FR3116833B1 - Procede de captation d’impuretes organometalliques en presence d’une masse de captation sur support meso-macroporeux - Google Patents

Procede de captation d’impuretes organometalliques en presence d’une masse de captation sur support meso-macroporeux Download PDF

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Publication number
FR3116833B1
FR3116833B1 FR2012320A FR2012320A FR3116833B1 FR 3116833 B1 FR3116833 B1 FR 3116833B1 FR 2012320 A FR2012320 A FR 2012320A FR 2012320 A FR2012320 A FR 2012320A FR 3116833 B1 FR3116833 B1 FR 3116833B1
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volume
support
capturing
mass
caption
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FR2012320A
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FR3116833A1 (fr
Inventor
Philibert Leflaive
Etienne Girard
Antoine Fecant
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Priority to FR2012320A priority Critical patent/FR3116833B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to MX2023005248A priority patent/MX2023005248A/es
Priority to US18/037,137 priority patent/US20230416617A1/en
Priority to AU2021388708A priority patent/AU2021388708A1/en
Priority to JP2023532274A priority patent/JP2023550822A/ja
Priority to KR1020237017334A priority patent/KR20230113741A/ko
Priority to CN202180079710.6A priority patent/CN116507701A/zh
Priority to EP21810364.6A priority patent/EP4251716A1/fr
Priority to PCT/EP2021/082068 priority patent/WO2022112080A1/fr
Publication of FR3116833A1 publication Critical patent/FR3116833A1/fr
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/003Specific sorbent material, not covered by C10G25/02 or C10G25/03
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0225Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057Surface area, e.g. B.E.T specific surface area
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057Surface area, e.g. B.E.T specific surface area
    • B01J20/28061Surface area, e.g. B.E.T specific surface area being in the range 100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B01J20/28073Pore volume, e.g. total pore volume, mesopore volume, micropore volume being in the range 0.5-1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28088Pore-size distribution
    • B01J20/28092Bimodal, polymodal, different types of pores or different pore size distributions in different parts of the sorbent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/3078Thermal treatment, e.g. calcining or pyrolizing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/32Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204Inorganic carriers, supports or substrates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/32Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234Inorganic material layers
    • B01J20/3236Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/32Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3291Characterised by the shape of the carrier, the coating or the obtained coated product
    • B01J20/3293Coatings on a core, the core being particle or fiber shaped, e.g. encapsulated particles, coated fibers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/202Heteroatoms content, i.e. S, N, O, P
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/205Metal content
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02Gasoline

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

Procédé de captation d'impuretés organométalliques dans une charge hydrocarbonée de type essence contenant des composés soufrés et des oléfines dans lequel on met en contact ladite charge, de l’hydrogène et d’une masse de captation comprenant une phase active à base de nickel, et un support d’alumine mésoporeux et macroporeux comprenant une distribution bimodale de mésopores et dans lequel :- le volume des mésopores de diamètre supérieur ou égal à 2 nm et inférieur à 18 nm correspond entre 10 et 30% en volume du volume poreux total dudit support ;- le volume des mésopores de diamètre supérieur ou égal à 18 nm et inférieur à 50 nm correspond entre 30 et 50% en volume du volume poreux total dudit support ; le volume des macropores de diamètre supérieur ou égal à 50 nm et inférieur à 8000 nm correspond entre 30 et 50% en volume du volume poreux total dudit support.
FR2012320A 2020-11-27 2020-11-27 Procede de captation d’impuretes organometalliques en presence d’une masse de captation sur support meso-macroporeux Active FR3116833B1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR2012320A FR3116833B1 (fr) 2020-11-27 2020-11-27 Procede de captation d’impuretes organometalliques en presence d’une masse de captation sur support meso-macroporeux
US18/037,137 US20230416617A1 (en) 2020-11-27 2021-11-18 Method for capturing organometallic impurities in the presence of a capture mass on a mesoporous-macroporous support
AU2021388708A AU2021388708A1 (en) 2020-11-27 2021-11-18 Method for capturing organometallic impurities in the presence of a capture mass on a mesoporous-macroporous support
JP2023532274A JP2023550822A (ja) 2020-11-27 2021-11-18 メソ多孔性・マクロ多孔性担体上の捕捉塊の存在中での有機金属不純物の捕捉方法
MX2023005248A MX2023005248A (es) 2020-11-27 2021-11-18 Proceso de captura de impurezas organometalicas en la presencia de una masa de captura sobre un soporte meso-macroporoso.
KR1020237017334A KR20230113741A (ko) 2020-11-27 2021-11-18 메조포러스-마크로포러스 지지체 상의 포획 매스의 존재 하에서 유기 금속 불순물을 포획하는 방법
CN202180079710.6A CN116507701A (zh) 2020-11-27 2021-11-18 在中孔-大孔载体上的捕获物质存在下捕获有机金属杂质的方法
EP21810364.6A EP4251716A1 (fr) 2020-11-27 2021-11-18 Procede de captation d'impuretes organometalliques en presence d'une masse de captation sur support meso-macroporeux
PCT/EP2021/082068 WO2022112080A1 (fr) 2020-11-27 2021-11-18 Procede de captation d'impuretes organometalliques en presence d'une masse de captation sur support meso-macroporeux

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2012320 2020-11-27
FR2012320A FR3116833B1 (fr) 2020-11-27 2020-11-27 Procede de captation d’impuretes organometalliques en presence d’une masse de captation sur support meso-macroporeux

Publications (2)

Publication Number Publication Date
FR3116833A1 FR3116833A1 (fr) 2022-06-03
FR3116833B1 true FR3116833B1 (fr) 2023-11-03

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Application Number Title Priority Date Filing Date
FR2012320A Active FR3116833B1 (fr) 2020-11-27 2020-11-27 Procede de captation d’impuretes organometalliques en presence d’une masse de captation sur support meso-macroporeux

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Country Link
US (1) US20230416617A1 (fr)
EP (1) EP4251716A1 (fr)
JP (1) JP2023550822A (fr)
KR (1) KR20230113741A (fr)
CN (1) CN116507701A (fr)
AU (1) AU2021388708A1 (fr)
FR (1) FR3116833B1 (fr)
MX (1) MX2023005248A (fr)
WO (1) WO2022112080A1 (fr)

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5266300A (en) 1989-08-02 1993-11-30 Texaco Inc. Method of making porous alumina
FR2764214B1 (fr) * 1997-06-10 1999-07-16 Inst Francais Du Petrole Procede et masses de captation pour l'elimination du mercure et de l'arsenic dans les coupes hydrocarbonees
FR2794381B1 (fr) 1999-06-02 2001-06-29 Inst Francais Du Petrole Masse d'elimination d'arsenic et de mercure dans des hydrocarbures a base de nickel supporte
FR2797639B1 (fr) 1999-08-19 2001-09-21 Inst Francais Du Petrole Procede de production d'essences a faible teneur en soufre
FR2811328B1 (fr) 2000-07-06 2002-08-23 Inst Francais Du Petrole Procede comprenant deux etapes d'hydrodesulfuration d'essence et une elimination intermediaire de l'h2s forme au cours de la premiere etape
US6589908B1 (en) 2000-11-28 2003-07-08 Shell Oil Company Method of making alumina having bimodal pore structure, and catalysts made therefrom
FR2876113B1 (fr) 2004-10-06 2008-12-12 Inst Francais Du Petrole Procede de captation selective de l'arsenic dans les essences riches en soufre et en olefines
US7790130B2 (en) 2007-08-31 2010-09-07 Uop Llc Wide mesoporous alumina composites having trimodal pore structure
CN104248987B (zh) 2013-06-28 2016-04-27 中国石油化工股份有限公司 球形蒙脱石介孔复合材料和负载型催化剂及其制备方法和应用以及乙酸乙酯的制备方法
CN104248985B (zh) 2013-06-28 2016-06-29 中国石油化工股份有限公司 球形蒙脱石介孔复合载体和负载型催化剂及其制备方法和应用以及乙酸乙酯的制备方法
CN108855197B (zh) 2017-05-10 2019-09-27 中国石油化工股份有限公司 丙烷脱氢催化剂及其制备方法以及丙烷脱氢制丙烯的方法
FR3080117B1 (fr) * 2018-04-11 2020-04-03 IFP Energies Nouvelles Procede de captation de l'arsenic mettant en œuvre une masse de captation a base de particules d'oxyde de nickel

Also Published As

Publication number Publication date
FR3116833A1 (fr) 2022-06-03
AU2021388708A1 (en) 2023-06-22
AU2021388708A9 (en) 2024-04-18
MX2023005248A (es) 2023-05-23
JP2023550822A (ja) 2023-12-05
US20230416617A1 (en) 2023-12-28
CN116507701A (zh) 2023-07-28
EP4251716A1 (fr) 2023-10-04
WO2022112080A1 (fr) 2022-06-02
KR20230113741A (ko) 2023-08-01

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