MX2023005248A - Proceso de captura de impurezas organometalicas en la presencia de una masa de captura sobre un soporte meso-macroporoso. - Google Patents

Proceso de captura de impurezas organometalicas en la presencia de una masa de captura sobre un soporte meso-macroporoso.

Info

Publication number
MX2023005248A
MX2023005248A MX2023005248A MX2023005248A MX2023005248A MX 2023005248 A MX2023005248 A MX 2023005248A MX 2023005248 A MX2023005248 A MX 2023005248A MX 2023005248 A MX2023005248 A MX 2023005248A MX 2023005248 A MX2023005248 A MX 2023005248A
Authority
MX
Mexico
Prior art keywords
volume
mesoporous
capturing
substrate
mesopores
Prior art date
Application number
MX2023005248A
Other languages
English (en)
Inventor
Philibert Leflaive
Etienne Girard
Antoine Fecant
Original Assignee
Ifp Energies Now
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ifp Energies Now filed Critical Ifp Energies Now
Publication of MX2023005248A publication Critical patent/MX2023005248A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28061—Surface area, e.g. B.E.T specific surface area being in the range 100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B01J20/28073—Pore volume, e.g. total pore volume, mesopore volume, micropore volume being in the range 0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28088—Pore-size distribution
    • B01J20/28092—Bimodal, polymodal, different types of pores or different pore size distributions in different parts of the sorbent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3291—Characterised by the shape of the carrier, the coating or the obtained coated product
    • B01J20/3293—Coatings on a core, the core being particle or fiber shaped, e.g. encapsulated particles, coated fibers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

La invención se refiere a un proceso de captura de impurezas organometálicas en una materia prima hidrocarbonada del tipo de la gasolina que contiene compuestos azufrados y olefinas, en el que tal materia prima se pone en contacto con hidrógeno y una masa de captura que comprende una fase activa a base de níquel, y un soporte de alúmina mesoporosa y macroporosa que comprende una distribución bimodal de mesoporos y donde: - el volumen de mesoporos de diámetro superior o igual a 2 nm e inferior a 18 nm corresponde a entre el 10 y el 30% en volumen, del volumen total de los poros de tal soporte; - el volumen de mesoporos de diámetro superior o igual a 18 nm e inferior a 50 nm corresponde a entre el 30 y el 50% en volumen, del volumen total de los poros de tal soporte; el volumen de los macroporos de diámetro superior o igual a 50 nm e inferior a 8000 nm corresponde a entre el 30 y el 50% en volumen, del volumen total de poros de tal soporte.
MX2023005248A 2020-11-27 2021-11-18 Proceso de captura de impurezas organometalicas en la presencia de una masa de captura sobre un soporte meso-macroporoso. MX2023005248A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2012320A FR3116833B1 (fr) 2020-11-27 2020-11-27 Procede de captation d’impuretes organometalliques en presence d’une masse de captation sur support meso-macroporeux
PCT/EP2021/082068 WO2022112080A1 (fr) 2020-11-27 2021-11-18 Procede de captation d'impuretes organometalliques en presence d'une masse de captation sur support meso-macroporeux

Publications (1)

Publication Number Publication Date
MX2023005248A true MX2023005248A (es) 2023-05-23

Family

ID=74347324

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2023005248A MX2023005248A (es) 2020-11-27 2021-11-18 Proceso de captura de impurezas organometalicas en la presencia de una masa de captura sobre un soporte meso-macroporoso.

Country Status (9)

Country Link
US (1) US20230416617A1 (es)
EP (1) EP4251716A1 (es)
JP (1) JP2023550822A (es)
KR (1) KR20230113741A (es)
CN (1) CN116507701A (es)
AU (1) AU2021388708A1 (es)
FR (1) FR3116833B1 (es)
MX (1) MX2023005248A (es)
WO (1) WO2022112080A1 (es)

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5266300A (en) 1989-08-02 1993-11-30 Texaco Inc. Method of making porous alumina
FR2764214B1 (fr) * 1997-06-10 1999-07-16 Inst Francais Du Petrole Procede et masses de captation pour l'elimination du mercure et de l'arsenic dans les coupes hydrocarbonees
FR2794381B1 (fr) 1999-06-02 2001-06-29 Inst Francais Du Petrole Masse d'elimination d'arsenic et de mercure dans des hydrocarbures a base de nickel supporte
FR2797639B1 (fr) 1999-08-19 2001-09-21 Inst Francais Du Petrole Procede de production d'essences a faible teneur en soufre
FR2811328B1 (fr) 2000-07-06 2002-08-23 Inst Francais Du Petrole Procede comprenant deux etapes d'hydrodesulfuration d'essence et une elimination intermediaire de l'h2s forme au cours de la premiere etape
US6589908B1 (en) 2000-11-28 2003-07-08 Shell Oil Company Method of making alumina having bimodal pore structure, and catalysts made therefrom
FR2876113B1 (fr) 2004-10-06 2008-12-12 Inst Francais Du Petrole Procede de captation selective de l'arsenic dans les essences riches en soufre et en olefines
US7790130B2 (en) 2007-08-31 2010-09-07 Uop Llc Wide mesoporous alumina composites having trimodal pore structure
CN104248987B (zh) 2013-06-28 2016-04-27 中国石油化工股份有限公司 球形蒙脱石介孔复合材料和负载型催化剂及其制备方法和应用以及乙酸乙酯的制备方法
CN104248985B (zh) 2013-06-28 2016-06-29 中国石油化工股份有限公司 球形蒙脱石介孔复合载体和负载型催化剂及其制备方法和应用以及乙酸乙酯的制备方法
CN108855197B (zh) 2017-05-10 2019-09-27 中国石油化工股份有限公司 丙烷脱氢催化剂及其制备方法以及丙烷脱氢制丙烯的方法
FR3080117B1 (fr) * 2018-04-11 2020-04-03 IFP Energies Nouvelles Procede de captation de l'arsenic mettant en œuvre une masse de captation a base de particules d'oxyde de nickel

Also Published As

Publication number Publication date
US20230416617A1 (en) 2023-12-28
CN116507701A (zh) 2023-07-28
WO2022112080A1 (fr) 2022-06-02
FR3116833A1 (fr) 2022-06-03
KR20230113741A (ko) 2023-08-01
AU2021388708A1 (en) 2023-06-22
AU2021388708A9 (en) 2024-04-18
FR3116833B1 (fr) 2023-11-03
JP2023550822A (ja) 2023-12-05
EP4251716A1 (fr) 2023-10-04

Similar Documents

Publication Publication Date Title
Lovell et al. CO2 reforming of methane over MCM-41-supported nickel catalysts: altering support acidity by one-pot synthesis at room temperature
TW583168B (en) Hydrogenation catalyst and hydrogenation process
US8586813B2 (en) Catalyst for metathesis of ethylene and 2-butene and/or double bond isomerization
Węgrzyniak et al. Catalytic behaviour of chromium oxide supported on CMK-3 carbon replica in the dehydrogenation propane to propene
US9783745B2 (en) Method for selective hydrogenation using a catalyst containing copper and at least one metal selected from between nickel or cobalt
CA2576964A1 (en) Process for the selective hydrogenation of alkynes and/or dienes in an olefin-containing hydrocarbon stream
WO2006001912A3 (en) Catalyst for hydroprocessing of fischer-tropsch products
KR20000022887A (ko) 물질 스트림의 정제용 촉매 및 정제 방법
RU2007141711A (ru) Способ получения полупродукта с пониженным содержанием азота и катализатора для его осуществления
KR20090019821A (ko) 촉매독을 포함하는 ｃ4 올레핀 스트림 중 부타디엔의 선택적인 수소화 방법 및 1-부텐에서 2-부텐으로의 동시 이성질화
WO2007119455A1 (ja) 燃料基材の水素化精製方法
MY154844A (en) Two-step process for desulphurizing olefinic gasolines comprising arsenic
KR20100058681A (ko) 아세틸렌의 선택적 수소화를 위한 팔라듐계 촉매
CA2508605A1 (en) Heavy feed hpc process using a mixture of catalysts
Zhang et al. Synergistic effect between Sn and K promoters on supported platinum catalyst for isobutane dehydrogenation
MX2023005248A (es) Proceso de captura de impurezas organometalicas en la presencia de una masa de captura sobre un soporte meso-macroporoso.
CN103664458A (zh) 一种粗异戊烯选择性加氢的方法
MY155825A (en) A process for hydrocracking and hydro-isomerisation of a paraffinic feedstock
US9637381B2 (en) Process for pre-reforming hydrocarbon streams containing olefins, pre-reforming catalyst and a process for preparing said catalyst
RU2015120331A (ru) Способ получения бензина с низким содержанием серы
CN103664457A (zh) 粗异戊烯选择性加氢的方法
MX2023005247A (es) Proceso de acabado de hidrodesulfuracion en la presencia de un catalizador sobre un soporte meso-macroporoso.
WO2009111720A3 (en) Catalyst and process for the selective hydrodesulfurization of an olefin containing hydrocarbon feedstock
US10610853B2 (en) Method for treatment of gas
JP4065590B2 (ja) チオフェン系硫黄化合物の吸着除去方法