FR2910352B1 - Procede d'hydroconversion en phase slurry de charges hydrocarbonees lourdes et ou de charbon utilisant un catalyseur supporte - Google Patents

Procede d'hydroconversion en phase slurry de charges hydrocarbonees lourdes et ou de charbon utilisant un catalyseur supporte

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Publication number
FR2910352B1
FR2910352B1 FR0611403A FR0611403A FR2910352B1 FR 2910352 B1 FR2910352 B1 FR 2910352B1 FR 0611403 A FR0611403 A FR 0611403A FR 0611403 A FR0611403 A FR 0611403A FR 2910352 B1 FR2910352 B1 FR 2910352B1
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FR
France
Prior art keywords
degrees
catalytic metal
balls
fraction
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0611403A
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English (en)
Other versions
FR2910352A1 (fr
Inventor
Auberger Magalie Roy
Denis Guillaume
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR0611403A priority Critical patent/FR2910352B1/fr
Priority to AU2007249084A priority patent/AU2007249084B2/en
Priority to CA2615225A priority patent/CA2615225C/fr
Priority to US11/961,132 priority patent/US7807044B2/en
Priority to CN2007101857267A priority patent/CN101255360B/zh
Priority to SA07280716A priority patent/SA07280716B1/ar
Publication of FR2910352A1 publication Critical patent/FR2910352A1/fr
Application granted granted Critical
Publication of FR2910352B1 publication Critical patent/FR2910352B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0063—Granulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B01J35/40—
    • B01J35/60—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • C10G49/04—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing nickel, cobalt, chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B01J35/613—
    • B01J35/615—
    • B01J35/635—
    • B01J35/66—
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range

Abstract

L'invention concerne un procédé de conversion de charges lourdes opérant en réacteur slurry en présence d'hydrogène et en présence d'un catalyseur comprenant au moins un métal catalytique ou un composé de métal catalytique du groupe VIB et/ou VIII supporté sur alumine, dont la structure poreuse se compose d'une pluralité d'agglomérats juxtaposés et formés chacun d'une pluralité de plaquettes aciculaires, les plaquettes de chaque agglomérat étant orientées généralement radialement les unes vis à vis des autres et par rapport au centre de l'agglomérat, ledit catalyseur ayant une forme irrégulière et non sphérique et se présentant majoritairement sous forme de fragments, obtenu selon un procédé de préparation incluant les étapes suivantes:a) granulation à partir d'une poudre d'alumine active présentant une structure mal cristallisée et/ou amorphe, de façon à obtenir des agglomérats sous forme de billes,b) mûrissement en atmosphère humide entre 60 et 100 degres C puis séchage desdites billes,c) tamisage pour récupérer une fraction desdites billes,d) concassage de ladite fraction,e) calcination d'une partie au moins de ladite fraction concassée à une température comprise entre 250 et 900 degres C,f) imprégnation acide et traitement hydrothermal à une température comprise entre 80 et 250 degres C,g) séchage puis calcination à une température comprise entre 500 et 1100 degres C.h) dépôt par imprégnation d' au moins un métal catalytique ou un composé de métal catalytique du groupe VIB et/ou du groupe VIII.Le procédé selon l'invention met en oeuvre un catalyseur dont la texture poreuse, la forme et la granulométrie spécifiques, conduisent à des performances améliorées.
FR0611403A 2006-12-21 2006-12-21 Procede d'hydroconversion en phase slurry de charges hydrocarbonees lourdes et ou de charbon utilisant un catalyseur supporte Expired - Fee Related FR2910352B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR0611403A FR2910352B1 (fr) 2006-12-21 2006-12-21 Procede d'hydroconversion en phase slurry de charges hydrocarbonees lourdes et ou de charbon utilisant un catalyseur supporte
AU2007249084A AU2007249084B2 (en) 2006-12-21 2007-12-17 Process for slurry phase hydroconversion of heavy hydrocarbon feeds and/or coal using a supported catalyst
CA2615225A CA2615225C (fr) 2006-12-21 2007-12-19 Procede d'hydroconversion en phase slurry de charges hydrocarbonees lourdes et ou de charbon utilisant un catalyseur supporte
US11/961,132 US7807044B2 (en) 2006-12-21 2007-12-20 Process for slurry phase hydroconversion of heavy hydrocarbon feeds and/or coal using a supported catalyst
CN2007101857267A CN101255360B (zh) 2006-12-21 2007-12-21 使用担载催化剂的重质烃原料和/或煤浆料相加氢转化方法
SA07280716A SA07280716B1 (ar) 2006-12-21 2007-12-29 عملية تحويل مائية في طور ملاطي للتغذيات الهيدروكربونية الثقيلة و/أو الفحم باستعمال عامل حفاز مثبت

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0611403A FR2910352B1 (fr) 2006-12-21 2006-12-21 Procede d'hydroconversion en phase slurry de charges hydrocarbonees lourdes et ou de charbon utilisant un catalyseur supporte

Publications (2)

Publication Number Publication Date
FR2910352A1 FR2910352A1 (fr) 2008-06-27
FR2910352B1 true FR2910352B1 (fr) 2010-10-08

Family

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FR0611403A Expired - Fee Related FR2910352B1 (fr) 2006-12-21 2006-12-21 Procede d'hydroconversion en phase slurry de charges hydrocarbonees lourdes et ou de charbon utilisant un catalyseur supporte

Country Status (6)

Country Link
US (1) US7807044B2 (fr)
CN (1) CN101255360B (fr)
AU (1) AU2007249084B2 (fr)
CA (1) CA2615225C (fr)
FR (1) FR2910352B1 (fr)
SA (1) SA07280716B1 (fr)

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AU2010238811B2 (en) 2009-04-21 2015-01-29 Albemarle Europe Sprl Hydrotreating catalyst containing phosphorus and boron
FR2958656B1 (fr) * 2010-04-13 2012-05-11 Inst Francais Du Petrole Procede d'hydroconversion de charges petrolieres via une technologie en slurry permettant la recuperation des metaux du catalyseur et de la charge mettant en oeuvre une etape d'extraction.
FR2958658B1 (fr) * 2010-04-13 2012-03-30 Inst Francais Du Petrole Procede d'hydroconversion de charges petrolieres via une technologie en slurry permettant la recuperation des metaux du catalyseur et de la charge mettant en oeuvre une etape de lixiviation.
FR2958657B1 (fr) * 2010-04-13 2012-05-11 Inst Francais Du Petrole Procede d'hydroconversion de charges petrolieres via une technologie en slurry permettant la recuperation des metaux du catalyseur et de la charge mettant en oeuvre une etape de cokefaction.
US9243194B2 (en) 2009-10-08 2016-01-26 IFP Energies Nouvelles Process for hydroconversion of heavy carbon-containing feedstocks that integrate a boiling-bed technology and a slurry technology
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US11788017B2 (en) 2017-02-12 2023-10-17 Magëmã Technology LLC Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil
US10604709B2 (en) 2017-02-12 2020-03-31 Magēmā Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials
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FR3116832B1 (fr) * 2020-11-27 2023-11-03 Ifp Energies Now Procede d’hydrodesulfuration de finition en presence d’un catalyseur sur support meso-macroporeux
FR3116826B1 (fr) * 2020-11-27 2023-11-03 Ifp Energies Now Procede d’hydrodesulfuration mettant en œuvre un catalyseur comprenant un support d’alumine flash
FR3116831B1 (fr) * 2020-11-27 2023-11-03 Ifp Energies Now Procede d’hydrogenation selective d’une essence en presence d’un catalyseur sur support meso-macroporeux
FR3116829B1 (fr) * 2020-11-27 2023-11-03 Ifp Energies Now Procede d’hydrodesulfuration en presence d’un catalyseur sur support meso-macroporeux

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Also Published As

Publication number Publication date
FR2910352A1 (fr) 2008-06-27
CA2615225C (fr) 2015-10-27
US20080149531A1 (en) 2008-06-26
CN101255360B (zh) 2012-09-05
SA07280716B1 (ar) 2011-05-04
CA2615225A1 (fr) 2008-06-21
US7807044B2 (en) 2010-10-05
CN101255360A (zh) 2008-09-03
AU2007249084B2 (en) 2011-08-11
AU2007249084A1 (en) 2008-07-10

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