BRPI1014950A2 - catalisador de hidrotratamento contendo fósforo e boro. - Google Patents
catalisador de hidrotratamento contendo fósforo e boro.Info
- Publication number
- BRPI1014950A2 BRPI1014950A2 BRPI1014950A BRPI1014950A BRPI1014950A2 BR PI1014950 A2 BRPI1014950 A2 BR PI1014950A2 BR PI1014950 A BRPI1014950 A BR PI1014950A BR PI1014950 A BRPI1014950 A BR PI1014950A BR PI1014950 A2 BRPI1014950 A2 BR PI1014950A2
- Authority
- BR
- Brazil
- Prior art keywords
- boron
- catalyst containing
- containing phosphorus
- hydrotreating catalyst
- hydrotreating
- Prior art date
Links
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 title 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title 1
- 229910052796 boron Inorganic materials 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
- 229910052698 phosphorus Inorganic materials 0.000 title 1
- 239000011574 phosphorus Substances 0.000 title 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/882—Molybdenum and cobalt
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/883—Molybdenum and nickel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/638—Pore volume more than 1.0 ml/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0219—Coating the coating containing organic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
- B01J6/001—Calcining
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Nanotechnology (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US17125309P | 2009-04-21 | 2009-04-21 | |
PCT/EP2010/002458 WO2010121807A1 (en) | 2009-04-21 | 2010-04-21 | Hydrotreating catalyst containing phosphorus and boron |
Publications (2)
Publication Number | Publication Date |
---|---|
BRPI1014950A2 true BRPI1014950A2 (pt) | 2017-06-27 |
BRPI1014950B1 BRPI1014950B1 (pt) | 2018-10-23 |
Family
ID=42320026
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI1014950A BRPI1014950B1 (pt) | 2009-04-21 | 2010-04-21 | catalisador de hidrotratamento contendo fósforo e boro. |
Country Status (15)
Country | Link |
---|---|
US (2) | US11318453B2 (pt) |
EP (1) | EP2421645B1 (pt) |
JP (1) | JP5548257B2 (pt) |
KR (1) | KR101767375B1 (pt) |
CN (2) | CN102438745A (pt) |
AU (1) | AU2010238811B2 (pt) |
BR (1) | BRPI1014950B1 (pt) |
CA (1) | CA2758285C (pt) |
DK (1) | DK2421645T3 (pt) |
EA (1) | EA020295B1 (pt) |
ES (1) | ES2559006T3 (pt) |
HU (1) | HUE028562T2 (pt) |
PL (1) | PL2421645T3 (pt) |
SG (1) | SG175266A1 (pt) |
WO (1) | WO2010121807A1 (pt) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11318453B2 (en) * | 2009-04-21 | 2022-05-03 | Albemarle Catalysts Company B.V. | Hydrotreating catalyst containing phosphorus and boron |
US9254478B2 (en) | 2009-08-24 | 2016-02-09 | Albemarle Corporation | Solutions and catalysts comprising group VI metal, group VIII metal, phosphorus and an additive |
JP5635752B2 (ja) * | 2009-09-25 | 2014-12-03 | 日本ケッチェン株式会社 | 水素化処理触媒の製造方法、並びに当該触媒を用いる炭化水素油の水素化処理方法 |
US10507458B2 (en) | 2012-08-29 | 2019-12-17 | Indian Oil Corporation Limited | Hydrotreating catalyst and process for preparing the same |
US11633727B2 (en) | 2012-10-10 | 2023-04-25 | Albemarle Catalysts Company B.V. | Supported hydrotreating catalysts having enhanced activity |
US11731118B2 (en) | 2012-10-10 | 2023-08-22 | Albemarle Catalysts Company B.V. | Supported hydrotreating catalysts having enhanced activity |
FR3014707B1 (fr) * | 2013-12-13 | 2017-03-31 | Ifp Energies Now | Procede de preparation d'un catalyseur, catalyseur et son utilisation dans un procede d'hydroconversion et/ou d'hydrotraitement |
US20150174559A1 (en) | 2013-12-19 | 2015-06-25 | Basf Corporation | Phosphorus-Modified FCC Catalysts |
US9895680B2 (en) | 2013-12-19 | 2018-02-20 | Basf Corporation | FCC catalyst compositions containing boron oxide |
US9441167B2 (en) | 2013-12-19 | 2016-09-13 | Basf Corporation | Boron oxide in FCC processes |
US9796932B2 (en) | 2013-12-19 | 2017-10-24 | Basf Corporation | FCC catalyst compositions containing boron oxide and phosphorus |
JP6802806B2 (ja) * | 2015-04-24 | 2020-12-23 | アルベマール・ユーロプ・エスピーアールエル | ドープされた担体に金属有機硫化物を含有する水素化処理触媒 |
EP3302790A4 (en) | 2015-05-29 | 2019-01-16 | Advanced Refining Technologies, LLC | HYDRAULIC CATALYST WITH HIGH HDN SELECTIVITY |
EP3655154A1 (en) * | 2017-07-21 | 2020-05-27 | Albemarle Europe Srl | Hydrotreating catalyst with a titanium containing carrier and organic additive |
SG11202000462VA (en) * | 2017-07-21 | 2020-02-27 | Albemarle Europe Srl | Hydrotreating catalyst with a titanium containing carrier and sulfur containing organic additive |
BR102019028121B1 (pt) | 2019-12-27 | 2021-12-14 | Petróleo Brasileiro S.A. - Petrobras | Método de obtenção de um suporte para catalisadores de hidrorrefino, processo de obtenção de catalisadores de hidrorrefino, catalisadores de hidrorrefino e uso do suporte |
RU2726374C1 (ru) * | 2020-01-17 | 2020-07-13 | Акционерное общество "Газпромнефть - Омский НПЗ" (АО "Газпромнефть - ОНПЗ") | Способ приготовления носителя для катализатора гидроочистки |
US11891577B2 (en) | 2020-02-10 | 2024-02-06 | Hindustan Petroleum Corporation Limited | FCC additive composition for bottoms cracking and a process for preparation thereof |
TW202224768A (zh) * | 2020-08-26 | 2022-07-01 | 美商先進精鍊科技有限公司 | 在氫加工催化劑中併入硼、所獲得之催化劑、及其用途 |
CA3236960A1 (en) | 2021-11-05 | 2023-05-11 | Tjostil Vlaar | Supported hydrotreating catalysts having enhanced activity |
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US2938001A (en) * | 1956-12-13 | 1960-05-24 | Universal Oil Prod Co | Catalyst composite |
GB885866A (en) * | 1960-05-23 | 1961-12-28 | Universal Oil Prod Co | Boron phosphate catalyst composition |
BE612739A (pt) | 1961-01-26 | |||
US3453219A (en) * | 1966-12-19 | 1969-07-01 | Universal Oil Prod Co | Petroleum crude oil hydrorefining catalyst |
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US3666685A (en) | 1970-04-23 | 1972-05-30 | Universal Oil Prod Co | Catalytic hydrorefining of petroleum crude oils and residual oils |
US3954670A (en) | 1974-03-27 | 1976-05-04 | Exxon Research & Engineering Co. | Boria-alumina catalyst base |
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EA020295B1 (ru) | 2014-10-30 |
CN106964328A (zh) | 2017-07-21 |
JP5548257B2 (ja) | 2014-07-16 |
AU2010238811B2 (en) | 2015-01-29 |
US11986813B2 (en) | 2024-05-21 |
KR20110138234A (ko) | 2011-12-26 |
WO2010121807A1 (en) | 2010-10-28 |
CA2758285A1 (en) | 2010-10-28 |
CN102438745A (zh) | 2012-05-02 |
EP2421645A1 (en) | 2012-02-29 |
US20120037540A1 (en) | 2012-02-16 |
EP2421645B1 (en) | 2015-11-11 |
US11318453B2 (en) | 2022-05-03 |
HUE028562T2 (en) | 2016-12-28 |
US20220219157A1 (en) | 2022-07-14 |
CA2758285C (en) | 2018-01-16 |
BRPI1014950B1 (pt) | 2018-10-23 |
KR101767375B1 (ko) | 2017-08-11 |
AU2010238811A1 (en) | 2011-11-10 |
ES2559006T3 (es) | 2016-02-10 |
SG175266A1 (en) | 2011-11-28 |
DK2421645T3 (en) | 2016-02-15 |
JP2012524649A (ja) | 2012-10-18 |
EA201101526A1 (ru) | 2012-03-30 |
PL2421645T3 (pl) | 2016-05-31 |
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