CN104350175B - 含碱土金属的膜的沉积法 - Google Patents
含碱土金属的膜的沉积法 Download PDFInfo
- Publication number
- CN104350175B CN104350175B CN201380030127.1A CN201380030127A CN104350175B CN 104350175 B CN104350175 B CN 104350175B CN 201380030127 A CN201380030127 A CN 201380030127A CN 104350175 B CN104350175 B CN 104350175B
- Authority
- CN
- China
- Prior art keywords
- strontium
- substrate
- film
- metal
- double
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 29
- 239000002184 metal Substances 0.000 title claims abstract description 29
- 238000004062 sedimentation Methods 0.000 title description 3
- 239000000758 substrate Substances 0.000 claims abstract description 80
- 238000000034 method Methods 0.000 claims abstract description 79
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 21
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 21
- 230000001590 oxidative effect Effects 0.000 claims abstract description 14
- 150000004820 halides Chemical class 0.000 claims abstract description 13
- 239000007800 oxidant agent Substances 0.000 claims abstract description 13
- 229910001507 metal halide Inorganic materials 0.000 claims abstract description 8
- 150000005309 metal halides Chemical class 0.000 claims abstract description 8
- 239000002243 precursor Substances 0.000 claims description 42
- 229910052712 strontium Inorganic materials 0.000 claims description 40
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical group [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 40
- 238000000151 deposition Methods 0.000 claims description 35
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Chemical compound [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 claims description 24
- 239000011575 calcium Substances 0.000 claims description 23
- 238000000746 purification Methods 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 15
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 14
- 229910052791 calcium Inorganic materials 0.000 claims description 14
- 239000010410 layer Substances 0.000 claims description 14
- 238000005229 chemical vapour deposition Methods 0.000 claims description 13
- 230000008021 deposition Effects 0.000 claims description 12
- 239000011777 magnesium Substances 0.000 claims description 9
- 239000002356 single layer Substances 0.000 claims description 9
- YRAJNWYBUCUFBD-UHFFFAOYSA-N 2,2,6,6-tetramethylheptane-3,5-dione Chemical compound CC(C)(C)C(=O)CC(=O)C(C)(C)C YRAJNWYBUCUFBD-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- 229910000018 strontium carbonate Inorganic materials 0.000 claims description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- NGAZZOYFWWSOGK-UHFFFAOYSA-N heptan-3-one Chemical group CCCCC(=O)CC NGAZZOYFWWSOGK-UHFFFAOYSA-N 0.000 claims description 6
- PSGXLVFDRABBNK-UHFFFAOYSA-N COC(C(C(C)(C)C)=O)(C(C(C)(C)C)=O)OCC Chemical compound COC(C(C(C)(C)C)=O)(C(C(C)(C)C)=O)OCC PSGXLVFDRABBNK-UHFFFAOYSA-N 0.000 claims description 5
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- 230000026030 halogenation Effects 0.000 claims description 5
- 238000005658 halogenation reaction Methods 0.000 claims description 5
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 claims description 5
- 150000001298 alcohols Chemical class 0.000 claims description 4
- 150000001735 carboxylic acids Chemical class 0.000 claims description 4
- 150000002823 nitrates Chemical class 0.000 claims description 4
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 3
- VTMZJSHZYFCGMO-UHFFFAOYSA-N [Mg].CC1C(=C(C(=C1C)C)C)C Chemical compound [Mg].CC1C(=C(C(=C1C)C)C)C VTMZJSHZYFCGMO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 claims description 2
- XZPXMWMVWDSEMY-UHFFFAOYSA-N 2,2,3-trimethyloctane Chemical compound CCCCCC(C)C(C)(C)C XZPXMWMVWDSEMY-UHFFFAOYSA-N 0.000 claims 3
- 150000002576 ketones Chemical class 0.000 claims 3
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 claims 1
- 239000000376 reactant Substances 0.000 abstract description 32
- 229910000000 metal hydroxide Inorganic materials 0.000 abstract description 4
- 150000004692 metal hydroxides Chemical class 0.000 abstract description 4
- 150000004972 metal peroxides Chemical class 0.000 abstract description 4
- 239000012535 impurity Substances 0.000 abstract description 3
- 150000005323 carbonate salts Chemical class 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 58
- 239000010408 film Substances 0.000 description 52
- 238000000231 atomic layer deposition Methods 0.000 description 19
- 238000006243 chemical reaction Methods 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 10
- -1 alcohol compound Chemical class 0.000 description 8
- 230000008569 process Effects 0.000 description 7
- 229910001631 strontium chloride Inorganic materials 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910002651 NO3 Inorganic materials 0.000 description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 4
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 239000004065 semiconductor Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000006557 surface reaction Methods 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000010574 gas phase reaction Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000011017 operating method Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 238000000844 transformation Methods 0.000 description 2
- 239000012808 vapor phase Substances 0.000 description 2
- LIEOGMBLMOOSAY-UHFFFAOYSA-N CC1=C(C)C(C)([Mg]C2(C)C(C)=C(C)C(C)=C2C)C(C)=C1C Chemical compound CC1=C(C)C(C)([Mg]C2(C)C(C)=C(C)C(C)=C2C)C(C)=C1C LIEOGMBLMOOSAY-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- KHMFYFVXTICBEL-UHFFFAOYSA-N [4-(4-fluorophenyl)phenyl]boronic acid Chemical compound C1=CC(B(O)O)=CC=C1C1=CC=C(F)C=C1 KHMFYFVXTICBEL-UHFFFAOYSA-N 0.000 description 1
- USZGMDQWECZTIQ-UHFFFAOYSA-N [Mg](C1C=CC=C1)C1C=CC=C1 Chemical compound [Mg](C1C=CC=C1)C1C=CC=C1 USZGMDQWECZTIQ-UHFFFAOYSA-N 0.000 description 1
- RKIUFTQRZWQWET-UHFFFAOYSA-N [O-2].[Sr+2].N#CC#N Chemical compound [O-2].[Sr+2].N#CC#N RKIUFTQRZWQWET-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000012707 chemical precursor Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 235000002020 sage Nutrition 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- UUCCCPNEFXQJEL-UHFFFAOYSA-L strontium dihydroxide Chemical compound [OH-].[OH-].[Sr+2] UUCCCPNEFXQJEL-UHFFFAOYSA-L 0.000 description 1
- 229910001866 strontium hydroxide Inorganic materials 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000000427 thin-film deposition Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/40—Oxides
- C23C16/404—Oxides of alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/06—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Vapour Deposition (AREA)
- Formation Of Insulating Films (AREA)
Abstract
本发明描述在基板上进行化学反应以沉积金属膜的方法。该方法包括:使基板暴露于含有第二族金属的第一反应物气流及含有卤化物的第二反应物气流下,以在基板上形成含有金属卤化物的第一层;使该基板暴露于含有氧化剂的第三反应物气体下,以在基板上形成含有金属过氧化物或金属氢氧化物的第二层;使该基板暴露于热或等离子体下以将金属过氧化物或金属氢氧化物转化为金属氧化物。该方法可重复进行,藉以形成不含任何金属碳酸盐杂质的金属氧化物膜。
Description
技术领域
本发明实施例大体上有关于金属膜沉积法,且特别是关于含有第二族金属的膜的沉积法。
背景技术
在包括半导体处理、扩散阻障涂层、用于磁性读/写头的介电材料及随机存取存储器在内的各种不同工业中,于基板表面上沉积薄膜都是一项重要工艺。含有过渡金属的金属氧化物膜用于半导体应用中,可用于包括高介电常数(高K)闸极介电膜、铁电式存储器的活性材料、薄膜式电池阴极(cathode)、硅基发光装置和存储器单元中的材料。许多金氧凝相系统(metal-oxygen condensed phase system)采用已知在不同氧化电位下呈稳定状态且具有明确定义的化学计量态的金属氧化物。就这些材料而言,当一旦超过氧化电位临界值时通常能够恒定地获得期望的金属氧化物,且达成平衡。
沉积薄膜的方法包括化学气相沉积法(CVD)及原子层沉积法(ALD)。CVD工艺涉及使基板暴露于一或更多种挥发性前体中,使前体在基板上反应及/或分解而产生薄膜。大多数的ALD工艺是基于二元反应顺序,两种表面反应各自依序发生。由于这些表面反应是先后顺序进行,因此该两种气相反应物不会接触,且可能形成和沉积粒子的可能的气相反应受到限制。目前用于沉积金属氧化物膜(特别是氧化锶膜)的方法涉及使用臭氧,但臭氧会导致形成不期望的产物SrCO3。因此,需要发展出可沉积SrO薄膜又不会形成SrCO3的方法。
发明内容
本发明的一方面是关于一种在基板上沉积金属氧化物膜的方法。该方法包括(a)使基板表面暴露于金属前体流体及卤化物前体流体,藉以在该基板表面上提供金属卤化物膜,其中该金属包括第二族金属;接着(b)使含有该金属卤化物膜的基板表面暴露于氧化剂;及(c)随后使该基板表面受热或暴露于等离子体下,以在该基板上提供金属氧化物膜。在一或更多个实施例中,该方法进一步包括在每个暴露步骤之后流入净化气体。在一或更多个实施例中,步骤(a)、步骤(b)或步骤(c)重复一次或多次。
在一或更多个实施例中,该金属前体是选自于锶前体、钙前体及镁前体之中。在进一步的实施例中,该金属前体包括Sr(thd)2(双(四甲基庚二酮酸)锶,bis(tetramethylheptanedionate)strontium)、Sr(methd)2(双(甲氧基乙氧基四甲基庚二酮酸)锶,bis(methoxyethoxytetramethylheptanedionate)strontium)及Sr(dpm)2(双(二新戊酰基甲烷)锶,bis(dipivaloylmethanate)strontium)、Ca(C11H19O2)2(双(四甲基庚二酮酸)钙,bis(tetramethylheptanedionate)Calcium)、C10H2F12O4Ca(六氟戊二酮酸钙,calciumhexafluoropentane-dionate)、C6H14O4Ca(甲氧基乙醇钙,calciummethoxyethoxide)、Mg(C5H5)2(双(环戊二烯基)镁(II),Bis(cyclopentadienyl)magnesium(II))、C20H30Mg(双(五甲基环戊二烯)镁,bis(pentamethyl cyclopentadienyl)magnesium)或上述化合物的组合物。
在某些实施例中,该卤化物前体包括F2、Cl2、Br2及I2。在一或更多个实施例中,该氧化剂包括以下物质的其中一者或更多者:H2O、H2O2、O2、O3、N2O、NO、NOx、硝酸盐类化合物(nitrates)、醇类化合物(alcohols)、羧酸类化合物(carboxylicacids)、CO、CO2及HCOH。在一或更多个实施例中,该基板受热或暴露于等离子体。
本发明的第二种方面是关于一种在基板上沉积氧化锶膜的方法。该方法包括:(a)使基板表面暴露在锶前体及卤化物前体的交替脉冲下,藉以在该基板表面上提供卤化锶膜;接着(b)使该包含卤化锶膜的基板表面暴露于氧化剂;及(c)使该基板表面受热或暴露于等离子体,藉以在该基板表面上提供氧化锶膜。在某些实施例中,该锶前体包括Sr(thd)2(双(四甲基庚二酮)锶)、Sr(methd)2(双(甲氧基乙氧基四甲基庚二酮)锶)或Sr(dpm)2(双(二叔戊酰基甲烷)锶)。在一或更多个实施例中,该卤化物前体是选自下列物质,这些物质包括:F2、Cl2、Br2及I2。
在一或更多个实施例中,该氧化剂包括以下物质的其中一者或更多者:H2O、H2O2、O2、O3、N2O、NO、NOx、硝酸盐类化合物、醇类化合物、羧酸类化合物、CO、CO2及HCOH。在一或更多个实施例中,该方法进一步包括在每个暴露步骤之后流入净化气体。在某些实施例中,步骤(a)、步骤(b)或步骤(c)重复一次或更多次。
本发明的第三种方面是关于一种在基板上沉积不含碳酸锶的氧化锶金属膜的方法。该方法包括:(a)在处理腔室内安置基板;(b)执行沉积工艺,该沉积工艺包括:在使该基板上形成一部分单层(partial monolayer)的条件下使锶前体气体及Cl2气体流到该腔室内的该基板的至少一部分处,该部分单层包含末端具有氯的锶;流入净化气体;在能于该基板上形成一部分单层的条件下使水蒸气流至该腔室内的该基板,该部分单层包含SrO2或Sr(OH)2;及流入净化气体;(c)使具有含SrO2或Sr(OH)2的薄膜的基板受热或暴露于等离子体,且流入净化气体;及(d)重复步骤(b)和步骤(c);其中该沉积工艺是选自于化学气相沉积法及原子层沉积法或上述方法的组合。于一或更多个实施例中,在步骤(c)中,使该基板受热。
具体实施方式
在描述本发明的数个示例性实施例之前,应了解本发明不局限于下述内容中所举出的详细解说内容或工艺步骤。本发明能够做出其他实施例且可采用各种方式实施或进行。
尽管本文中已参照数个特定实施例来描述本发明,但应了解此等实施例仅用于解说本发明的原理和应用。本领域技术人员将明白在不偏离本发明精神与范围下,当可对本发明的方法及设备做出各种修饰和变化。因此,意指本发明涵盖落入后附权利要求书中的各种修饰和变化及其均等物。
特别是在半导体工业中,小型化要求对薄膜沉积工艺达到原子级的控制,以在高深宽比的结构上制造保角性涂层。一种沉积薄膜的方法是化学气相沉积法(CVD),在CVD法中,气相化学前体分子及反应物气体在温度控制的表面上及/或上方进行反应而形成薄膜。反应性物种、能量、化学药品供应速率、基板温度及基板本身有助于决定膜的性质。在典型的CVD工艺中,将气相的反应物引入反应器中,并利用热、等离子体或其他方式活化这些反应物。随后反应性物种吸附于基板表面上,且这些反应性物种在基板表面上进行化学反应或与其他引入的物种反应而形成固体膜。反应副产物从基板表面脱附,并将该反应器中的这些副产物移除或净化。
用于沉积薄膜的化学气相沉积法的变化型是原子层沉积法(ALD),ALD沉积法采用依序进行的自我限制性表面反应来形成厚度精确控制在埃等级或单层等级的膜层。大多数的ALD工艺是基于沉积出二元化合物膜(binary compound film)的二元反应顺序。该两个表面反应各别依序发生,且由于该两个反应是自我限制性的(self-limiting),因此可在原子等级的控制下沉积薄膜。由于该等表面反应是依序先后进行(sequential),因此该两种气相反应物不会接触,且可能形成和沉积粒子的可能的气相反应受到限制。该等表面反应的自我限制本性亦允许在每个反应循环期间驱使该反应完全,而形成连续且无针孔的薄膜。
当用于本案说明书及后附权利要求书时,″净化(purge)″一词用以表示任何去除系统中的内含物的工艺。净化步骤可表示借着使用其他气体(例如,惰性气体)取代该等内含物(例如,气态反应物)或在系统中导入真空(或部分真空)而去除该等内含物。
根据一或更多个实施例中,本发明关于一种利用化学反应沉积金属氧化物膜的方法。该等方法亦称为工艺,其包括依序使基板或一部分的基板暴露于含有化学前体或反应物(包括第一反应物气体、第二反应物气体及第三反应物气体)的各种沉积气体。在该等暴露动作之间可流入净化气体。在第一沉积工艺期间,第一反应物气体与第二反应物气体在基板上形成由金属卤化物所形成的至少一部分膜层。随后亦使该基板暴露于第三反应物气体。于第二沉积工艺期间,第三反应物气体在该基板上形成由金属过氧化物/金属氢氧化物所形成的至少一部分膜层。随后使该基板受热或暴露于等离子体以在基板上提供具有期望厚度的金属氧化物膜。本领域技术人员将明白,在进行第二沉积工艺之前,该第一沉积工艺可重复多次,并在进行第一沉积工艺之前,该第二沉积工艺可重复多次,且首先执行的工艺可为该等工艺中的任一者。
在一特定实施例中,该第一反应物气体可包括本领域技术人员已知含有任何适当碱土金属或第二族金属的金属前体。合适的第二族金属包括锶、钙、镁及诸如此类金属。此等合适的金属物种是该些能形成稳定碳酸盐的金属物种。合适的碱土金属前体的列表包括:Sr(thd)2(双(四甲基庚二酮)锶)、Sr(methd)2(双(甲氧基乙氧基四甲基庚二酮)锶)及Sr(dpm)2(双(二叔戊酰基甲烷)锶)、Ca(C11H19O2)2(双(四甲基庚二酮酸)钙)、C10H2F12O4Ca(六氟戊二酮酸钙,calcium hexafluoropentane-dionate)、C6H14O4Ca(甲氧基乙醇钙)、Mg(C5H5)2(双(环戊二烯基)镁(II))、C20H30Mg(双(五甲基环戊二烯)镁)及上述化合物的组合物。在另一实施例中,该第二反应物气体可包括本领域技术人员已知任何含有合适的卤化物的气体。合适的卤化物物种包括F2、Cl2、Br2、I2及诸如此类者。在另一实施例中,该基板暴露于第三反应物气体,且该第三反应物气体包括含有OH的物种或氧化剂。在另一实施例中,合适的氧化剂包括,但不限于H2O、H2O2、O2、O3、N2O、NO、NOx、硝酸盐类化合物、醇类化合物、羧酸类化合物、CO、CO2及HCOH。特别是在某些实施例中,该氧化剂包括水。在特定实施例中,本发明方法于第一沉积循环期间在基板上形成含有金属卤化物的第一层,且随后在第二沉积循环期间,使该含有金属卤化物的基板暴露于氧化剂中以在基板上提供含有金属过氧化物或金属氢氧化物的层。在另一实施例中,使该基板受热或暴露于等离子体以提供期望的金属氧化物膜。特别是,该等方法包括重复进行该第一、第二或第三循环以形成金属氧化物膜。特别是,该金属氧化物膜实质没有形成任何金属碳酸盐。更明确言之,该金属氧化物膜不含金属碳酸盐形成作用。
在详细实施例中,该等方法包括使该基板受热或暴露于等离子体以获得期望的金属氧化物膜。在一实施例中,该基板受到加热。
等离子体可用于处理本文中所述的膜。在一实施例中,该基板暴露于等离子体气体。典型的等离子体气体可包括惰性气体,例如氮气、氢气、氩气、氖气、氦气或上述气体的组合物。可在该处理腔室的外部(例如利用远端等离子体产生系统)产生该等离子体。通常,可由微波(MW)频率产生器或射频(RF)产生器于远处产生等离子体。
本发明所构想的合适的金属氧化物膜列表包括,但不限于:SrO、MgO、CaO。
在详细实施例中,该方法包括在处理腔室内安置基板,且执行第一沉积循环,该第一沉积循环包括首先在能使该基板上形成一部分单层(partial monolayer)的条件下使含有锶前体的气体和含有卤化物前体的气体流至该腔室内的该基板的至少一部分处,该部分单层包含末端具有氯的锶,随后使净化气体流入该腔室。接着,在能于该基板上形成一部分单层的条件下使水蒸气流至该腔室内的基板;该部分单层包含氢氧化锶;及随后使净化气体流入该腔室。在此之后,在可形成含有氧化锶的层的条件下施加热或流入等离子体以作用于该腔室内的该基板的至少一部分,随后使净化气体流入该腔室。接着可重复进行该第一、第二及第三工艺或循环,直到该氧化锶膜达到期望厚度。
在净化期间,通常将惰性气体引入该处理腔室以净化反应区域或去除该反应区域的任何残留的反应性化合物或副产物。或者,该净化气体可在该沉积工艺全程过程中连续流动,如此在安排该等反应气体之间的延迟时间内仅有净化气体流动。
半导体工业极为需要金属氧化物薄膜。在具体实施例中举出获得氧化锶膜的方法。以前的方法涉及在沉积循环中使用锶前体及臭氧。此种方法通常会在膜内形成碳酸锶(SrCO3)。碳酸锶是一种不受欢迎的杂质。为避免膜内含有碳酸锶,在特定实施例中,锶前体选自下列化合物,包括:Sr(thd)2(双(四甲基庚二酮)锶)、Sr(methd)2(双(甲氧基乙氧基四甲基庚二酮)锶)及Sr(dpm)2(双(二叔戊酰基甲烷)锶)及诸如此类化合物,且可将该锶前体脉冲注入该含有基板的腔室中。随后,可将卤化物前体(例如,Cl2)脉冲注入该腔室内以形成含有氯化锶(SrCl2)的部分单层。在此之后,流入净化气体。接着,在能于该基板上形成部分单层的条件下使水蒸汽流至该腔室内的基板;该部分单层包含氰氧化锶(Sr(OH)2)或过氧化锶(SrO2),随后使净化气体流入该腔室。应了解,可使各种氧化剂(包括水蒸气、H2O2、O2、O3、N2O、NO、NOx、硝酸盐类化合物、醇类化合物、羧酸类化合物、CO、CO2、HCOH及诸如此类者)流入该腔室中以提供期望的Sr(OH)2或SrO2。接着,可使该基板受热或暴露于等离子体以在基板上提供所需的含有氧化锶(SrO)的膜。该等脉冲/净化循环可重复进行一次或更多次,直到含有氧化锶的膜达到期望厚度。
不受理论约束,SrCl2是非挥发性且因此其行为类似于NaCl,因为SrCl2没有蒸汽压并且是由阴离子和阳离子所形成的大型网状结构所组成。当SrCl2与水蒸汽反应时,会沉积SrO2且伴随生成副产物HCl。不同于习知涉及使用锶前体和臭氧且形成SrCO3的方法,在诸如本发明方法中,非挥发性卤化物作为中间物的用途在此之前尚属未知。因此,本文中所述的本发明方法大幅地改善氧化锶膜沉积工艺。
在本发明一实施例中,是在原位相继地执行该等方法,而无需让基板暴露于空气中。
本发明的具体实施例提出用于在基板上获得不含任何金属碳酸盐杂质的金属氧化物膜的方法。尤其是利用气相沉积法(例如CVD、ALD或等离子体增强CVD(PE-CVD)及等离子体增强ALD(PE-ALD))制备诸如SrO、CaO及MgO的膜。处理腔室被配置成可在沉积工艺期间使基板暴露于一连串的气体及/或等离子体。
在某些实施例中,该基板暴露于第一反应物气体与第二反应物气体。当在CVD反应中,该暴露于第一反应物气体与第二反应物气体的动作可实质同时进行,或当在ALD反应中,该暴露于第一反应物气体与第二反应物气体的动作可先后依序进行。当用于本案说明书及后附权利要求书时,″实质同时(substantially simultaneously)″一词意指该两种前体气体流入该腔室内而彼此反应并且一起与基板表面发生反应。本领域技术人员将可理解,在其他种前体扩散到同一个区域之前,该基板可能有多个区域会短暂地只暴露在一种前体下。
在典型的原子层沉积腔室中,可通过空间型或时域型工艺(time domainprocess)使该基板暴露于第一反应物气体与第二反应物气体。时域型ALD是一种传统工艺,在该工艺中,第一反应物气体流入腔室内与该表面发生反应。在流入第二反应物气体之前,先净化该腔室内的第一反应物气体。在空间型ALD中,使第一反应物气体与第二反应物气体同时流入该腔室内,但两种气体在空间上是隔离开的,使得在两股气流之间具有一区域而可防止气体混合。在空间型ALD中,必需相对于该气体分配板移动该基板,或相对于该基板而移动该气体分配板。
在某些实施例中,可于文中所述方法中用于沉积或形成金属氧化物材料的等离子体系统及处理腔室或处理系统包括CVD腔室,其可购自位于美国加州圣塔克拉拉市的应用材料公司。在共同受让的美国专利第5,846,332、6,079,356及6,106,625号中描述等离子体系统与处理腔室的进一步揭示内容。在其他实施例中,在2009年6月30日申请且共同受让的美国专利申请案第12/494,901号(美国专利申请案公开号第2010/0003406号)中描述可于文中所述方法中用来沉积或形成金属氧化物材料的PE-ALD处理腔室或处理系统。文中所述某些实施例中所使用的ALD处理腔室可包含各种盖组件。在文中所述实施例中的某些实施例过程中亦可使用其他ALD处理腔室,且该等腔室可购自应用材料公司。在共同受让的美国专利第6,821,563、6,878,206、6,916,398及7,780,785号中可找到ALD处理腔室的详细描述。在另一实施例中,配置成能以ALD及习知CVD两种模式操作的腔室可用于沉积金属氧化物材料,且在共同受让的美国专利第7,204,886号中描述此种腔室。
在本案说明书各处,″一个实施例″、″某些实施例″、″一或更多个实施例″、″一实施例″、″一个方面″、″某些方面″、″一或更多个方面″、″一方面″意指配合该实施例所述的特定特征、结构、材料或特性是包括在本发明的至少一个实施例内。因此,当本案说明书各处中出现诸如″在一或更多个实施例中″、″在某些实施例中″、″在一个实施例中″、″在一实施例中″、″根据一或更多个方面″、″在一方面中″等等用语时不一定是指本发明的同一个实施例或同一个方面。此外,在一或更多个实施例或方面中可使用任何适当方式组合该等特定的特征、结构、材料或特性。上述方法的叙述顺序不应视为限制,且该等方法可不按顺序使用所述的操作步骤或可添加或省略操作步骤。
应了解,上述内容欲作为示范解说,而非限制之用。本领域普通技术人员在阅读上述说明内容后,当可领会本发明的诸多其他实施例。因此,本发明范围应由后附权利要求书所决定,且此等权利要求书亦涵盖所有范围内的等效物。
Claims (18)
1.一种在基板上沉积金属氧化物膜的方法,包括:
(a)使基板表面暴露于金属前体及卤化物前体,藉以在所述基板表面上提供金属卤化物膜,其中所述金属前体包括第二族金属,且其中所述卤化物前体选自F2、C12、Br2或I2;随后
(b)使含有所述金属卤化物膜的基板表面暴露于氧化剂;及
(c)随后使所述基板表面受热或暴露于等离子体以在所述基板上提供金属氧化物膜。
2.如权利要求1所述的方法,进一步包括在每个暴露步骤之后流入净化气体。
3.如权利要求1所述的方法,其特征在于,步骤(a)、步骤(b)或步骤(c)重复一次或更多次。
4.如权利要求1所述的方法,其特征在于,所述金属前体是选自于锶前体、钙前体及镁前体之中。
5.如权利要求1所述的方法,其特征在于,所述金属前体包括:Sr(thd)2(双(四甲基庚二酮酸)锶)(bis(tetramethylheptanedionate)strontium)、Sr(methd)2(双(甲氧基乙氧基四甲基庚二酮酸)锶)(bis(methoxyethoxytetramethylheptanedionate)strontium)及Sr(dpm)2(双(二新戊酰基甲烷)锶)(bis(dipivaloylmethanate)strontium)、Ca(C11H19O2)2(双(四甲基庚二酮酸)钙)、C10H2F12O4Ca(六氟戊二酮酸钙)、C6H14O4Ca(甲氧基乙醇钙)、Mg(C5H5)2(双(环戊二烯基)镁(II))、C20H30Mg(双(五甲基环戊二烯)镁)或上述化合物的组合物。
6.如权利要求1所述的方法,其特征在于,所述氧化剂包括以下物质的其中一者或更多者:H2O、H2O2、O2、O3、N2O、NOx、硝酸盐类(nitrates)、醇类(alcohols)、羧酸类(carboxylicacids)、CO、CO2及HCOH。
7.如权利要求1所述的方法,其特征在于,所述金属氧化物膜具有达约的厚度。
8.如权利要求1所述的方法,其特征在于,所述基板受热。
9.如权利要求1所述的方法,其特征在于,所述基板暴露于等离子体。
10.一种在基板上沉积氧化锶膜的方法,所述方法包括:
(a)使基板表面暴露在锶前体及卤化物前体的交替脉冲下,藉以在所述基板表面上提供卤化锶膜,且其中所述卤化物前体选自F2、Cl2、Br2或I2;随后
(b)使包含卤化锶膜的所述基板表面暴露于氧化剂;及
(c)使所述基板表面受热或暴露于等离子体下,藉以在所述基板表面上提供氧化锶膜。
11.如权利要求10所述的方法,其特征在于,所述锶前体包括Sr(thd)2(双(四甲基庚二酮)锶)、Sr(methd)2(双(甲氧基乙氧基四甲基庚二酮)锶)或Sr(dpm)2(双(二叔戊酰基甲烷)锶)。
12.如权利要求10所述的方法,其中所述氧化剂包括以下物质的其中一者或更多者:H2O、H2O2、O2、O3、N2O、NOx、硝酸盐类、醇类、羧酸类、CO、CO2及HCOH。
13.如权利要求10所述的方法,进一步包括在每个暴露步骤之后流入净化气体。
14.如权利要求10所述的方法,其特征在于,步骤(a)、步骤(b)或步骤(c)重复一次或更多次。
15.一种在基板上沉积不含碳酸锶的氧化锶金属膜的方法,该方法包括:
(a)在处理腔室内安置基板;
(b)执行沉积工艺,所述沉积工艺包括:
(i)在能于所述基板上形成一部分单层的条件下使锶前驱物气体及Cl2气体流到所述腔室内的所述基板的至少一部分处,所述部分单层包含末端具有氯的锶;
(ii)流入净化气体;
(iii)在能于所述基板上形成一部分单层的条件下使水蒸气流至所述腔室内的所述基板,所述部分单层包含SrO2或Sr(OH)2;及
(iv)流入净化气体;
(c)使所述基板受热或暴露于等离子体,所述基板上具有所述含SrO2或Sr(OH)2的薄膜,
(i)流入净化气体;及
(d)重复步骤(b)和步骤(c);
其中,所述沉积工艺是选自化学气相沉积及原子层沉积或上述沉积工艺的组合。
16.如权利要求15所述的方法,其特征在于,在步骤(c)中,所述基板受热。
17.如权利要求15所述的方法,其特征在于,所述锶前体包括Sr(thd)2(双(四甲基庚二酮)锶)、Sr(methd)2(双(甲氧基乙氧基四甲基庚二酮)锶)或Sr(dpm)2(双(二叔戊酰基甲烷)锶)。
18.如权利要求15所述的方法,其特征在于,所述金属氧化物膜具有达约的厚度。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261666069P | 2012-06-29 | 2012-06-29 | |
US61/666,069 | 2012-06-29 | ||
US13/923,599 US10233541B2 (en) | 2012-06-29 | 2013-06-21 | Deposition of films containing alkaline earth metals |
US13/923,599 | 2013-06-21 | ||
PCT/US2013/048420 WO2014004949A1 (en) | 2012-06-29 | 2013-06-28 | Deposition of films containing alkaline earth metals |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104350175A CN104350175A (zh) | 2015-02-11 |
CN104350175B true CN104350175B (zh) | 2017-05-31 |
Family
ID=49778440
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201380030127.1A Active CN104350175B (zh) | 2012-06-29 | 2013-06-28 | 含碱土金属的膜的沉积法 |
Country Status (5)
Country | Link |
---|---|
US (1) | US10233541B2 (zh) |
KR (1) | KR102156326B1 (zh) |
CN (1) | CN104350175B (zh) |
TW (1) | TWI605148B (zh) |
WO (1) | WO2014004949A1 (zh) |
Families Citing this family (276)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9394608B2 (en) | 2009-04-06 | 2016-07-19 | Asm America, Inc. | Semiconductor processing reactor and components thereof |
US8802201B2 (en) | 2009-08-14 | 2014-08-12 | Asm America, Inc. | Systems and methods for thin-film deposition of metal oxides using excited nitrogen-oxygen species |
US9312155B2 (en) | 2011-06-06 | 2016-04-12 | Asm Japan K.K. | High-throughput semiconductor-processing apparatus equipped with multiple dual-chamber modules |
US10854498B2 (en) | 2011-07-15 | 2020-12-01 | Asm Ip Holding B.V. | Wafer-supporting device and method for producing same |
US20130023129A1 (en) | 2011-07-20 | 2013-01-24 | Asm America, Inc. | Pressure transmitter for a semiconductor processing environment |
US9017481B1 (en) | 2011-10-28 | 2015-04-28 | Asm America, Inc. | Process feed management for semiconductor substrate processing |
US10714315B2 (en) | 2012-10-12 | 2020-07-14 | Asm Ip Holdings B.V. | Semiconductor reaction chamber showerhead |
US20160376700A1 (en) | 2013-02-01 | 2016-12-29 | Asm Ip Holding B.V. | System for treatment of deposition reactor |
US10683571B2 (en) | 2014-02-25 | 2020-06-16 | Asm Ip Holding B.V. | Gas supply manifold and method of supplying gases to chamber using same |
US10167557B2 (en) | 2014-03-18 | 2019-01-01 | Asm Ip Holding B.V. | Gas distribution system, reactor including the system, and methods of using the same |
US11015245B2 (en) | 2014-03-19 | 2021-05-25 | Asm Ip Holding B.V. | Gas-phase reactor and system having exhaust plenum and components thereof |
US10858737B2 (en) | 2014-07-28 | 2020-12-08 | Asm Ip Holding B.V. | Showerhead assembly and components thereof |
US9890456B2 (en) | 2014-08-21 | 2018-02-13 | Asm Ip Holding B.V. | Method and system for in situ formation of gas-phase compounds |
US10941490B2 (en) | 2014-10-07 | 2021-03-09 | Asm Ip Holding B.V. | Multiple temperature range susceptor, assembly, reactor and system including the susceptor, and methods of using the same |
US10276355B2 (en) | 2015-03-12 | 2019-04-30 | Asm Ip Holding B.V. | Multi-zone reactor, system including the reactor, and method of using the same |
US10458018B2 (en) | 2015-06-26 | 2019-10-29 | Asm Ip Holding B.V. | Structures including metal carbide material, devices including the structures, and methods of forming same |
US10600673B2 (en) | 2015-07-07 | 2020-03-24 | Asm Ip Holding B.V. | Magnetic susceptor to baseplate seal |
US10211308B2 (en) | 2015-10-21 | 2019-02-19 | Asm Ip Holding B.V. | NbMC layers |
US11139308B2 (en) | 2015-12-29 | 2021-10-05 | Asm Ip Holding B.V. | Atomic layer deposition of III-V compounds to form V-NAND devices |
US10529554B2 (en) | 2016-02-19 | 2020-01-07 | Asm Ip Holding B.V. | Method for forming silicon nitride film selectively on sidewalls or flat surfaces of trenches |
US10190213B2 (en) | 2016-04-21 | 2019-01-29 | Asm Ip Holding B.V. | Deposition of metal borides |
US10865475B2 (en) | 2016-04-21 | 2020-12-15 | Asm Ip Holding B.V. | Deposition of metal borides and silicides |
US10032628B2 (en) | 2016-05-02 | 2018-07-24 | Asm Ip Holding B.V. | Source/drain performance through conformal solid state doping |
US10367080B2 (en) | 2016-05-02 | 2019-07-30 | Asm Ip Holding B.V. | Method of forming a germanium oxynitride film |
US11453943B2 (en) | 2016-05-25 | 2022-09-27 | Asm Ip Holding B.V. | Method for forming carbon-containing silicon/metal oxide or nitride film by ALD using silicon precursor and hydrocarbon precursor |
US10612137B2 (en) * | 2016-07-08 | 2020-04-07 | Asm Ip Holdings B.V. | Organic reactants for atomic layer deposition |
US9859151B1 (en) | 2016-07-08 | 2018-01-02 | Asm Ip Holding B.V. | Selective film deposition method to form air gaps |
US10714385B2 (en) | 2016-07-19 | 2020-07-14 | Asm Ip Holding B.V. | Selective deposition of tungsten |
KR102532607B1 (ko) | 2016-07-28 | 2023-05-15 | 에이에스엠 아이피 홀딩 비.브이. | 기판 가공 장치 및 그 동작 방법 |
US9887082B1 (en) | 2016-07-28 | 2018-02-06 | Asm Ip Holding B.V. | Method and apparatus for filling a gap |
US9812320B1 (en) | 2016-07-28 | 2017-11-07 | Asm Ip Holding B.V. | Method and apparatus for filling a gap |
US10643826B2 (en) | 2016-10-26 | 2020-05-05 | Asm Ip Holdings B.V. | Methods for thermally calibrating reaction chambers |
US11532757B2 (en) | 2016-10-27 | 2022-12-20 | Asm Ip Holding B.V. | Deposition of charge trapping layers |
US10229833B2 (en) | 2016-11-01 | 2019-03-12 | Asm Ip Holding B.V. | Methods for forming a transition metal nitride film on a substrate by atomic layer deposition and related semiconductor device structures |
US10714350B2 (en) | 2016-11-01 | 2020-07-14 | ASM IP Holdings, B.V. | Methods for forming a transition metal niobium nitride film on a substrate by atomic layer deposition and related semiconductor device structures |
US10643904B2 (en) | 2016-11-01 | 2020-05-05 | Asm Ip Holdings B.V. | Methods for forming a semiconductor device and related semiconductor device structures |
KR102546317B1 (ko) | 2016-11-15 | 2023-06-21 | 에이에스엠 아이피 홀딩 비.브이. | 기체 공급 유닛 및 이를 포함하는 기판 처리 장치 |
KR20180068582A (ko) | 2016-12-14 | 2018-06-22 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 |
US11581186B2 (en) | 2016-12-15 | 2023-02-14 | Asm Ip Holding B.V. | Sequential infiltration synthesis apparatus |
US11447861B2 (en) | 2016-12-15 | 2022-09-20 | Asm Ip Holding B.V. | Sequential infiltration synthesis apparatus and a method of forming a patterned structure |
KR102700194B1 (ko) | 2016-12-19 | 2024-08-28 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 |
US10269558B2 (en) | 2016-12-22 | 2019-04-23 | Asm Ip Holding B.V. | Method of forming a structure on a substrate |
US10867788B2 (en) | 2016-12-28 | 2020-12-15 | Asm Ip Holding B.V. | Method of forming a structure on a substrate |
US11390950B2 (en) | 2017-01-10 | 2022-07-19 | Asm Ip Holding B.V. | Reactor system and method to reduce residue buildup during a film deposition process |
US10655221B2 (en) | 2017-02-09 | 2020-05-19 | Asm Ip Holding B.V. | Method for depositing oxide film by thermal ALD and PEALD |
US10468261B2 (en) | 2017-02-15 | 2019-11-05 | Asm Ip Holding B.V. | Methods for forming a metallic film on a substrate by cyclical deposition and related semiconductor device structures |
US10529563B2 (en) | 2017-03-29 | 2020-01-07 | Asm Ip Holdings B.V. | Method for forming doped metal oxide films on a substrate by cyclical deposition and related semiconductor device structures |
KR102457289B1 (ko) | 2017-04-25 | 2022-10-21 | 에이에스엠 아이피 홀딩 비.브이. | 박막 증착 방법 및 반도체 장치의 제조 방법 |
US10770286B2 (en) | 2017-05-08 | 2020-09-08 | Asm Ip Holdings B.V. | Methods for selectively forming a silicon nitride film on a substrate and related semiconductor device structures |
US10892156B2 (en) | 2017-05-08 | 2021-01-12 | Asm Ip Holding B.V. | Methods for forming a silicon nitride film on a substrate and related semiconductor device structures |
US12040200B2 (en) | 2017-06-20 | 2024-07-16 | Asm Ip Holding B.V. | Semiconductor processing apparatus and methods for calibrating a semiconductor processing apparatus |
US11306395B2 (en) | 2017-06-28 | 2022-04-19 | Asm Ip Holding B.V. | Methods for depositing a transition metal nitride film on a substrate by atomic layer deposition and related deposition apparatus |
US10685834B2 (en) | 2017-07-05 | 2020-06-16 | Asm Ip Holdings B.V. | Methods for forming a silicon germanium tin layer and related semiconductor device structures |
KR20190009245A (ko) | 2017-07-18 | 2019-01-28 | 에이에스엠 아이피 홀딩 비.브이. | 반도체 소자 구조물 형성 방법 및 관련된 반도체 소자 구조물 |
US11018002B2 (en) | 2017-07-19 | 2021-05-25 | Asm Ip Holding B.V. | Method for selectively depositing a Group IV semiconductor and related semiconductor device structures |
US11374112B2 (en) | 2017-07-19 | 2022-06-28 | Asm Ip Holding B.V. | Method for depositing a group IV semiconductor and related semiconductor device structures |
US10541333B2 (en) | 2017-07-19 | 2020-01-21 | Asm Ip Holding B.V. | Method for depositing a group IV semiconductor and related semiconductor device structures |
US10590535B2 (en) | 2017-07-26 | 2020-03-17 | Asm Ip Holdings B.V. | Chemical treatment, deposition and/or infiltration apparatus and method for using the same |
US10770336B2 (en) | 2017-08-08 | 2020-09-08 | Asm Ip Holding B.V. | Substrate lift mechanism and reactor including same |
US10692741B2 (en) | 2017-08-08 | 2020-06-23 | Asm Ip Holdings B.V. | Radiation shield |
US11769682B2 (en) | 2017-08-09 | 2023-09-26 | Asm Ip Holding B.V. | Storage apparatus for storing cassettes for substrates and processing apparatus equipped therewith |
US11139191B2 (en) | 2017-08-09 | 2021-10-05 | Asm Ip Holding B.V. | Storage apparatus for storing cassettes for substrates and processing apparatus equipped therewith |
US10249524B2 (en) | 2017-08-09 | 2019-04-02 | Asm Ip Holding B.V. | Cassette holder assembly for a substrate cassette and holding member for use in such assembly |
USD900036S1 (en) | 2017-08-24 | 2020-10-27 | Asm Ip Holding B.V. | Heater electrical connector and adapter |
US11830730B2 (en) | 2017-08-29 | 2023-11-28 | Asm Ip Holding B.V. | Layer forming method and apparatus |
US11295980B2 (en) | 2017-08-30 | 2022-04-05 | Asm Ip Holding B.V. | Methods for depositing a molybdenum metal film over a dielectric surface of a substrate by a cyclical deposition process and related semiconductor device structures |
KR102491945B1 (ko) | 2017-08-30 | 2023-01-26 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 |
US11056344B2 (en) | 2017-08-30 | 2021-07-06 | Asm Ip Holding B.V. | Layer forming method |
KR102401446B1 (ko) | 2017-08-31 | 2022-05-24 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 |
KR102630301B1 (ko) | 2017-09-21 | 2024-01-29 | 에이에스엠 아이피 홀딩 비.브이. | 침투성 재료의 순차 침투 합성 방법 처리 및 이를 이용하여 형성된 구조물 및 장치 |
US10844484B2 (en) | 2017-09-22 | 2020-11-24 | Asm Ip Holding B.V. | Apparatus for dispensing a vapor phase reactant to a reaction chamber and related methods |
US10658205B2 (en) | 2017-09-28 | 2020-05-19 | Asm Ip Holdings B.V. | Chemical dispensing apparatus and methods for dispensing a chemical to a reaction chamber |
US10403504B2 (en) | 2017-10-05 | 2019-09-03 | Asm Ip Holding B.V. | Method for selectively depositing a metallic film on a substrate |
US10319588B2 (en) | 2017-10-10 | 2019-06-11 | Asm Ip Holding B.V. | Method for depositing a metal chalcogenide on a substrate by cyclical deposition |
US10923344B2 (en) | 2017-10-30 | 2021-02-16 | Asm Ip Holding B.V. | Methods for forming a semiconductor structure and related semiconductor structures |
US10910262B2 (en) | 2017-11-16 | 2021-02-02 | Asm Ip Holding B.V. | Method of selectively depositing a capping layer structure on a semiconductor device structure |
KR102443047B1 (ko) | 2017-11-16 | 2022-09-14 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 방법 및 그에 의해 제조된 장치 |
US11022879B2 (en) | 2017-11-24 | 2021-06-01 | Asm Ip Holding B.V. | Method of forming an enhanced unexposed photoresist layer |
CN111344522B (zh) | 2017-11-27 | 2022-04-12 | 阿斯莫Ip控股公司 | 包括洁净迷你环境的装置 |
KR102597978B1 (ko) | 2017-11-27 | 2023-11-06 | 에이에스엠 아이피 홀딩 비.브이. | 배치 퍼니스와 함께 사용하기 위한 웨이퍼 카세트를 보관하기 위한 보관 장치 |
US10872771B2 (en) | 2018-01-16 | 2020-12-22 | Asm Ip Holding B. V. | Method for depositing a material film on a substrate within a reaction chamber by a cyclical deposition process and related device structures |
CN111630203A (zh) | 2018-01-19 | 2020-09-04 | Asm Ip私人控股有限公司 | 通过等离子体辅助沉积来沉积间隙填充层的方法 |
TWI799494B (zh) | 2018-01-19 | 2023-04-21 | 荷蘭商Asm 智慧財產控股公司 | 沈積方法 |
USD903477S1 (en) | 2018-01-24 | 2020-12-01 | Asm Ip Holdings B.V. | Metal clamp |
US11018047B2 (en) | 2018-01-25 | 2021-05-25 | Asm Ip Holding B.V. | Hybrid lift pin |
USD880437S1 (en) | 2018-02-01 | 2020-04-07 | Asm Ip Holding B.V. | Gas supply plate for semiconductor manufacturing apparatus |
US11081345B2 (en) | 2018-02-06 | 2021-08-03 | Asm Ip Holding B.V. | Method of post-deposition treatment for silicon oxide film |
US11685991B2 (en) | 2018-02-14 | 2023-06-27 | Asm Ip Holding B.V. | Method for depositing a ruthenium-containing film on a substrate by a cyclical deposition process |
US10896820B2 (en) | 2018-02-14 | 2021-01-19 | Asm Ip Holding B.V. | Method for depositing a ruthenium-containing film on a substrate by a cyclical deposition process |
US10731249B2 (en) | 2018-02-15 | 2020-08-04 | Asm Ip Holding B.V. | Method of forming a transition metal containing film on a substrate by a cyclical deposition process, a method for supplying a transition metal halide compound to a reaction chamber, and related vapor deposition apparatus |
US10658181B2 (en) | 2018-02-20 | 2020-05-19 | Asm Ip Holding B.V. | Method of spacer-defined direct patterning in semiconductor fabrication |
KR102636427B1 (ko) | 2018-02-20 | 2024-02-13 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 방법 및 장치 |
US10975470B2 (en) | 2018-02-23 | 2021-04-13 | Asm Ip Holding B.V. | Apparatus for detecting or monitoring for a chemical precursor in a high temperature environment |
US11473195B2 (en) | 2018-03-01 | 2022-10-18 | Asm Ip Holding B.V. | Semiconductor processing apparatus and a method for processing a substrate |
US11629406B2 (en) | 2018-03-09 | 2023-04-18 | Asm Ip Holding B.V. | Semiconductor processing apparatus comprising one or more pyrometers for measuring a temperature of a substrate during transfer of the substrate |
US11114283B2 (en) | 2018-03-16 | 2021-09-07 | Asm Ip Holding B.V. | Reactor, system including the reactor, and methods of manufacturing and using same |
KR102646467B1 (ko) | 2018-03-27 | 2024-03-11 | 에이에스엠 아이피 홀딩 비.브이. | 기판 상에 전극을 형성하는 방법 및 전극을 포함하는 반도체 소자 구조 |
US11088002B2 (en) | 2018-03-29 | 2021-08-10 | Asm Ip Holding B.V. | Substrate rack and a substrate processing system and method |
US11230766B2 (en) | 2018-03-29 | 2022-01-25 | Asm Ip Holding B.V. | Substrate processing apparatus and method |
KR102501472B1 (ko) | 2018-03-30 | 2023-02-20 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 방법 |
TWI811348B (zh) | 2018-05-08 | 2023-08-11 | 荷蘭商Asm 智慧財產控股公司 | 藉由循環沉積製程於基板上沉積氧化物膜之方法及相關裝置結構 |
US12025484B2 (en) | 2018-05-08 | 2024-07-02 | Asm Ip Holding B.V. | Thin film forming method |
KR20190129718A (ko) | 2018-05-11 | 2019-11-20 | 에이에스엠 아이피 홀딩 비.브이. | 기판 상에 피도핑 금속 탄화물 막을 형성하는 방법 및 관련 반도체 소자 구조 |
KR102596988B1 (ko) | 2018-05-28 | 2023-10-31 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 방법 및 그에 의해 제조된 장치 |
US11718913B2 (en) | 2018-06-04 | 2023-08-08 | Asm Ip Holding B.V. | Gas distribution system and reactor system including same |
TWI840362B (zh) | 2018-06-04 | 2024-05-01 | 荷蘭商Asm Ip私人控股有限公司 | 水氣降低的晶圓處置腔室 |
US11286562B2 (en) | 2018-06-08 | 2022-03-29 | Asm Ip Holding B.V. | Gas-phase chemical reactor and method of using same |
KR102568797B1 (ko) | 2018-06-21 | 2023-08-21 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 시스템 |
US10797133B2 (en) | 2018-06-21 | 2020-10-06 | Asm Ip Holding B.V. | Method for depositing a phosphorus doped silicon arsenide film and related semiconductor device structures |
TWI815915B (zh) | 2018-06-27 | 2023-09-21 | 荷蘭商Asm Ip私人控股有限公司 | 用於形成含金屬材料及包含含金屬材料的膜及結構之循環沉積方法 |
JP2021529254A (ja) | 2018-06-27 | 2021-10-28 | エーエスエム・アイピー・ホールディング・ベー・フェー | 金属含有材料ならびに金属含有材料を含む膜および構造体を形成するための周期的堆積方法 |
KR102686758B1 (ko) | 2018-06-29 | 2024-07-18 | 에이에스엠 아이피 홀딩 비.브이. | 박막 증착 방법 및 반도체 장치의 제조 방법 |
US10612136B2 (en) | 2018-06-29 | 2020-04-07 | ASM IP Holding, B.V. | Temperature-controlled flange and reactor system including same |
US10388513B1 (en) | 2018-07-03 | 2019-08-20 | Asm Ip Holding B.V. | Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition |
US10755922B2 (en) | 2018-07-03 | 2020-08-25 | Asm Ip Holding B.V. | Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition |
US10767789B2 (en) | 2018-07-16 | 2020-09-08 | Asm Ip Holding B.V. | Diaphragm valves, valve components, and methods for forming valve components |
US11053591B2 (en) | 2018-08-06 | 2021-07-06 | Asm Ip Holding B.V. | Multi-port gas injection system and reactor system including same |
US10883175B2 (en) | 2018-08-09 | 2021-01-05 | Asm Ip Holding B.V. | Vertical furnace for processing substrates and a liner for use therein |
US10829852B2 (en) | 2018-08-16 | 2020-11-10 | Asm Ip Holding B.V. | Gas distribution device for a wafer processing apparatus |
US11430674B2 (en) | 2018-08-22 | 2022-08-30 | Asm Ip Holding B.V. | Sensor array, apparatus for dispensing a vapor phase reactant to a reaction chamber and related methods |
KR102707956B1 (ko) | 2018-09-11 | 2024-09-19 | 에이에스엠 아이피 홀딩 비.브이. | 박막 증착 방법 |
US11024523B2 (en) | 2018-09-11 | 2021-06-01 | Asm Ip Holding B.V. | Substrate processing apparatus and method |
US11049751B2 (en) | 2018-09-14 | 2021-06-29 | Asm Ip Holding B.V. | Cassette supply system to store and handle cassettes and processing apparatus equipped therewith |
KR20200038184A (ko) | 2018-10-01 | 2020-04-10 | 에이에스엠 아이피 홀딩 비.브이. | 기판 유지 장치, 장치를 포함하는 시스템, 및 이를 이용하는 방법 |
US11232963B2 (en) | 2018-10-03 | 2022-01-25 | Asm Ip Holding B.V. | Substrate processing apparatus and method |
KR102592699B1 (ko) | 2018-10-08 | 2023-10-23 | 에이에스엠 아이피 홀딩 비.브이. | 기판 지지 유닛 및 이를 포함하는 박막 증착 장치와 기판 처리 장치 |
US10847365B2 (en) | 2018-10-11 | 2020-11-24 | Asm Ip Holding B.V. | Method of forming conformal silicon carbide film by cyclic CVD |
US10811256B2 (en) | 2018-10-16 | 2020-10-20 | Asm Ip Holding B.V. | Method for etching a carbon-containing feature |
KR102605121B1 (ko) | 2018-10-19 | 2023-11-23 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 및 기판 처리 방법 |
KR102546322B1 (ko) | 2018-10-19 | 2023-06-21 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 및 기판 처리 방법 |
USD948463S1 (en) | 2018-10-24 | 2022-04-12 | Asm Ip Holding B.V. | Susceptor for semiconductor substrate supporting apparatus |
US11087997B2 (en) | 2018-10-31 | 2021-08-10 | Asm Ip Holding B.V. | Substrate processing apparatus for processing substrates |
KR20200051105A (ko) | 2018-11-02 | 2020-05-13 | 에이에스엠 아이피 홀딩 비.브이. | 기판 지지 유닛 및 이를 포함하는 기판 처리 장치 |
US11572620B2 (en) | 2018-11-06 | 2023-02-07 | Asm Ip Holding B.V. | Methods for selectively depositing an amorphous silicon film on a substrate |
US11031242B2 (en) | 2018-11-07 | 2021-06-08 | Asm Ip Holding B.V. | Methods for depositing a boron doped silicon germanium film |
US10847366B2 (en) | 2018-11-16 | 2020-11-24 | Asm Ip Holding B.V. | Methods for depositing a transition metal chalcogenide film on a substrate by a cyclical deposition process |
US10818758B2 (en) | 2018-11-16 | 2020-10-27 | Asm Ip Holding B.V. | Methods for forming a metal silicate film on a substrate in a reaction chamber and related semiconductor device structures |
US12040199B2 (en) | 2018-11-28 | 2024-07-16 | Asm Ip Holding B.V. | Substrate processing apparatus for processing substrates |
US11217444B2 (en) | 2018-11-30 | 2022-01-04 | Asm Ip Holding B.V. | Method for forming an ultraviolet radiation responsive metal oxide-containing film |
KR102636428B1 (ko) | 2018-12-04 | 2024-02-13 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치를 세정하는 방법 |
US11158513B2 (en) | 2018-12-13 | 2021-10-26 | Asm Ip Holding B.V. | Methods for forming a rhenium-containing film on a substrate by a cyclical deposition process and related semiconductor device structures |
TW202037745A (zh) | 2018-12-14 | 2020-10-16 | 荷蘭商Asm Ip私人控股有限公司 | 形成裝置結構之方法、其所形成之結構及施行其之系統 |
TW202405220A (zh) | 2019-01-17 | 2024-02-01 | 荷蘭商Asm Ip 私人控股有限公司 | 藉由循環沈積製程於基板上形成含過渡金屬膜之方法 |
KR20200091543A (ko) | 2019-01-22 | 2020-07-31 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 |
CN111524788B (zh) | 2019-02-01 | 2023-11-24 | Asm Ip私人控股有限公司 | 氧化硅的拓扑选择性膜形成的方法 |
TW202044325A (zh) | 2019-02-20 | 2020-12-01 | 荷蘭商Asm Ip私人控股有限公司 | 填充一基板之一表面內所形成的一凹槽的方法、根據其所形成之半導體結構、及半導體處理設備 |
US11482533B2 (en) | 2019-02-20 | 2022-10-25 | Asm Ip Holding B.V. | Apparatus and methods for plug fill deposition in 3-D NAND applications |
TWI845607B (zh) | 2019-02-20 | 2024-06-21 | 荷蘭商Asm Ip私人控股有限公司 | 用來填充形成於基材表面內之凹部的循環沉積方法及設備 |
KR102626263B1 (ko) | 2019-02-20 | 2024-01-16 | 에이에스엠 아이피 홀딩 비.브이. | 처리 단계를 포함하는 주기적 증착 방법 및 이를 위한 장치 |
TWI842826B (zh) | 2019-02-22 | 2024-05-21 | 荷蘭商Asm Ip私人控股有限公司 | 基材處理設備及處理基材之方法 |
KR20200108242A (ko) | 2019-03-08 | 2020-09-17 | 에이에스엠 아이피 홀딩 비.브이. | 실리콘 질화물 층을 선택적으로 증착하는 방법, 및 선택적으로 증착된 실리콘 질화물 층을 포함하는 구조체 |
KR20200108243A (ko) | 2019-03-08 | 2020-09-17 | 에이에스엠 아이피 홀딩 비.브이. | SiOC 층을 포함한 구조체 및 이의 형성 방법 |
KR20200108248A (ko) | 2019-03-08 | 2020-09-17 | 에이에스엠 아이피 홀딩 비.브이. | SiOCN 층을 포함한 구조체 및 이의 형성 방법 |
JP2020167398A (ja) | 2019-03-28 | 2020-10-08 | エーエスエム・アイピー・ホールディング・ベー・フェー | ドアオープナーおよびドアオープナーが提供される基材処理装置 |
KR20200116855A (ko) | 2019-04-01 | 2020-10-13 | 에이에스엠 아이피 홀딩 비.브이. | 반도체 소자를 제조하는 방법 |
US11447864B2 (en) | 2019-04-19 | 2022-09-20 | Asm Ip Holding B.V. | Layer forming method and apparatus |
KR20200125453A (ko) | 2019-04-24 | 2020-11-04 | 에이에스엠 아이피 홀딩 비.브이. | 기상 반응기 시스템 및 이를 사용하는 방법 |
KR20200130121A (ko) | 2019-05-07 | 2020-11-18 | 에이에스엠 아이피 홀딩 비.브이. | 딥 튜브가 있는 화학물질 공급원 용기 |
KR20200130118A (ko) | 2019-05-07 | 2020-11-18 | 에이에스엠 아이피 홀딩 비.브이. | 비정질 탄소 중합체 막을 개질하는 방법 |
KR20200130652A (ko) | 2019-05-10 | 2020-11-19 | 에이에스엠 아이피 홀딩 비.브이. | 표면 상에 재료를 증착하는 방법 및 본 방법에 따라 형성된 구조 |
JP2020188254A (ja) | 2019-05-16 | 2020-11-19 | エーエスエム アイピー ホールディング ビー.ブイ. | ウェハボートハンドリング装置、縦型バッチ炉および方法 |
JP2020188255A (ja) | 2019-05-16 | 2020-11-19 | エーエスエム アイピー ホールディング ビー.ブイ. | ウェハボートハンドリング装置、縦型バッチ炉および方法 |
USD975665S1 (en) | 2019-05-17 | 2023-01-17 | Asm Ip Holding B.V. | Susceptor shaft |
USD947913S1 (en) | 2019-05-17 | 2022-04-05 | Asm Ip Holding B.V. | Susceptor shaft |
USD935572S1 (en) | 2019-05-24 | 2021-11-09 | Asm Ip Holding B.V. | Gas channel plate |
USD922229S1 (en) | 2019-06-05 | 2021-06-15 | Asm Ip Holding B.V. | Device for controlling a temperature of a gas supply unit |
KR20200141002A (ko) | 2019-06-06 | 2020-12-17 | 에이에스엠 아이피 홀딩 비.브이. | 배기 가스 분석을 포함한 기상 반응기 시스템을 사용하는 방법 |
KR20200143254A (ko) | 2019-06-11 | 2020-12-23 | 에이에스엠 아이피 홀딩 비.브이. | 개질 가스를 사용하여 전자 구조를 형성하는 방법, 상기 방법을 수행하기 위한 시스템, 및 상기 방법을 사용하여 형성되는 구조 |
USD944946S1 (en) | 2019-06-14 | 2022-03-01 | Asm Ip Holding B.V. | Shower plate |
USD931978S1 (en) | 2019-06-27 | 2021-09-28 | Asm Ip Holding B.V. | Showerhead vacuum transport |
KR20210005515A (ko) | 2019-07-03 | 2021-01-14 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치용 온도 제어 조립체 및 이를 사용하는 방법 |
JP7499079B2 (ja) | 2019-07-09 | 2024-06-13 | エーエスエム・アイピー・ホールディング・ベー・フェー | 同軸導波管を用いたプラズマ装置、基板処理方法 |
CN112216646A (zh) | 2019-07-10 | 2021-01-12 | Asm Ip私人控股有限公司 | 基板支撑组件及包括其的基板处理装置 |
KR20210010307A (ko) | 2019-07-16 | 2021-01-27 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 |
KR20210010816A (ko) | 2019-07-17 | 2021-01-28 | 에이에스엠 아이피 홀딩 비.브이. | 라디칼 보조 점화 플라즈마 시스템 및 방법 |
KR20210010820A (ko) | 2019-07-17 | 2021-01-28 | 에이에스엠 아이피 홀딩 비.브이. | 실리콘 게르마늄 구조를 형성하는 방법 |
US11643724B2 (en) | 2019-07-18 | 2023-05-09 | Asm Ip Holding B.V. | Method of forming structures using a neutral beam |
TWI839544B (zh) | 2019-07-19 | 2024-04-21 | 荷蘭商Asm Ip私人控股有限公司 | 形成形貌受控的非晶碳聚合物膜之方法 |
KR20210010817A (ko) | 2019-07-19 | 2021-01-28 | 에이에스엠 아이피 홀딩 비.브이. | 토폴로지-제어된 비정질 탄소 중합체 막을 형성하는 방법 |
CN112309843A (zh) | 2019-07-29 | 2021-02-02 | Asm Ip私人控股有限公司 | 实现高掺杂剂掺入的选择性沉积方法 |
CN112309899A (zh) | 2019-07-30 | 2021-02-02 | Asm Ip私人控股有限公司 | 基板处理设备 |
CN112309900A (zh) | 2019-07-30 | 2021-02-02 | Asm Ip私人控股有限公司 | 基板处理设备 |
US11587814B2 (en) | 2019-07-31 | 2023-02-21 | Asm Ip Holding B.V. | Vertical batch furnace assembly |
US11587815B2 (en) | 2019-07-31 | 2023-02-21 | Asm Ip Holding B.V. | Vertical batch furnace assembly |
US11227782B2 (en) | 2019-07-31 | 2022-01-18 | Asm Ip Holding B.V. | Vertical batch furnace assembly |
KR20210018759A (ko) | 2019-08-05 | 2021-02-18 | 에이에스엠 아이피 홀딩 비.브이. | 화학물질 공급원 용기를 위한 액체 레벨 센서 |
USD965044S1 (en) | 2019-08-19 | 2022-09-27 | Asm Ip Holding B.V. | Susceptor shaft |
USD965524S1 (en) | 2019-08-19 | 2022-10-04 | Asm Ip Holding B.V. | Susceptor support |
JP2021031769A (ja) | 2019-08-21 | 2021-03-01 | エーエスエム アイピー ホールディング ビー.ブイ. | 成膜原料混合ガス生成装置及び成膜装置 |
KR20210024423A (ko) | 2019-08-22 | 2021-03-05 | 에이에스엠 아이피 홀딩 비.브이. | 홀을 구비한 구조체를 형성하기 위한 방법 |
USD979506S1 (en) | 2019-08-22 | 2023-02-28 | Asm Ip Holding B.V. | Insulator |
USD930782S1 (en) | 2019-08-22 | 2021-09-14 | Asm Ip Holding B.V. | Gas distributor |
USD940837S1 (en) | 2019-08-22 | 2022-01-11 | Asm Ip Holding B.V. | Electrode |
USD949319S1 (en) | 2019-08-22 | 2022-04-19 | Asm Ip Holding B.V. | Exhaust duct |
KR20210024420A (ko) | 2019-08-23 | 2021-03-05 | 에이에스엠 아이피 홀딩 비.브이. | 비스(디에틸아미노)실란을 사용하여 peald에 의해 개선된 품질을 갖는 실리콘 산화물 막을 증착하기 위한 방법 |
US11286558B2 (en) | 2019-08-23 | 2022-03-29 | Asm Ip Holding B.V. | Methods for depositing a molybdenum nitride film on a surface of a substrate by a cyclical deposition process and related semiconductor device structures including a molybdenum nitride film |
KR20210029090A (ko) | 2019-09-04 | 2021-03-15 | 에이에스엠 아이피 홀딩 비.브이. | 희생 캡핑 층을 이용한 선택적 증착 방법 |
KR20210029663A (ko) | 2019-09-05 | 2021-03-16 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 |
US11562901B2 (en) | 2019-09-25 | 2023-01-24 | Asm Ip Holding B.V. | Substrate processing method |
CN112593212B (zh) | 2019-10-02 | 2023-12-22 | Asm Ip私人控股有限公司 | 通过循环等离子体增强沉积工艺形成拓扑选择性氧化硅膜的方法 |
TWI846953B (zh) | 2019-10-08 | 2024-07-01 | 荷蘭商Asm Ip私人控股有限公司 | 基板處理裝置 |
KR20210042810A (ko) | 2019-10-08 | 2021-04-20 | 에이에스엠 아이피 홀딩 비.브이. | 활성 종을 이용하기 위한 가스 분배 어셈블리를 포함한 반응기 시스템 및 이를 사용하는 방법 |
TWI846966B (zh) | 2019-10-10 | 2024-07-01 | 荷蘭商Asm Ip私人控股有限公司 | 形成光阻底層之方法及包括光阻底層之結構 |
US12009241B2 (en) | 2019-10-14 | 2024-06-11 | Asm Ip Holding B.V. | Vertical batch furnace assembly with detector to detect cassette |
TWI834919B (zh) | 2019-10-16 | 2024-03-11 | 荷蘭商Asm Ip私人控股有限公司 | 氧化矽之拓撲選擇性膜形成之方法 |
US11637014B2 (en) | 2019-10-17 | 2023-04-25 | Asm Ip Holding B.V. | Methods for selective deposition of doped semiconductor material |
KR20210047808A (ko) | 2019-10-21 | 2021-04-30 | 에이에스엠 아이피 홀딩 비.브이. | 막을 선택적으로 에칭하기 위한 장치 및 방법 |
KR20210050453A (ko) | 2019-10-25 | 2021-05-07 | 에이에스엠 아이피 홀딩 비.브이. | 기판 표면 상의 갭 피처를 충진하는 방법 및 이와 관련된 반도체 소자 구조 |
US11646205B2 (en) | 2019-10-29 | 2023-05-09 | Asm Ip Holding B.V. | Methods of selectively forming n-type doped material on a surface, systems for selectively forming n-type doped material, and structures formed using same |
KR20210054983A (ko) | 2019-11-05 | 2021-05-14 | 에이에스엠 아이피 홀딩 비.브이. | 도핑된 반도체 층을 갖는 구조체 및 이를 형성하기 위한 방법 및 시스템 |
US11501968B2 (en) | 2019-11-15 | 2022-11-15 | Asm Ip Holding B.V. | Method for providing a semiconductor device with silicon filled gaps |
KR20210062561A (ko) | 2019-11-20 | 2021-05-31 | 에이에스엠 아이피 홀딩 비.브이. | 기판의 표면 상에 탄소 함유 물질을 증착하는 방법, 상기 방법을 사용하여 형성된 구조물, 및 상기 구조물을 형성하기 위한 시스템 |
CN112951697A (zh) | 2019-11-26 | 2021-06-11 | Asm Ip私人控股有限公司 | 基板处理设备 |
US11450529B2 (en) | 2019-11-26 | 2022-09-20 | Asm Ip Holding B.V. | Methods for selectively forming a target film on a substrate comprising a first dielectric surface and a second metallic surface |
CN112885692A (zh) | 2019-11-29 | 2021-06-01 | Asm Ip私人控股有限公司 | 基板处理设备 |
CN112885693A (zh) | 2019-11-29 | 2021-06-01 | Asm Ip私人控股有限公司 | 基板处理设备 |
JP7527928B2 (ja) | 2019-12-02 | 2024-08-05 | エーエスエム・アイピー・ホールディング・ベー・フェー | 基板処理装置、基板処理方法 |
KR20210070898A (ko) | 2019-12-04 | 2021-06-15 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 |
TW202125596A (zh) | 2019-12-17 | 2021-07-01 | 荷蘭商Asm Ip私人控股有限公司 | 形成氮化釩層之方法以及包括該氮化釩層之結構 |
KR20210080214A (ko) | 2019-12-19 | 2021-06-30 | 에이에스엠 아이피 홀딩 비.브이. | 기판 상의 갭 피처를 충진하는 방법 및 이와 관련된 반도체 소자 구조 |
TW202142733A (zh) | 2020-01-06 | 2021-11-16 | 荷蘭商Asm Ip私人控股有限公司 | 反應器系統、抬升銷、及處理方法 |
JP2021109175A (ja) | 2020-01-06 | 2021-08-02 | エーエスエム・アイピー・ホールディング・ベー・フェー | ガス供給アセンブリ、その構成要素、およびこれを含む反応器システム |
US11993847B2 (en) | 2020-01-08 | 2024-05-28 | Asm Ip Holding B.V. | Injector |
KR102675856B1 (ko) | 2020-01-20 | 2024-06-17 | 에이에스엠 아이피 홀딩 비.브이. | 박막 형성 방법 및 박막 표면 개질 방법 |
TW202130846A (zh) | 2020-02-03 | 2021-08-16 | 荷蘭商Asm Ip私人控股有限公司 | 形成包括釩或銦層的結構之方法 |
TW202146882A (zh) | 2020-02-04 | 2021-12-16 | 荷蘭商Asm Ip私人控股有限公司 | 驗證一物品之方法、用於驗證一物品之設備、及用於驗證一反應室之系統 |
US11776846B2 (en) | 2020-02-07 | 2023-10-03 | Asm Ip Holding B.V. | Methods for depositing gap filling fluids and related systems and devices |
US11781243B2 (en) | 2020-02-17 | 2023-10-10 | Asm Ip Holding B.V. | Method for depositing low temperature phosphorous-doped silicon |
TW202203344A (zh) | 2020-02-28 | 2022-01-16 | 荷蘭商Asm Ip控股公司 | 專用於零件清潔的系統 |
US11876356B2 (en) | 2020-03-11 | 2024-01-16 | Asm Ip Holding B.V. | Lockout tagout assembly and system and method of using same |
KR20210116240A (ko) | 2020-03-11 | 2021-09-27 | 에이에스엠 아이피 홀딩 비.브이. | 조절성 접합부를 갖는 기판 핸들링 장치 |
KR20210117157A (ko) | 2020-03-12 | 2021-09-28 | 에이에스엠 아이피 홀딩 비.브이. | 타겟 토폴로지 프로파일을 갖는 층 구조를 제조하기 위한 방법 |
KR20210124042A (ko) | 2020-04-02 | 2021-10-14 | 에이에스엠 아이피 홀딩 비.브이. | 박막 형성 방법 |
TW202146689A (zh) | 2020-04-03 | 2021-12-16 | 荷蘭商Asm Ip控股公司 | 阻障層形成方法及半導體裝置的製造方法 |
TW202145344A (zh) | 2020-04-08 | 2021-12-01 | 荷蘭商Asm Ip私人控股有限公司 | 用於選擇性蝕刻氧化矽膜之設備及方法 |
US11821078B2 (en) | 2020-04-15 | 2023-11-21 | Asm Ip Holding B.V. | Method for forming precoat film and method for forming silicon-containing film |
KR20210128343A (ko) | 2020-04-15 | 2021-10-26 | 에이에스엠 아이피 홀딩 비.브이. | 크롬 나이트라이드 층을 형성하는 방법 및 크롬 나이트라이드 층을 포함하는 구조 |
US11996289B2 (en) | 2020-04-16 | 2024-05-28 | Asm Ip Holding B.V. | Methods of forming structures including silicon germanium and silicon layers, devices formed using the methods, and systems for performing the methods |
KR20210132576A (ko) | 2020-04-24 | 2021-11-04 | 에이에스엠 아이피 홀딩 비.브이. | 바나듐 나이트라이드 함유 층을 형성하는 방법 및 이를 포함하는 구조 |
KR20210132600A (ko) | 2020-04-24 | 2021-11-04 | 에이에스엠 아이피 홀딩 비.브이. | 바나듐, 질소 및 추가 원소를 포함한 층을 증착하기 위한 방법 및 시스템 |
TW202146831A (zh) | 2020-04-24 | 2021-12-16 | 荷蘭商Asm Ip私人控股有限公司 | 垂直批式熔爐總成、及用於冷卻垂直批式熔爐之方法 |
KR20210134226A (ko) | 2020-04-29 | 2021-11-09 | 에이에스엠 아이피 홀딩 비.브이. | 고체 소스 전구체 용기 |
KR20210134869A (ko) | 2020-05-01 | 2021-11-11 | 에이에스엠 아이피 홀딩 비.브이. | Foup 핸들러를 이용한 foup의 빠른 교환 |
TW202147543A (zh) | 2020-05-04 | 2021-12-16 | 荷蘭商Asm Ip私人控股有限公司 | 半導體處理系統 |
KR20210141379A (ko) | 2020-05-13 | 2021-11-23 | 에이에스엠 아이피 홀딩 비.브이. | 반응기 시스템용 레이저 정렬 고정구 |
TW202146699A (zh) | 2020-05-15 | 2021-12-16 | 荷蘭商Asm Ip私人控股有限公司 | 形成矽鍺層之方法、半導體結構、半導體裝置、形成沉積層之方法、及沉積系統 |
KR20210143653A (ko) | 2020-05-19 | 2021-11-29 | 에이에스엠 아이피 홀딩 비.브이. | 기판 처리 장치 |
KR20210145078A (ko) | 2020-05-21 | 2021-12-01 | 에이에스엠 아이피 홀딩 비.브이. | 다수의 탄소 층을 포함한 구조체 및 이를 형성하고 사용하는 방법 |
KR102702526B1 (ko) | 2020-05-22 | 2024-09-03 | 에이에스엠 아이피 홀딩 비.브이. | 과산화수소를 사용하여 박막을 증착하기 위한 장치 |
TW202201602A (zh) | 2020-05-29 | 2022-01-01 | 荷蘭商Asm Ip私人控股有限公司 | 基板處理方法 |
TW202212620A (zh) | 2020-06-02 | 2022-04-01 | 荷蘭商Asm Ip私人控股有限公司 | 處理基板之設備、形成膜之方法、及控制用於處理基板之設備之方法 |
TW202218133A (zh) | 2020-06-24 | 2022-05-01 | 荷蘭商Asm Ip私人控股有限公司 | 形成含矽層之方法 |
TW202217953A (zh) | 2020-06-30 | 2022-05-01 | 荷蘭商Asm Ip私人控股有限公司 | 基板處理方法 |
TW202202649A (zh) | 2020-07-08 | 2022-01-16 | 荷蘭商Asm Ip私人控股有限公司 | 基板處理方法 |
KR20220010438A (ko) | 2020-07-17 | 2022-01-25 | 에이에스엠 아이피 홀딩 비.브이. | 포토리소그래피에 사용하기 위한 구조체 및 방법 |
TW202204662A (zh) | 2020-07-20 | 2022-02-01 | 荷蘭商Asm Ip私人控股有限公司 | 用於沉積鉬層之方法及系統 |
US12040177B2 (en) | 2020-08-18 | 2024-07-16 | Asm Ip Holding B.V. | Methods for forming a laminate film by cyclical plasma-enhanced deposition processes |
KR20220027026A (ko) | 2020-08-26 | 2022-03-07 | 에이에스엠 아이피 홀딩 비.브이. | 금속 실리콘 산화물 및 금속 실리콘 산질화물 층을 형성하기 위한 방법 및 시스템 |
TW202229601A (zh) | 2020-08-27 | 2022-08-01 | 荷蘭商Asm Ip私人控股有限公司 | 形成圖案化結構的方法、操控機械特性的方法、裝置結構、及基板處理系統 |
USD990534S1 (en) | 2020-09-11 | 2023-06-27 | Asm Ip Holding B.V. | Weighted lift pin |
USD1012873S1 (en) | 2020-09-24 | 2024-01-30 | Asm Ip Holding B.V. | Electrode for semiconductor processing apparatus |
US12009224B2 (en) | 2020-09-29 | 2024-06-11 | Asm Ip Holding B.V. | Apparatus and method for etching metal nitrides |
KR20220045900A (ko) | 2020-10-06 | 2022-04-13 | 에이에스엠 아이피 홀딩 비.브이. | 실리콘 함유 재료를 증착하기 위한 증착 방법 및 장치 |
CN114293174A (zh) | 2020-10-07 | 2022-04-08 | Asm Ip私人控股有限公司 | 气体供应单元和包括气体供应单元的衬底处理设备 |
TW202229613A (zh) | 2020-10-14 | 2022-08-01 | 荷蘭商Asm Ip私人控股有限公司 | 於階梯式結構上沉積材料的方法 |
TW202217037A (zh) | 2020-10-22 | 2022-05-01 | 荷蘭商Asm Ip私人控股有限公司 | 沉積釩金屬的方法、結構、裝置及沉積總成 |
TW202223136A (zh) | 2020-10-28 | 2022-06-16 | 荷蘭商Asm Ip私人控股有限公司 | 用於在基板上形成層之方法、及半導體處理系統 |
TW202235649A (zh) | 2020-11-24 | 2022-09-16 | 荷蘭商Asm Ip私人控股有限公司 | 填充間隙之方法與相關之系統及裝置 |
TW202235675A (zh) | 2020-11-30 | 2022-09-16 | 荷蘭商Asm Ip私人控股有限公司 | 注入器、及基板處理設備 |
US11946137B2 (en) | 2020-12-16 | 2024-04-02 | Asm Ip Holding B.V. | Runout and wobble measurement fixtures |
TW202231903A (zh) | 2020-12-22 | 2022-08-16 | 荷蘭商Asm Ip私人控股有限公司 | 過渡金屬沉積方法、過渡金屬層、用於沉積過渡金屬於基板上的沉積總成 |
USD980813S1 (en) | 2021-05-11 | 2023-03-14 | Asm Ip Holding B.V. | Gas flow control plate for substrate processing apparatus |
USD980814S1 (en) | 2021-05-11 | 2023-03-14 | Asm Ip Holding B.V. | Gas distributor for substrate processing apparatus |
USD1023959S1 (en) | 2021-05-11 | 2024-04-23 | Asm Ip Holding B.V. | Electrode for substrate processing apparatus |
USD981973S1 (en) | 2021-05-11 | 2023-03-28 | Asm Ip Holding B.V. | Reactor wall for substrate processing apparatus |
USD990441S1 (en) | 2021-09-07 | 2023-06-27 | Asm Ip Holding B.V. | Gas flow control plate |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3880816T2 (de) | 1987-06-16 | 1993-08-12 | Kawasaki Steel Co | Komplexverbindungen zur bildung von duennfilmen aus supraleitenden oxyden und verfahren zur bildung von duennfilmen aus supraleitenden oxyden. |
JPH01212220A (ja) | 1987-10-09 | 1989-08-25 | Fujitsu Ltd | 超伝導材料の気相成長方法 |
JP2551983B2 (ja) | 1988-09-27 | 1996-11-06 | 富士通株式会社 | 化学気相成長を用いた酸化物超伝導膜の作成方法 |
JPH06166597A (ja) * | 1990-10-19 | 1994-06-14 | Mitsubishi Materials Corp | ビスマス−ストロンチウム−カルシウム−銅酸化物系超電導体の化学的蒸着方法 |
US5846332A (en) | 1996-07-12 | 1998-12-08 | Applied Materials, Inc. | Thermally floating pedestal collar in a chemical vapor deposition chamber |
US6106625A (en) | 1997-12-02 | 2000-08-22 | Applied Materials, Inc. | Reactor useful for chemical vapor deposition of titanium nitride |
US6079356A (en) | 1997-12-02 | 2000-06-27 | Applied Materials, Inc. | Reactor optimized for chemical vapor deposition of titanium |
US6878206B2 (en) | 2001-07-16 | 2005-04-12 | Applied Materials, Inc. | Lid assembly for a processing system to facilitate sequential deposition techniques |
US6720259B2 (en) * | 2001-10-02 | 2004-04-13 | Genus, Inc. | Passivation method for improved uniformity and repeatability for atomic layer deposition and chemical vapor deposition |
US7204886B2 (en) | 2002-11-14 | 2007-04-17 | Applied Materials, Inc. | Apparatus and method for hybrid chemical processing |
US7780785B2 (en) | 2001-10-26 | 2010-08-24 | Applied Materials, Inc. | Gas delivery apparatus for atomic layer deposition |
US6916398B2 (en) | 2001-10-26 | 2005-07-12 | Applied Materials, Inc. | Gas delivery apparatus and method for atomic layer deposition |
US6821563B2 (en) | 2002-10-02 | 2004-11-23 | Applied Materials, Inc. | Gas distribution system for cyclical layer deposition |
US7476460B2 (en) | 2003-10-29 | 2009-01-13 | Hewlett-Packard Development Company, L.P. | Thin metal oxide film and method of making the same |
WO2005097484A1 (ja) * | 2004-03-31 | 2005-10-20 | Konica Minolta Holdings, Inc. | 透明導電性フィルム、透明導電性フィルムの製造方法及び有機エレクトロルミネッセンス素子 |
KR100581993B1 (ko) * | 2004-06-09 | 2006-05-22 | 삼성전자주식회사 | 원자층 증착법을 이용한 물질 형성방법 |
KR100576081B1 (ko) | 2005-01-31 | 2006-05-03 | 삼성전자주식회사 | 박막 제조 방법과 이를 이용한 플래시 메모리 장치의 제조방법 및 커패시터의 제조 방법 |
CN101182339A (zh) | 2006-07-31 | 2008-05-21 | 罗门哈斯电子材料有限公司 | 有机金属化合物 |
WO2009086263A1 (en) | 2007-12-28 | 2009-07-09 | Sigma-Aldrich Co. | Methods for preparing thin films using substituted pyrrolyl-metal precursors |
US8291857B2 (en) | 2008-07-03 | 2012-10-23 | Applied Materials, Inc. | Apparatuses and methods for atomic layer deposition |
US8883270B2 (en) * | 2009-08-14 | 2014-11-11 | Asm America, Inc. | Systems and methods for thin-film deposition of metal oxides using excited nitrogen—oxygen species |
TW201120232A (en) | 2009-11-30 | 2011-06-16 | Air Liquide | Deposition of alkaline earth metal fluoride films in gas phase at low temperature |
WO2012074511A2 (en) * | 2009-11-30 | 2012-06-07 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Deposition of alkaline earth metal fluoride films in gas phase at low temperature |
US20120308739A1 (en) * | 2011-05-30 | 2012-12-06 | L'air Liquide Societe Anonyme Pour I'etude Et I'exploitation Des Procedes Georges Claude | Methods for deposition of alkaline earth metal fluoride films |
-
2013
- 2013-06-21 US US13/923,599 patent/US10233541B2/en active Active
- 2013-06-25 TW TW102122551A patent/TWI605148B/zh active
- 2013-06-28 WO PCT/US2013/048420 patent/WO2014004949A1/en active Application Filing
- 2013-06-28 CN CN201380030127.1A patent/CN104350175B/zh active Active
- 2013-06-28 KR KR1020157002453A patent/KR102156326B1/ko active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
WO2014004949A1 (en) | 2014-01-03 |
TWI605148B (zh) | 2017-11-11 |
TW201406986A (zh) | 2014-02-16 |
KR20150027817A (ko) | 2015-03-12 |
CN104350175A (zh) | 2015-02-11 |
KR102156326B1 (ko) | 2020-09-15 |
US10233541B2 (en) | 2019-03-19 |
US20140004274A1 (en) | 2014-01-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104350175B (zh) | 含碱土金属的膜的沉积法 | |
US10043657B2 (en) | Plasma assisted atomic layer deposition metal oxide for patterning applications | |
JP6916297B2 (ja) | 強誘電体材料としてのケイ素ドープ酸化ハフニウムの堆積のための新規配合物 | |
TWI410519B (zh) | 於基材上形成含金屬層之氣相沈積方法 | |
TW201903190A (zh) | 使用反應物氣體之緩慢下降流量之電漿輔助循環沉積方法 | |
TWI493071B (zh) | 金屬矽酸鹽膜的原子層沈積 | |
US7077904B2 (en) | Method for atomic layer deposition (ALD) of silicon oxide film | |
CN104471689A (zh) | 用于沉积贫氧金属膜的方法 | |
US9831083B2 (en) | Method of manufacturing semiconductor device, substrate processing apparatus and non-transitory computer-readable recording medium | |
CN110050328A (zh) | 半导体处理设备 | |
KR20020002579A (ko) | 원자층 증착법을 이용한 지르코늄산화막 형성방법 | |
TW201323647A (zh) | 利用包含鉿或鋯之前驅物之膜的原子層沉積 | |
TW201126009A (en) | Systems and methods for thin-film deposition of metal oxides using excited nitrogen-oxygen species | |
JP2021182632A (ja) | 強誘電体材料としてのケイ素ドープ酸化ハフニウムの堆積のための新規配合物 | |
CN102575344A (zh) | 含金属-硅膜的脉冲化学气相沉积 | |
TW201119012A (en) | Semiconductor device including carbon-containing electrode and method for fabricating the same | |
TW201202465A (en) | Titanium-containing precursors for vapor deposition | |
TWI784098B (zh) | 用於氣相沈積含鈦膜的形成含鈦膜之組成物 | |
JP2007502021A (ja) | 基板上への材料蒸着方法及び基板上への層形成方法 | |
JP2010258411A (ja) | ジルコニウム含有膜の原子層堆積に有用なジルコニウム前駆体 | |
Mione et al. | Atmospheric-pressure plasma-enhanced spatial ALD of SiO2 studied by gas-phase infrared and optical emission spectroscopy | |
JP2023545471A (ja) | 阻害剤分子を使用する高アスペクト比構造のための堆積方法 | |
CN102046839B (zh) | 五氧化二钽取向膜的制造方法 | |
US20050276922A1 (en) | Method of forming thin dielectric layers | |
KR20020003003A (ko) | 원자층 증착법을 이용한 하프니움산화막 형성방법 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |