DE69403885T2 - Verfahren zur Herstellung von Cycloolefinen - Google Patents

Verfahren zur Herstellung von Cycloolefinen

Info

Publication number
DE69403885T2
DE69403885T2 DE69403885T DE69403885T DE69403885T2 DE 69403885 T2 DE69403885 T2 DE 69403885T2 DE 69403885 T DE69403885 T DE 69403885T DE 69403885 T DE69403885 T DE 69403885T DE 69403885 T2 DE69403885 T2 DE 69403885T2
Authority
DE
Germany
Prior art keywords
cycloolefins
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69403885T
Other languages
English (en)
Other versions
DE69403885D1 (de
Inventor
Takahiko Takewaki
Naoko Fujita
Toshiharu Yokoyama
Takao Maki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corp filed Critical Mitsubishi Chemical Corp
Publication of DE69403885D1 publication Critical patent/DE69403885D1/de
Application granted granted Critical
Publication of DE69403885T2 publication Critical patent/DE69403885T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0211—Impregnation using a colloidal suspension
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/04—Benzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • C07C5/11—Partial hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
DE69403885T 1993-12-24 1994-12-20 Verfahren zur Herstellung von Cycloolefinen Expired - Fee Related DE69403885T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP32845693 1993-12-24
JP117994 1994-01-11
JP2980494 1994-02-28

Publications (2)

Publication Number Publication Date
DE69403885D1 DE69403885D1 (de) 1997-07-24
DE69403885T2 true DE69403885T2 (de) 1998-01-29

Family

ID=27274797

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69403885T Expired - Fee Related DE69403885T2 (de) 1993-12-24 1994-12-20 Verfahren zur Herstellung von Cycloolefinen

Country Status (5)

Country Link
US (1) US5569803A (de)
EP (1) EP0659718B1 (de)
KR (1) KR100336001B1 (de)
CN (1) CN1044469C (de)
DE (1) DE69403885T2 (de)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE1009128A3 (fr) * 1994-12-19 1996-12-03 Mitsubishi Chem Corp Procede de production de cycloolefines.
US6248924B1 (en) * 1996-06-19 2001-06-19 Basf Aktiengesellschaft Process for reacting an organic compound in the presence of a supported ruthenium catalyst
FI102730B (fi) * 1997-06-16 1999-02-15 Neste Oy Hyvän rikinsietokyvyn omaava hydrauskatalyytti
JPH1129503A (ja) * 1997-07-08 1999-02-02 Asahi Chem Ind Co Ltd シクロオレフィンの製造方法
CN1104950C (zh) * 1997-11-27 2003-04-09 出光兴产株式会社 以氧化铝为载体的钌催化剂
DE19854635A1 (de) * 1998-11-26 2000-05-31 Basf Ag Trägerkatalysator und dessen Einsatz in der Hydrierung
JP4777891B2 (ja) * 2004-07-09 2011-09-21 旭化成ケミカルズ株式会社 シクロオレフィン製造用触媒及び製造方法
KR100966947B1 (ko) * 2005-08-26 2010-06-30 아사히 가세이 케미칼즈 가부시키가이샤 시클로올레핀의 제조 방법
CN101269326B (zh) * 2007-03-21 2010-05-19 中国科学院大连化学物理研究所 用于苯加氢制环己烯的整体催化剂及其制备方法
EP2238217A1 (de) * 2008-02-01 2010-10-13 Johnson Matthey PLC Verfahren zur umwandlung von fettsäuren und derivate daraus
US20100197486A1 (en) * 2008-07-31 2010-08-05 Celanese International Corporation Catalysts for making ethyl acetate from acetic acid
EP2368634B1 (de) * 2008-12-22 2022-06-08 Asahi Kasei Kabushiki Kaisha Verfahren zur herstellung eines rutheniumkatalysators zur verwendung bei der cycloolefinherstellung sowie verfahren und vorrichtung zur herstellung von cycloolefin
GB0913193D0 (en) * 2009-07-29 2009-09-02 Johnson Matthey Plc Deoxygenation process
IT1402745B1 (it) * 2010-10-27 2013-09-18 Polimeri Europa Spa Catalizzatore a base di rutenio e suo impiego nell'idrogenazione selettiva di composti aromatici o poliinsaturi
CN102898268B (zh) * 2012-09-29 2014-12-24 中国天辰工程有限公司 一种连续生产环己烯的方法
CN102989521B (zh) * 2012-12-17 2015-03-04 中国科学院大连化学物理研究所 一种用于苯选择加氢的含锆尖晶石系负载蜂窝整体催化剂及其制备方法
CN103272581B (zh) * 2013-05-06 2014-09-17 中国科学院宁波材料技术与工程研究所 用于乙烯和丁烯歧化制备丙烯的催化剂及其制备方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US473436A (en) * 1892-04-19 Julius niese
US3912787A (en) * 1972-07-26 1975-10-14 Phillips Petroleum Co Selective partial hydrogenation of aromatics
US4055512A (en) * 1974-05-09 1977-10-25 Mitsubishi Chemical Industries Ltd. Catalyst for producing cycloolefin and method for making the same
DE3164339D1 (en) * 1980-12-31 1984-07-26 Stamicarbon Process for the preparation of a cycloalkene through partial hydrogenation of the corresponding aromatic hydrocarbon
JPS6059215B2 (ja) * 1983-02-24 1985-12-24 工業技術院長 ベンゼンからのシクロヘキセンの製法
EP0170915B1 (de) * 1984-07-31 1989-04-05 Sumitomo Chemical Company, Limited Verfahren zur Herstellung von Zykloolefinen
JPH064545B2 (ja) * 1985-09-11 1994-01-19 住友化学工業株式会社 シクロオレフインの製造方法
CA1267914A (en) * 1985-10-03 1990-04-17 Hajime Nagahara Process for producing cycloolefins
US4678861A (en) * 1985-10-23 1987-07-07 Asahi Kasei Kogyo Kabushiki Kaisha Process for producing a cycloolefin
JP2814711B2 (ja) * 1990-07-13 1998-10-27 三菱化学株式会社 シクロオレフィンの製造法
US5414171A (en) * 1992-02-26 1995-05-09 Catalytica, Inc. Process and washed catalyst for partially hydrogenating aromatics to produce cycloolefins
US5334790A (en) * 1992-02-26 1994-08-02 Catalytica Process and catalyst for partially hydrogenating aromatics to produce cycloolefins

Also Published As

Publication number Publication date
US5569803A (en) 1996-10-29
CN1108637A (zh) 1995-09-20
DE69403885D1 (de) 1997-07-24
KR100336001B1 (ko) 2002-11-27
EP0659718B1 (de) 1997-06-18
KR950017874A (ko) 1995-07-20
CN1044469C (zh) 1999-08-04
EP0659718A1 (de) 1995-06-28

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee