FR3115794B1 - Procede d’hydrogenation selective mettant en œuvre un catalyseur de forme mousse - Google Patents

Procede d’hydrogenation selective mettant en œuvre un catalyseur de forme mousse Download PDF

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Publication number
FR3115794B1
FR3115794B1 FR2011075A FR2011075A FR3115794B1 FR 3115794 B1 FR3115794 B1 FR 3115794B1 FR 2011075 A FR2011075 A FR 2011075A FR 2011075 A FR2011075 A FR 2011075A FR 3115794 B1 FR3115794 B1 FR 3115794B1
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FR
France
Prior art keywords
selective hydrogenation
catalyst
hydrogenation process
foam catalyst
comprised
Prior art date
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Active
Application number
FR2011075A
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English (en)
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FR3115794A1 (fr
Inventor
Florent Allain
Yacine Haroun
Marion Servel
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR2011075A priority Critical patent/FR3115794B1/fr
Priority to JP2023526004A priority patent/JP2023547645A/ja
Priority to CN202180073347.7A priority patent/CN116648494A/zh
Priority to PCT/EP2021/079077 priority patent/WO2022090024A1/fr
Priority to US18/033,420 priority patent/US20240018423A1/en
Priority to EP21791416.7A priority patent/EP4237516A1/fr
Publication of FR3115794A1 publication Critical patent/FR3115794A1/fr
Application granted granted Critical
Publication of FR3115794B1 publication Critical patent/FR3115794B1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/40—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/618—Surface area more than 1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/657—Pore diameter larger than 1000 nm
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/06—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of thermal cracking in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/34—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts
    • C10G9/36—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Nanotechnology (AREA)

Abstract

La présente invention concerne un procédé d’hydrogénation sélective de composés polyinsaturés contenant au moins 2 atomes de carbone par molécule en présence d’un catalyseur comprenant une phase active à base d’au moins un métal du groupe VIII et un support se présentant sous la forme d’une mousse céramique ou métallique, ledit catalyseur comprenant une surface géométrique comprise entre 1000 et 7000 m²/m3 et un diamètre des pores compris entre 0,2 et 1,5 mm.
FR2011075A 2020-10-29 2020-10-29 Procede d’hydrogenation selective mettant en œuvre un catalyseur de forme mousse Active FR3115794B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR2011075A FR3115794B1 (fr) 2020-10-29 2020-10-29 Procede d’hydrogenation selective mettant en œuvre un catalyseur de forme mousse
JP2023526004A JP2023547645A (ja) 2020-10-29 2021-10-20 発泡触媒を用いる選択的水素化方法
CN202180073347.7A CN116648494A (zh) 2020-10-29 2021-10-20 使用发泡催化剂的选择性氢化方法
PCT/EP2021/079077 WO2022090024A1 (fr) 2020-10-29 2021-10-20 Procede d'hydrogenation selective mettant en œuvre un catalyseur de forme mousse
US18/033,420 US20240018423A1 (en) 2020-10-29 2021-10-20 Method for selective hydrogenation using a foamed catalyst
EP21791416.7A EP4237516A1 (fr) 2020-10-29 2021-10-20 Procede d'hydrogenation selective mettant en ?uvre un catalyseur de forme mousse

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2011075 2020-10-29
FR2011075A FR3115794B1 (fr) 2020-10-29 2020-10-29 Procede d’hydrogenation selective mettant en œuvre un catalyseur de forme mousse

Publications (2)

Publication Number Publication Date
FR3115794A1 FR3115794A1 (fr) 2022-05-06
FR3115794B1 true FR3115794B1 (fr) 2023-01-13

Family

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FR2011075A Active FR3115794B1 (fr) 2020-10-29 2020-10-29 Procede d’hydrogenation selective mettant en œuvre un catalyseur de forme mousse

Country Status (6)

Country Link
US (1) US20240018423A1 (fr)
EP (1) EP4237516A1 (fr)
JP (1) JP2023547645A (fr)
CN (1) CN116648494A (fr)
FR (1) FR3115794B1 (fr)
WO (1) WO2022090024A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3137849A1 (fr) * 2022-07-18 2024-01-19 IFP Energies Nouvelles Procede de preparation d’un catalyseur comprenant un metal du groupe viii a partir d’une alumine alpha
FR3137848A1 (fr) * 2022-07-18 2024-01-19 IFP Energies Nouvelles Procede de preparation d’un catalyseur comprenant un metal du groupe viii et un support sous la forme d’un monolithe ou d’une mousse enduit d’alumine alpha

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101094077B1 (ko) 2010-02-16 2011-12-15 한국에너지기술연구원 금속 폼 표면에 코발트 촉매 분말이 코팅된 코발트 금속 폼 촉매의 제조방법 및 그 코발트 금속 폼 촉매, 이 코발트 금속 폼 촉매를 이용한 열매체 순환 열교환형 반응기 및 이 열매체 순환 열교환형 반응기를 이용한 피셔-트롭쉬 합성 반응에 의한 액체 연료의 생산 방법
EP2764916B1 (fr) * 2013-02-06 2017-06-28 Alantum Europe GmbH Corps en mousse métallique à surface modifiée, son procédé de production et son utilisation
KR101626649B1 (ko) 2014-03-25 2016-06-01 영남대학교 산학협력단 금속 폼 형태의 연료개질용 촉매 및 상기 촉매를 구비한 마이크로 채널구조 연료개질기
JP6929288B2 (ja) 2015-12-22 2021-09-01 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒床、及び酸化窒素を減少させるための方法
WO2018054740A1 (fr) * 2016-09-23 2018-03-29 Basf Se Procédé de préparation d'un lit fixe de catalyseur comprenant des corps moulés de catalyseur structurés dopés
EP3515597A1 (fr) * 2016-09-23 2019-07-31 Basf Se Procédé d'hydrogénation de composés organiques en présence de co et d'un lit fixe de catalyseur contenant des corps moulés de catalyseur monolithiques
EP3515593A1 (fr) * 2016-09-23 2019-07-31 Basf Se Procédé d'activation d'un lit fixe de catalyseur contenant des corps moulés catalytiques monolithiques ou composé de corps moulés catalytiques monolithiques
WO2018054755A1 (fr) * 2016-09-23 2018-03-29 Basf Se Procédé permettant de produire un lit fixe à action catalytique pour l'hydrogénation de composés organiques
FR3061197A1 (fr) * 2016-12-22 2018-06-29 IFP Energies Nouvelles Procede d'hydrogenation selective mettant en œuvre un catalyseur a base de nickel prepare au moyen d'un additif comprenant une fonction ester
FR3087787B1 (fr) * 2018-10-25 2020-12-18 Ifp Energies Now Procede d’hydrogenation comprenant un catalyseur prepare par addition d’un compose organique en phase gazeuse
FR3116831B1 (fr) * 2020-11-27 2023-11-03 Ifp Energies Now Procede d’hydrogenation selective d’une essence en presence d’un catalyseur sur support meso-macroporeux

Also Published As

Publication number Publication date
CN116648494A (zh) 2023-08-25
FR3115794A1 (fr) 2022-05-06
WO2022090024A1 (fr) 2022-05-05
US20240018423A1 (en) 2024-01-18
EP4237516A1 (fr) 2023-09-06
JP2023547645A (ja) 2023-11-13

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