytes for high voltage battery application
CN109904518A (zh) * 2019-01-29 2019-06-18 中国科学院金属研究所 一种固态电解质膜的制备方法和应用
KR102495135B1 (ko) 2019-04-03 2023-02-02 주식회사 엘지에너지솔루션 리튬 이차 전지용 전해질 및 이를 포함하는 리튬 이차 전지
US10727545B1 (en) * 2019-04-12 2020-07-28 Ses Holdings Pte. Ltd. Methods of charging secondary lithium metal batteries to reactive dead lithium with redox shuttling additives and battery control systems incorporating the same
FR3095552B1 (fr) * 2019-04-25 2021-04-02 Renault Sas Procédé de formation d’une cellule de batterie Li-ion
CN110176622B (zh) * 2019-05-15 2022-05-24 华南理工大学 一种金属锂二次电池电解液及其制备方法与应用
CN110148785A (zh) * 2019-05-29 2019-08-20 珠海冠宇电池有限公司 一种适配硅碳负极的电解液和锂离子电池
US11973178B2 (en) 2019-06-26 2024-04-30 Ionblox, Inc. Lithium ion cells with high performance electrolyte and silicon oxide active materials achieving very long cycle life performance
CN112864459B (zh) * 2019-11-28 2022-07-12 广东工业大学 一种电解液及其制备方法和二次锂金属电池
CN115606027B (zh) * 2020-06-15 2025-12-30 株式会社村田制作所 二次电池
US11450883B2 (en) 2020-06-30 2022-09-20 Toyota Motor Engineering & Manufacturing North America, Inc. Enhanced solid closo-borane electrolytes for batteries
US12355079B2 (en) 2020-07-02 2025-07-08 Ionblox, Inc. Lithium ion cells with silicon based active materials and negative electrodes with water-based binders having good adhesion and cohesion
CN112599874B (zh) * 2020-12-09 2022-06-14 中国科学院上海硅酸盐研究所 一种提高准固态锂离子电池性能的电化学预处理方法
CN116547043A (zh) * 2021-03-19 2023-08-04 科慕埃弗西有限公司 锂离子电池的热保护
CN115050930B (zh) * 2022-02-07 2023-06-09 万向一二三股份公司 一种复合高镍层状正极材料、正极片及全固态锂电池
US12469884B2 (en) 2022-06-22 2025-11-11 Toyota Motor Engineering & Manufacturing North America, Inc. Electrolytes with low cationic mobility activation energies
CN115746040B (zh) * 2022-11-08 2025-06-17 中国科学院兰州化学物理研究所 一种硼酸酯离子液体润滑添加剂、制备方法及其应用
CN119764631B (zh) * 2024-12-30 2026-03-27 孝感楚能新能源创新科技有限公司 一种电池的化成方法及应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4020240A (en) * 1975-09-03 1977-04-26 P. R. Mallory & Co., Inc. Electrochemical cell with clovoborate salt in electrolyte and method of operation and composition of matter
US4071664A (en) * 1977-04-01 1978-01-31 P. R. Mallory & Co. Inc. Electrolyte salt additive
CN1227561A (zh) * 1996-08-16 1999-09-01 默克专利股份有限公司 硼酸锂配合物的制备方法

Family Cites Families (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52101287A (en) * 1976-02-20 1977-08-25 Japan Synthetic Rubber Co Ltd Preparation of conjugated diene polymers
US4201839A (en) 1978-11-01 1980-05-06 Exxon Research And Engineering Co. Cell containing an alkali metal anode, a solid cathode, and a closoborane and/or closocarborane electrolyte
US4331743A (en) * 1980-09-02 1982-05-25 Duracell International Inc. Method for increasing recycling life of non-aqueous cells
JPS58220366A (ja) * 1982-06-17 1983-12-21 Sanyo Electric Co Ltd 非水電解質電池
JPS59167969A (ja) * 1983-03-11 1984-09-21 Sanyo Electric Co Ltd 非水電解液電池
JPS59189565A (ja) * 1983-04-12 1984-10-27 Sanyo Electric Co Ltd 非水電解液電池
US4586943A (en) 1983-10-20 1986-05-06 Sumitomo Electric Industries, Ltd. Method for the production of glass preform for optical fibers
US4869977A (en) * 1988-04-25 1989-09-26 Amoco Corporation Electrolyte additive for lithium-sulfur dioxide electrochemical cell
US5571635A (en) 1994-04-15 1996-11-05 National Research Council Of Canada Electrolyte for a secondary cell
FR2719161B1 (fr) 1994-04-22 1996-08-02 Accumulateurs Fixes Générateur électrochimique rechargeable au lithium à anode de carbone.
US5849432A (en) 1995-11-03 1998-12-15 Arizona Board Of Regents Wide electrochemical window solvents for use in electrochemical devices and electrolyte solutions incorporating such solvents
US6346351B1 (en) 1996-09-30 2002-02-12 Danionics A/S Lithium salt/carbonate electrolyte system, a method for the preparation thereof, the use thereof and a battery containing the electrolyte system
WO1998043983A1 (en) 1997-04-03 1998-10-08 Colorado State University Research Foundation Polyhalogenated monoheteroborane anion compositions
DE19724709A1 (de) 1997-06-13 1998-12-17 Hoechst Ag Elektrolytsystem für Lithiumbatterien und dessen Verwendung sowie Verfahren zur Erhöhung der Sicherheit von Lithiumbatterien
DE19910968A1 (de) * 1999-03-12 2000-11-09 Merck Patent Gmbh Anwendung von Additiven in Elektrolyten für elektrochemische Zellen
US6200356B1 (en) * 1999-05-17 2001-03-13 The United States Of America As Represented By The Secretary Of The Army Lithium ion secondary electrochemical cell and a method of preventing the electrochemical dissolution of a copper current collector therein
JP3824465B2 (ja) 1999-08-02 2006-09-20 セントラル硝子株式会社 イオン性錯体の合成法
JP4547748B2 (ja) * 1999-10-29 2010-09-22 パナソニック株式会社 非水電解質電池
JP3732986B2 (ja) 1999-12-22 2006-01-11 三洋電機株式会社 リチウム二次電池
US20020110739A1 (en) * 2000-05-26 2002-08-15 Mcewen Alan B. Non-flammable electrolytes
JP4762411B2 (ja) * 2000-06-26 2011-08-31 パナソニック株式会社 二次電池用非水電解液およびこれを用いた非水電解液二次電池
KR100756812B1 (ko) * 2000-07-17 2007-09-07 마츠시타 덴끼 산교 가부시키가이샤 비수 전기화학 장치
EP1195834B1 (en) * 2000-10-03 2010-09-15 Central Glass Company, Limited Electrolyte for electrochemical device
US6335466B1 (en) 2000-10-31 2002-01-01 Colorado State University Research Foundation Fluorinated amino polyhedral borate compounds
US6924061B1 (en) * 2001-02-13 2005-08-02 The United States Of America As Represented By The Secretary Of Army Nonflammable non-aqueous electrolyte and non-aqueous electrolyte cells comprising the same
CN1278444C (zh) * 2001-04-09 2006-10-04 三星Sdi株式会社 锂二次电池的无水电解液及包含它的锂二次电池的制备方法
US6849752B2 (en) * 2001-11-05 2005-02-01 Central Glass Company, Ltd. Process for synthesizing ionic metal complex
JP3714237B2 (ja) * 2001-11-19 2005-11-09 日亜化学工業株式会社 ハーフバナドセン化合物の製造方法
US7172834B1 (en) * 2002-07-29 2007-02-06 The United States Of America As Represented By The Secretary Of The Army Additive for enhancing the performance of electrochemical cells
US7632317B2 (en) * 2002-11-04 2009-12-15 Quallion Llc Method for making a battery
US20050106470A1 (en) * 2003-01-22 2005-05-19 Yoon Sang Y. Battery having electrolyte including one or more additives
US6781005B1 (en) * 2003-05-01 2004-08-24 Air Products And Chemicals, Inc. Process for the fluorination of boron hydrides
JP4728598B2 (ja) 2003-06-16 2011-07-20 株式会社豊田中央研究所 リチウムイオン二次電池
US7968235B2 (en) * 2003-07-17 2011-06-28 Uchicago Argonne Llc Long life lithium batteries with stabilized electrodes
US7311993B2 (en) * 2003-09-04 2007-12-25 Air Products And Chemicals, Inc. Polyfluorinated boron cluster anions for lithium electrolytes
CA2479589C (en) * 2003-09-04 2011-05-24 Air Products And Chemicals, Inc. Polyfluorinated boron cluster anions for lithium electrolytes
JP2005166536A (ja) * 2003-12-04 2005-06-23 Sanyo Electric Co Ltd 非水電解質二次電池
US7785740B2 (en) * 2004-04-09 2010-08-31 Air Products And Chemicals, Inc. Overcharge protection for electrochemical cells
US7311933B2 (en) * 2004-04-13 2007-12-25 Eastman Kodak Company Packaging material for inhibiting microbial growth
US7419623B2 (en) * 2004-08-03 2008-09-02 Air Products And Chemicals, Inc. Proton conducting mediums for electrochemical devices and electrochemical devices comprising the same
US7465517B2 (en) * 2004-08-23 2008-12-16 Air Products And Chemicals, Inc. High purity lithium polyhalogenated boron cluster salts useful in lithium batteries
US20060216612A1 (en) * 2005-01-11 2006-09-28 Krishnakumar Jambunathan Electrolytes, cells and methods of forming passivation layers
US20070072085A1 (en) * 2005-09-26 2007-03-29 Zonghai Chen Overcharge protection for electrochemical cells
TWI338396B (en) * 2006-01-17 2011-03-01 Lg Chemical Ltd Additives for non-aqueous electrolyte and lithium secondary battery using the same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4020240A (en) * 1975-09-03 1977-04-26 P. R. Mallory & Co., Inc. Electrochemical cell with clovoborate salt in electrolyte and method of operation and composition of matter
US4071664A (en) * 1977-04-01 1978-01-31 P. R. Mallory & Co. Inc. Electrolyte salt additive
CN1227561A (zh) * 1996-08-16 1999-09-01 默克专利股份有限公司 硼酸锂配合物的制备方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Kang Xu,Shengshui Zhang,T. Richard Jow et al..LiBOB as Salt for Lithium-Ion Batteries A Possible Solution forHigh Temperature Operation.Electrochemical and Solid-State Letters5 1.2001,5(1),A26-A29.
Kang Xu,Shengshui Zhang,T. Richard Jow et al..LiBOB as Salt for Lithium-Ion Batteries A Possible Solution forHigh Temperature Operation.Electrochemical and Solid-State Letters5 1.2001,5(1),A26-A29. *

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