FR3071500B1 - Synthese de latex de poly(fluorure de vinylidene) sans tensioactif par polymerisation en emulsion raft - Google Patents

Synthese de latex de poly(fluorure de vinylidene) sans tensioactif par polymerisation en emulsion raft Download PDF

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Publication number
FR3071500B1
FR3071500B1 FR1758966A FR1758966A FR3071500B1 FR 3071500 B1 FR3071500 B1 FR 3071500B1 FR 1758966 A FR1758966 A FR 1758966A FR 1758966 A FR1758966 A FR 1758966A FR 3071500 B1 FR3071500 B1 FR 3071500B1
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FR
France
Prior art keywords
emulsion polymerization
surfactant
synthesis
vinylidene fluoride
latex
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FR1758966A
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English (en)
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FR3071500A1 (fr
Inventor
Samuel Devisme
Andrew Kahn
Mathieu Fuentes-Exposito
Timothy McKenna
Franck D'Agosto
Muriel Lansalot
Anthony Bonnet
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Centre National de la Recherche Scientifique CNRS
Arkema France SA
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Arkema France SA
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Publication date
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to FR1758966A priority Critical patent/FR3071500B1/fr
Priority to CN201880062906.2A priority patent/CN111148772B/zh
Priority to PCT/EP2018/075677 priority patent/WO2019063445A1/fr
Priority to US16/649,686 priority patent/US11326008B2/en
Priority to JP2020517113A priority patent/JP7254782B2/ja
Publication of FR3071500A1 publication Critical patent/FR3071500A1/fr
Application granted granted Critical
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/22—Vinylidene fluoride
    • C08F214/225—Vinylidene fluoride with non-fluorinated comonomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C08F14/22—Vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/16—Homopolymers or copolymers of vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/40—Chemical modification of a polymer taking place solely at one end or both ends of the polymer backbone, i.e. not in the side or lateral chains
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films

Abstract

La présente invention concerne un procédé de production d'un latex fluoré stable par polymérisation en émulsion en l'absence de tensioactif fluoré, stabilisé par un copolymère séquencé amphiphile formé in situ. L'invention concerne en outre la dispersion aqueuse comprenant les chaînes de polymère fluoré et les copolymères séquencés amphiphiles, obtenue par ce procédé.
FR1758966A 2017-09-27 2017-09-27 Synthese de latex de poly(fluorure de vinylidene) sans tensioactif par polymerisation en emulsion raft Active FR3071500B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1758966A FR3071500B1 (fr) 2017-09-27 2017-09-27 Synthese de latex de poly(fluorure de vinylidene) sans tensioactif par polymerisation en emulsion raft
CN201880062906.2A CN111148772B (zh) 2017-09-27 2018-09-21 通过raft乳液聚合合成不含表面活性剂的聚(偏二氟乙烯)胶乳
PCT/EP2018/075677 WO2019063445A1 (fr) 2017-09-27 2018-09-21 Synthèse de latex de poly(fluorure de vinylidène) exempts de tensioactif par polymérisation raft en émulsion
US16/649,686 US11326008B2 (en) 2017-09-27 2018-09-21 Synthesis of surfactant-free poly (vinylidene fluoride) latexes via raft emulsion polymerization
JP2020517113A JP7254782B2 (ja) 2017-09-27 2018-09-21 Ｒａｆｔ乳化重合による界面活性剤を含まないポリ（フッ化ビニリデン）ラテックスの合成

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1758966 2017-09-27
FR1758966A FR3071500B1 (fr) 2017-09-27 2017-09-27 Synthese de latex de poly(fluorure de vinylidene) sans tensioactif par polymerisation en emulsion raft

Publications (2)

Publication Number Publication Date
FR3071500A1 FR3071500A1 (fr) 2019-03-29
FR3071500B1 true FR3071500B1 (fr) 2020-05-15

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
FR1758966A Active FR3071500B1 (fr) 2017-09-27 2017-09-27 Synthese de latex de poly(fluorure de vinylidene) sans tensioactif par polymerisation en emulsion raft

Country Status (5)

Country Link
US (1) US11326008B2 (fr)
JP (1) JP7254782B2 (fr)
CN (1) CN111148772B (fr)
FR (1) FR3071500B1 (fr)
WO (1) WO2019063445A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20210197130A1 (en) * 2018-06-08 2021-07-01 Arkema Inc. Fluoropolymer latex coatings for membranes
JP2022529256A (ja) * 2019-04-16 2022-06-20 ローディア オペレーションズ 選択的親水性マクロ－ｒａｆｔ剤を使用する、高い固形分で低い粘度のラテックスの調製方法
CN112062918B (zh) * 2020-09-14 2022-12-09 浙江理工大学 无硫无皂原位raft乳液共聚合成聚合物/颜料杂化乳胶的方法
CN112457438B (zh) * 2020-12-26 2022-05-10 张家港邦力材料科技有限公司 基于双子型含氟表面活性剂制备氟聚烯烃的方法
CN114230739B (zh) * 2021-12-14 2023-08-11 西安交通大学 一种线性-非线性嵌段聚合物及其制备方法
EP4332128A1 (fr) 2022-09-05 2024-03-06 Arkema France Polymérisation en émulsion de fluorure de vinylidène utilisant de l'alcool polyvinylique comme seul stabilisateur
CN116082544A (zh) * 2022-12-16 2023-05-09 江苏中兴派能电池有限公司 聚偏氟乙烯及其制备方法、正极片以及锂离子电池

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NZ333277A (en) * 1996-07-10 2000-09-29 Commw Scient Ind Res Org Polymerization using dithiocarboxylic acid derivatives as chain transfer agents
EP1392744B1 (fr) * 2001-05-02 2008-07-09 3M Innovative Properties Company Procede de polymerisation par emulsion aqueuse exempte d'emulsifiant permettant de produire des fluoropolymeres
MXPA04006145A (es) * 2001-12-21 2005-03-31 Univ Sydney Dispersiones acuosas de particulas de polimero.
US9561309B2 (en) * 2004-05-27 2017-02-07 Advanced Cardiovascular Systems, Inc. Antifouling heparin coatings
US20060281845A1 (en) * 2005-06-10 2006-12-14 Ramin Amin-Sanayei Aqueous process for making fluoropolymers
US8338518B2 (en) * 2005-06-10 2012-12-25 Arkema Inc. Aqueous process for making a stable fluoropolymer dispersion
US8765890B2 (en) * 2005-06-10 2014-07-01 Arkema Inc. Aqueous process for making fluoropolymers
FR2889703A1 (fr) * 2005-08-09 2007-02-16 Arkema Sa Procede de preparation d'un materiau polymerique comprenant un copolymere multibloc obtenu par polymerisation radicalaire controlee
US8034874B2 (en) * 2005-11-23 2011-10-11 Boston Scientific Scimed, Inc. Medical devices having polymeric regions that contain fluorocarbon-containing block copolymers
EP2530073A4 (fr) * 2010-01-27 2014-10-08 Mitsubishi Rayon Co Nouvel agent de transfert de chaîne et polymérisation en émulsion l'utilisant
WO2013092587A1 (fr) * 2011-12-21 2013-06-27 Solvay Sa Procédé pour la préparation de polymère de chlorure de vinylidène
EP2809698B1 (fr) * 2012-01-31 2016-01-27 Rhodia Operations Polymérisation en phase dispersée de monomères vinyliques halogénés en présence de stabilisants réactifs vivants
FR2986235B1 (fr) * 2012-01-31 2015-02-06 Rhodia Operations Stabilisants reactifs poly(n-vinyl lactame) vivants pour polymerisation en phase dispersee
FR2989972B1 (fr) * 2012-04-26 2015-03-27 Arkema France Copolymerisation radicalaire controlee a partir de trifluoroethylene
US10377843B2 (en) * 2014-05-12 2019-08-13 Solvay Specialty Polymers Italy S.P.A. Method for the controlled polymerization of fluoromonomers
FR3025204B1 (fr) * 2014-08-28 2018-08-10 Chryso Copolymeres a blocs utilisables comme fluidifiants
CN104610519B (zh) * 2015-01-19 2017-03-22 巨化集团技术中心 一种聚偏氟乙烯‑聚乙二醇嵌段共聚物的制备方法
CN105037667B (zh) * 2015-08-27 2017-12-19 济南大学 一种两亲性聚偏氟乙烯基嵌段共聚物及其应用
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Also Published As

Publication number Publication date
WO2019063445A1 (fr) 2019-04-04
JP7254782B2 (ja) 2023-04-10
CN111148772A (zh) 2020-05-12
CN111148772B (zh) 2022-06-07
US20200255566A1 (en) 2020-08-13
JP2020535255A (ja) 2020-12-03
FR3071500A1 (fr) 2019-03-29
US11326008B2 (en) 2022-05-10

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