FR2986235B1 - Stabilisants reactifs poly(n-vinyl lactame) vivants pour polymerisation en phase dispersee - Google Patents

Stabilisants reactifs poly(n-vinyl lactame) vivants pour polymerisation en phase dispersee

Info

Publication number
FR2986235B1
FR2986235B1 FR1200292A FR1200292A FR2986235B1 FR 2986235 B1 FR2986235 B1 FR 2986235B1 FR 1200292 A FR1200292 A FR 1200292A FR 1200292 A FR1200292 A FR 1200292A FR 2986235 B1 FR2986235 B1 FR 2986235B1
Authority
FR
France
Prior art keywords
phase polymerization
disperse phase
vinyl lactam
live poly
stabilizers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1200292A
Other languages
English (en)
Other versions
FR2986235A1 (fr
Inventor
Mathias Destarac
James Wilson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Operations SAS
Original Assignee
Rhodia Operations SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1200292A priority Critical patent/FR2986235B1/fr
Application filed by Rhodia Operations SAS filed Critical Rhodia Operations SAS
Priority to EP13702040.0A priority patent/EP2809698B1/fr
Priority to JP2014553760A priority patent/JP6356073B2/ja
Priority to US14/375,323 priority patent/US9255163B2/en
Priority to CN201380013409.0A priority patent/CN104144956B/zh
Priority to PCT/EP2013/051793 priority patent/WO2013113752A1/fr
Publication of FR2986235A1 publication Critical patent/FR2986235A1/fr
Application granted granted Critical
Publication of FR2986235B1 publication Critical patent/FR2986235B1/fr
Priority to JP2017007266A priority patent/JP2017141438A/ja
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8135—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers, e.g. vinyl esters (polyvinylacetate)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02—Monomers containing chlorine
    • C08F14/04—Monomers containing two carbon atoms
    • C08F14/06—Vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02—Monomers containing chlorine
    • C08F14/04—Monomers containing two carbon atoms
    • C08F14/08—Vinylidene chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C08F14/20—Vinyl fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C08F14/22—Vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F26/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F26/06—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/40—Redox systems
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/10—General cosmetic use
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients
    • A61K2800/33—Free of surfactant
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/52—Stabilizers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
FR1200292A 2012-01-31 2012-01-31 Stabilisants reactifs poly(n-vinyl lactame) vivants pour polymerisation en phase dispersee Expired - Fee Related FR2986235B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1200292A FR2986235B1 (fr) 2012-01-31 2012-01-31 Stabilisants reactifs poly(n-vinyl lactame) vivants pour polymerisation en phase dispersee
JP2014553760A JP6356073B2 (ja) 2012-01-31 2013-01-30 リビング反応安定剤の存在下でのハロゲン化ビニルモノマーの分散相重合
US14/375,323 US9255163B2 (en) 2012-01-31 2013-01-30 Dispersed phase polymerization of halogenated vinyl monomers in the presence of live reactive stabilizers
CN201380013409.0A CN104144956B (zh) 2012-01-31 2013-01-30 活性反应性稳定剂存在下卤化的乙烯基单体的分散相聚合反应
EP13702040.0A EP2809698B1 (fr) 2012-01-31 2013-01-30 Polymérisation en phase dispersée de monomères vinyliques halogénés en présence de stabilisants réactifs vivants
PCT/EP2013/051793 WO2013113752A1 (fr) 2012-01-31 2013-01-30 Polymérisation en phase dispersée de monomères vinyliques halogénés en présence de stabilisants réactifs vivants
JP2017007266A JP2017141438A (ja) 2012-01-31 2017-01-19 リビング反応安定剤の存在下でのハロゲン化ビニルモノマーの分散相重合

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1200292A FR2986235B1 (fr) 2012-01-31 2012-01-31 Stabilisants reactifs poly(n-vinyl lactame) vivants pour polymerisation en phase dispersee

Publications (2)

Publication Number Publication Date
FR2986235A1 FR2986235A1 (fr) 2013-08-02
FR2986235B1 true FR2986235B1 (fr) 2015-02-06

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
FR1200292A Expired - Fee Related FR2986235B1 (fr) 2012-01-31 2012-01-31 Stabilisants reactifs poly(n-vinyl lactame) vivants pour polymerisation en phase dispersee

Country Status (2)

Country Link
JP (2) JP6356073B2 (fr)
FR (1) FR2986235B1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3143054B1 (fr) * 2014-05-12 2019-07-10 Solvay Specialty Polymers Italy S.p.A. Procédé de polymérisation contrôlée de monomères fluorés
FR3071500B1 (fr) * 2017-09-27 2020-05-15 Arkema France Synthese de latex de poly(fluorure de vinylidene) sans tensioactif par polymerisation en emulsion raft
US20230212430A1 (en) * 2020-11-17 2023-07-06 Resonac Corporation Adhesive set, adhesive body, and manufacturing method therefor
WO2022265048A1 (fr) * 2021-06-18 2022-12-22 Ａｇｃ株式会社 Procédé de production d'un copolymère contenant du fluor

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5312882A (en) * 1993-07-30 1994-05-17 The University Of North Carolina At Chapel Hill Heterogeneous polymerization in carbon dioxide
DE19512883A1 (de) * 1995-04-06 1996-10-10 Basf Ag Wäßrige Polymerisatdispersion
JPH09188708A (ja) * 1996-01-05 1997-07-22 Denki Kagaku Kogyo Kk 水溶液微粒子含有材並びにその塗布シート・フィルムの製造方法
JPH09216903A (ja) * 1996-02-13 1997-08-19 Denki Kagaku Kogyo Kk 高内相比乳化状重合体組成物の製造方法
JP3773408B2 (ja) * 2000-06-15 2006-05-10 第一工業製薬株式会社 ビニルピロリドン重合体の製造方法
AU2002238665A1 (en) * 2001-02-26 2002-09-12 Rhodia Chimie Use of an amphiphilic block copolymer as adhesion promoters of film-forming aqueous compositions on a low-energy surface
ATE388970T1 (de) * 2001-05-04 2008-03-15 Rhodia Chimie Sa Blockcopolymer-tenside durch eine kontrollierte radikalpolymerisation hergestellt
CN1625571B (zh) * 2001-12-21 2010-10-06 悉尼大学 聚合物颗粒的水分散液
FR2839723B1 (fr) * 2002-05-14 2004-07-23 Rhodia Chimie Sa Polymere obtenu par polymerisation radicalaire controlee comprenant au moins une fonction boronate, association avec un compose ligand et utilisations
FR2859210B1 (fr) * 2003-09-01 2008-05-09 Oreal Copolymeres ethyleniques sequences comprenant une sequence vinyllactame, compositions cosmetiques les contenant, et utilisation de ces copolymeres en cosmetique
FR2859727B1 (fr) * 2003-09-15 2008-06-27 Oreal Copolymeres ethyleniques sequences comprenant une sequence vinyllactame, compositions cosmetiques ou pharmaceutiques les contenant, et utilisation de ces copolymeres en cosmetique
FR2868072B1 (fr) * 2004-07-28 2006-06-30 Coatex Soc Par Actions Simplif Polymeres obtenus par l'utilisation de composes soufres comme agents de transfert pour la polymerisation radicalaire controlee de l'acide acrylique et leurs applications
NZ594255A (en) * 2009-01-23 2013-09-27 Commw Scient Ind Res Org RAFT polymerisation
US20120202946A1 (en) * 2009-10-29 2012-08-09 Solvay Specialty Polymers Italy S.P.A. Process for the isolation of sulfonyl fluoride polymers and polymers obtained therefrom
FR2965264B1 (fr) * 2010-09-27 2013-11-29 Rhodia Operations Polymerisation radicalaire controlee de n-vinyl lactames en milieu aqueux
US9850364B2 (en) * 2011-12-21 2017-12-26 Solvay Sa Process for the preparation of a vinylidene chloride polymer composite

Also Published As

Publication number Publication date
JP6356073B2 (ja) 2018-07-11
JP2015504960A (ja) 2015-02-16
FR2986235A1 (fr) 2013-08-02
JP2017141438A (ja) 2017-08-17

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