EA199900737A1 - Способ разложения гидропероксида - Google Patents

Способ разложения гидропероксида

Info

Publication number
EA199900737A1
EA199900737A1 EA199900737A EA199900737A EA199900737A1 EA 199900737 A1 EA199900737 A1 EA 199900737A1 EA 199900737 A EA199900737 A EA 199900737A EA 199900737 A EA199900737 A EA 199900737A EA 199900737 A1 EA199900737 A1 EA 199900737A1
Authority
EA
Eurasian Patent Office
Prior art keywords
decomposition
hydroperoxide
discretion
hydroxides
sol
Prior art date
Application number
EA199900737A
Other languages
English (en)
Other versions
EA002422B1 (ru
Inventor
Джое Дуглас Друлайнер
Норман Херрон
Стефен Пол Джордан
Костантинос Куртакис
Самуэл Ливингстон Лейн
Лео Эрнест Мэнзер
Брюс Эдмунд Смарт
Original Assignee
Е.И. Дюпон Де Немур Энд Компани
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Е.И. Дюпон Де Немур Энд Компани filed Critical Е.И. Дюпон Де Немур Энд Компани
Publication of EA199900737A1 publication Critical patent/EA199900737A1/ru
Publication of EA002422B1 publication Critical patent/EA002422B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Улучшенный способ разложения алкил или ароматических гидропероксидов с получением смеси продуктов реакции разложения, содержащих соответствующий спирт и кетон. Улучшение относится к разложению гидропероксида путем контакта гидропероксида с каталитическим количеством гетерогенного катализатора из Au, Ag, Cu или золь-гель соединения, содержащих определенные комбинации Cr, Co, Zr, Ta, Si, Mg, Nb, Al и Ti, причем некоторые из этих металлов комбинируются с оксидом, например неорганическая матрица гидроксидов или оксидов или их комбинации. Катализаторы также могут, по усмотрению, наносится на приемлемый элемент носителя.Международная заявка была опубликована вместе с отчетом о международном поиске.
EA199900737A 1997-02-11 1998-02-10 Способ разложения гидропероксида EA002422B1 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US3756497P 1997-02-11 1997-02-11
US4516597P 1997-04-30 1997-04-30
PCT/US1998/002926 WO1998034894A2 (en) 1997-02-11 1998-02-10 Hydroperoxide decomposition process

Publications (2)

Publication Number Publication Date
EA199900737A1 true EA199900737A1 (ru) 2000-02-28
EA002422B1 EA002422B1 (ru) 2002-04-25

Family

ID=26714254

Family Applications (1)

Application Number Title Priority Date Filing Date
EA199900737A EA002422B1 (ru) 1997-02-11 1998-02-10 Способ разложения гидропероксида

Country Status (16)

Country Link
US (1) US6284927B1 (ru)
EP (1) EP1012130B9 (ru)
JP (1) JP3976793B2 (ru)
KR (1) KR20000070969A (ru)
CN (1) CN1102923C (ru)
AU (1) AU6167498A (ru)
BR (1) BR9815441B1 (ru)
CA (1) CA2279493A1 (ru)
CZ (1) CZ295000B6 (ru)
DE (1) DE69810944T2 (ru)
EA (1) EA002422B1 (ru)
HK (1) HK1027554A1 (ru)
ID (1) ID22219A (ru)
PL (1) PL336762A1 (ru)
SK (1) SK105899A3 (ru)
WO (1) WO1998034894A2 (ru)

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US6160183A (en) * 1998-02-10 2000-12-12 E. I. Du Pont De Nemours And Company Direct oxidation of cycloalkanes
CZ2001547A3 (cs) * 1998-08-26 2001-08-15 E. I. Du Pont De Nemours And Company Způsob rozkladu hydroxyperoxidů
BR9917285A (pt) * 1999-03-10 2001-12-26 Du Pont Processo de decomposição de hidroperóxidos
US6169215B1 (en) * 1999-03-25 2001-01-02 Mobil Oil Corporation Production of phenol
AU2000267916A1 (en) * 2000-08-18 2002-03-04 E.I. Du Pont De Nemours And Company Improved hydroperoxide decomposition catalyst
FR2823745A1 (fr) * 2001-04-20 2002-10-25 Rhodia Polyamide Intermediates Procede de decomposition catalytique des hydroperoxydes organiques
US6984761B2 (en) * 2002-12-16 2006-01-10 Exxonmobil Chemical Patents Inc. Co-production of phenol, acetone, α-methylstyrene and propylene oxide, and catalyst therefor
US7081552B2 (en) * 2004-08-17 2006-07-25 Solutia Inc. Catalysts for cycloalkanes oxidation and decomposition of cycloalkyl hydroperoxide
CN100364663C (zh) * 2006-04-07 2008-01-30 浙江大学 负载型纳米金催化剂及制备方法
WO2007137021A2 (en) * 2006-05-16 2007-11-29 Shell Oil Company Catalysts comprising a combination of oxidized metals and a method for cleaving phenylalkyl hydroperoxides using the catalysts
US7417003B2 (en) * 2006-12-29 2008-08-26 Uop Llc Solid acid catalyst and process for decomposition of cumene hydroperoxide
JP4955440B2 (ja) * 2007-03-29 2012-06-20 Ｊｘ日鉱日石エネルギー株式会社 ジヒドロキシ芳香族化合物の製造方法
CN102177121B (zh) * 2008-10-10 2015-05-13 埃克森美孚化学专利公司 生产苯酚的方法
EP2352715A1 (en) * 2008-10-10 2011-08-10 Exxonmobil Chemical Company Process for producing phenol
CN105732304A (zh) 2009-02-26 2016-07-06 埃克森美孚化学专利公司 苯酚的制备方法
US9321710B2 (en) 2010-01-25 2016-04-26 Exxonmobil Chemical Patents Inc. Process for producing phenol
WO2012036824A1 (en) 2010-09-14 2012-03-22 Exxonmobil Chemical Patents Inc. Oxidation of alkylbenzenes and cycloalkylbenzenes
CN102161526B (zh) * 2011-03-04 2012-12-12 北京化工大学 氧化镁负载钴铁金属磁性纳米材料在降解废水中橙黄ⅱ的应用
KR101579360B1 (ko) 2011-04-19 2015-12-21 엑손모빌 케미칼 패턴츠 인코포레이티드 페놀의 제조 방법
US9388102B2 (en) 2011-04-19 2016-07-12 Exxonmobil Chemical Patents Inc. Process for producing phenol
WO2013052217A2 (en) 2011-10-07 2013-04-11 Exxonmobil Chemical Patents Inc. Mixed metal oxide catalysts and use thereof
CN104326870A (zh) * 2014-09-16 2015-02-04 上海洪鲁化工技术有限公司 一种环己基过氧化氢的加氢分解方法
WO2016083256A1 (en) * 2014-11-28 2016-06-02 Rhodia Operations Process for the manufacture of alcohol and/or ketone
CN106268847A (zh) * 2015-06-08 2017-01-04 中国石油化工股份有限公司 一种环己烷氧化液分解催化剂的制备及分解工艺

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US2609395A (en) 1949-12-16 1952-09-02 Phillips Petroleum Co Oxidation of hydrocarbons
US2675407A (en) 1952-04-10 1954-04-13 Standard Oil Dev Co Air oxidation of cycloalkanes
US2851496A (en) * 1954-07-27 1958-09-09 Du Pont Preparation of oxidation products of cyclohexane
US2854487A (en) * 1955-04-12 1958-09-30 Distillers Co Yeast Ltd Process for the manufacture of carbinols
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FR1547427A (fr) 1967-05-26 1968-11-29 Rhone Poulenc Sa Perfectionnement à la préparation de mélanges cycloalcanols/cycloalcanones
US3598869A (en) 1967-12-05 1971-08-10 Celanese Corp Oxidation of cyclohexane to nylon precursors
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BE777013A (nl) * 1970-12-30 1972-06-21 Shell Int Research Werkwijze voor de ontleding van organische peroxyverbindingen
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NL9100521A (nl) * 1991-03-25 1992-10-16 Stamicarbon Werkwijze voor de bereiding van een alkanon en/of alkanol.
NL9201756A (nl) * 1992-10-09 1994-05-02 Univ Delft Tech Werkwijze voor de gekatalyseerde ontleding van organische hydroperoxiden.
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US5414141A (en) 1993-11-12 1995-05-09 Texaco Chemical Inc. Use of supported palladium catalysts in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide
US5414163A (en) 1993-11-12 1995-05-09 Texaco Chemical Inc. Use of titania or zirconia in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide
US5364988A (en) 1993-11-12 1994-11-15 Texaco Chemical Company Use of supported chromium catalyst in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide
BE1007904A3 (nl) * 1993-12-23 1995-11-14 Dsm Nv Werkwijze voor de bereiding van een alkanol en/of een alkanon.
CA2146314A1 (en) 1994-04-04 1995-10-05 Manoj V. Bhinde Metal-ligand catalysts for oxydation of alkanes and decomposition of organic hydroperoxydes
CN1093109C (zh) 1996-09-03 2002-10-23 纳幕尔杜邦公司 分解氢过氧化物的方法

Also Published As

Publication number Publication date
MX219178B (ru) 2004-02-16
CN1246841A (zh) 2000-03-08
WO1998034894A2 (en) 1998-08-13
US6284927B1 (en) 2001-09-04
CA2279493A1 (en) 1998-08-13
EP1012130B9 (en) 2003-05-02
WO1998034894A3 (en) 1999-01-21
MX9907212A (ru) 2000-02-28
HK1027554A1 (en) 2001-01-19
DE69810944D1 (en) 2003-02-27
BR9815441A (pt) 2001-10-23
CZ283299A3 (cs) 2000-05-17
EP1012130A2 (en) 2000-06-28
KR20000070969A (ko) 2000-11-25
PL336762A1 (en) 2000-07-17
AU6167498A (en) 1998-08-26
SK105899A3 (en) 2000-07-11
JP3976793B2 (ja) 2007-09-19
EA002422B1 (ru) 2002-04-25
CZ295000B6 (cs) 2005-05-18
DE69810944T2 (de) 2003-11-13
JP2001511787A (ja) 2001-08-14
CN1102923C (zh) 2003-03-12
ID22219A (id) 1999-09-16
EP1012130B1 (en) 2003-01-22
BR9815441B1 (pt) 2009-12-01

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Legal Events

Date Code Title Description
PC4A Registration of transfer of a eurasian patent by assignment