MX2023005247A - Proceso de acabado de hidrodesulfuracion en la presencia de un catalizador sobre un soporte meso-macroporoso. - Google Patents

Proceso de acabado de hidrodesulfuracion en la presencia de un catalizador sobre un soporte meso-macroporoso.

Info

Publication number
MX2023005247A
MX2023005247A MX2023005247A MX2023005247A MX2023005247A MX 2023005247 A MX2023005247 A MX 2023005247A MX 2023005247 A MX2023005247 A MX 2023005247A MX 2023005247 A MX2023005247 A MX 2023005247A MX 2023005247 A MX2023005247 A MX 2023005247A
Authority
MX
Mexico
Prior art keywords
volume
support
catalyst
hydrodesulphurisation
meso
Prior art date
Application number
MX2023005247A
Other languages
English (en)
Inventor
Philibert Leflaive
Etienne Girard
Antoine Fecant
Original Assignee
Ifp Energies Now
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ifp Energies Now filed Critical Ifp Energies Now
Publication of MX2023005247A publication Critical patent/MX2023005247A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B01J35/50—
    • B01J35/613—
    • B01J35/615—
    • B01J35/635—
    • B01J35/638—
    • B01J35/647—
    • B01J35/651—
    • B01J35/653—
    • B01J35/657—
    • B01J35/69—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/033—Using Hydrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Nanotechnology (AREA)

Abstract

La invención se refiere a un proceso para el tratamiento de una materia prima hidrocarbonada que contiene azufre, parcialmente desulfurada, resultante de una etapa previa de hidrodesulfuración, en la presencia de un catalizador que comprende una fase activa que comprende un metal del grupo VIII y un soporte de alúmina mesoporoso y macroporoso que comprende una distribución bimodal de mesoporos y en el que: - el volumen de mesoporos de diámetro superior o igual a 2 nm e inferior a 18 nm corresponde a entre el 10 y el 30% en volumen, del volumen total de los poros de tal soporte; - el volumen de mesoporos de diámetro superior o igual a 18 nm e inferior a 50 nm corresponde entre el 30 y el 50% en volumen, del volumen total de los poros de tal soporte; - el volumen de macroporos de diámetro superior o igual a 50 nm e inferior a 8000 nm corresponde a entre el 30 y el 50% en volumen, del volumen total de los poros de tal soporte.
MX2023005247A 2020-11-27 2021-11-18 Proceso de acabado de hidrodesulfuracion en la presencia de un catalizador sobre un soporte meso-macroporoso. MX2023005247A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2012321A FR3116832B1 (fr) 2020-11-27 2020-11-27 Procede d’hydrodesulfuration de finition en presence d’un catalyseur sur support meso-macroporeux
PCT/EP2021/082069 WO2022112081A1 (fr) 2020-11-27 2021-11-18 Procede d'hydrodesulfuration de finition en presence d'un catalyseur sur support meso-macroporeux

Publications (1)

Publication Number Publication Date
MX2023005247A true MX2023005247A (es) 2023-05-23

Family

ID=74347325

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2023005247A MX2023005247A (es) 2020-11-27 2021-11-18 Proceso de acabado de hidrodesulfuracion en la presencia de un catalizador sobre un soporte meso-macroporoso.

Country Status (9)

Country Link
US (1) US20240010931A1 (es)
EP (1) EP4251717A1 (es)
JP (1) JP2023550823A (es)
KR (1) KR20230113298A (es)
CN (1) CN116568395A (es)
AU (1) AU2021388768A1 (es)
FR (1) FR3116832B1 (es)
MX (1) MX2023005247A (es)
WO (1) WO2022112081A1 (es)

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5266300A (en) 1989-08-02 1993-11-30 Texaco Inc. Method of making porous alumina
FR2757084B1 (fr) * 1996-12-13 1999-01-29 Rhodia Chimie Sa Utilisation pour l'oxydation directe des composes soufres en soufre et/ou sulfates a basse temperature d'un catalyseur a base de molybdene
FR2797639B1 (fr) 1999-08-19 2001-09-21 Inst Francais Du Petrole Procede de production d'essences a faible teneur en soufre
FR2811328B1 (fr) 2000-07-06 2002-08-23 Inst Francais Du Petrole Procede comprenant deux etapes d'hydrodesulfuration d'essence et une elimination intermediaire de l'h2s forme au cours de la premiere etape
US6589908B1 (en) 2000-11-28 2003-07-08 Shell Oil Company Method of making alumina having bimodal pore structure, and catalysts made therefrom
FR2910352B1 (fr) * 2006-12-21 2010-10-08 Inst Francais Du Petrole Procede d'hydroconversion en phase slurry de charges hydrocarbonees lourdes et ou de charbon utilisant un catalyseur supporte
US7790130B2 (en) 2007-08-31 2010-09-07 Uop Llc Wide mesoporous alumina composites having trimodal pore structure
CN104248987B (zh) 2013-06-28 2016-04-27 中国石油化工股份有限公司 球形蒙脱石介孔复合材料和负载型催化剂及其制备方法和应用以及乙酸乙酯的制备方法
CN104248985B (zh) 2013-06-28 2016-06-29 中国石油化工股份有限公司 球形蒙脱石介孔复合载体和负载型催化剂及其制备方法和应用以及乙酸乙酯的制备方法
BR112016025596B1 (pt) * 2014-05-01 2021-07-20 Shell Internationale Research Maatschappij B.V. Catalisador de hidrodessulfurização seletiva e processo para hidrodessulfurização seletiva dos compostos de enxofre contidos em uma matéria-prima de hidrocarboneto
BR112018069469B1 (pt) * 2016-03-23 2023-01-10 Shell Internationale Research Maatschappij B.V. Composição catalítica útil na redução catalítica de compostos de enxofre contidos em uma corrente de gás, método de preparação da mesma e processo de hidrólise
CN108855197B (zh) 2017-05-10 2019-09-27 中国石油化工股份有限公司 丙烷脱氢催化剂及其制备方法以及丙烷脱氢制丙烯的方法
CN109894122B (zh) * 2017-12-07 2021-06-01 中国石油天然气股份有限公司 一种fcc汽油加氢脱硫催化剂及其制备方法

Also Published As

Publication number Publication date
JP2023550823A (ja) 2023-12-05
EP4251717A1 (fr) 2023-10-04
KR20230113298A (ko) 2023-07-28
CN116568395A (zh) 2023-08-08
US20240010931A1 (en) 2024-01-11
WO2022112081A1 (fr) 2022-06-02
AU2021388768A1 (en) 2023-06-22
FR3116832A1 (fr) 2022-06-03
FR3116832B1 (fr) 2023-11-03

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