CN110832687B - 用于全固态电池的复合固体电解质膜和包含其的全固态电池 - Google Patents

用于全固态电池的复合固体电解质膜和包含其的全固态电池 Download PDF

Info

Publication number
CN110832687B
CN110832687B CN201980003373.5A CN201980003373A CN110832687B CN 110832687 B CN110832687 B CN 110832687B CN 201980003373 A CN201980003373 A CN 201980003373A CN 110832687 B CN110832687 B CN 110832687B
Authority
CN
China
Prior art keywords
solid
layer
secondary battery
plasticizer
electrolyte membrane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201980003373.5A
Other languages
English (en)
Chinese (zh)
Other versions
CN110832687A (zh
Inventor
柳志勋
金贵龙
安智熙
姜盛中
李在宪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LG Energy Solution Ltd
Original Assignee
LG Energy Solution Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LG Energy Solution Ltd filed Critical LG Energy Solution Ltd
Publication of CN110832687A publication Critical patent/CN110832687A/zh
Application granted granted Critical
Publication of CN110832687B publication Critical patent/CN110832687B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0565Polymeric materials, e.g. gel-type or solid-type
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562Solid materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4235Safety or regulating additives or arrangements in electrodes, separators or electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1399Processes of manufacture of electrodes based on electro-active polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/411Organic material
    • H01M50/414Synthetic resins, e.g. thermoplastics or thermosetting resins
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/411Organic material
    • H01M50/414Synthetic resins, e.g. thermoplastics or thermosetting resins
    • H01M50/417Polyolefins
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/449Separators, membranes or diaphragms characterised by the material having a layered structure
    • H01M50/451Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/449Separators, membranes or diaphragms characterised by the material having a layered structure
    • H01M50/457Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0068Solid electrolytes inorganic
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0082Organic polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0085Immobilising or gelification of electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0088Composites
    • H01M2300/0094Composites in the form of layered products, e.g. coatings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Dispersion Chemistry (AREA)
  • Secondary Cells (AREA)
  • Conductive Materials (AREA)
  • Battery Electrode And Active Subsutance (AREA)
CN201980003373.5A 2018-03-27 2019-03-22 用于全固态电池的复合固体电解质膜和包含其的全固态电池 Active CN110832687B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR20180035291 2018-03-27
KR10-2018-0035291 2018-03-27
PCT/KR2019/003400 WO2019190126A1 (ko) 2018-03-27 2019-03-22 전고체 전지용 복합 고체 전해질 막 및 이를 포함하는 전고체 전지

Publications (2)

Publication Number Publication Date
CN110832687A CN110832687A (zh) 2020-02-21
CN110832687B true CN110832687B (zh) 2023-05-05

Family

ID=68062314

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201980003373.5A Active CN110832687B (zh) 2018-03-27 2019-03-22 用于全固态电池的复合固体电解质膜和包含其的全固态电池

Country Status (7)

Country Link
US (1) US11476498B2 (pl)
EP (1) EP3675265B1 (pl)
JP (1) JP7045593B2 (pl)
KR (1) KR102424995B1 (pl)
CN (1) CN110832687B (pl)
PL (1) PL3675265T3 (pl)
WO (1) WO2019190126A1 (pl)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102395655B1 (ko) * 2018-10-11 2022-05-06 주식회사 엘지에너지솔루션 복합 전해질막 및 상기 복합 전해질막을 포함하는 전고체 전지
US11955595B2 (en) * 2019-04-22 2024-04-09 Bioenno Tech LLC High-ionic conductivity ceramic-polymer nanocomposite solid state electrolyte
TWI719683B (zh) * 2019-10-22 2021-02-21 輝能科技股份有限公司 陶瓷隔離層
CN111342142A (zh) * 2020-03-11 2020-06-26 电子科技大学 一种锂电芯结构、锂电池结构及其制备方法
CN112086611B (zh) * 2020-09-29 2022-09-23 中国第一汽车股份有限公司 一种复合隔膜及其制备方法和应用
CN113258032B (zh) * 2021-04-19 2024-02-02 浙江锋锂新能源科技有限公司 负极材料、负极浆料、电芯、耐低温电池及其制备方法
CN113278310B (zh) * 2021-04-30 2022-06-17 惠州锂威新能源科技有限公司 一种复合陶瓷颗粒及其制备方法和应用
CN113471518A (zh) * 2021-06-22 2021-10-01 暨南大学 一种金属锂二次电池用高致密固态电解质膜及其制备方法
CN113675477B (zh) * 2021-07-07 2023-04-21 华南理工大学 一种适用于4.5v全固态电池的非对称层状聚合物基复合固态电解质及制备方法与应用
CN113659192B (zh) * 2021-08-24 2023-07-14 蜂巢能源科技有限公司 硫化物全固态电芯及其制备方法、全固态锂离子电池
CN113782826B (zh) * 2021-08-25 2024-04-05 珠海冠宇电池股份有限公司 一种固态电解质及包含该固态电解质的固态电池
WO2023106851A1 (ko) 2021-12-08 2023-06-15 주식회사 엘지에너지솔루션 고분자 고체 전해질의 제조방법 및 이로부터 제조된 고분자 고체 전해질
KR20230086622A (ko) 2021-12-08 2023-06-15 주식회사 엘지에너지솔루션 고분자 고체 전해질의 제조방법 및 이로부터 제조된 고분자 고체 전해질
CN114300645A (zh) * 2021-12-10 2022-04-08 湖南立方新能源科技有限责任公司 一种负极片及其制备方法以及锂离子电池
WO2024006758A2 (en) * 2022-06-27 2024-01-04 The Regents Of The University Of California Li-ion-conducting polymer and polymer-ceramic electrolytes for solid state batteries
CN117059887B (zh) * 2023-10-12 2023-12-22 清陶(昆山)能源发展股份有限公司 复合固态电解质膜的制备方法、锂离子电池

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09293518A (ja) * 1996-04-26 1997-11-11 Asahi Chem Ind Co Ltd 薄膜状電解質および該電解質を用いた電池
JP2006016550A (ja) * 2004-07-02 2006-01-19 Mitsubishi Plastics Ind Ltd 多孔性フィルム、電池用セパレータおよび電池
CN102709597A (zh) * 2012-06-01 2012-10-03 中国东方电气集团有限公司 一种复合全固态聚合物电解质锂离子电池及其制备方法
CN106159318A (zh) * 2015-04-07 2016-11-23 中国科学院上海硅酸盐研究所 石榴石型固体电解质支撑的新型片式固态二次锂电池及其制备方法
WO2017135553A1 (ko) * 2016-02-03 2017-08-10 한국생산기술연구원 Llzo 고체전해질을 포함하는 전고체 리튬이차전지 및 그의 제조방법

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5437692A (en) 1994-11-02 1995-08-01 Dasgupta; Sankar Method for forming an electrode-electrolyte assembly
JPH09134730A (ja) * 1995-11-07 1997-05-20 Sanyo Electric Co Ltd 固体電解質電池及びその製造方法
JP3747963B2 (ja) * 1996-06-24 2006-02-22 旭化成ケミカルズ株式会社 高耐熱性ポリエチレン微多孔膜
KR100376051B1 (ko) 1998-03-06 2003-06-12 주식회사 엘지화학 고분자전해질이충전된전극및이의제조방법
JPH11339557A (ja) * 1998-05-29 1999-12-10 Fuji Photo Film Co Ltd 高分子固体電解質およびこれを用いた非水電解質二次電池
JP2000268875A (ja) 1999-03-15 2000-09-29 Toshiba Corp 非水電解液二次電池及びその製造方法
DE19957285A1 (de) 1999-11-29 2001-06-21 Fraunhofer Ges Forschung Folien für elektrochemische Bauelemente sowie Verfahren zu deren Herstellung
JP4033595B2 (ja) 2000-02-02 2008-01-16 三洋電機株式会社 リチウムポリマー二次電池
US6413667B1 (en) * 2000-03-29 2002-07-02 Valence Technology (Nevada), Inc. Flat, bonded-electrode rechargeable electrochemical cell and method of making same
JP2001319690A (ja) 2000-05-12 2001-11-16 Hitachi Maxell Ltd ポリマー電解質電池およびその製造方法
KR20020002858A (ko) 2000-06-30 2002-01-10 한승우 리튬이온 고분자 전지 제조방법
US7470488B2 (en) 2000-08-12 2008-12-30 Lg Chemical Co., Ltd. Multi-component composite film method for preparing the same
KR100373204B1 (ko) * 2000-08-12 2003-02-25 주식회사 엘지화학 고분자 전해질용 다성분계 복합 분리막 및 그의 제조방법
KR100759541B1 (ko) 2001-06-21 2007-09-18 삼성에스디아이 주식회사 폴리머 리튬 전지 및 그 제조방법
JP2013069682A (ja) 2011-09-05 2013-04-18 Asahi Kasei Corp 電気化学デバイスの製造方法
KR101422908B1 (ko) * 2012-04-02 2014-07-23 삼성정밀화학 주식회사 리튬이온 이차전지용 전해질 및 이것을 포함하는 리튬이온 이차전지
KR101747864B1 (ko) 2014-08-28 2017-06-27 삼성전자주식회사 복합전해질 및 이를 포함하는 리튬전지
US10205190B2 (en) 2014-08-28 2019-02-12 Samsung Electronics Co., Ltd. Composite electrolyte including polymeric ionic liquid and inorganic particles and lithium battery including the same
KR101734301B1 (ko) 2015-11-18 2017-05-12 한국에너지기술연구원 리튬 이온 전도성 고체전해질, 그의 제조방법 및 그를 포함하는 리튬 전지
KR101876861B1 (ko) * 2016-08-04 2018-07-10 한국생산기술연구원 전고체 리튬이차전지용 복합 고체전해질 및 그의 제조방법
KR20180035291A (ko) 2016-09-28 2018-04-06 엘지전자 주식회사 공기조화 시스템

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09293518A (ja) * 1996-04-26 1997-11-11 Asahi Chem Ind Co Ltd 薄膜状電解質および該電解質を用いた電池
JP2006016550A (ja) * 2004-07-02 2006-01-19 Mitsubishi Plastics Ind Ltd 多孔性フィルム、電池用セパレータおよび電池
CN102709597A (zh) * 2012-06-01 2012-10-03 中国东方电气集团有限公司 一种复合全固态聚合物电解质锂离子电池及其制备方法
CN106159318A (zh) * 2015-04-07 2016-11-23 中国科学院上海硅酸盐研究所 石榴石型固体电解质支撑的新型片式固态二次锂电池及其制备方法
WO2017135553A1 (ko) * 2016-02-03 2017-08-10 한국생산기술연구원 Llzo 고체전해질을 포함하는 전고체 리튬이차전지 및 그의 제조방법

Also Published As

Publication number Publication date
EP3675265B1 (en) 2021-07-28
US11476498B2 (en) 2022-10-18
KR20190113605A (ko) 2019-10-08
CN110832687A (zh) 2020-02-21
KR102424995B1 (ko) 2022-07-25
JP7045593B2 (ja) 2022-04-01
PL3675265T3 (pl) 2021-12-13
EP3675265A4 (en) 2021-01-06
WO2019190126A1 (ko) 2019-10-03
JP2020526897A (ja) 2020-08-31
US20200153041A1 (en) 2020-05-14
EP3675265A1 (en) 2020-07-01

Similar Documents

Publication Publication Date Title
CN110832687B (zh) 用于全固态电池的复合固体电解质膜和包含其的全固态电池
EP3067979B1 (en) All-solid-state battery containing nano-solid electrolyte and method of manufacturing the same
CN110915051B (zh) 锂金属电池
US9287540B2 (en) Separators for a lithium ion battery
JP4465492B2 (ja) 再充電可能なハイブリッドバッテリ/スーパーキャパシタシステム
JP7094436B2 (ja) 複合電解質膜及び該複合電解質膜を含む全固体電池
CN111384399B (zh) 用于锂金属电极的保护性涂层
KR20060044828A (ko) 세퍼레이터 및 이 세퍼레이터를 사용한 비수전해질 전지
JP4088755B2 (ja) 非水電解質二次電池
US20010041290A1 (en) Lithium polymer secondary battery
JP2001210377A (ja) 高分子電解質組成物、その製造方法及びこれを利用したリチウム二次電池
JP7451009B2 (ja) 全固体電池用負極の製造方法
CN113795940A (zh) 锂二次电池用正极、其制造方法及包括其的锂二次电池
JPH11283612A (ja) リチウム二次電池
KR20180083273A (ko) 겔 폴리머 전해질용 조성물 및 이를 포함하는 리튬 이차전지
JP4624589B2 (ja) 固体型リチウムポリマー電池用バナジウム系複合正極およびそれを用いたリチウムポリマー電池
JP2023553179A (ja) ゲルポリマー電解質二次電池の製造方法及びこれにより製造されたゲルポリマー電解質二次電池
KR20240001926A (ko) 리튬 이차 전지용 음극의 제조 방법 및 리튬 이차 전지
JP2022140503A (ja) 蓄電池のカソード、関連する蓄電池および電池
JP2024501710A (ja) ゲルポリマー電解質二次電池の製造方法及びこれにより製造されたゲルポリマー電解質二次電池

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right

Effective date of registration: 20220802

Address after: Seoul, South Kerean

Applicant after: LG Energy Solution,Ltd.

Address before: Seoul, South Kerean

Applicant before: LG CHEM, Ltd.

TA01 Transfer of patent application right
GR01 Patent grant
GR01 Patent grant