CN1102923C - 氢过氧化物的分解方法 - Google Patents

氢过氧化物的分解方法 Download PDF

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Publication number
CN1102923C
CN1102923C CN98802426A CN98802426A CN1102923C CN 1102923 C CN1102923 C CN 1102923C CN 98802426 A CN98802426 A CN 98802426A CN 98802426 A CN98802426 A CN 98802426A CN 1102923 C CN1102923 C CN 1102923C
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CN
China
Prior art keywords
hydroperoxide
catalyst
solution
decomposition
chhp
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN98802426A
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English (en)
Chinese (zh)
Other versions
CN1246841A (zh
Inventor
J·D·德鲁林纳
N·赫龙
S·P·乔丹
K·库尔塔基斯
S·L·拉内
L·E·曼泽尔
B·E·斯马特
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Invista Technologies Sarl
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of CN1246841A publication Critical patent/CN1246841A/zh
Application granted granted Critical
Publication of CN1102923C publication Critical patent/CN1102923C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
CN98802426A 1997-02-11 1998-02-10 氢过氧化物的分解方法 Expired - Fee Related CN1102923C (zh)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US3756497P 1997-02-11 1997-02-11
US60/037,564 1997-02-11
US60/037564 1997-02-11
US4516597P 1997-04-30 1997-04-30
US60/045,165 1997-04-30
US60/045165 1997-04-30

Publications (2)

Publication Number Publication Date
CN1246841A CN1246841A (zh) 2000-03-08
CN1102923C true CN1102923C (zh) 2003-03-12

Family

ID=26714254

Family Applications (1)

Application Number Title Priority Date Filing Date
CN98802426A Expired - Fee Related CN1102923C (zh) 1997-02-11 1998-02-10 氢过氧化物的分解方法

Country Status (15)

Country Link
US (1) US6284927B1 (enExample)
EP (1) EP1012130B9 (enExample)
JP (1) JP3976793B2 (enExample)
KR (1) KR20000070969A (enExample)
CN (1) CN1102923C (enExample)
AU (1) AU6167498A (enExample)
BR (1) BR9815441B1 (enExample)
CA (1) CA2279493A1 (enExample)
CZ (1) CZ295000B6 (enExample)
DE (1) DE69810944T2 (enExample)
EA (1) EA002422B1 (enExample)
ID (1) ID22219A (enExample)
PL (1) PL336762A1 (enExample)
SK (1) SK105899A3 (enExample)
WO (1) WO1998034894A2 (enExample)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6160183A (en) * 1998-02-10 2000-12-12 E. I. Du Pont De Nemours And Company Direct oxidation of cycloalkanes
RU2239624C2 (ru) * 1998-08-26 2004-11-10 Е.И.Дюпон Де Немур Энд Компани Способ разложения гидропероксида
PL357043A1 (en) * 1999-03-10 2004-07-12 E.I.Du Pont De Nemours And Company Hydroperoxide decomposition process
US6169215B1 (en) * 1999-03-25 2001-01-02 Mobil Oil Corporation Production of phenol
JP2004506703A (ja) * 2000-08-18 2004-03-04 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 改良されたヒドロペルオキシド分解触媒
FR2823745A1 (fr) * 2001-04-20 2002-10-25 Rhodia Polyamide Intermediates Procede de decomposition catalytique des hydroperoxydes organiques
US6984761B2 (en) * 2002-12-16 2006-01-10 Exxonmobil Chemical Patents Inc. Co-production of phenol, acetone, α-methylstyrene and propylene oxide, and catalyst therefor
US7081552B2 (en) * 2004-08-17 2006-07-25 Solutia Inc. Catalysts for cycloalkanes oxidation and decomposition of cycloalkyl hydroperoxide
CN100364663C (zh) * 2006-04-07 2008-01-30 浙江大学 负载型纳米金催化剂及制备方法
US8026398B2 (en) * 2006-05-16 2011-09-27 Narayana Mysore Catalysts comprising a combination of oxidized metals and a method for cleaving phenylalkyl hydroperoxides using the catalysts
US7417003B2 (en) * 2006-12-29 2008-08-26 Uop Llc Solid acid catalyst and process for decomposition of cumene hydroperoxide
JP4955440B2 (ja) * 2007-03-29 2012-06-20 Ｊｘ日鉱日石エネルギー株式会社 ジヒドロキシ芳香族化合物の製造方法
CN102177121B (zh) * 2008-10-10 2015-05-13 埃克森美孚化学专利公司 生产苯酚的方法
US8445730B2 (en) 2008-10-10 2013-05-21 Exxonmobil Chemical Patents Inc. Process for producing phenol
CN105732304A (zh) 2009-02-26 2016-07-06 埃克森美孚化学专利公司 苯酚的制备方法
WO2012145031A2 (en) 2011-04-19 2012-10-26 Exxonmobil Chemical Patents Inc. Process for producing phenol
WO2012145030A1 (en) 2011-04-19 2012-10-26 Exxonmobil Chemical Patents Inc. Process for producing phenol
US8921610B2 (en) 2010-09-14 2014-12-30 Exxonmobil Chemical Patents Inc. Oxidation of alkylbenzenes
CN102161526B (zh) * 2011-03-04 2012-12-12 北京化工大学 氧化镁负载钴铁金属磁性纳米材料在降解废水中橙黄ⅱ的应用
US9388102B2 (en) 2011-04-19 2016-07-12 Exxonmobil Chemical Patents Inc. Process for producing phenol
WO2013052217A2 (en) 2011-10-07 2013-04-11 Exxonmobil Chemical Patents Inc. Mixed metal oxide catalysts and use thereof
CN104326870A (zh) * 2014-09-16 2015-02-04 上海洪鲁化工技术有限公司 一种环己基过氧化氢的加氢分解方法
ES2731818T3 (es) * 2014-11-28 2019-11-19 Rhodia Operations Proceso para la fabricación de alcohol y/o cetona a partir de hidroperóxidos
CN106268847A (zh) * 2015-06-08 2017-01-04 中国石油化工股份有限公司 一种环己烷氧化液分解催化剂的制备及分解工艺

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3941845A (en) * 1972-10-21 1976-03-02 Stamicarbon, B.V. Process for preparing cycloalkanones and cycloalkanols
CN1066839A (zh) * 1991-03-25 1992-12-09 Dsm有限公司 制备烷酮和/或烷醇的方法
CN1107829A (zh) * 1993-12-23 1995-09-06 Dsm有限公司 制备烷酮和/或烷醇的方法

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3093686A (en) 1963-06-11 Production of cyclic alcohols
US2609395A (en) 1949-12-16 1952-09-02 Phillips Petroleum Co Oxidation of hydrocarbons
US2675407A (en) 1952-04-10 1954-04-13 Standard Oil Dev Co Air oxidation of cycloalkanes
US2851496A (en) * 1954-07-27 1958-09-09 Du Pont Preparation of oxidation products of cyclohexane
US2854487A (en) * 1955-04-12 1958-09-30 Distillers Co Yeast Ltd Process for the manufacture of carbinols
US3530185A (en) 1966-08-08 1970-09-22 Du Pont Oxidation process
FR1547427A (fr) 1967-05-26 1968-11-29 Rhone Poulenc Sa Perfectionnement à la préparation de mélanges cycloalcanols/cycloalcanones
US3598869A (en) 1967-12-05 1971-08-10 Celanese Corp Oxidation of cyclohexane to nylon precursors
US3927105A (en) 1968-04-08 1975-12-16 Rhone Poulenc Sa Process for the preparation of mixtures of cycloalkanols and cycloalkanones
FR2087365A5 (enExample) 1970-05-15 1971-12-31 Rhone Poulenc Sa
GB1347913A (en) 1970-06-09 1974-02-27 Basf Ag Production of cycloalkanols and cycloalkanones
US3957876A (en) 1970-07-31 1976-05-18 E. I. Du Pont De Nemours And Company Process for the oxidation of cyclohexane
BE777013A (nl) * 1970-12-30 1972-06-21 Shell Int Research Werkwijze voor de ontleding van organische peroxyverbindingen
NL174343C (nl) 1973-10-09 1984-06-01 Stamicarbon Werkwijze voor het bereiden van cycloalkanonen en cycloalkanolen door omzetting van een cycloalkylhydroperoxide.
US3987100A (en) 1974-04-11 1976-10-19 E. I. Du Pont De Nemours And Company Cyclohexane oxidation in the presence of binary catalysts
GB1502767A (en) 1974-05-06 1978-03-01 Burmah Oil Trading Ltd Production of phenols
US4326084A (en) 1979-10-11 1982-04-20 E. I. Du Pont De Nemours And Company Process for producing a mixture containing cyclohexanol and cyclohexanone from cyclohexane
GB8303574D0 (en) * 1983-02-09 1983-03-16 Ici Plc Hydrocarbon conversion processes
US4503257A (en) 1983-05-18 1985-03-05 E. I. Du Pont De Nemours And Company Cyclohexyl hydroperoxide decomposition process
US4783557A (en) 1986-09-12 1988-11-08 Mitsui Petrochemical Industries, Ltd. Processes for preparing hydroxynaphthalenes
NL8802592A (nl) 1988-10-21 1990-05-16 Stamicarbon Werkwijze voor de bereiding van een k/a-mengsel.
US5023383A (en) 1989-01-13 1991-06-11 Mitsubishi Petrochemical Co., Ltd. Method for producing aromatic alcohol
NL9000893A (nl) * 1990-04-14 1991-11-01 Stamicarbon Werkwijze voor de bereiding van een cycloalkanon en/of cycloalkanol.
NL9201756A (nl) * 1992-10-09 1994-05-02 Univ Delft Tech Werkwijze voor de gekatalyseerde ontleding van organische hydroperoxiden.
US5364988A (en) 1993-11-12 1994-11-15 Texaco Chemical Company Use of supported chromium catalyst in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide
US5414141A (en) 1993-11-12 1995-05-09 Texaco Chemical Inc. Use of supported palladium catalysts in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide
US5401889A (en) 1993-11-12 1995-03-28 Texaco Chemical Inc. Preparation of tertiary butyl alcohol by catalytic decomposition of tertiary butyl hydroperoxide
US5399794A (en) 1993-11-12 1995-03-21 Texaco Chemical Inc. Use of supported palladium/gold catalysts in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide
US5414163A (en) 1993-11-12 1995-05-09 Texaco Chemical Inc. Use of titania or zirconia in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide
EP0676238A3 (en) 1994-04-04 1996-05-01 Sun Co Inc R & M Metal-ligand catalysts for the oxidation of alkenes and addition of hydroperoxides.
US6191311B1 (en) 1996-09-03 2001-02-20 E. I. Du Pont De Nemours And Company Hydroperoxide decomposition processes

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3941845A (en) * 1972-10-21 1976-03-02 Stamicarbon, B.V. Process for preparing cycloalkanones and cycloalkanols
CN1066839A (zh) * 1991-03-25 1992-12-09 Dsm有限公司 制备烷酮和/或烷醇的方法
CN1107829A (zh) * 1993-12-23 1995-09-06 Dsm有限公司 制备烷酮和/或烷醇的方法

Also Published As

Publication number Publication date
EP1012130B1 (en) 2003-01-22
BR9815441B1 (pt) 2009-12-01
CZ295000B6 (cs) 2005-05-18
EA199900737A1 (ru) 2000-02-28
BR9815441A (pt) 2001-10-23
WO1998034894A3 (en) 1999-01-21
KR20000070969A (ko) 2000-11-25
MX219178B (enExample) 2004-02-16
AU6167498A (en) 1998-08-26
HK1027554A1 (en) 2001-01-19
CZ283299A3 (cs) 2000-05-17
CN1246841A (zh) 2000-03-08
SK105899A3 (en) 2000-07-11
EP1012130A2 (en) 2000-06-28
DE69810944D1 (en) 2003-02-27
PL336762A1 (en) 2000-07-17
US6284927B1 (en) 2001-09-04
JP3976793B2 (ja) 2007-09-19
DE69810944T2 (de) 2003-11-13
JP2001511787A (ja) 2001-08-14
WO1998034894A2 (en) 1998-08-13
ID22219A (id) 1999-09-16
EA002422B1 (ru) 2002-04-25
MX9907212A (enExample) 2000-02-28
CA2279493A1 (en) 1998-08-13
EP1012130B9 (en) 2003-05-02

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C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
ASS Succession or assignment of patent right

Owner name: INVISTA TECH SARL

Free format text: FORMER OWNER: E. I. DU PONT DE NEMOURS AND CO.

Effective date: 20060113

C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20060113

Address after: Zurich Switzerland

Patentee after: INVISTA TECHNOLOGIES S.A.R.L.

Address before: Delaware, USA

Patentee before: E. I. du Pont de Nemours and Co.

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20030312

Termination date: 20160210

CF01 Termination of patent right due to non-payment of annual fee