FR3116829B1 - Procede d’hydrodesulfuration en presence d’un catalyseur sur support meso-macroporeux - Google Patents
Procede d’hydrodesulfuration en presence d’un catalyseur sur support meso-macroporeux Download PDFInfo
- Publication number
- FR3116829B1 FR3116829B1 FR2012317A FR2012317A FR3116829B1 FR 3116829 B1 FR3116829 B1 FR 3116829B1 FR 2012317 A FR2012317 A FR 2012317A FR 2012317 A FR2012317 A FR 2012317A FR 3116829 B1 FR3116829 B1 FR 3116829B1
- Authority
- FR
- France
- Prior art keywords
- volume
- support
- catalyst
- mesopores
- corresponds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000011148 porous material Substances 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 230000002902 bimodal effect Effects 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/882—Molybdenum and cobalt
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- B01J35/613—
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- B01J35/615—
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- B01J35/635—
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- B01J35/638—
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- B01J35/647—
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- B01J35/651—
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- B01J35/653—
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- B01J35/66—
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- B01J35/69—
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- B01J35/695—
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0063—Granulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/06—Washing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/10—Heat treatment in the presence of water, e.g. steam
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/28—Phosphorising
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
- B01J6/001—Calcining
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
Abstract
Procédé d’hydrodésulfuration d’une coupe essence oléfinique contenant du soufre dans lequel on met en contact ladite coupe essence, de l’hydrogène et un catalyseur comprenant un métal du groupe VIB, un métal du groupe VIII, et un support d’alumine mésoporeux et macroporeux comprenant une distribution bimodale de mésopores et dans lequel :- le volume des mésopores de diamètre supérieur ou égal à 2 nm et inférieur à 18 nm correspond entre 10 et 30% en volume du volume poreux total dudit support ;- le volume des mésopores de diamètre supérieur ou égal à 18 nm et inférieur à 50 nm correspond entre 30 et 50% en volume du volume poreux total dudit support ;- le volume des macropores de diamètre supérieur ou égal à 50 nm et inférieur à 8000 nm correspond entre 30 à 50% en volume du volume poreux total dudit support.
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR2012317A FR3116829B1 (fr) | 2020-11-27 | 2020-11-27 | Procede d’hydrodesulfuration en presence d’un catalyseur sur support meso-macroporeux |
JP2023532271A JP2023550820A (ja) | 2020-11-27 | 2021-11-18 | メソ-マクロ多孔質担体上における触媒の存在下での水素化脱硫方法 |
AU2021387713A AU2021387713A1 (en) | 2020-11-27 | 2021-11-18 | Method for hydrodesulfurization in the presence of a catalyst on a mesoporous-macroporous substrate |
US18/036,540 US20230415131A1 (en) | 2020-11-27 | 2021-11-18 | Method for hydrodesulfurization in the presence of a catalyst on a mesoporous-macroporous substrate |
KR1020237017333A KR20230115292A (ko) | 2020-11-27 | 2021-11-18 | 메조포러스-마크로포러스 기재상의 촉매 존재하에서의 수소화탈황 방법 |
CN202180079711.0A CN116547070A (zh) | 2020-11-27 | 2021-11-18 | 在中孔-大孔基质上的催化剂的存在下的加氢脱硫方法 |
PCT/EP2021/082066 WO2022112078A1 (fr) | 2020-11-27 | 2021-11-18 | Procede d'hydrodesulfuration en presence d'un catalyseur sur support meso-macroporeux |
EP21807139.7A EP4251715A1 (fr) | 2020-11-27 | 2021-11-18 | Procede d'hydrodesulfuration en presence d'un catalyseur sur support meso-macroporeux |
MX2023005253A MX2023005253A (es) | 2020-11-27 | 2021-11-18 | Proceso de hidrodesulfuracion en la presencia de un catalizador sobre un soporte meso-macroporoso. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR2012317 | 2020-11-27 | ||
FR2012317A FR3116829B1 (fr) | 2020-11-27 | 2020-11-27 | Procede d’hydrodesulfuration en presence d’un catalyseur sur support meso-macroporeux |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3116829A1 FR3116829A1 (fr) | 2022-06-03 |
FR3116829B1 true FR3116829B1 (fr) | 2023-11-03 |
Family
ID=74347322
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR2012317A Active FR3116829B1 (fr) | 2020-11-27 | 2020-11-27 | Procede d’hydrodesulfuration en presence d’un catalyseur sur support meso-macroporeux |
Country Status (9)
Country | Link |
---|---|
US (1) | US20230415131A1 (fr) |
EP (1) | EP4251715A1 (fr) |
JP (1) | JP2023550820A (fr) |
KR (1) | KR20230115292A (fr) |
CN (1) | CN116547070A (fr) |
AU (1) | AU2021387713A1 (fr) |
FR (1) | FR3116829B1 (fr) |
MX (1) | MX2023005253A (fr) |
WO (1) | WO2022112078A1 (fr) |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6589908B1 (en) | 2000-11-28 | 2003-07-08 | Shell Oil Company | Method of making alumina having bimodal pore structure, and catalysts made therefrom |
KR101399700B1 (ko) | 2006-01-17 | 2014-05-26 | 엑손모빌 리서치 앤드 엔지니어링 컴퍼니 | 나프타 수소첨가탈황을 위한 고온 알루미나 지지체를 가진 선택적 촉매 |
FR2904242B1 (fr) | 2006-07-28 | 2012-09-28 | Inst Francais Du Petrole | Procede d'hydrodesulfuration de coupes contenant des composes soufres et des olefines en presence d'un catalyseur supporte comprenant des elements des groupes viii et vib |
FR2910352B1 (fr) * | 2006-12-21 | 2010-10-08 | Inst Francais Du Petrole | Procede d'hydroconversion en phase slurry de charges hydrocarbonees lourdes et ou de charbon utilisant un catalyseur supporte |
BR112016025596B1 (pt) * | 2014-05-01 | 2021-07-20 | Shell Internationale Research Maatschappij B.V. | Catalisador de hidrodessulfurização seletiva e processo para hidrodessulfurização seletiva dos compostos de enxofre contidos em uma matéria-prima de hidrocarboneto |
BR112018069469B1 (pt) * | 2016-03-23 | 2023-01-10 | Shell Internationale Research Maatschappij B.V. | Composição catalítica útil na redução catalítica de compostos de enxofre contidos em uma corrente de gás, método de preparação da mesma e processo de hidrólise |
CN109420504B (zh) | 2017-08-31 | 2021-08-27 | 中国石油天然气股份有限公司 | 一种催化裂化汽油加氢脱硫催化剂及制备方法 |
CN109894122B (zh) | 2017-12-07 | 2021-06-01 | 中国石油天然气股份有限公司 | 一种fcc汽油加氢脱硫催化剂及其制备方法 |
-
2020
- 2020-11-27 FR FR2012317A patent/FR3116829B1/fr active Active
-
2021
- 2021-11-18 EP EP21807139.7A patent/EP4251715A1/fr active Pending
- 2021-11-18 WO PCT/EP2021/082066 patent/WO2022112078A1/fr active Application Filing
- 2021-11-18 CN CN202180079711.0A patent/CN116547070A/zh active Pending
- 2021-11-18 KR KR1020237017333A patent/KR20230115292A/ko unknown
- 2021-11-18 US US18/036,540 patent/US20230415131A1/en active Pending
- 2021-11-18 AU AU2021387713A patent/AU2021387713A1/en active Pending
- 2021-11-18 JP JP2023532271A patent/JP2023550820A/ja active Pending
- 2021-11-18 MX MX2023005253A patent/MX2023005253A/es unknown
Also Published As
Publication number | Publication date |
---|---|
WO2022112078A1 (fr) | 2022-06-02 |
JP2023550820A (ja) | 2023-12-05 |
AU2021387713A1 (en) | 2023-06-22 |
MX2023005253A (es) | 2023-05-23 |
US20230415131A1 (en) | 2023-12-28 |
EP4251715A1 (fr) | 2023-10-04 |
KR20230115292A (ko) | 2023-08-02 |
FR3116829A1 (fr) | 2022-06-03 |
CN116547070A (zh) | 2023-08-04 |
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