KR980000573A - 지지된 루테늄 촉매의 존재하에 유기 화합물을 반응시키는 방법 - Google Patents

지지된 루테늄 촉매의 존재하에 유기 화합물을 반응시키는 방법 Download PDF

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KR980000573A
KR980000573A KR1019970026801A KR19970026801A KR980000573A KR 980000573 A KR980000573 A KR 980000573A KR 1019970026801 A KR1019970026801 A KR 1019970026801A KR 19970026801 A KR19970026801 A KR 19970026801A KR 980000573 A KR980000573 A KR 980000573A
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catalyst
group
support
pore
metals
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KR1019970026801A
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KR100464581B1 (ko
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토마스 륄
보리스 브라이차이델
콘라드 크놀
자비네 바이구니
요헴 헨켈만
파울 내걸레
헤르만 가우제폴
노르베르트 니쓰너
안드레아스 헨네
롤프 레브퀴허
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카르크, 메이어
바스프 악티엔게젤샤프트
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Priority claimed from DE19624485A external-priority patent/DE19624485A1/de
Priority claimed from DE19624835A external-priority patent/DE19624835A1/de
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/392—Metal surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
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  • General Chemical & Material Sciences (AREA)
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  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
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Abstract

본 발명에 따르면, 활성 금속으로서 루테늄이 단독으로 또는 1종 이상의 ⅠB족, ⅦB족, 또는 ⅧB족 금속과 함께 지지체에 촉매의 전체 중량을 기준으로 0.01 내지 30중량%의 양으로 도포되어 이루어지고, 여기서 상기 지지체의 공극 용적 중 10% 내지 50%ㄴ은 공극 직경이 50nm 내지 10,000nm범위내인 마크로 공극으로 이루어지고, 상기 지지체의 공극 용적 중 50% 내지 90%는 공극 직경이 2nm 내지 50nm범위내인 메조 공극으로 이루어지며, 상기 공극 용적의 합이 100%인 촉매를 제조할 수 있으며, 이러한 촉매의 존재하에 유기 화합물을 반응시킬 수 있다.
본 발명의 촉매는 고 반응성 (고 전환수), 고 선택성 및 장기간의 가사 시간을 나타낸다. 따라서, 본 발명의 방법에 의하면, 높은 공간 속도에서 장기간의 가사(司使)시간 동안 극히 높은 전환수로 수행될 수 있으며, 대응하는 수소화 반응 생성물은 높은 수율 및 순도로 얻어진다. 또한, 본 발명의 방법에 따르면, 촉매 내에 단지 소량의 금속 함량을 사용했을 때 매우 양호한 결과가 얻어지는 잇점이 있다.

Description

지지된 루테늄 촉매의 존재하에 유기 화합물을 반응시키는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. 활성 금속으로서 루테늄이 단독으로 또는 1종 이상의 ⅠB족, ⅦB족, 또는 ⅧB족 금속과 함께 지지체에 촉매의 전체 중량을 기준으로 0.01 내지 30중량%의 양으로 도포되어 이루어지고, 여기서 상기 지지체의 공극 용적 중 10% 내지 50%는 공극 직경이 50nm 내지 10,000nm 범위내의 마크로 공극으로 이루어지고, 상기 지지체의 공극 요적 중 50% 내지 90%는 공극 직경이 2nm 내지 50nm 범위내인 메조 공극으로 이루어지며, 상기 공극 용적의 합이 100%인 촉매의 존재하에 유기 화합물을 반응시키는 방법.
  2. 촉매 지지체의 공극 용적 중 10% 내지 50%는 공극 직경이 50nm 내지 10,000nm 범위내인 마크로 공극으로 이루어지고, 상기 지지체의 공극 용적 중 50% 내지 90%는 공극 직경이 2nm 내지 50nm 범위내인 메조 공극으로 이루어지며, 상기 공극 용적의 합은 100%인, 활성 금속으로서 루테늄이 단독으로 또는 1종 이상의 ⅠB족, ⅦB족, 또는 ⅧB족 금속과 함께 지지체에 촉매의 전체 중량을 기준으로 0.01 내지 30중량%의 양으로 도포되어 이루어지는 촉매의 존재하에, 또는 활성 금속으로서 팔라듐이 단독으로 또는 1종 이상의 IB족, ⅦB족, ⅧB족 금속과 함께 지지체에 촉매의 전체 중량을 기준으로 0.01 내지 30 중량%의 양으로 도포되어 이루어지는 촉매의 존재하에, 1개 이상의 C-C다중 결합을 가지고 있는 중합체를 수소화시키는 방법.
  3. 촉매 지지체으 ㅣ공극 용적 중 10% 내지 50%는 공극 직경이 50nm 내지 10,000nm 범위내인 마크로 공극으로 이루어지고, 상기 지지체의 공극 용적 중 50% 내지 90%는 공극 직경이 2nm 내지 50nm 범위내인 메조 공극으로 이루어지며, 상기 공극 용적의 합은 100%인, 활성 금속으로서 루테늄이 단독으로 또는 1종 이상의 ⅠB족, ⅦB족, 또는 ⅧB족 금속과 함께 지지체에 촉매의 전체 중량을 기준으로 0.01 내지 30중량%의 양으로 도포되어 이루어지는 촉매, 또는 활성 금속으로서 팔라듐이 단독으로 또는 1종 이상의 ⅠB족, ⅦB족, ⅧB족 금속과 함께 상기 지지체에 촉매의 전체 중량을 기준으로 0.01 내지 30중량%의 양으로 도포되어 이루어지는 촉매.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970026801A 1996-06-19 1997-06-19 지지된루테늄촉매의존재하에유기화합물을반응시키는방법 KR100464581B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE19624485.4 1996-06-19
DE19624485A DE19624485A1 (de) 1996-06-19 1996-06-19 Verfahren zur Hydrierung einer aromatischen Verbindung in Gegenwart eines geträgerten Rutheniumkatalysators
DE19624835.3 1996-06-21
DE19624835A DE19624835A1 (de) 1996-06-21 1996-06-21 Verfahren zur Hydrierung von Polymeren mit Ruthenium- oder Palladiumkatalysatoren

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KR980000573A true KR980000573A (ko) 1998-03-30
KR100464581B1 KR100464581B1 (ko) 2005-07-04

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US (2) US6248924B1 (ko)
EP (1) EP0814098B2 (ko)
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CN (1) CN1095690C (ko)
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US6248924B1 (en) 2001-06-19
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