CN101072767B - 制备n-苯基吡唑-1-甲酰胺的方法 - Google Patents

制备n-苯基吡唑-1-甲酰胺的方法 Download PDF

Info

Publication number
CN101072767B
CN101072767B CN2005800419739A CN200580041973A CN101072767B CN 101072767 B CN101072767 B CN 101072767B CN 2005800419739 A CN2005800419739 A CN 2005800419739A CN 200580041973 A CN200580041973 A CN 200580041973A CN 101072767 B CN101072767 B CN 101072767B
Authority
CN
China
Prior art keywords
formula
mixture
compound
mmol
compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
CN2005800419739A
Other languages
English (en)
Chinese (zh)
Other versions
CN101072767A (zh
Inventor
R·夏皮罗
E·D-G·泰勒
W·T·齐默尔曼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FMC Agro Singapore Pte Ltd
FMC Corp
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=36353328&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN101072767(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Individual filed Critical Individual
Publication of CN101072767A publication Critical patent/CN101072767A/zh
Application granted granted Critical
Publication of CN101072767B publication Critical patent/CN101072767B/zh
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/58—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C237/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups
    • C07C237/28—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a non-condensed six-membered aromatic ring of the carbon skeleton
    • C07C237/30—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a non-condensed six-membered aromatic ring of the carbon skeleton having the nitrogen atom of the carboxamide group bound to hydrogen atoms or to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/16—Halogen atoms or nitro radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/18—One oxygen or sulfur atom
    • C07D231/20—One oxygen atom attached in position 3 or 5
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2005800419739A 2004-12-07 2005-12-06 制备n-苯基吡唑-1-甲酰胺的方法 Ceased CN101072767B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US63389904P 2004-12-07 2004-12-07
US60/633,899 2004-12-07
PCT/US2005/044131 WO2006062978A1 (en) 2004-12-07 2005-12-06 Method for preparing n-phenylpyrazole-1-carboxamides

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201110166224.6A Division CN102285899B (zh) 2004-12-07 2005-12-06 制备n-苯基吡唑-1-甲酰胺的方法

Publications (2)

Publication Number Publication Date
CN101072767A CN101072767A (zh) 2007-11-14
CN101072767B true CN101072767B (zh) 2011-07-27

Family

ID=36353328

Family Applications (2)

Application Number Title Priority Date Filing Date
CN2005800419739A Ceased CN101072767B (zh) 2004-12-07 2005-12-06 制备n-苯基吡唑-1-甲酰胺的方法
CN201110166224.6A Expired - Lifetime CN102285899B (zh) 2004-12-07 2005-12-06 制备n-苯基吡唑-1-甲酰胺的方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN201110166224.6A Expired - Lifetime CN102285899B (zh) 2004-12-07 2005-12-06 制备n-苯基吡唑-1-甲酰胺的方法

Country Status (23)

Country Link
US (1) US7528260B2 (OSRAM)
EP (1) EP1828164B1 (OSRAM)
JP (1) JP4996477B2 (OSRAM)
KR (1) KR101280086B1 (OSRAM)
CN (2) CN101072767B (OSRAM)
AR (1) AR051839A1 (OSRAM)
AT (1) ATE408609T1 (OSRAM)
AU (1) AU2005314155C1 (OSRAM)
BR (1) BRPI0516911B1 (OSRAM)
CA (1) CA2587528C (OSRAM)
DE (1) DE602005009866D1 (OSRAM)
DK (1) DK1828164T3 (OSRAM)
ES (1) ES2314753T3 (OSRAM)
GT (1) GT200500354A (OSRAM)
IL (1) IL183091A (OSRAM)
MX (1) MX265618B (OSRAM)
PL (1) PL1828164T3 (OSRAM)
RS (1) RS50672B (OSRAM)
RU (1) RU2397165C2 (OSRAM)
TW (1) TWI363756B (OSRAM)
UA (1) UA93861C2 (OSRAM)
WO (1) WO2006062978A1 (OSRAM)
ZA (1) ZA200704202B (OSRAM)

Families Citing this family (83)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20080038426A (ko) * 2005-08-24 2008-05-06 이 아이 듀폰 디 네모아 앤드 캄파니 무척추 해충 방제용 안트라닐아미드
KR101433395B1 (ko) 2006-07-19 2014-08-26 이 아이 듀폰 디 네모아 앤드 캄파니 3-치환된 2-아미노-5-할로벤즈아미드의 제조 방법
AU2012203792B2 (en) * 2006-07-19 2013-02-21 Fmc Corporation Process for making substituted 2H-3,1-benzoxazine-2,4(1H)-diones
TWI395728B (zh) 2006-12-06 2013-05-11 Du Pont 製備２-胺基-５-氰基苯甲酸衍生物之方法
TWI415827B (zh) * 2006-12-21 2013-11-21 Du Pont 製備２-胺基-５-氰基苯甲酸衍生物之方法
TWI430980B (zh) * 2007-06-29 2014-03-21 Du Pont 製備２－胺基－5－氰基苯甲酸衍生物之方法
EP2205555B1 (en) * 2007-11-08 2011-12-21 E. I. du Pont de Nemours and Company Process for preparing 2-amino-5-cyanobenzoic acid derivatives
TWI432421B (zh) * 2007-12-19 2014-04-01 Du Pont 製備２－胺基－５－氰基苯甲酸衍生物之方法
TWI431000B (zh) * 2008-03-05 2014-03-21 Du Pont 製備２－胺基－５－氰基苯甲酸衍生物之方法
CN101550130B (zh) * 2008-04-01 2012-11-07 中国中化股份有限公司 一种制备3-卤代-1-(3-氯-2-吡啶基)-1h-吡唑-5-甲酰卤的方法
CN101333213B (zh) * 2008-07-07 2011-04-13 中国中化股份有限公司 1-取代吡啶基-吡唑酰胺类化合物及其应用
JP5570520B2 (ja) * 2008-11-14 2014-08-13 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 非水和性結晶形を調製する方法
CN101747318A (zh) * 2008-12-11 2010-06-23 中国中化集团公司 1-(3，5-二氯吡啶基)-1h-5-吡唑羧酸酯类化合物
KR101687743B1 (ko) 2008-12-18 2016-12-19 바이엘 인텔렉쳐 프로퍼티 게엠베하 살해충제로서의 테트라졸 치환된 안트라닐산 아미드
CN101492387B (zh) * 2009-03-09 2012-07-25 浙江大学 2-氨基-5-氯-n,3-二甲基苯甲酰胺的制备方法
TWI547238B (zh) 2009-09-04 2016-09-01 杜邦股份有限公司 用於塗覆繁殖體之鄰胺苯甲酸二醯胺組合物
TWI501726B (zh) 2009-09-04 2015-10-01 Du Pont Ｎ－（苯腈）吡唑甲醯胺含水配方
CN102047914B (zh) * 2009-10-29 2014-02-26 中国中化股份有限公司 一种杀虫剂组合物
CN102947293B (zh) 2010-04-16 2016-02-24 拜耳知识产权有限责任公司 作为杀虫剂的三唑取代的邻氨基苯甲酰胺
TWI471318B (zh) * 2010-05-13 2015-02-01 Du Pont 製備非水合晶型之方法
CN103068820A (zh) 2010-06-15 2013-04-24 拜耳知识产权有限责任公司 新的邻位取代的芳基酰胺衍生物
CN101967139B (zh) * 2010-09-14 2013-06-05 中化蓝天集团有限公司 一种含一氟甲氧基吡唑的邻甲酰氨基苯甲酰胺类化合物、其合成方法及应用
US8563469B2 (en) 2010-12-13 2013-10-22 E I Du Pont De Nemours And Company Acrylate/methacrylate-based random copolymer/anthranilic diamide compositions for propagule coating
US8652998B2 (en) 2010-12-13 2014-02-18 E I Du Pont De Nemours And Company Branched copolymer/anthranilic diamide compositions for propagule coating
US8569268B2 (en) 2010-12-13 2013-10-29 E I Du Pont De Nemours And Company Acrylate/methacrylate-based diblock copolymer/anthranilic diamide compositions for propagule coating
US8709976B2 (en) 2010-12-13 2014-04-29 E I Du Pont De Nemours And Company Anthranilic diamide compositions for propagle coating
US8563470B2 (en) 2010-12-13 2013-10-22 E I Du Pont De Nemours And Company Anthranilic diamide and cyclodextrin compositions for propagule coating
US8575065B2 (en) 2010-12-13 2013-11-05 E I Du Pont De Nemours And Company Acrylate/methacrylate-based star copolymer/anthranilic diamide compositions for propagle coating
CN102060770A (zh) * 2010-12-27 2011-05-18 浙江工业大学 一种邻甲酰胺基苯甲酰胺类化合物及中间体的制备与应用
WO2012103436A1 (en) 2011-01-28 2012-08-02 E. I. Du Pont De Nemours And Company Method for preparing 2-aminobenzamide derivatives
MX369283B (es) * 2011-07-08 2019-11-04 Bayer Ip Gmbh Preparacion de 2-amino-5-ciano-n, 3-dimetilbenzamida.
US8921567B2 (en) 2011-08-12 2014-12-30 Basf Se Process for preparing N-substituted 1H-pyrazole-5-carbonylchloride compounds
IN2014CN01136A (OSRAM) 2011-08-12 2015-04-10 Basf Se
BR112014003646A2 (pt) 2011-08-18 2017-03-07 Basf Se composto de fórmula (i), método para preparar um composto de fórmula (i), composição agrícola ou veterinária, método para combater ou controlar pragas invertebradas do grupo de insetos, aracnídeos ou nematoides, método para proteger plantas, método para a proteção de semente, semente e método para tratar um animal infestado ou infectado por parasitas
US9556141B2 (en) 2011-11-21 2017-01-31 Basf Se Process for preparing N-substituted 1H-pyrazole-5-carboxylate compounds and derivatives thereof
CN102428926A (zh) * 2011-11-28 2012-05-02 北京燕化永乐农药有限公司 一种复配杀虫剂
BR112014015507B8 (pt) 2011-12-19 2022-11-08 Du Pont Composição inseticida, composição líquida e método para proteger um propágulo geotrópico e planta derivada deste contra uma praga de inseto fitófago
BR112014015633A8 (pt) 2011-12-19 2017-07-04 Du Pont composição inseticida, propágulo geotrópico, composição líquida e método de proteção de um propágulo geotrópico e planta derivada deste contra praga de insento fitófago
ES2571435T3 (es) 2011-12-19 2016-05-25 Du Pont Composiciones de nanopartículas que contienen polímeros e insecticidas de diamida de ácido antranílico para recubrimiento de propágulos
JP2013129602A (ja) * 2011-12-20 2013-07-04 Sumitomo Chemical Co Ltd 有害生物の防除方法
CN104245666B (zh) 2012-02-07 2019-01-11 拜耳知识产权有限责任公司 取代的邻氨基苯甲酸衍生物的制备方法
JP2016520539A (ja) 2013-03-28 2016-07-14 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ スルフィミンの製造方法およびそれらのＮ−（２−アミノ−ベンゾイル）−スルフィミンへのｉｎ−ｓｉｔｕ転化
AU2013405902B2 (en) 2013-11-19 2017-03-09 Halliburton Energy Services, Inc Measuring critical shear stress for mud filtercake removal
WO2015162260A1 (en) * 2014-04-25 2015-10-29 Basf Se Process for preparing anthranilamide esters and derivatives
CN104003976B (zh) * 2014-05-07 2016-03-16 肇庆市真格生物科技有限公司 多取代吡啶基吡唑酰胺及其制备方法和用途
TWI678354B (zh) * 2014-05-29 2019-12-01 新加坡商艾佛艾姆希農業新加坡有限公司 藉空氣氧化製備３-甲基-２-硝基苯甲酸之製程
CN104557860B (zh) * 2015-02-05 2017-03-15 浙江新安化工集团股份有限公司 一种邻甲酰胺基苯甲酰胺衍生物、其制备方法以及一种杀虫剂
CN104844569A (zh) * 2015-05-18 2015-08-19 常州大学 一种氯虫酰胺的合成方法
CN107522689B (zh) * 2016-06-21 2021-11-23 华东理工大学 氯虫苯甲酰胺的多晶型及其制备方法
CN107021889B (zh) * 2017-06-08 2019-09-27 联化科技（台州）有限公司 一种芳香族氯化物的制备方法及装置
WO2019123194A1 (en) 2017-12-20 2019-06-27 Pi Industries Ltd. Anthranilamides, their use as insecticide and processes for preparing the same.
AU2018389763B2 (en) 2017-12-20 2023-02-23 Pi Industries Ltd. Pyrazolopyridine-diamides, their use as insecticide and processes for preparing the same.
KR102811706B1 (ko) 2018-01-30 2025-05-22 피아이 인더스트리스 엘티디. 새로운 안트라닐아미드, 살충제로서 그의 용도 및 그의 제조 방법
EA202191554A1 (ru) * 2018-12-03 2021-09-02 Фмк Корпорейшн Способ получения n-фенилпиразол-1-карбоксамидов
PT3927701T (pt) * 2019-02-18 2025-02-03 Pi Industries Ltd Um processo de preparação de diamidas antranílicas e seus intermediários
CA3129950A1 (en) * 2019-02-22 2020-08-27 Pi Industries Ltd. A process for the synthesis anthranilic diamide compounds and intermediates thereof
CN111825653A (zh) 2019-04-19 2020-10-27 安道麦马克西姆有限公司 取代吡唑类化合物的制备及其作为邻氨基苯甲酰胺前体的用途
CN109970582A (zh) * 2019-05-06 2019-07-05 苏州山青竹生物医药有限公司 一种制备2-氨基-5-氯-3-甲基苯甲酸的方法
TWI875815B (zh) 2019-09-27 2025-03-11 美商富曼西公司 新穎鄰胺基苯甲醯胺組合物
AU2020372895A1 (en) * 2019-11-01 2022-05-26 Fmc Corporation An efficient new process for synthesis of 2-amino-5-chloro-N-,3-dimethylbenzamide
KR20220157967A (ko) 2020-03-25 2022-11-29 이시하라 산교 가부시끼가이샤 시클라닐리프롤의 제조 중간체의 제조 방법
AR122564A1 (es) * 2020-06-08 2022-09-21 Adama Makhteshim Ltd Proceso para la preparación de antranilamidas
TW202219046A (zh) * 2020-07-23 2022-05-16 美商富曼西公司 藉由使用一結晶中間體改善剋安勃製程
TW202219045A (zh) * 2020-07-23 2022-05-16 美商富曼西公司 用於製備n-苯基吡唑-1-甲醯胺之組合物及方法
TW202227405A (zh) * 2020-08-24 2022-07-16 以色列商安道麥馬克西姆有限公司 用於製備經取代的吡唑之方法
IL301271A (en) 2020-09-17 2023-05-01 Pi Industries Ltd A process for the synthesis of anthranilic acid/amide compounds and intermediates thereof
AR123593A1 (es) 2020-09-26 2022-12-21 Pi Industries Ltd Un proceso para la síntesis de compuestos antranílicos de ácido / amida e intermedios de los mismos
CN112552284B (zh) * 2020-12-18 2022-08-12 重庆华歌生物化学有限公司 一种氯虫苯甲酰胺的制备方法
CN112574190B (zh) * 2020-12-21 2022-11-11 江苏快达农化股份有限公司 一种氯虫苯甲酰胺的合成方法
WO2022136931A1 (en) * 2020-12-24 2022-06-30 Gsp Crop Science Private Limited Improved process for preparation of anthranilamides
WO2022162447A1 (en) * 2021-01-27 2022-08-04 Laurus Labs Limited Processes for preparation of chlorantraniliprole or a salt or its intermediates thereof
CN115181031B (zh) * 2021-04-02 2024-03-15 江苏扬农化工股份有限公司 一种2-氨基-5-氯苯甲酸衍生物的制备方法
WO2023110710A1 (en) 2021-12-13 2023-06-22 Syngenta Crop Protection Ag Method for controlling diamide resistant pests & compounds therefor
CN117186059A (zh) * 2022-05-31 2023-12-08 山东友道化学有限公司 一种双酰胺类化合物的生产方法
CN117466762A (zh) * 2022-07-20 2024-01-30 沈阳中化农药化工研发有限公司 一种2-氨基-3,5-二氯-n-甲基苯甲酰胺的制备方法
CN120379959A (zh) 2022-08-16 2025-07-25 安道麦马克西姆有限公司 用于经由氨基-氰基-苯衍生物制备溴氰虫酰胺的方法
TW202409000A (zh) 2022-08-29 2024-03-01 美商富曼西公司 用於製備３－鹵代－４，５－二氫－１ｈ－吡唑之高效新方法
WO2024116197A1 (en) * 2022-11-30 2024-06-06 Natco Pharma Limited An improved process for the preparation of intermediate of cyantraniliprole
CN115772090B (zh) * 2022-12-19 2024-06-07 九江善水科技股份有限公司 一种氯虫苯甲酰胺关键中间体的合成方法
WO2025041011A1 (en) 2023-08-18 2025-02-27 Adama Makhteshim Ltd. Water-based compositions containing pyrethroids
CN117105908B (zh) * 2023-10-23 2023-12-22 帕潘纳(北京)科技有限公司 一种双酰胺杀虫剂及应用
WO2025104727A1 (en) 2023-11-16 2025-05-22 Adama Makhteshim Ltd. Solid state forms of cyantraniliprole and uses thereof
WO2025188963A1 (en) 2024-03-06 2025-09-12 Fmc Corporation Metal catalyzed synthesis of 2-aminobenzamide derivatives

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL6603319A (OSRAM) * 1966-03-15 1967-09-18
NL6815727A (OSRAM) * 1967-11-09 1969-05-13
BE758911A (fr) * 1969-11-15 1971-05-13 Basf Ag Preparation d'alpha-aminonitriles aromatiques
US3840540A (en) * 1970-07-13 1974-10-08 Pfizer 2-substituted-3,4-dihydro-4-oxoquin-azolines as herbicides
DE2115625B2 (de) * 1971-03-31 1978-07-06 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von N-o-Cyanophenyl-N', N'-disubstituierten Formamidinen und deren Salzen
GB1410178A (en) * 1972-03-13 1975-10-15 Pfizer Substituted quinazolinones as herbicides
US3843791A (en) * 1973-01-11 1974-10-22 Pfizer Method of killing insects with quinazolinones and quinazoline-thiones
US4137325A (en) * 1977-03-17 1979-01-30 American Home Products Corporation Antisecretory oxamic acid esters
DE3103563A1 (de) * 1981-02-03 1982-08-26 Basf Ag, 6700 Ludwigshafen "verfahren zur herstellung von anthranilsaeureamiden"
JPS57167464A (en) 1981-04-10 1982-10-15 Sumitomo Chemical Co Dyeing of hydrophobic fiber
CA2131184A1 (en) 1992-04-03 1993-10-14 Jan Willem Hubert Smeets Selective n-acylation of amino alcohols
CN1227235C (zh) * 1999-12-09 2005-11-16 辛根塔参与股份公司 作为杀菌剂的吡唑羧酰胺和吡唑硫代羧酰胺
MY138097A (en) 2000-03-22 2009-04-30 Du Pont Insecticidal anthranilamides
DE10038327A1 (de) * 2000-08-05 2002-02-14 Philips Corp Intellectual Pty Integrierter Schaltkreis mit Selbsttest-Schaltung
WO2002048115A2 (en) * 2000-12-11 2002-06-20 E. I. Du Pont De Nemours And Company Quinazolinones and pyridinopyrimidinones for controlling invertebrate pests
MY142967A (en) * 2001-08-13 2011-01-31 Du Pont Method for controlling particular insect pests by applying anthranilamide compounds
AR036872A1 (es) * 2001-08-13 2004-10-13 Du Pont Compuesto de antranilamida, composicion que lo comprende y metodo para controlar una plaga de invertebrados
JP4095959B2 (ja) 2001-08-15 2008-06-04 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 無脊椎有害生物を防除するためのオルト置換アリールアミド類
ATE417829T1 (de) * 2001-08-16 2009-01-15 Du Pont Substituierte anthranilamide und ihre verwendung als pesticide
JP2005505576A (ja) * 2001-09-21 2005-02-24 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 殺節足動物用アントラニルアミド
GB2380323B (en) * 2001-09-29 2003-11-05 Motorola Inc Antenna for use in radio communications
ES2319972T3 (es) * 2001-10-15 2009-05-18 E.I. Du Pont De Nemours And Company Iminobenzoxazinas, iminobenzotiazinas e iminoquinazolinas para controlar plagas de invertebrados.
KR101011837B1 (ko) * 2002-01-22 2011-01-31 이 아이 듀폰 디 네모아 앤드 캄파니 무척추 해충 방제를 위한 퀴나졸린(디)온
TWI326283B (en) 2002-07-31 2010-06-21 Du Pont Method for preparing fused oxazinones
MXPA05003337A (es) * 2002-10-04 2005-07-05 Du Pont Insecticidas de antranilamida.
WO2004046129A2 (en) * 2002-11-15 2004-06-03 E.I. Du Pont De Nemours And Company Novel anthranilamide insecticides
MD3864C2 (ro) * 2003-01-28 2009-11-30 E.I. Du Pont De Nemours And Company Compuşi ai cianoantranilamidei, compoziţii pe baza ei şi procedeu de combatere a dăunătorilor nevertebraţi
KR20060008336A (ko) 2003-06-12 2006-01-26 이 아이 듀폰 디 네모아 앤드 캄파니 융합된 옥사지논 제조 방법

Also Published As

Publication number Publication date
AU2005314155C1 (en) 2024-05-30
CN101072767A (zh) 2007-11-14
CA2587528A1 (en) 2006-06-15
EP1828164A1 (en) 2007-09-05
KR20070089995A (ko) 2007-09-04
AU2005314155A1 (en) 2006-06-15
ZA200704202B (en) 2008-08-27
TW200624421A (en) 2006-07-16
CA2587528C (en) 2012-11-20
UA93861C2 (uk) 2011-03-25
BRPI0516911B1 (pt) 2016-08-30
ES2314753T3 (es) 2009-03-16
WO2006062978A1 (en) 2006-06-15
JP2008523069A (ja) 2008-07-03
RU2007125710A (ru) 2009-01-20
CN102285899A (zh) 2011-12-21
TWI363756B (en) 2012-05-11
ATE408609T1 (de) 2008-10-15
CN102285899B (zh) 2014-09-17
EP1828164B1 (en) 2008-09-17
KR101280086B1 (ko) 2013-07-01
DE602005009866D1 (de) 2008-10-30
IL183091A (en) 2011-05-31
BRPI0516911A (pt) 2008-09-23
MX2007006630A (es) 2007-06-19
AR051839A1 (es) 2007-02-14
JP4996477B2 (ja) 2012-08-08
US20070299265A1 (en) 2007-12-27
MX265618B (es) 2009-04-02
US7528260B2 (en) 2009-05-05
AU2005314155B2 (en) 2011-07-14
IL183091A0 (en) 2007-09-20
RU2397165C2 (ru) 2010-08-20
RS50672B (sr) 2010-06-30
PL1828164T3 (pl) 2009-01-30
DK1828164T3 (da) 2008-12-08
GT200500354A (es) 2006-07-03

Similar Documents

Publication Publication Date Title
CN101072767B (zh) 制备n-苯基吡唑-1-甲酰胺的方法
CN1307161C (zh) 取代的二氢3－卤代－1h－吡唑－5－羧酸酯其制备及应用
CN101541740B (zh) 制备2-氨基-5-氰基苯甲酸衍生物的方法
CN101970397B (zh) 制备2-氨基-5-氰基苯甲酸衍生物的方法
CN101600682A (zh) 3-取代2-氨基-5-卤代苯甲酰胺的制备方法
CN103764649B (zh) 通过苯并噁嗪酮与胺反应制备四唑取代的邻氨基苯甲酸二酰胺衍生物的方法
PL216029B1 (pl) Sposób wytwarzania 3-chlorowco-4,5-dihydro-1H-pirazoli
CN100522958C (zh) 2-取代-5-氧代-3-吡唑烷羧酸酯的制备和应用
JP2018027964A (ja) 置換アントラニル酸誘導体を製造する方法
CN100376565C (zh) 稠合嗪酮的制备方法
CN113382984A (zh) N-苯基吡唑-1-甲酰胺的制备方法
JP6372560B2 (ja) ピラゾール化合物の製造方法
KR20150000902A (ko) 1-아릴-5-알킬 피라졸 화합물의 개선된 제조 방법
CA2601870C (en) Conversion of 2-pyrazolines to pyrazoles using bromine
CN102007114B (zh) 邻氨基苯甲酰胺系化合物的制造方法
RU2317983C2 (ru) Замещенные дигидро 3-галоген-1h-пиразол-5-карбоксилаты, их получение и использование
AU2012203792A1 (en) Process for making substituted 2H-3,1-benzoxazine-2,4(1H)-diones
JP2004083571A (ja) フェノキシ基で置換された２−ピリドン化合物の製造法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20180713

Address after: Singapore Singapore

Co-patentee after: FMC Corp.

Patentee after: FMC agricultural Singapore Ltd.

Address before: American Delaware

Patentee before: DuPont

TR01 Transfer of patent right
IW01 Full invalidation of patent right

Decision date of declaring invalidation: 20220902

Decision number of declaring invalidation: 58006

Granted publication date: 20110727

IW01 Full invalidation of patent right