CN1625571B - 聚合物颗粒的水分散液 - Google Patents

聚合物颗粒的水分散液 Download PDF

Info

Publication number
CN1625571B
CN1625571B CN028275217A CN02827521A CN1625571B CN 1625571 B CN1625571 B CN 1625571B CN 028275217 A CN028275217 A CN 028275217A CN 02827521 A CN02827521 A CN 02827521A CN 1625571 B CN1625571 B CN 1625571B
Authority
CN
China
Prior art keywords
polymerization
alkyl
optionally substituted
raft agent
amphiphilic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN028275217A
Other languages
English (en)
Chinese (zh)
Other versions
CN1625571A (zh
Inventor
C·H·苏克
E·里扎多
A·K·塞雷利斯
B·S·霍凯特
R·G·吉尔伯特
C·J·弗古森
R·J·休斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Sydney
Original Assignee
University of Sydney
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from AUPR9708A external-priority patent/AUPR970801A0/en
Priority claimed from AU2002950772A external-priority patent/AU2002950772A0/en
Application filed by University of Sydney filed Critical University of Sydney
Publication of CN1625571A publication Critical patent/CN1625571A/zh
Application granted granted Critical
Publication of CN1625571B publication Critical patent/CN1625571B/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/22Emulsion polymerisation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C329/00Thiocarbonic acids; Halides, esters or anhydrides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C329/00Thiocarbonic acids; Halides, esters or anhydrides thereof
    • C07C329/12Dithiocarbonic acids; Derivatives thereof
    • C07C329/14Esters of dithiocarbonic acids
    • C07C329/16Esters of dithiocarbonic acids having sulfur atoms of dithiocarbonic groups bound to acyclic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/22Emulsion polymerisation
    • C08F2/24Emulsion polymerisation with the aid of emulsifying agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D157/00Coating compositions based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00Living radical polymerisation
    • C08F2438/03Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Polymerisation Methods In General (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Sealing Material Composition (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN028275217A 2001-12-21 2002-12-20 聚合物颗粒的水分散液 Expired - Lifetime CN1625571B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
AUPR9708 2001-12-21
AUPR9708A AUPR970801A0 (en) 2001-12-21 2001-12-21 Aqueous dispersions of polymer particles
AU2002950772A AU2002950772A0 (en) 2002-08-14 2002-08-14 Aqueous dispersions of polymer particles
AU2002/950772 2002-08-14
PCT/AU2002/001735 WO2003055919A1 (en) 2001-12-21 2002-12-20 Aqueous dispersions of polymer particles

Publications (2)

Publication Number Publication Date
CN1625571A CN1625571A (zh) 2005-06-08
CN1625571B true CN1625571B (zh) 2010-10-06

Family

ID=25646866

Family Applications (1)

Application Number Title Priority Date Filing Date
CN028275217A Expired - Lifetime CN1625571B (zh) 2001-12-21 2002-12-20 聚合物颗粒的水分散液

Country Status (13)

Country Link
US (2) US7745553B2 (enExample)
EP (1) EP1463765B1 (enExample)
JP (2) JP4405807B2 (enExample)
KR (2) KR101000839B1 (enExample)
CN (1) CN1625571B (enExample)
AU (1) AU2002350285B2 (enExample)
BR (1) BR0215285B1 (enExample)
CA (1) CA2470522C (enExample)
IL (2) IL162557A0 (enExample)
MX (1) MXPA04006145A (enExample)
NZ (1) NZ533519A (enExample)
WO (1) WO2003055919A1 (enExample)
ZA (1) ZA200404992B (enExample)

Families Citing this family (80)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2868068B1 (fr) 2004-03-29 2006-07-14 Coatex Soc Par Actions Simplif Nouveaux composes soufres : utilisation comme agent de transfert pour la polymerisation radicalaire controlee de l'acide acrylique, polymeres obtenus et leurs applications
US20060036030A1 (en) * 2002-11-06 2006-02-16 Kuraray Co., Ltd. Thermoplastic polymer powder
FR2868072B1 (fr) * 2004-07-28 2006-06-30 Coatex Soc Par Actions Simplif Polymeres obtenus par l'utilisation de composes soufres comme agents de transfert pour la polymerisation radicalaire controlee de l'acide acrylique et leurs applications
US7851572B2 (en) 2004-07-28 2010-12-14 Coatex S.A.S. Polymers produced by using sulphur compounds in the form of transfer agents for controlled radical polymerisation of acrylic acid and the use thereof
WO2006023790A1 (en) * 2004-08-20 2006-03-02 Noveon, Inc. Curable thiocarbonate compounds and compositions
BRPI0516445B1 (pt) * 2004-10-04 2018-11-21 Univ Sydney métodos para polimerizar monômero para formar polímero na superfície de material particulado, e para preparar uma tinta de pintura, tinta de pintura em pó termofundível, carga, adesivo, tonalizador, tinta de impressão líquida, revestimento base, selante, produto diagnóstico ou produto terapêutico, e tinta, tinta em pó termofundível, carga, adesivo, tonalizante, tinta líquida, revestimento base, selante, produto diagnóstico ou produto terapêutico
CN101084241B (zh) * 2004-10-04 2011-08-17 悉尼大学 使用raft试剂的表面聚合方法和聚合产物
JP2007039654A (ja) * 2005-07-08 2007-02-15 Tosoh Corp クロロプレン系ブロック共重合体及びその製造法
DE112006001808T5 (de) * 2005-07-08 2008-06-19 Tosoh Corporation Blockcopolymer auf Chloroprenbasis, seifenfreier Latex auf Polychloroprenbasis und Verfahren zur Herstellung derselbigen
US7230063B1 (en) * 2005-12-22 2007-06-12 The Goodyear Tire & Rubber Company Functional trithiocarbonate RAFT agents
JP4978946B2 (ja) * 2006-02-08 2012-07-18 株式会社 資生堂 Gpcスタンダード用イオン性ポリマー
KR20070097742A (ko) * 2006-03-29 2007-10-05 주식회사 엘지화학 염화비닐계 수지 제조용 분산제 및 이를 이용한 염화비닐계수지의 제조 방법
CA2643596A1 (en) * 2006-04-03 2007-10-11 The University Of Sydney Polymer product and interfacial polymerisation process using raft agent
EP2041193B1 (fr) 2006-07-05 2010-12-29 Solvay SA Procédé de préparation d'un latex d'un polymère vinylique chloré
US20090306311A1 (en) 2008-06-05 2009-12-10 The Administrators Of The Tulane Educational Fund Methods and instrumentation for during-synthesis monitoring of polymer functional evolution
WO2008046156A1 (en) * 2006-10-20 2008-04-24 The University Of Sydney Vesiculated polymer particles
GB0624729D0 (en) * 2006-12-12 2007-01-17 Univ Leeds Reversible micelles and applications for their use
WO2008122576A1 (en) * 2007-04-05 2008-10-16 Dsm Ip Assets B.V. Aqueous oligomer / polymer emulsion with cationic functionality
JP5133606B2 (ja) * 2007-06-04 2013-01-30 Agcセイミケミカル株式会社 界面活性剤
JP2009001776A (ja) 2007-06-11 2009-01-08 Rohm & Haas Co 水性エマルジョンポリマー会合性増粘剤
ES2365106T3 (es) * 2007-08-02 2011-09-22 Dsm Ip Assets B.V. Dispersiones acuosas que contienen copolímeros de bloques cristalizables.
CN101918465A (zh) * 2008-01-17 2010-12-15 帝斯曼知识产权资产管理有限公司 利用raft得到的水性可交联嵌段共聚物
EP2268758B1 (en) 2008-03-20 2013-12-18 Avery Dennison Corporation Acrylic polymers having controlled placement of functional groups
FR2931154B1 (fr) * 2008-05-14 2011-04-08 Univ Paris Curie Copolymere amphiphile a blocs, procede pour sa preparation
US8912273B2 (en) 2008-06-17 2014-12-16 Basf Se Process for the preparation of an aqueous polymer dispersion
WO2010000725A1 (en) * 2008-06-30 2010-01-07 Dsm Ip Assets B.V. Adhesion to metal surfaces with block copolymers obtained using raft
FR2934861B1 (fr) * 2008-08-05 2012-12-28 Arkema France Nouveaux modifiants chocs du type coeur-ecorce pour matrices polymeres transparentes.
WO2010038046A1 (en) * 2008-10-03 2010-04-08 Chamelic Ltd Ab diblock copolymers and applications for their use
EP2182011A1 (de) 2008-10-29 2010-05-05 Basf Se Verfahren zur Herstellung von wässrigen Polyacrylsäurelösungen mittels kontrollierter radikalischer Polymerisation
EP2401304A4 (en) * 2009-02-24 2012-09-05 Univ Sydney Polymer Particles
US20100315588A1 (en) * 2009-06-16 2010-12-16 Bausch & Lomb Incorporated Biomedical devices
NZ600426A (en) 2009-12-01 2014-05-30 Univ Sydney Water swellable polymer materials
EP2921477A3 (en) * 2010-01-27 2015-11-25 Mitsubishi Rayon Co., Ltd. Novel chain transfer agent and emulsion polymerization using same
GB201003970D0 (en) * 2010-03-10 2010-04-21 Univ Sheffield Polymer synthesis
US9644063B2 (en) 2010-05-19 2017-05-09 Avery Dennison Corporation Ordered architectures in acrylic polymers
CN101864049A (zh) * 2010-06-12 2010-10-20 陕西科技大学 一种高分子表面活性剂的制备方法
CN101982478A (zh) * 2010-09-26 2011-03-02 北京印刷学院 一种大分子表面活性剂和核-壳两亲型聚合物微球及其制备方法
US9428649B2 (en) * 2010-11-05 2016-08-30 E Ink California, Llc Electrophoretic dispersion
JP2012233147A (ja) * 2011-03-31 2012-11-29 Canon Inc 高分子粒子の製造方法
US9339781B2 (en) * 2011-05-31 2016-05-17 The University Of Sydney Polymer particles
KR101887243B1 (ko) * 2011-07-13 2018-08-09 에이지씨 세이미 케미칼 가부시키가이샤 경화성 수지 조성물 및 그 용도
WO2013035206A1 (ja) * 2011-09-09 2013-03-14 ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン 電子装置用シール剤組成物
EP2766404B1 (en) 2011-10-14 2019-11-13 Avery Dennison Corporation Controlled architecture polymers
CN104271621B (zh) * 2011-12-21 2017-09-05 索尔维公司 用于制备偏二氯乙烯聚合物的方法
CN104125968B (zh) * 2011-12-21 2017-10-13 索尔维公司 用于制备偏二氯乙烯聚合物/粘土复合材料的方法
FR2986235B1 (fr) * 2012-01-31 2015-02-06 Rhodia Operations Stabilisants reactifs poly(n-vinyl lactame) vivants pour polymerisation en phase dispersee
FR2986234B1 (fr) * 2012-01-31 2014-06-13 Rhodia Operations Stabilisants reactifs poly(n-vinyl lactame) vivants pour polymerisation en phase dispersee
WO2013113750A1 (fr) * 2012-01-31 2013-08-08 Rhodia Operations Stabilisants réactifs poly(n-vinyl lactame) vivants pour polymérisation en phase dispersée
JP5805006B2 (ja) * 2012-05-14 2015-11-04 株式会社クラレ ビニルエステルとビニルエーテルの共重合体、およびその製造方法
CN102690217B (zh) * 2012-05-31 2014-04-16 同济大学 一种用于可逆加成断裂链转移聚合的高效链转移剂三硫酯的制备方法
CN102746475B (zh) * 2012-06-18 2014-04-23 浙江理工大学 含异氰酸酯基团的三硫代碳酸酯化合物及制备方法和应用
CN102746478B (zh) * 2012-07-13 2014-07-16 浙江大学 含玻璃化温度高于100℃嵌段的嵌段共聚物及制备方法
EP2907856B1 (en) * 2012-10-11 2019-05-01 The Yokohama Rubber Co., Ltd. Water-based primer composition
WO2014181523A1 (ja) * 2013-05-07 2014-11-13 株式会社豊田自動織機 ポリマーとその製造方法
FR3012462B1 (fr) * 2013-10-31 2016-01-01 Arkema France Compositions stables de poly (3,4-ethylenedioxythiophene) et de stabilisants anioniques a acidite limitee
US10647793B2 (en) 2014-03-28 2020-05-12 Synthomer (Uk) Limited Use of a sulphur or phosphorous-containing polymer as a processing aid in a polyvinyl chloride polymer composition
MX2016012328A (es) 2014-03-28 2017-01-23 Synthomer (Uk) Ltd Agente de suspension secundario para reaccion de polimerizacion en suspension.
US9732169B2 (en) * 2014-07-22 2017-08-15 University Of South Carolina Raft agents and their use in the development of polyvinylpyrrolidone grafted nanoparticles
JP2018520994A (ja) * 2015-05-08 2018-08-02 ザ ルブリゾル コーポレイションThe Lubrizol Corporation 水溶性連鎖移動剤
CA2977932A1 (en) * 2016-09-23 2018-03-23 Rohm And Haas Company Latex functionalized with structural units of an amino acid
WO2019026914A1 (ja) * 2017-07-31 2019-02-07 デンカ株式会社 ブロック共重合体及びブロック共重合体の製造方法
FR3071500B1 (fr) * 2017-09-27 2020-05-15 Arkema France Synthese de latex de poly(fluorure de vinylidene) sans tensioactif par polymerisation en emulsion raft
BR112020008116A2 (pt) * 2017-10-31 2020-11-03 The University Of Sydney partículas de clorotalonil revestidas e seu processo de preparação, composição agroquímica compreendendo referidas partículas, método para controlar ou prevenir infestação de plantas úteis por microrganismos fitopatogênicos e método para reduzir a toxicidade por inalação de partículas de clorotalonil ou composições compreendendo as mesmas
KR20190064794A (ko) * 2017-12-01 2019-06-11 현대자동차주식회사 메타크릴계 블록 공중합체의 제조 방법
TWI800575B (zh) * 2017-12-20 2023-05-01 美商盧伯利索先進材料有限公司 苯乙烯馬來醯胺嵌段共聚物顏料分散劑及其形成方法
KR101997538B1 (ko) * 2017-12-29 2019-07-09 금호석유화학 주식회사 Raft제 및 이를 이용한 공중합체의 제조방법
CN112004849A (zh) * 2018-05-31 2020-11-27 Sika技术股份公司 用于制备明确限定的梳形聚合物的方法
CN109867736B (zh) * 2019-03-15 2022-01-04 重庆科技学院 一种可逆加成断裂链转移试剂及其制备方法和应用
AU2020251047A1 (en) * 2019-04-01 2021-10-28 The University Of Sydney Non-core-shell polymer particles
JP7465165B2 (ja) * 2020-07-09 2024-04-10 テクノUmg株式会社 ポリマーを含む粒子の水分散体の製造方法、及びブロックポリマーの製造方法
CN113463402B (zh) * 2021-06-28 2024-04-02 深圳万知达科技有限公司 一种pH响应超疏水-亲水可逆转化材料表面的制备方法
JP7405891B2 (ja) * 2022-03-29 2023-12-26 テクノUmg株式会社 Raft重合用反応液
JP7405892B2 (ja) * 2022-03-29 2023-12-26 テクノUmg株式会社 Raft重合用反応液の製造方法
US12319769B2 (en) 2022-03-29 2025-06-03 Techno-Umg Co., Ltd. Raft polymerization reaction solution and raft polymerization reaction solution production method
CN115181276A (zh) * 2022-08-26 2022-10-14 潍坊瑞通环保科技有限公司 改性环氧树脂及其制备方法、环氧树脂涂料及其制备方法、应用
CN116496454B (zh) * 2023-06-30 2023-09-26 河北合众建材有限公司 一种低温法合成多支化保坍型聚醚减水剂及制备方法
CN116693906B (zh) * 2023-07-07 2023-11-28 珠海嘉雄包装材料有限公司 一种高强度pe复合膜及其制备工艺
WO2025064359A1 (en) * 2023-09-20 2025-03-27 Isp Investments Llc Block copolymers with polyether moieties and applications thereof
CN117089315B (zh) * 2023-10-19 2024-02-09 宁波长阳科技股份有限公司 一种水性锂电池聚酰亚胺粘合剂及制备方法、锂电池极片
WO2025097130A1 (en) * 2023-11-03 2025-05-08 The Brigham And Women's Hospital, Inc. Injectable in situ cross-linked depots for ultra-long-term delivery of hydrophilic drugs

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999031144A1 (en) * 1997-12-18 1999-06-24 E.I. Du Pont De Nemours And Company Polymerization process with living characteristics and polymers made therefrom
WO2001077198A1 (en) * 2000-04-07 2001-10-18 E.I. Dupont De Nemours And Company Process of microgel synthesis and products produced therefrom

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69709110T2 (de) * 1996-07-10 2002-04-25 Commonwealth Scientific And Industrial Research Organisation, Clayton Polymerisation mit "living" kennzeichen
AUPO669697A0 (en) * 1997-05-08 1997-06-05 Unisearch Limited Polymerisation reactions under miniemulsion conditions
EP1149075B1 (en) * 1997-07-21 2008-12-31 Commonwealth Scientific and Industrial Research Organisation Synthesis of dithioester chain transfer agents
AUPP337298A0 (en) * 1998-05-07 1998-05-28 University Of Melbourne, The Process for microgel preparation
NZ509746A (en) 1998-07-10 2003-09-26 Commw Scient Ind Res Org Microgels and process for their preparation
US7064151B1 (en) * 2000-04-07 2006-06-20 E. I. Du Pont De Nemours And Company Process of microgel synthesis and products produced therefrom
AU2001274146A1 (en) * 2000-05-29 2001-12-11 Bio Merieux Biocompatible polymer for fixing biological ligands
US6458968B2 (en) * 2000-06-09 2002-10-01 Rensselaer Polytechnic Institute Dithiocarboxylic ester synthetic process
EP1205492A1 (en) * 2000-11-08 2002-05-15 ETHZ, Laboratorium für Technische Chemie LTC Process for producing homo- and co-polymers by RAFT miniemulsion polymerization

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999031144A1 (en) * 1997-12-18 1999-06-24 E.I. Du Pont De Nemours And Company Polymerization process with living characteristics and polymers made therefrom
WO2001077198A1 (en) * 2000-04-07 2001-10-18 E.I. Dupont De Nemours And Company Process of microgel synthesis and products produced therefrom

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
WO 0177198 A1,全文.
WO 9931144 A1,全文.

Also Published As

Publication number Publication date
ZA200404992B (en) 2005-04-26
CA2470522C (en) 2012-05-01
US7745553B2 (en) 2010-06-29
EP1463765B1 (en) 2018-07-18
WO2003055919A1 (en) 2003-07-10
NZ533519A (en) 2007-07-27
IL162557A (en) 2010-05-31
JP5173914B2 (ja) 2013-04-03
BR0215285B1 (pt) 2014-10-14
EP1463765A1 (en) 2004-10-06
KR20100109960A (ko) 2010-10-11
AU2002350285A1 (en) 2003-07-15
AU2002350285B2 (en) 2008-02-28
BR0215285A (pt) 2004-11-16
CA2470522A1 (en) 2003-07-10
JP4405807B2 (ja) 2010-01-27
EP1463765A4 (en) 2006-05-10
KR101000839B1 (ko) 2010-12-14
JP2009173943A (ja) 2009-08-06
JP2005513252A (ja) 2005-05-12
US20100227975A1 (en) 2010-09-09
IL162557A0 (en) 2005-11-20
MXPA04006145A (es) 2005-03-31
CN1625571A (zh) 2005-06-08
KR20040076260A (ko) 2004-08-31
US20060223936A1 (en) 2006-10-05

Similar Documents

Publication Publication Date Title
CN1625571B (zh) 聚合物颗粒的水分散液
JP2009173943A6 (ja) Raft剤の製造方法、raft剤を用いるポリマー粒子の水性分散液の製造方法およびその方法により得た水性分散液から得られる製品
CN101460525B (zh) 聚合物产品以及使用raft剂的界面聚合反应法
CN102361889B (zh) Raft聚合
JP4711685B2 (ja) 制御された重合
CN1331851C (zh) 链转移剂
CN107108489A (zh) 通用的raft剂
JP2003501528A (ja) ハロゲン化されたキサントゲン酸エステルにより制御された遊離ラジカル重合によって重合体を合成するための方法
JP2001518947A (ja) 制御された遊離ラジカル重合法
JP2003530473A (ja) ミクロゲル合成の方法およびそれから製造される製品
CN101563369A (zh) 小泡状聚合物颗粒
CN107922344A (zh) 通用的raft剂
CN100354313C (zh) 控制聚合
HK1070082B (en) Aqueous dispersions of polymer particles
HK1070082A (en) Aqueous dispersions of polymer particles
JP2025054053A (ja) 粘度調整剤、液状組成物およびその粘度調整方法、インクならびにインクジェットプリンター

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CX01 Expiry of patent term
CX01 Expiry of patent term

Granted publication date: 20101006